【标题速读】【JACS】【2022年】【10月】

声明:本专栏主要对生命科学领域的一些期刊文章标题进行翻译,所有内容均由本人手工整理翻译。由于本人专业为生物分析相关,其他领域如果出现翻译错误请谅解。

Liang and co-workers report a simple yet versatile and effective strategy to optimize biocatalytic activity by using a metal-organic framework to rapidly “lock” the ultrasound-activated but more fragile conformation of metalloenzymes. This novel strategy gives rise to new possibilities for the exploitation of highly efficient biocatalysts for diverse applications.
Liang 及其同事报告了一种简单但通用且有效的策略,通过使用金属有机骨架快速“锁定”超声波激活但更脆弱的金属酶构象来优化生物催化活性。 这种新颖的策略为开发用于各种应用的高效生物催化剂带来了新的可能性。

Some inorganic solids undergo phase transitions that result in the formation of “molecules” in their crystalline frameworks, which are frequently accompanied by dramatic changes in physical properties. We have discovered the creation of a linear ruthenium trimer with atypical three-center–four-electron bonding in RuP at its metal–insulator transition.
一些无机固体经历相变,导致在其结晶框架中形成“分子”,这通常伴随着物理性质的显着变化。 我们发现在 RuP 的金属 - 绝缘体转变中产生了具有非典型三中心 - 四电子键合的线性钌三聚体。

Folded π molecules tend to form well-aligned 1D molecular columns of patterns (“box”, “braid”, or “stair”) with high packing energy, which is mainly contributed by numerous weak π interactions. As a result of effective suppression of molecular motion, all of the compounds show very high exciton utilization in solids.
折叠的 π 分子倾向于形成排列良好的一维分子柱模式(“盒子”、“辫子”或“阶梯”),具有高堆积能,这主要是由许多弱 π 相互作用造成的。 由于有效抑制分子运动,所有化合物在固体中都显示出非常高的激子利用率。

Photoreactive surfaces for anchoring heterogenous cells have been developed using a photoactivatable dibenzocyclooctyne precursor. On the surface, a variety of cells can be selectively anchored onto the light-irradiated areas where various cell-anchoring molecules are conjugated through the click reaction. This surface has achieved single-cell pair arrays for intercellular communication analysis.
已经使用可光活化的二苯并环辛炔前体开发了用于锚定异质细胞的光反应表面。 在表面上,各种细胞可以选择性地锚定在光照射区域上,各种细胞锚定分子通过点击反应结合在一起。 该表面已经实现了用于细胞间通讯分析的单细胞对阵列。

Nuclear spin hyperpolarization of water at room temperature is essential for high-sensitivity NMR/MRI applications but has been a challenging task. Using organic nanocrystals doped with a photoexcited triplet polarizing agent, the polarization transfer from nanocrystals to liquid water is demonstrated for the first time.
室温下水的核自旋超极化对于高灵敏度 NMR/MRI 应用至关重要,但一直是一项具有挑战性的任务。 使用掺杂有光激发三线态偏振剂的有机纳米晶体,首次证明了从纳米晶体到液态水的偏振转移。

We report a multicomponent synthesis of a crystalline two-dimensional covalent organic framework (COF) by connecting acetaldehyde with aromatic aldehyde and acetonitrile building blocks to form cyano-substituted buta-1,3-diene linkages. Our multicomponent synthesis strategy may provide new insights for synthesizing COFs with structural diversity and functional variability.
我们通过将乙醛与芳香醛和乙腈结构单元连接起来形成氰基取代的丁-1,3-二烯键,报告了结晶二维共价有机骨架 (COF) 的多组分合成。 我们的多组分合成策略可能为合成具有结构多样性和功能可变性的 COF 提供新的见解。
Suspensions of colloidal particles experience spontaneous phase separation into particle-rich and particle-depleted domains in the presence of depletant when the enthalpy gain overwhelms entropic loss. The particle-rich solid phase has either crystalline or amorphous arrays depending on the rate of assembly.
当焓增益超过熵损失时,胶体颗粒的悬浮液在存在耗尽剂的情况下会自发相分离成富含颗粒和耗尽颗粒的区域。 富含颗粒的固相具有结晶或非晶阵列,具体取决于组装速率。

The Pd1–Cu1 dual-atom catalyst is highly active/selective in the acetylene semi-hydrogenation reaction. Compared to the single-atom catalyst, it offers sterically favorable sites for the simultaneous adsorption of reactants and changes the reaction path to render high reactivity at low temperature.
Pd1-Cu1双原子催化剂在乙炔半加氢反应中具有高活性/选择性。 与单原子催化剂相比,它为反应物的同时吸附提供了空间上有利的位点,并改变了反应路径以在低温下提供高反应性。

Functional-unit-based material design is an efficient approach for identifying high-performance functional materials. The discovery process includes the identification of useful functional units relevant to the desired properties (such as linear triatomic resonant bonds for thermoelectrics) and screening for desired materials within the space of compounds containing these units.
基于功能单元的材料设计是识别高性能功能材料的有效方法。 发现过程包括识别与所需特性相关的有用功能单元(例如热电的线性三原子共振键),以及在包含这些单元的化合物空间内筛选所需材料。

Non-oxidative coupling of methane on Pt surfaces has been thoroughly investigated from an orbital perspective. Based on the analysis, a single atom alloy catalyst with a single Pt atom embedded in the Au surface was rationally proposed.
已从轨道角度对甲烷在 Pt 表面的非氧化偶联进行了彻底研究。 在此基础上,合理地提出了在Au表面嵌入单个Pt原子的单原子合金催化剂。

Chemotherapy is almost exclusively administered via the intravenous route, which results in severe limitations. Therefore, the development of effective and less expensive chemotherapy that improves patients' quality of life could be a game changer in medical oncology. While subcutaneous (SC) administration has the potential to meet these criteria, it is extremely restrictive as it cannot be applied to most anticancer drugs, such as irritant or vesicant ones, due to prohibitive local toxicity. In this article, Bordat and co-workers reported an easy, safe, and robust approach for the SC administration of irritant/vesicant anticancer drugs through the design of well-defined hydrophilic polymer prodrugs by the “drug-initiated” method. The cover illustrates the SC administration of water-soluble polymer prodrugs.
化疗几乎完全通过静脉内途径给药,这导致严重的局限性。 因此,开发有效且成本较低的化学疗法来改善患者的生活质量可能会改变肿瘤内科的游戏规则。 虽然皮下 (SC) 给药有可能满足这些标准,但由于局部毒性过高,它不能应用于大多数抗癌药物,例如刺激性或发泡性药物,因此它受到了极大的限制。 在这篇文章中,Bordat 及其同事报告了一种简单、安全和稳健的方法,通过“药物引发”方法设计定义明确的亲水性聚合物前体药物,通过 SC 给药刺激性/发泡性抗癌药物。 封面说明了水溶性聚合物前药的 SC 给药。

A π-conjugated nickel coordination complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and PVDF, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm−1) with excellent stability against atmospheric oxidation.
设计并合成了含有噻吩并[3,2-b]噻吩单元的π-共轭镍配位络合物。 由此产生的镍络合物和 PVDF 的复合膜可以在大气条件下通过简单的溶液工艺制造,具有非常高的 n 型电导率(>200 S cm-1)和出色的抗大气氧化稳定性。

Under high pressure, two-dimensional (2D) van der Waals hydrogenated germanene (GeH) exhibits structural and superconducting transitions. A superconducting transition with the critical temperature (Tc) of 5.41 K at 8.39 GPa is demonstrated in GeH, accompanied by the dehydrogenation process. Pressure-induced irreversible transition from the 2D crystalline phase to the 2D amorphous phase is achieved under compression above 16.80 GPa and decompression while superconductivity remains.
在高压下,二维 (2D) 范德瓦尔斯氢化锗烯 (GeH) 表现出结构和超导转变。 在 GeH 中证明了在 8.39 GPa 下临界温度 (Tc) 为 5.41 K 的超导转变,并伴随着脱氢过程。 在超过 16.80 GPa 的压缩和减压下实现从 2D 晶相到 2D 非晶相的压力诱导不可逆转变,同时保持超导性。

Organosulfides are promising cathodes for rechargeable lithium batteries. In this work, thiuram monosulfide without any active sites becomes electrochemically active via an in situ electrochemical oxidation strategy. As visually illustrated in the cover art, it is converted into an active material for rechargeable lithium batteries after electrochemical oxidation.
有机硫化物是可充电锂电池的有前途的阴极。 在这项工作中,没有任何活性位点的秋兰姆单硫化物通过原位电化学氧化策略变得具有电化学活性。 如封面艺术所示,它在电化学氧化后转化为可充电锂电池的活性材料。

Spinel structured Co3O4 consisting of tetrahedral (Co2+-O)Td and octahedral (Co3+-O)Oh geometric configurations. This work has determined the superiority and dominant role of the (Co3+-O)Oh configuration in alkaline water reduction compared with (Co2+-O)Td.
尖晶石结构的 Co3O4 由四面体 (Co2+-O)Td 和八面体 (Co3+-O)Oh 几何构型组成。 与 (Co2+-O)Td 相比,这项工作确定了 (Co3+-O)Oh 构型在碱性水还原中的优势和主导作用。

Amorphous palladium sulfide enables selective electrocatalytic semihydrogenation of terminal alkynes in water with excellent tolerance to easily reducible groups and deactivating skeletons because of specific σ-alkynyl adsorption on isolated palladium sites.
无定形硫化钯能够在水中对末端炔烃进行选择性电催化半氢化,对易于还原的基团和失活骨架具有出色的耐受性,因为在孤立的钯位点上具有特异性 σ-炔基吸附。

We present a successful application of a blind approach to reaction discovery, which revealed a plethora of competing thermal pathways affecting the multistep switching mechanism of donor–acceptor Stenhouse adducts (DASAs). Our approach bridges the gap between short fs/ps relaxation dynamics and long ns/ms reaction regimes.
我们展示了盲法在反应发现中的成功应用,揭示了影响供体-受体 Stenhouse 加合物 (DASA) 多步转换机制的过多竞争性热通路。 我们的方法弥合了短 fs/ps 弛豫动力学和长 ns/ms 反应机制之间的差距。

Thin, cross-linked zwitterionic polymer coatings with an in-built gradient of super-hydrophilic sulfobetaine molecules lower the activity of water at electrodes and protect aqueous electrolytes from electrochemical reduction in batteries.
薄的、交联的两性离子聚合物涂层具有内置的超亲水性磺基甜菜碱分子梯度,可降低电极处水的活性,并保护含水电解质免受电池中的电化学还原。

Extreme ultraviolet (EUV) radiation ejects secondary electrons from the photoacid generator (PAG)-tethered cyclic polyphthalaldehyde resist matrix. The PAG accepts the ejected secondary electrons and generates the corresponding acid, which in turn causes the resist matrix to depolymerize, allowing fine features to be printed by EUV radiation.
极紫外 (EUV) 辐射从光致产酸剂 (PAG) 束缚的环状聚苯二甲醛抗蚀剂基质中射出二次电子。 PAG 接受射出的二次电子并产生相应的酸,这反过来会导致抗蚀剂基质解聚,从而允许通过 EUV 辐射印刷精细特征。
1.A Potential Roadmap to Integrated Metal Organic Framework Artificial Photosynthetic Arrays.
集成金属有机框架人工光合阵列的潜在路线图。

2.Cyanurate-Linked Covalent Organic Frameworks Enabled by Dynamic Nucleophilic Aromatic Substitution.
由动态亲核芳香取代实现的氰尿酸酯连接的共价有机框架。

3.A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands.
利用双阴离子氨基硼化物配体的高性能单分子磁体。

4.Identifying Metal-Oxo/Peroxo Intermediates in Catalytic Water Oxidation by In Situ Electrochemical Mass Spectrometry.
通过原位电化学质谱法鉴定催化水氧化中的金属-氧/过氧中间体。

5.Maximizing Vanadium Deployment in Redox Flow Batteries Through Chelation.
通过螯合作用最大化钒在氧化还原液流电池中的部署。

6.Optically Switchable NIR Photoluminescence of PbS Semiconducting Nanocrystals using Diarylethene Photoswitches.
使用二芳基乙烯光开关的 PbS 半导体纳米晶体的光可切换 NIR 光致发光。

7.Asymmetric Hydrogenation of Oximes Synergistically Assisted by Lewis and Brønsted Acids.
Lewis 和 Brønsted 酸协同辅助肟的不对称氢化。

8.Syntheses of Bufospirostenin A and Ophiopogonol A by a Conformation-Controlled Transannular Prins Cyclization.
通过构象控制的跨环 Prins 环化合成蟾蜍螺菌素 A 和麦冬酚 A。

9.Remote and Proximal Hydroaminoalkylation of Alkenes Enabled by Photoredox/Nickel Dual Catalysis.
通过光氧化还原/镍双催化实现烯烃的远程和近端加氢氨基烷基化。

10.Intercepting Hydrogen Evolution with Hydrogen-Atom Transfer: Electron-Initiated Hydrofunctionalization of Alkenes.
用氢原子转移拦截氢的析出:电子引发的烯烃加氢官能化。

11.Total Synthesis of Ginkgolide C and Formal Syntheses of Ginkgolides A and B.
银杏内酯C的全合成和银杏内酯A、B的形式合成。

12.Conversion of Aryl Azides to Aminopyridines.
芳基叠氮化物转化为氨基吡啶。

13.Gram-Scale Enantioselective Synthesis of (+)-Lucidumone.
(+)-Lucidumone 的克级对映选择性合成。

14.Catalytic Enantioselective Sulfur Alkylation of Sulfenamides for the Asymmetric Synthesis of Sulfoximines.
次磺酰胺的催化对映选择性硫烷基化用于亚砜亚胺的不对称合成。

15.Copper-Catalyzed Coupling of Alkyl Vicinal Bis(boronic Esters) to an Array of Electrophiles.
铜催化偶联烷基邻位双(硼酸酯)与一系列亲电子试剂。

16.A Spectroscopically Observed Iron Nitrosyl Intermediate in the Reduction of Nitrate by a Surface-Conjugated Electrocatalyst.
表面共轭电催化剂还原硝酸盐过程中的光谱观察亚硝酰铁中间体。

17.Investigation of Water Evaporation Process at Air/Water Interface using Hofmeister Ions.
使用霍夫迈斯特离子研究空气/水界面的水蒸发过程。

18.Domain-Specific Phase Transitions in a Supramolecular Nanostructure.
超分子纳米结构中的域特定相变。

19.The Growth Dynamics of Organic–Inorganic Metal Halide Perovskite Films.
有机-无机金属卤化物钙钛矿薄膜的生长动力学。

20.Linear Trimer Molecule Formation by Three-Center–Four-Electron Bonding in a Crystalline Solid RuP.
在结晶固体 RuP 中通过三中心-四电子键合形成线性三聚体分子。

21.Locking the Ultrasound-Induced Active Conformation of Metalloenzymes in Metal–Organic Frameworks.
锁定金属有机框架中金属酶的超声诱导活性构象。

22.Bioinformatic Atlas of Radical SAM Enzyme-Modified RiPP Natural Products Reveals an Isoleucine–Tryptophan Crosslink.
自由基 SAM 酶修饰的 RiPP 天然产物的生物信息学图谱揭示了异亮氨酸-色氨酸交联。

23.High-Resolution Cryo-Electron Microscopy Reveals the Unique Striated Hollow Structure of Photocatalytic Macrocyclic Polydiacetylene Nanotubes.
高分辨率冷冻电子显微镜揭示了光催化大环聚二乙炔纳米管的独特条纹空心结构。

24.High Exciton Utilization of 1D Molecular Column with High Packing Energy Formed by Folded π-Molecules.
由折叠 π 分子形成的具有高堆积能的一维分子柱的高激子利用。

25.Multidimensional Control of Repeating Unit/Sequence/Topology for One-Step Synthesis of Block Polymers from Monomer Mixtures.
从单体混合物一步合成嵌段聚合物的重复单元/序列/拓扑的多维控制。

26.π-Extended Ligands in Two-Coordinate Coinage Metal Complexes.
π - 双配位造币金属配合物中的扩展配体。

27.Insights into the Mechanism of Carbon Dioxide and Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I) Heterodinuclear Catalyst.
使用 Co(III)/K(I) 杂双核催化剂深入了解二氧化碳和环氧丙烷开环共聚的机理。

28.Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides.
相关的热力学和动力学氢化铼。

29.Ni-Centered Coordination-Induced Spin-State Switching Triggered by Electrical Stimulation.
由电刺激触发的以镍为中心的配位诱导自旋状态切换。

30.Atomistic Insights into Activation and Degradation of La0.6Sr0.4CoO3−δ Electrocatalysts under Oxygen Evolution Conditions.
La0.6Sr0.4CoO3−δ 电催化剂在析氧条件下的活化和降解的原子洞察。

31.Bioorthogonal Photoreactive Surfaces for Single-Cell Analysis of Intercellular Communications.
用于细胞间通讯单细胞分析的生物正交光反应表面。

32.Directed, Remote Dirhodium C(sp3)-H Functionalization, Desaturative Annulation, and Desaturation.
定向、远程二铑 C(sp3)-H 功能化、去饱和环化和去饱和。

33.Scalable Synthesis and Characterization of Multilayer γ-Graphyne, New Carbon Crystals with a Small Direct Band Gap.
多层 γ-石墨烯、具有小直接带隙的新型碳晶体的可扩展合成和表征。

34.Thermodynamics and Kinetics of the Cathode–Electrolyte Interface in All-Solid-State Li–S Batteries.
全固态锂硫电池中阴极-电解质界面的热力学和动力学。

35.Proton Hyperpolarization Relay from Nanocrystals to Liquid Water.
从纳米晶体到液态水的质子超极化中继。

36.Stereochemically Active Lone Pairs and Nonlinear Optical Properties of Two-Dimensional Multilayered Tin and Germanium Iodide Perovskites.
二维多层锡和碘化锗钙钛矿的立体化学活性孤对和非线性光学性质。

37.Fluorogenic Dimers as Bright Switchable Probes for Enhanced Super-Resolution Imaging of Cell Membranes.
荧光二聚体作为用于增强细胞膜超分辨率成像的明亮可切换探针。

38.Hydrogen-Bonded Water-Aminium Assemblies for Synthesis of Zeotypes with Ordered Heteroatoms.
用于合成具有有序杂原子的 Zeotypes 的氢键合水-铵组件。

39.Chain-to-Layer Dimensionality Engineering of Chiral Hybrid Perovskites to Realize Passive Highly Circular-Polarization-Sensitive Photodetection.
手性杂化钙钛矿的链层维度工程实现被动高圆偏振敏感光电检测。

40.Removal of Stomatin, a Membrane-Associated Cell Division Protein, Results in Specific Cellular Lipid Changes.
去除 Stomatin(一种膜相关细胞分裂蛋白)会导致特定的细胞脂质变化。

41.Treating Superhard Materials as Anomalies.
将超硬材料视为异常。

42.A Counterion/Ligand-Tuned Chemo- and Enantioselective Copper-Catalyzed Intermolecular Radical 1,2-Carboamination of Alkenes.
抗衡离子/配体调节的化学和对映选择性铜催化的烯烃分子间自由基 1,2-碳胺化。

43.Design of a Flexible, Zn-Selective Protein Scaffold that Displays Anti-Irving–Williams Behavior.
显示反 Irving-Williams 行为的灵活、Zn 选择性蛋白质支架的设计。

44.Repurposing Cyanine Photoinstability To Develop Near-Infrared Light-Activatable Nanogels for In Vivo Cargo Delivery.
重新利用花青的光不稳定性来开发用于体内货物输送的近红外光可激活纳米凝胶。

45.Ligand-Enabled C–H Hydroxylation with Aqueous H2O2 at Room Temperature.
在室温下用 H2O2 水溶液进行配体使能的 C-H 羟基化。

46.A Toolkit for Engineering Proteins in Living Cells: Peptide with a Tryptophan-Selective Ru-TAP Complex to Regioselectively Photolabel Specific Proteins.
用于在活细胞中设计蛋白质的工具包:具有色氨酸选择性 Ru-TAP 复合物的肽以区域选择性光标记特定蛋白质。

47.Control of Hot Carrier Cooling in Lead Halide Perovskites by Point Defects.
通过点缺陷控制卤化铅钙钛矿中的热载流子冷却。

48.A Charge-Neutral Self-Assembled L2Zn2 Helicate as Bench-Stable Receptor for Anion Recognition at Nanomolar Concentration.
电荷中性的自组装 L2Zn2 螺旋酸盐作为稳定受体用于纳摩尔浓度下的阴离子识别。

49.What is the Real Origin of the Activity of Fe–N–C Electrocatalysts in the O2 Reduction Reaction? Critical Roles of Coordinating Pyrrolic N and Axially Adsorbing Species.
Fe-N-C 电催化剂在 O2 还原反应中活性的真正来源是什么?协调吡咯 N 和轴向吸附物质的关键作用。

50.The Progress and Outlook of Metal Single-Atom-Site Catalysis.
金属单原子中心催化的进展与展望。

51.Matrix-Directed Mineralization for Bulk Structural Materials.
大块结构材料的基质定向矿化。

52.Strategies That Utilize Ion Pairing Interactions to Exert Selectivity Control in the Functionalization of C–H Bonds.
利用离子对相互作用对 C-H 键功能化进行选择性控制的策略。

53.Lipid Expansion Microscopy.
脂质膨胀显微镜。

54.Multi-Component Synthesis of a Buta-1,3-diene-Linked Covalent Organic Framework.
丁-1,3-二烯连接的共价有机骨架的多组分合成。

55.Ni-Catalyzed Oxygen Transfer from N2O onto sp3-Hybridized Carbons.
Ni 催化的氧从 N2O 转移到 sp3 杂化碳上。

56.Identification of Oxidation State +1 in a Molecular Uranium Complex.
分子铀络合物中 +1 氧化态的鉴定。

57.Solution Deposition for Chalcogenide Perovskites: A Low-Temperature Route to BaMS3 Materials (M = Ti, Zr, Hf).
硫族化物钙钛矿的溶液沉积:BaMS3 材料(M = Ti、Zr、Hf)的低温途径。

58.Noncoordinating Flame-Retardant Functional Electrolyte Solvents for Rechargeable Lithium-Ion Batteries.
用于可充电锂离子电池的非配位阻燃功能性电解质溶剂。

59.Enantioselective Selenol-ene Using Rh-Hydride Catalysis.
使用 Rh-氢化物催化的对映选择性硒醇烯。

60.Chemistry of Ketene Transformation to Gasoline Catalyzed by H-SAPO-11.
H-SAPO-11 催化乙烯酮转化为汽油的化学。

61.Tunable Optical Molecular Thermometers Based on Metallacrowns.
基于金属冠的可调谐光学分子温度计。

62.Spontaneous Seed Formation during Electrodeposition Drives Epitaxial Growth of Metastable Bismuth Selenide Microcrystals.
电沉积过程中自发晶种的形成驱动亚稳态硒化铋微晶的外延生长。

63.Tailoring Morphology and Elemental Distribution of Cu-In Nanocrystals via Galvanic Replacement.
通过电流置换调整 Cu-In 纳米晶体的形态和元素分布。

64.Reaction of Thiosulfate Dehydrogenase with a Substrate Mimic Induces Dissociation of the Cysteine Heme Ligand Giving Insights into the Mechanism of Oxidative Catalysis.
硫代硫酸盐脱氢酶与底物模拟物的反应诱导半胱氨酸血红素配体的解离,从而深入了解氧化催化的机制。

65.Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster.
硫化物提高银纳米团簇的近单位光致发光量子产率。

66.13C ENDOR Characterization of the Central Carbon within the Nitrogenase Catalytic Cofactor Indicates That the CFe6 Core Is a Stabilizing “Heart of Steel”.
固氮酶催化辅助因子中中心碳的 13C ENDOR 表征表明 CFe6 核心是稳定的“钢心”。

67.Chemical Synthesis of Post-Translationally Modified H2AX Reveals Redundancy in Interplay between Histone Phosphorylation, Ubiquitination, and Methylation on the Binding of 53BP1 with Nucleosomes.
翻译后修饰的 H2AX 的化学合成揭示了组蛋白磷酸化、泛素化和甲基化对 53BP1 与核小体结合的相互作用的冗余。

68.Capillary-Assisted Molecular Pendulum Bioanalysis.
毛细管辅助分子摆生物分析。

69.Folding and Duplex Formation in Sequence-Defined Aniline Benzaldehyde Oligoarylacetylenes.
序列确定的苯胺苯甲醛低聚芳基乙炔中的折叠和双链体形成。

70.An Iridium-Stabilized Borenium Intermediate.
一种铱稳定的硼中间体。

71.Modulating the Electromechanical Response of Bio-Inspired Amino Acid-Based Architectures through Supramolecular Co-Assembly.
通过超分子共组装调节仿生氨基酸结构的机电响应。

72.Mechano-bioconjugation Strategy Empowering Fusion Protein Therapeutics with Aggregation Resistance, Prolonged Circulation, and Enhanced Antitumor Efficacy.
机械-生物共轭策略赋予融合蛋白治疗以抗聚集、延长循环和增强抗肿瘤功效。

73.Direct Determination of the Phase Diagram of a Depletion-Mediated Colloidal System.
耗尽介导胶体系统相图的直接测定。

74.Palette of Rechargeable Mechanoluminescent Fluids Produced by a Biomineral-Inspired Suppressed Dissolution Approach.
由受生物矿物启发的抑制溶解方法生产的可充电机械发光流体调色板。

75.Engineering Poly(ethylene glycol) Nanoparticles for Accelerated Blood Clearance Inhibition and Targeted Drug Delivery.
用于加速血液清除抑制和靶向药物输送的工程聚(乙二醇)纳米颗粒。

76.Design, Synthesis, and Characterization of Stapled Oligosaccharides.
短链寡糖的设计、合成和表征。

77.Halogenated Zn2+ Solvation Structure for Reversible Zn Metal Batteries.
用于可逆锌金属电池的卤化 Zn2+ 溶剂化结构。

78.Solid-State Chemical Recycling of Polycarbonates to Epoxides and Carbon Dioxide Using a Heterodinuclear Mg(II)Co(II) Catalyst.
使用异双核 Mg(II)Co(II) 催化剂将聚碳酸酯固态化学回收为环氧化物和二氧化碳。

79.Iron/Photosensitizer Hybrid System Enables the Synthesis of Polyaryl-Substituted Azafluoranthenes.
铁/光敏剂混合系统可合成聚芳基取代的氮杂荧蒽。

80.Metal–Support Interactions in Molecular Single-Site Cluster Catalysts.
分子单中心团簇催化剂中的金属-载体相互作用。
