D带中心，经典案例！

D带中心，经典案例

https://www.bilibili.com/video/BV1gj411X7N3/?share_source=copy_web&vd_source=756a60736d1f26ff9c3eee296d9c6e11

1. 
   
2. d带中心越接近于0，吸附越强。

2.

1. Zheng, J.-H.; Li, G.; Zhang, J.-M.; Cheng, N.; Ji, L.-F.; Yang, J.; Zhang, J.; Zhang, B.-W.; Jiang, Y.-X.; Sun, S.-G. General Strategy for Evaluating the D-Band Center Shift and Ethanol Oxidation Reaction Pathway towards Pt-Based Electrocatalysts. Sci. China Chem.2023, 66 (1), 279–288. https://doi.org/10.1007/s11426-022-1420-2.
2. 两种金属结合---调节表面电子结构---调节d带中心---吸附。

3.

1. Yin, J.; Jin, J.; Yin, Z.; Zhu, L.; Du, X.; Peng, Y.; Xi, P.; Yan, C.-H.; Sun, S. The Built-in Electric Field across FeN/Fe3N Interface for Efficient Electrochemical Reduction of CO2 to CO. Nat Commun2023, 14 (1), 1724. https://doi.org/10.1038/s41467-023-37360-9.
2. d带中心是负值，越接近于0，说明其吸附越强。

4.

1. Sun, X.; Sun, L.; Li, G.; Tuo, Y.; Ye, C.; Yang, J.; Low, J.; Yu, X.; Bitter, J. H.; Lei, Y.; Wang, D.; Li, Y. Phosphorus Tailors the d ‐Band Center of Copper Atomic Sites for Efficient CO 2 Photoreduction under Visible‐Light Irradiation. Angew Chem Int Ed2022, 61 (38). https://doi.org/10.1002/anie.202207677.
2. CO2RR要注意气氛的影响，会有副反应，电解液和试剂保持干净，尤其是氮还原更要注重纯净。
3. 提高CO2还原为CO的法拉第效率。

5.

1. 综述
2. Jiao, S.; Fu, X.; Huang, H. Descriptors for the Evaluation of Electrocatalytic Reactions: D‐Band Theory and Beyond. Adv Funct Materials2022, 32 (4), 2107651. https://doi.org/10.1002/adfm.202107651.