【标题速读】【Angew】【2022年】【3月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Chimeric antigen receptor (CAR) T cell therapy suffers from complications including cytokine release syndromes and T cell exhaustion. To curb these drawbacks, Jianfeng Zhou, Wenshe Ray Liu et al. report in their Research Article (e202109550) a chemogenetic switch that can be reversibly turned on and off to control the expression of CAR using a clinically approved small-molecule drug, asunaprevir. This novel technique will potentially enable delicate modulation of CAR-T activation during cancer treatment.

嵌合抗原受体 (CAR) T 细胞疗法会出现并发症，包括细胞因子释放综合征和 T 细胞耗竭。为了遏制这些弊端，Jianfeng Zhou、Wenshe Ray Liu 等人。在他们的研究文章 (e202109550) 中报告了一种化学遗传学开关，可以使用临床批准的小分子药物 asunaprevir 可逆地打开和关闭以控制 CAR 的表达。这项新技术将有可能在癌症治疗过程中对 CAR-T 激活进行精细调节。

2.Hollow triple-shelled Zn/MFI single crystals were designed by Ning Wang and co-workers in their Research Article (e202114786). They exhibit a rather long lifetime as well as an enhanced shape selectivity for p-xylene.

空心三壳 Zn/MFI 单晶是由 Ning Wang 及其同事在他们的研究文章 (e202114786) 中设计的。它们表现出相当长的寿命以及对二甲苯增强的形状选择性。

3.Multi-photon absorption (MPA) is needed for certain applications requiring tight spatial control and long wavelength excitation, but few examples of molecules exhibiting higher-order MPA exist. In their Communication (e202116181), Mark G. Humphrey and co-workers report that metallodendrimers can exhibit outstanding three- to six-photon absorption with fs-pulsed light, and they disclose the key role of metal-to-oligo(phenyleneethynylene) charge transfer in MPA activity.

某些需要严格空间控制和长波长激发的应用需要多光子吸收 (MPA)，但很少有分子表现出高阶 MPA 的例子。在他们的通讯 (e202116181) 中，Mark G. Humphrey 及其同事报告说，金属树枝状大分子可以通过飞秒脉冲光表现出出色的三到六光子吸收，并且他们揭示了金属到低聚（亚苯基乙炔基）电荷的关键作用MPA 活动中的转移。

4.Reduction-induced hydrogenation of a helical bilayer nanographene (C138H120) with K or Rb in 18-crown-6 is reported by Israel Fernández, Marina A. Petrukhina, Nazario Martín, and co-workers in their Research Article (e202115747). DFT calculations predict that localization of the first two electrons in the helicene moiety leads to a site-specific hydrogenation at the carbon atoms located on the edge of the central [6]helicene backbone (pink hydrogens). The third electron forms a radical trianion on the HBC leading to a final Rb complex.

Israel Fernández、Marina A. Petrukhina、Nazario Martín 及其同事在他们的研究文章 (e202115747) 中报道了 18-crown-6 中螺旋双层纳米石墨烯 (C138H120) 与 K 或 Rb 的还原诱导氢化。 DFT 计算预测，螺旋烯部分中前两个电子的定位会导致位于中心 [6] 螺旋烯主链边缘的碳原子（粉红色氢）发生位点特异性氢化。第三个电子在 HBC 上形成自由基三阴离子，形成最终的 Rb 络合物。

5.Electron Transfer In their Communication (e202114423), Bei Ding, Dongping Zhong et al. investigate the photoinduced proton-coupled electron transfer processes of the OaPAC BLUF domain W mutant.

通信中的电子转移 (e202114423)，丁北，钟东平等人。研究 OaPAC BLUF 结构域 W 突变体的光诱导质子耦合电子转移过程。

6.Batteries A covalent organic framework with highly accessible carbonyl groups for advanced potassium-ion batteries is reported in the Research Article by Xing-Long Wu et al. (e202117661).

电池 Xing-Long Wu 等人在研究文章中报道了一种具有易于接近的羰基的共价有机框架，用于先进的钾离子电池。 （e202117661）。

7.Deoxygenative Functionalizations of Aldehydes, Ketones and Carboxylic Acids.

醛、酮和羧酸的脱氧官能化。

8.Covalent Organic Framework with Highly Accessible Carbonyls and π-Cation Effect for Advanced Potassium-Ion Batteries.

用于先进钾离子电池的具有高度易接近的羰基和 π 阳离子效应的共价有机框架。

9.A Reversible Chemogenetic Switch for Chimeric Antigen Receptor T Cells.

嵌合抗原受体 T 细胞的可逆化学遗传学开关。

10.Substrate Profiling of Mitochondrial Caseinolytic Protease P via a Site-Specific Photocrosslinking Approach.

通过位点特异性光交联方法对线粒体酪蛋白分解蛋白酶 P 进行底物分析。

11.Direct and Unified Access to Carbon Radicals from Aliphatic Alcohols by Cost-Efficient Titanium-Mediated Homolytic C−OH Bond Cleavage.

通过经济高效的钛介导的均质 C−OH 键断裂，从脂肪醇中直接统一获取碳自由基。

12.Tandem Living Insertion and Controlled Radical Polymerization for Polyolefin–Polyvinyl Block Copolymers.

聚烯烃-聚乙烯嵌段共聚物的串联活性插入和受控自由基聚合。

13.Organic Supramolecular Zippers with Ultralong Organic Phosphorescence by a Dexter Energy Transfer Mechanism.

Dexter 能量转移机制具有超长有机磷光的有机超分子拉链。

14.In Situ Self-Assembly of Bispecific Peptide for Cancer Immunotherapy.

用于癌症免疫治疗的双特异性肽的原位自组装。

15.Accessing Highly Efficient Photothermal Conversion with Stable Open-Shell Aromatic Nitric Acid Radicals.

利用稳定的开壳芳香族硝酸自由基实现高效光热转换。

16.Two-Dimensional Polycyclic Photovoltaic Molecule with Low Trap Density for High-Performance Photocatalytic Hydrogen Evolution.

用于高性能光催化析氢的低陷阱密度二维多环光伏分子。

17.Efficient Long-Range Triplet Exciton Transport by Metal–Metal Interaction at Room Temperature.

室温下金属-金属相互作用的高效长程三重态激子传输。

18.Hetero-Lattice Intergrown and Robust MOF Membranes for Polyol Upgrading.

用于多元醇升级的异质晶格共生且坚固的 MOF 膜。

19.Electropolymerization of Metal Clusters Establishing a Versatile Platform for Enhanced Catalysis Performance.

金属簇的电聚合建立了增强催化性能的多功能平台。

20.Photoswitchable Epothilone-Based Microtubule Stabilisers Allow GFP-Imaging-Compatible, Optical Control over the Microtubule Cytoskeleton.

基于埃坡霉素的光开关微管稳定剂可以对微管细胞骨架进行 GFP 成像兼容的光学控制。

21.Rational Design of Zinc/Zeolite Catalyst: Selective Formation of p-Xylene from Methanol to Aromatics Reaction.

锌/沸石催化剂的合理设计：从甲醇到芳烃反应选择性生成对二甲苯。

22.High-Capacity and Long-Life Zinc Electrodeposition Enabled by a Self-Healable and Desolvation Shield for Aqueous Zinc-Ion Batteries.

通过水性锌离子电池的自愈和去溶剂化屏蔽实现高容量和长寿命的锌电沉积。

23.A Chemoenzymatic Cascade Combining a Hydration Catalyst with an Amine Dehydrogenase: Synthesis of Chiral Amines.

结合水合催化剂与胺脱氢酶的化学酶级联：手性胺的合成。

24.The Underlying Molecular Mechanism of Fence Engineering to Break the Activity–Stability Trade-Off in Catalysts for the Hydrogen Evolution Reaction.

打破析氢反应催化剂活性与稳定性权衡的栅栏工程的基本分子机制。

25.The Assembly and Jamming of Nanoparticle Surfactants at Liquid–Liquid Interfaces.

纳米颗粒表面活性剂在液-液界面的组装和干扰。

26.Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window.

用于产生具有宽带透明窗口的高效二次谐波的手性杂化铜 (I) 卤化物。

27.Asymmetric Hydroaminoalkylation of Alkenylazaarenes via Cooperative Photoredox and Chiral Hydrogen-Bonding Catalysis.

通过协同光氧化还原和手性氢键催化进行烯基氮杂芳烃的不对称氢氨基烷基化。

28.Experimental and Computational Studies on the Directing Ability of Chalcogenoethers in Palladium-Catalyzed Atroposelective C−H Olefination and Allylation.

硫属醚在钯催化的 Atropeselective C−H 烯化和烯丙基化中的导向能力的实验和计算研究。

29.Sustainable Superhydrophobic Surface with Tunable Nanoscale Hydrophilicity for Water Harvesting Applications.

用于集水应用的具有可调纳米级亲水性的可持续超疏水表面。

30.Dinuclear PtII Complexes with Strong Blue Phosphorescence for Operationally Stable Organic Light-Emitting Diodes with EQE up to 23 % at 1000 cd m−2.

具有强蓝色磷光的双核 PtII 配合物，可用于运行稳定的有机发光二极管，在 1000 cd m−2 时 EQE 高达 23 %。

31.Exceptional Manganese(II) Stability and Manganese(II)/Zinc(II) Selectivity with Rigid Polydentate Ligands.

刚性多齿配体具有出色的锰 (II) 稳定性和锰 (II)/锌 (II) 选择性。

32.Ultrasensitive Detection of Aqueous Uranyl Based on Uranyl-Triggered Protein Photocleavage.

基于铀酰触发的蛋白质光裂解对水性铀酰进行超灵敏检测。

33.Site-Specific Reduction-Induced Hydrogenation of a Helical Bilayer Nanographene with K and Rb Metals: Electron Multiaddition and Selective Rb+ Complexation.

螺旋双层纳米石墨烯与 K 和 Rb 金属的位点特异性还原诱导氢化：电子多重加成和选择性 Rb+ 络合。

34.Torque-Driven Orientation Motion of Chemotactic Colloidal Motors.

趋化胶体电机的扭矩驱动定向运动。

35.Lessons from an Array: Using an Electrode Surface to Control the Selectivity of a Solution-Phase Chemical Reaction.

阵列的经验教训：使用电极表面控制溶液相化学反应的选择性。

36.Site-Selective N-1 and C-3 Heteroarylation of Indole with Heteroarylnitriles by Organocatalysis under Visible Light.

在可见光下通过有机催化对吲哚与杂芳基腈进行位点选择性 N-1 和 C-3 杂芳基化。

37.Semiconducting Polymer Nano-regulators with Cascading Activation for Photodynamic Cancer Immunotherapy.

用于光动力癌症免疫治疗的具有级联激活功能的半导体聚合物纳米调节剂。

38.High-Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence.

具有巨大二次谐波产生和大双折射的高性能硫酸盐光学材料。

39.Robust Luminescent Molecules with High-Level Reverse Intersystem Crossing for Efficient Near Ultraviolet Organic Light-Emitting Diodes.

具有高水平反向系间窜越的鲁棒发光分子，可实现高效近紫外有机发光二极管。

40.Chirality Inversion in Self-Assembled Nanocomposites Directed by Curvature-Mediated Interactions.

由曲率介导的相互作用引导的自组装纳米复合材料的手性反转。

41.Formation and Reactivity of a Hexahydridosilicate [SiH6]2− Coordinated by a Macrocycle-Supported Strontium Cation.

由大环支撑的锶阳离子协调的六氢硅酸盐 [SiH6]2− 的形成和反应性。

42.Direct Observation of Ultrafast Proton Rocking in the BLUF Domain.

BLUF 域中超快质子摇摆的直接观测。

43.A Fluorescent Sensor for Quantitative Super-Resolution Imaging of Amyloid Fibril Assembly.

用于淀粉样原纤维组装定量超分辨率成像的荧光传感器。

44.Dissipative Organization of DNA Oligomers for Transient Catalytic Function.

用于瞬时催化功能的 DNA 寡聚物的耗散组织。

45.Total Synthesis of Isorosthin L and Isoadenolin I.

异大豆苷L和异腺苷I的全合成。

46.Highly Regio- and Enantioselective Hydrosilylation of gem-Difluoroalkenes by Nickel Catalysis.

通过镍催化对偕二氟烯烃进行高度区域和对映选择性硅氢加成。

47.Isolation and Properties of the Long Elusive Deep Blue Soluble [K3{(NtBu)3S}2]. Cage Radical.

难以捉摸的深蓝可溶物 [K3{(NtBu)3S}2] 的分离和性质。凯奇激进。

48.Synthesis of Cyclopropenols Enabled by Visible-Light-Induced Organocatalyzed [2+1] Cyclization.

通过可见光诱导的有机催化 [2+1] 环化实现环丙烯醇的合成。

49.Transformation of Covalent Organic Frameworks from N-Acylhydrazone to Oxadiazole Linkages for Smooth Electron Transfer in Photocatalysis.

共价有机框架从 N-酰腙到恶二唑键的转变，以实现光催化中顺利的电子转移。

50.Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion.

Na4B8O9F10：一种深紫外透明非线性光学氟硼酸盐，具有由优化色散引起的意想不到的短相位匹配波长。

51.Flash Electrochemical Approach to Carbocations.

碳正离子的快速电化学方法。

52.Topochemical Polymerization of a Diacetylene in a Chalcogen-Bonded (ChB) Assembly.

硫属键合 (ChB) 组装中丁二炔的拓扑化学聚合。

53.Outstanding Multi-Photon Absorption at π-Delocalizable Metallodendrimers.

π-离域金属树枝状聚合物具有出色的多光子吸收能力。

54.Polyyne [3]Rotaxanes: Synthesis via Dicobalt Carbonyl Complexes and Enhanced Stability.

聚炔[3]轮烷：通过二钴羰基配合物合成并增强稳定性。

55.Catalytic Enantioconvergent Allenylation of Aldehydes with Propargyl Halides.

醛与炔丙基卤化物的催化对映异构烯酰化。

56.Catalytic Transformation of PET and CO2 into High-Value Chemicals.

PET 和 CO2 催化转化为高价值化学品。

57.Hydrogen-bonded frameworks self-assembled from metal–nucleobase complexes and hexafluoro anions are reported by Wei Zhou, Zongbi Bao et al. in their Research Article (e202117609). Amino-rich ligands provide multiple H-bonding sites to stabilize the frameworks. In the confined channels, the electron-rich anions combined with the electron-deficient purine rings generate a micro-electric field to polarize and lock Xe atoms, thus achieving highly efficient Xe/Kr separation under ambient conditions.

Wei Zhou、Zongbi Bao 等人报道了由金属-核碱基配合物和六氟阴离子自组装的氢键框架。在他们的研究文章（e202117609）中。富含氨基的配体提供多个氢键位点以稳定框架。在受限通道中，富电子阴离子与缺电子嘌呤环结合产生微电场，极化并锁定Xe原子，从而在环境条件下实现高效的Xe/Kr分离。

58.The iron guanidine catalyst shows extraordinary copolymerization activity towards lactide, glycolide, and ϵ-caprolactone, as reported by Sonja Herres-Pawlis, Moshe Kol, and co-workers in their Research Article (e202112853). Depending on the reaction temperature and the mode of monomer addition, it either forms up to pentablock copolymers in a highly defined way or promotes transesterifications to such a high degree that random copolymers are produced. Therefore, it is a rare example of a catalyst mastering both microstructures: ordered and chaotic.

Sonja Herres-Pawlis、Moshe Kol 及其同事在他们的研究文章 (e202112853) 中报道，铁胍催化剂对丙交酯、乙交酯和ε-己内酯表现出非凡的共聚活性。根据反应温度和单体添加方式，它要么以高度限定的方式形成五嵌段共聚物，要么促进酯交换反应达到产生无规共聚物的高度。因此，它是掌握有序和混乱两种微观结构的催化剂的罕见例子。

59.Pentabenzopentaaza[10]circulene , the largest hetero[n]circulene, has been synthesized by a fold-in approach, as reported by Takayuki Tanaka and co-workers in their Communication (e202116789). The molecule exhibits a saddle-distorted structure in the solid state, reminiscent of a camel's back. The dynamic behavior was analyzed experimentally and theoretically, revealing a low transition state for the saddle-to-saddle inversion. In contrast, a planar, star-shaped conformer is energetically much higher, like a star in the sky.

正如 Takayuki Tanaka 及其同事在他们的通讯 (e202116789) 中报道的那样，五苯并五氮杂[10]环烯是最大的杂[n]环烯，已通过折叠方法合成。该分子在固态时表现出鞍形扭曲结构，让人想起骆驼的背部。通过实验和理论分析了动态行为，揭示了鞍座到鞍座反转的低过渡态。相比之下，平面星形构象异构体的能量要高得多，就像天空中的星星一样。

60.Perovskites The π-conjugated ionic compound QAPyBF4 was used as a perovskite modulator in the Research Article by Juin-Jei Liou, Taiho Park, Zong-Xiang Xu, and co-workers (e202117303). Experimental investigations showed that p-type conjugated cations [QAPy]2+ adsorb on the perovskite surface with under-coordinated Pb cations and highly electronegative [BF4]− anions enriched at the SnO2 interface. This spontaneous diffusion effect of cation and anion improves the band alignment at two adjacent perovskite interfaces and reduces recombination losses.

钙钛矿 在 Juin-Jei Liou、Taiho Park、Zong-Xiang Xu 及其同事的研究文章 (e202117303) 中，π-共轭离子化合物 QAPyBF4 被用作钙钛矿调节剂。实验研究表明，p 型共轭阳离子 [QAPy]2+ 吸附在钙钛矿表面，配位不足的 Pb 阳离子和富集在 SnO2 界面的高电负性 [BF4]− 阴离子。阳离子和阴离子的这种自发扩散效应改善了两个相邻钙钛矿界面处的能带排列并减少了复合损失。

61.Photopolymerization A photoinduced dual-wavelength approach for 3D printing and self-healing of thermosetting materials is reported in the Communication (e202114111) by Zhiheng Zhang, Nathaniel Corrigan, and Cyrille Boyer.

光聚合 张志恒、Nathaniel Corrigan 和 Cyrille Boyer 在通讯 (e202114111) 中报道了一种用于 3D 打印和热固性材料自修复的光诱导双波长方法。

62.Laser Chemistry In their Research Article (e202117227), Yasuyuki Tsuboi et al. report an optical tweezer technique using nanotextured Si that can efficiently trap polymer chains. The fluorescence color of the perylene-labeled polymer chains can be controlled by changing the laser intensity.

激光化学 在他们的研究文章 (e202117227) 中，Yasuyuki Tsuboi 等人。报告了一种使用纳米纹理硅的光镊技术，可以有效捕获聚合物链。苝标记的聚合物链的荧光颜色可以通过改变激光强度来控制。

63.Developing an Effective Glycan-Based Vaccine for Streptococcus Pyogenes.

开发一种有效的基于聚糖的化脓性链球菌疫苗。

64.Fluorescence Colour Control in Perylene-Labeled Polymer Chains Trapped by Nanotextured Silicon.

纳米纹理硅捕获的苝标记聚合物链的荧光颜色控制。

65.An Orthogonal Dynamic Covalent Polymer Network with Distinctive Topology Transformations for Shape- and Molecular Architecture Reconfiguration.

具有独特拓扑变换的正交动态共价聚合物网络，用于形状和分子结构重构。

66.Raman Fiber Photometry for Understanding Mitochondrial Superoxide Burst and Extracellular Calcium Ion Influx upon Acute Hypoxia in the Brain of Freely Moving Animals.

拉曼光纤光度测定法用于了解自由活动动物大脑急性缺氧时线粒体超氧化物爆发和细胞外钙离子流入。

67.Steering the Glycerol Electro-Reforming Selectivity via Cation–Intermediate Interactions.

通过阳离子-中间相互作用控制甘油电重整选择性。

68.Systematic Interrogation of Cellular Signaling in Live Cells Using a Membrane-Anchored DNA Multitasking Processor.

使用膜锚定 DNA 多任务处理器系统询问活细胞中的细胞信号转导。

69.DNA Origami-Encoded Integration of Heterostructures.

DNA 折纸编码的异质结构整合。

70.Synthesis of 20-Membered Macrocyclic Pseudo-Natural Products Yields Inducers of LC3 Lipidation.

20 元大环假天然产物的合成产生 LC3 脂化诱导剂。

71.Nickel-Mediated Enantioselective Photoredox Allylation of Aldehydes with Visible Light.

可见光下镍介导的醛对映选择性光氧化还原烯丙基化。

72.Manipulating Selective Metal-to-Metal Electron Transfer to Achieve Multi-Phase Transitions in an Asymmetric [Fe2Co]-Assembled Mixed-Valence Chain.

操纵选择性金属间电子转移以实现不对称 [Fe2Co] 组装混合价链中的多相转变。

73.Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes.

芳香酰胺与多氟芳烃的脱氧交叉偶联。

74.Sensitive Logic Nanodevices with Strong Response for Weak Inputs.

对弱输入具有强响应的敏感逻辑纳米器件。

75.Symmetrically Tetra-functionalized Pillar[6]arenes Prepared by Fragment Coupling.

通过片段偶联制备对称四官能化柱[6]芳烃。

76.An Efficient Rechargeable Aluminium–Amine Battery Working Under Quaternization Chemistry.

季铵化化学下工作的高效可充电铝胺电池。

77.Passerini–Smiles Reaction of α-Ketophosphonates: Platform for Phospha-Brook/Smiles Embedded Cascades.

α-酮膦酸盐的 Passerini–Smiles 反应：Phospha-Brook/Smiles 嵌入式级联平台。

78.Discovery of an Ultra-rapid and Sensitive Lysosomal Fluorescence Lipophagy Process.

超快速、灵敏的溶酶体荧光自噬过程的发现。

79.Screening Heteroatom Configurations for Reversible Sloping Capacity Promises High-Power Na-Ion Batteries.

筛选可逆倾斜容量的杂原子配置有望实现高功率钠离子电池。

80.Shape Permanence in Diarylethene-Functionalized Liquid-Crystal Elastomers Facilitated by Thiol-Anhydride Dynamic Chemistry.

硫醇酸酐动态化学促进二芳基乙烯官能化液晶弹性体的形状稳定性。

81.Modular Halogenation, α-Hydroxylation, and Acylation by a Remarkably Versatile Polyketide Synthase.

通过极其通用的聚酮合酶进行模块化卤化、α-羟基化和酰化。

82.Enzymatic C-to-C Protein Ligation.

酶促 C 到 C 蛋白质连接。

83.Surface Modification of Nano-Cu2O for Controlling CO2 Electrochemical Reduction to Ethylene and Syngas.

纳米 Cu2O 的表面改性用于控制 CO2 电化学还原为乙烯和合成气。

84.Highly Efficient Photocatalytic Reduction of CO2 to CO by In Situ Formation of a Hybrid Catalytic System Based on Molecular Iron Quaterpyridine Covalently Linked to Carbon Nitride.

通过原位形成基于与氮化碳共价连接的分子铁季吡啶的混合催化系统，高效光催化将 CO2 还原为 CO。

85.Ligand Engineering toward the Trade-Off between Stability and Activity in Cluster Catalysis.

团簇催化稳定性和活性之间权衡的配体工程。

86.Synergy Effect of a π-Conjugated Ionic Compound: Dual Interfacial Energy Level Regulation and Passivation to Promote Voc and Stability of Planar Perovskite Solar Cells.

π-共轭离子化合物的协同效应：双界面能级调节和钝化促进平面钙钛矿太阳能电池的 Voc 和稳定性。

87.Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C–H Bonds via Reversible η6-Coordination.

通过可逆 η6-配位，铑催化苯甲基 C-H 键的立体选择性氘化。

88.Hydrogen-Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton.

用于有效分离氙和氪的氢键金属-核碱基框架。

89.Novel Quinolizine AIE System: Visualization of Molecular Motion and Elaborate Tailoring for Biological Application.

新型喹嗪 AIE 系统：分子运动的可视化和生物应用的精心定制。

90.Master of Chaos and Order: Opposite Microstructures of PCL-co-PGA-co-PLA Accessible by a Single Catalyst.

混沌与秩序大师：单一催化剂可实现的 PCL-co-PGA-co-PLA 的相反微观结构。

91.HFIP Mediates a Direct C−C Coupling between Michael Acceptors and Eschenmoser's salt.

HFIP 介导 Michael 受体和 Eschenmoser 盐之间的直接 C−C 偶联。

92.A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [GaI]+ and [GaIIIH]2+.

布朗斯台德酸性氢化镓：NNNN-大环支持的 [Gal]+ 和 [GaIIIH]2+ 的轻松相互转化。

93.Transforming Escherichia coli Proteomembranes into Artificial Chloroplasts Using Molecular Photocatalysis.

利用分子光催化将大肠杆菌蛋白质膜转化为人造叶绿体。

94.A Photoinduced Dual-Wavelength Approach for 3D Printing and Self-Healing of Thermosetting Materials.

用于 3D 打印和热固性材料自我修复的光致双波长方法。

95.A Plausible Prebiotic One-Pot Synthesis of Orotate and Pyruvate Suggestive of Common Protometabolic Pathways.

乳清酸和丙酮酸的一种看似合理的益生元一锅合成暗示了常见的原代谢途径。

96.Asymmetric Cyclopropanation and Epoxidation via a Catalytically Formed Chiral Auxiliary.

通过催化形成的手性助剂进行不对称环丙烷化和环氧化。

97.Temperature-Directed Formation of Anisotropic Kettlebell and Tadpole Nanostructures in the Absence of a Swelling-Induced Solvent.

在没有膨胀诱导溶剂的情况下温度定向形成各向异性壶铃和蝌蚪纳米结构。

98.Bacteria-Triggered Solar Hydrogen Production via Platinum(II)-Tethered Chalcogenoviologens.

通过铂 (II) 系留的硫族化合物引发细菌触发太阳能制氢。

99.Metal–Organic Frameworks with Zero and Low-Valent Metal Nodes Connected by Tetratopic Phosphine Ligands.

具有通过四位膦配体连接的零价和低价金属节点的金属有机框架。

100.Inhibition of ACE2-Spike Interaction by an ACE2 Binder Suppresses SARS-CoV-2 Entry.

ACE2 结合剂抑制 ACE2-Spike 相互作用可抑制 SARS-CoV-2 进入。

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