【标题速读】【Angew】【2022年】【1月】

2023-08-15 00:28 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.The blue/orange dual fluorescence properties of tetramesityldiborane(4) are reported by Yoshiaki Shoji, Yasuhiro Ikabata et al. in their Research Article (e202113549). Theoretical calculations showed that the diborane(4) in the S1 state adopts a twisted or planar geometry, which is responsible for the blue or orange fluorescence, respectively. The relative intensity of the dual fluorescence is sensitive to the viscosity of the medium, highlighting the potential of the diborane(4) as a ratiometric viscosity sensor.

Yoshiaki Shoji、Yasuhiro Ikabata 等人报道了四均基乙硼烷 (4) 的蓝/橙色双荧光特性。在他们的研究文章（e202113549）中。理论计算表明，S1态的乙硼烷(4)采用扭曲或平面几何形状，分别产生蓝色或橙色荧光。双荧光的相对强度对介质的粘度敏感，凸显了乙硼烷 (4) 作为比率粘度传感器的潜力。

2.Porous aromatic framework (PAF) membranes with modifiable channels were synthesized by Yuyang Tian, Guangshan Zhu, and co-workers in their Research Article (e202113682). The pore size and chemistry of the membranes were readily modified by ion exchange, resulting in suitable membranes for the separation of different gas mixtures. With Br− in the framework, the membrane exhibited a H2/N2 selectivity of 72.7 with a H2 permeance of 51844 gas permeation units (GPU). With BF4−, the membrane showed a CO2 permeance of 23058 GPU, and an optimized CO2/N2 selectivity of 60.0 was achieved.

Yuyang Tian、Guangshan Zhu 及其同事在他们的研究文章 (e202113682) 中合成了具有可修饰通道的多孔芳香骨架 (PAF) 膜。膜的孔径和化学性质很容易通过离子交换进行改变，从而形成适合分离不同气体混合物的膜。骨架中含有 Br−，该膜的 H2/N2 选择性为 72.7，H2 渗透率为 51844 个气体渗透单位 (GPU)。使用 BF4−，膜的 CO2 渗透率为 23058 GPU，并且实现了 60.0 的优化 CO2/N2 选择性。

3.Diamidophosphate enabled phosphorylation chemistry facilitates the synthesis of closely related nucleotides and nucleoside triphosphates that are compatible with abiotic oligomerization, and ribozyme-mediated polymerization and ligation processes. The one-pot protocol spans nucleosides, nucleotides, and oligonucleotides, implying that the progression from prebiotic chemistry to those conducive for emergence of life's biochemistry could be a more continuous process than previously assumed. Details are discussed in the Research Article by Ulrich F. Müller, Ramanarayanan Krishnamurthy, and co-workers (e202113625).

二氨基磷酸盐启用的磷酸化化学促进了与非生物寡聚、核酶介导的聚合和连接过程相容的密切相关的核苷酸和核苷三磷酸的合成。一锅法方案涵盖核苷、核苷酸和寡核苷酸，这意味着从生命起源前的化学到有利于生命生物化学出现的化学的进展可能是一个比之前假设的更连续的过程。 Ulrich F. Müller、Ramanarayanan Krishnamurthy 及其同事的研究文章 (e202113625) 讨论了详细信息。

4.Fusion of extracellular vesicles to cells contributes to many critical biological pathways. Inspired by the natural fusion process, Hang Xing and co-workers developed a liposome fusion-based transport strategy, termed LiFT, that enables the incorporation of a variety of functional moieties onto both external and internal cell membrane surfaces with precise orientation control (e202111647). By using LiFT, asymmetric DNA modifications with orthogonal functionalities on each side of the cell membrane were achieved, realizing applications such as heterotypic cell assembly and intracellular metabolite detection.

细胞外囊泡与细胞的融合有助于许多关键的生物学途径。受自然融合过程的启发，Hang Xing 及其同事开发了一种基于脂质体融合的运输策略，称为 LiFT，该策略能够通过精确的方向控制将各种功能部分结合到外部和内部细胞膜表面上 (e202111647) 。通过使用LiFT，实现了细胞膜两侧具有正交功能的不对称DNA修饰，实现了异型细胞组装和细胞内代谢物检测等应用。

5.Proteins In their Communication (e202109961), Martin Blackledge et al. report the self-assembly of intrinsically disordered tardigrade proteins into fibrous gels in response to environmental stress.

蛋白质的通讯 (e202109961)，Martin Blackledge 等人。报告了本质上无序的缓步动物蛋白自组装成纤维凝胶以响应环境压力。

6.Foldamers In their Research Article (e202108364), Sunbum Kwon, Hee-Seung Lee et al. report on the conformational adaptation of β-peptide foldamers for the formation of metal–peptide frameworks.

Foldamers 在 Sunbum Kwon、Hee-Seung Lee 等人的研究文章 (e202108364) 中。关于β-肽折叠体的构象适应形成金属-肽框架的报告。

7.Principles of Water Electrolysis and Recent Progress in Cobalt-, Nickel-, and Iron-Based Oxides for the Oxygen Evolution Reaction.

水电解原理以及用于析氧反应的钴、镍和铁基氧化物的最新进展。

8.Heterocycle/Heteroallene Ring-Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers.

杂环/杂联烯开环共聚：选择性催化产生交替共聚物。

9.Conformational Adaptation of β-Peptide Foldamers for the Formation of Metal–Peptide Frameworks.

β-肽折叠体的构象适应形成金属-肽框架。

10.Selective 1Hα NMR Methods Reveal Functionally Relevant Proline cis/trans Isomers in Intrinsically Disordered Proteins: Characterization of Minor Forms, Effects of Phosphorylation, and Occurrence in Proteome.

选择性 1Hα NMR 方法揭示本质无序蛋白质中功能相关的脯氨酸顺式/反式异构体：次要形式的表征、磷酸化的影响以及蛋白质组中的出现。

11.Selective Approaches to α- and β-Arylated Vinyl Ethers.

α-和β-芳基化乙烯基醚的选择性方法。

12.An N-Trifluoromethylation/Cyclization Strategy for Accessing Diverse N-Trifluoromethyl Azoles from Nitriles and 1,3-Dipoles.

从腈和 1,3-偶极子获取多种 N-三氟甲基唑的 N-三氟甲基化/环化策略。

13.Enantioselective Synthesis of Silicon-Stereogenic Monohydrosilanes by Rhodium-Catalyzed Intramolecular Hydrosilylation.

通过铑催化分子内氢化硅烷化对映选择性合成硅立体单氢硅烷。

14.Metal-Free Phosphorus-Directed Borylation of C(sp2)−H Bonds.

C(sp2)−H 键的无金属磷定向硼化。

15.Macrocycle Dynamics in a Branched [8]Catenane Controlled by Three Different Stimuli in Three Different Regions.

三个不同区域的三种不同刺激控制的支链[8]链烷中的大循环动力学。

16.Chemoselective and Diastereoselective Synthesis of C-Aryl Nucleoside Analogues by Nickel-Catalyzed Cross-Coupling of Furanosyl Acetates with Aryl Iodides.

通过镍催化乙酸呋喃糖酯与芳基碘化物的交叉偶联化学选择性和非对映选择性合成 C-芳基核苷类似物。

17.Divergent and Modular Synthesis of Terpenoid Scaffolds via a AuI Catalyzed One-Pot Cascade.

通过 AuI 催化一锅级联进行萜类支架的发散和模块化合成。

18.Unlocking the Stereoselectivity and Substrate Acceptance of Enzymes: Proline-Induced Loop Engineering Test.

解锁酶的立体选择性和底物接受性：脯氨酸诱导环工程测试。

19.Selective Benzylic CH-Borylations by Tandem Cobalt Catalysis.

通过串联钴催化选择性苄基 CH-硼基化。

20.Installing a Green Engine To Drive an Enzyme Cascade: A Light-Powered In Vitro Biosystem for Poly(3-hydroxybutyrate) Synthesis.

安装绿色引擎来驱动酶级联：用于聚（3-羟基丁酸酯）合成的光动力体外生物系统。

21.Structural and Molecular Basis of the Catalytic Mechanism of Geranyl Pyrophosphate C6-Methyltransferase: Creation of an Unprecedented Farnesyl Pyrophosphate C6-Methyltransferase.

香叶基焦磷酸 C6-甲基转移酶催化机制的结构和分子基础：创建前所未有的法呢基焦磷酸 C6-甲基转移酶。

22.Energy Band Alignment and Redox-Active Sites in Metalloporphyrin-Spaced Metal-Catechol Frameworks for Enhanced CO2 Photoreduction.

金属卟啉间隔金属儿茶酚框架中的能带排列和氧化还原活性位点，用于增强 CO2 光还原。

23.A Biomimetic Approach for Spatially Controlled Cell Membrane Engineering Using Fusogenic Spherical Nucleic Acid.

使用融合球形核酸进行空间控制细胞膜工程的仿生方法。

24.Rhodium-Catalyzed Atroposelective Access to Axially Chiral Olefins via C−H Bond Activation and Directing Group Migration.

铑催化通过 C−H 键激活和引导基团迁移选择性地获得轴向手性烯烃。

25.Enhancing Dye-Triplet-Sensitized Upconversion Emission Through the Heavy-Atom Effect in CsLu2F7:Yb/Er Nanoprobes.

通过 CsLu2F7:Yb/Er 纳米探针中的重原子效应增强染料三重态敏化上转换发射。

26.Density-Dependent Emission Colors from a Conformation-Switching Chromophore in Polyurethanes.

聚氨酯中构象转换发色团的密度依赖性发射颜色。

27.Mo3S132− Intercalated Layered Double Hydroxide: Highly Selective Removal of Heavy Metals and Simultaneous Reduction of Ag+ Ions to Metallic Ag0 Ribbons.

Mo3S132− 插层层状双氢氧化物：高度选择性去除重金属并同时将 Ag+ 离子还原为金属 Ag0 带。

28.Photoinitiated anti-Hydropentafluorosulfanylation of Terminal Alkynes.

末端炔烃的光引发抗氢五氟磺酰化。

29.Five-Fold Symmetric Pentaindolo- and Pentakis(benzoindolo)Corannulenes: Unique Structural Dynamics Derived from the Combination of Helical and Bowl Inversions.

五重对称 Pentaindolo 和 Pentakis（苯并吲哚）Corannulenes：源自螺旋和碗反转组合的独特结构动力学。

30.Synthesis, Aromaticity, and Application of peri-Pentacenopentacene: Localized Representation of Benzenoid Aromatic Compounds.

近并五苯并五苯的合成、芳香性和应用：苯环芳香族化合物的局部表征。

31.Active Exsolved Metal–Oxide Interfaces in Porous Single-Crystalline Ceria Monoliths for Efficient and Durable CH4/CO2 Reforming.

多孔单晶二氧化铈整料中的活性溶解金属-氧化物界面，可实现高效、持久的 CH4/CO2 重整。

32.The Aryne Phosphate Reaction.

芳炔磷酸反应。

33.Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond.

Tetraaryldiborane(4) 可以响应 B-B 键周围的结构变化而发射双荧光。

34.Macrocyclic Donor–Acceptor Dyads Composed of a Perylene Bisimide Dye Surrounded by Oligothiophene Bridges.

由被低聚噻吩桥包围的苝双酰亚胺染料组成的大环供体-受体二元体。

35.Concurrent Prebiotic Formation of Nucleoside-Amidophosphates and Nucleoside-Triphosphates Potentiates Transition from Abiotic to Biotic Polymerization.

核苷-酰胺磷酸盐和核苷-三磷酸盐的同时益生元形成增强了从非生物聚合到生物聚合的转变。

36.Visible-Light-Induced C4-Selective Functionalization of Pyridinium Salts with Cyclopropanols.

吡啶鎓盐与环丙醇的可见光诱导 C4 选择性官能化。

37.Continuous Porous Aromatic Framework Membranes with Modifiable Sites for Optimized Gas Separation.

具有可修饰位点的连续多孔芳香骨架膜，可优化气体分离。

38.Calix[4]pyrrole-based Crosslinked Polymer Networks for Highly Effective Iodine Adsorption from Water.

Calix[4]吡咯基交联聚合物网络可高效吸附水中的碘。

39.Maximizing Electroactive Sites in a Three-Dimensional Covalent Organic Framework for Significantly Improved Carbon Dioxide Reduction Electrocatalysis.

最大化三维共价有机框架中的电活性位点，显着改善二氧化碳还原电催化。

40.Druggable Allosteric Sites in β-Propeller Lectins.

β-螺旋桨凝集素中的可药物变构位点。

41.Tumor-Cell-Specific Targeting of Ibrutinib: Introducing Electrostatic Antibody-Inhibitor Conjugates (AiCs).

依鲁替尼的肿瘤细胞特异性靶向：引入静电抗体抑制剂偶联物 (AiC)。

42.Intrinsically Disordered Tardigrade Proteins Self-Assemble into Fibrous Gels in Response to Environmental Stress.

本质上无序的缓步动物蛋白质自组装成纤维凝胶以应对环境压力。

43.Mediated Inner-Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through-Space Electronic Conjugation.

介导的内球电子转移通过空间电子共轭诱导二氧化碳均匀还原。

44.Solar Urea: Towards a Sustainable Fertilizer Industry.

太阳能尿素：迈向可持续化肥工业。

45.Synthesis of Functionalized Silsesquioxane Nanomaterials by Rhodium-Catalyzed Carbene Insertion into Si−H Bonds.

通过铑催化卡宾插入 Si−H 键合成功能化倍半硅氧烷纳米材料。

46.Athermal, Chemically Triggered Release of RNA from Thioester Nucleic Acids.

硫酯核酸的无热、化学触发 RNA 释放。

47.Configurational Lability at Tetrahedral Phosphorus: syn/anti-Isomerization of a P-Stereogenic Phosphiranium Cation by Intramolecular Epimerization at Phosphorus.

四面体磷的构型不稳定性：通过磷分子内差向异构化实现 P-立体磷鎓阳离子的顺式/反异构化。

48.Photocatalytic Sulfonylcarbocyclization of Alkynes Using SEt as a Traceless Directing Group: Access to Cyclopentenes and Indenes.

使用 SEt 作为无痕导向基团进行炔烃的光催化磺酰碳环化：获得环戊烯和茚。

49.Visible Light Induced Brønsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones.

可见光诱导布朗斯台德酸辅助钯催化重氮化合物和 N-甲苯磺酰腙的烷基 Heck 反应。

50.Solid-Phase-Supported Chemoenzymatic Synthesis of a Light-Activatable tRNA Derivative.

光激活 tRNA 衍生物的固相支持化学酶合成。

51.Enantioselective Synthesis of Chiral Carboxylic Acids from Alkynes and Formic Acid by Nickel-Catalyzed Cascade Reactions: Facile Synthesis of Profens.

通过镍催化级联反应从炔烃和甲酸对映选择性合成手性羧酸：Profens 的简便合成。

52.Vitamin D Inhibits the Early Aggregation of α-Synuclein and Modulates Exocytosis Revealed by Electrochemical Measurements.

电化学测量显示，维生素 D 抑制 α-突触核蛋白的早期聚集并调节胞吐作用。

53.Connecting Rheological Properties and Molecular Dynamics of Egg-Tempera Paints based on Egg Yolk.

连接基于蛋黄的蛋彩画涂料的流变特性和分子动力学。

54.Truly-Biocompatible Gold Catalysis Enables Vivo-Orthogonal Intra-CNS Release of Anxiolytics.

真正生物相容的金催化使抗焦虑药能够在体内正交中枢神经系统内释放。

55.Accessing Unsymmetrically Linked Heterocycles through Stereoselective Palladium-Catalyzed Domino Cyclization.

通过立体选择性钯催化多米诺环化获得不对称连接的杂环。

56.Multi-Stimuli-Induced Mechanical Bending and Reversible Fluorescence Switching in a Single Organic Crystal.

单一有机晶体中的多重刺激诱导机械弯曲和可逆荧光切换。

57.Photocleavable Fluorescent Membrane Tension Probes: Fast Release with Spatiotemporal Control in Inner Leaflets of Plasma Membrane, Nuclear Envelope, and Secretory Pathway.

可光裂解荧光膜张力探针：质膜内叶、核膜和分泌途径的时空控制快速释放。

58.Quantifying Intracellular Single Vesicular Catecholamine Concentration with Open Carbon Nanopipettes to Unveil the Effect of L-DOPA on Vesicular Structure.

使用开放碳纳米移液器定量细胞内单囊泡儿茶酚胺浓度，以揭示 L-DOPA 对囊泡结构的影响。

59.Layered Double Hydroxide-Assisted Fabrication of Prussian Blue Membranes for Precise Molecular Sieving.

用于精确分子筛分的层状双氢氧化物辅助普鲁士蓝膜的制造。

60.Air-Stable PdI Dimer Enabled Remote Functionalization: Access to Fluorinated 1,1-Diaryl Alkanes with Unprecedented Speed.

空气稳定的 PdI 二聚体实现远程功能化：以前所未有的速度获取氟化 1,1-二芳基烷烃。

61.Rigid Bridge-Confined Double-Decker Platinum(II) Complexes Towards High-Performance Red and Near-Infrared Electroluminescence.

刚性桥限制双层铂 (II) 配合物实现高性能红色和近红外电致发光。

62.A Defective Nanotube Molecule of C552H496N24 with Pyridinic and Pyrrolic Nitrogen Atoms.

具有吡啶和吡咯氮原子的 C552H496N24 有缺陷的纳米管分子。

63.Stacked but not Stuck: Unveiling the Role of π→π* Interactions with the Help of the Benzofuran–Formaldehyde Complex.

堆叠但不卡住：借助苯并呋喃-甲醛复合物揭示 π→π* 相互作用的作用。

64.Binary mesocrystals demonstrate the combination of nanocrystals from different materials within a highly ordered manner. While nanocubes appear to be simple in their geometry, they can arrange in various ways into a complex entity that not only directs its habitus but also its properties. In their Research Article (e202112461), Helmut Cölfen et al. report on the formation and structural analysis of micrometer-sized two- and three-dimensional binary particle assemblies, revealing their mesocrystalline nature and highlighting their importance within the growing field of metamaterials.

二元介晶展示了不同材料的纳米晶体以高度有序的方式组合。虽然纳米立方体的几何形状看起来很简单，但它们可以以各种方式排列成一个复杂的实体，不仅指导其惯态，而且指导其属性。 Helmut Cölfen 等人在他们的研究文章 (e202112461) 中。关于微米尺寸的二维和三维二元粒子组件的形成和结构分析的报告，揭示了它们的介晶性质并强调了它们在不断发展的超材料领域的重要性。

65.Depending on the nature of M+ , the hydrides of the H2Cu11 reactant behave differently. In the case of M=Cu or Ag, they act as regular two-electron ligands yielding [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (Cu12H2) or [AgH2Cu14{S2P(OiPr)2}6(C≡CPh)6]+ (AgH2Cu14); in the case of M=Au, they behave as electron donors to form [AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl] (AuCu11). Details of the study are presented by Jean-Yves Saillard, Chen-Wei Liu, and co-workers in their Research Article (e202113266).

根据 M+ 的性质，H2Cu11 反应物的氢化物表现不同。在 M=Cu 或 Ag 的情况下，它们充当常规双电子配体，产生 [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (Cu12H2) 或 [AgH2Cu14{S2P(OiPr)2} 6(C=CPh)6]+ (AgH2Cu14);在M=Au的情况下，它们作为电子供体形成[AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl] (AuCu11)。 Jean-Yves Saillard、Chen-Wei Liu 及其同事在他们的研究文章 (e202113266) 中介绍了该研究的详细信息。

66.Photomechanical crystals composed of 9-methylanthracene molecules were investigated by Daichi Kitagawa, Christopher J. Bardeen, Seiya Kobatake, and co-workers in their Research Article (e202114089). The crystals that expand under illumination could potentially be used as photon-powered actuators. Moreover, the quantitative connection between molecular reaction kinetics and mechanical response in well-defined single crystals provides a new benchmark for analyzing these photomechanical materials.

Daichi Kitakawa、Christopher J. Bardeen、Seiya Kobatake 及其同事在他们的研究文章 (e202114089) 中研究了由 9-甲基蒽分子组成的光机械晶体。在光照下膨胀的晶体有可能用作光子驱动的致动器。此外，明确的单晶中分子反应动力学和机械响应之间的定量联系为分析这些光机械材料提供了新的基准。

67.A sequence-controlled ring-opening metathesis polymerization strategy based on macrobicyclic olefins bearing a sacrificial silyloxide bridge was developed by Hong Yang and co-workers as described in their Communication (e202112526). The cover image depicts a “magic” production line of sequence-defined polymers. The monomeric sequence information shown as a colored ball chain is implanted in the macro-ring, while the small ring induces narrow polydispersity and high regio- and stereospecificity.

Hong Yang 及其同事开发了一种基于带有牺牲硅氧基桥的大双环烯烃的序列控制开环易位聚合策略，如他们的通讯 (e202112526) 中所述。封面图片描绘了一条“神奇”的序列定义聚合物生产线。显示为彩色球链的单体序列信息被植入大环中，而小环则产生窄的多分散性和高区域特异性和立体特异性。

68.Covalent Organic Frameworks Near-equilibrium growth of chemically stable covalent organic framework–graphene oxide hybrid materials for the hydrogen evolution reaction is reported in the Communication by Jianyi Chen, Jichen Dong, Yunqi Liu et al. (e202113067).

共价有机框架用于析氢反应的化学稳定的共价有机框架-氧化石墨烯杂化材料的近平衡生长在陈建一、董继辰、刘云琪等人的通讯中报道。（e202113067）。

69.Biosensors Molecular sensors for plant polyphenol imaging based on near-infrared fluorescent single wall carbon nanotubes are presented by Sebastian Kruss et al. in their Research Article (e202108373).

生物传感器 Sebastian Kruss 等人提出了基于近红外荧光单壁碳纳米管的植物多酚成像分子传感器。在他们的研究文章（e202108373）中。

70.Photocatalytic Conversion of Methane: Recent Advancements and Prospects.

甲烷的光催化转化：最新进展和前景。

71.Crystal Structure Classification of Copper-Based Sulfides as a Tool for the Design of Inorganic Functional Materials.

铜基硫化物的晶体结构分类作为无机功能材料设计的工具。

72.Detection and Imaging of the Plant Pathogen Response by Near-Infrared Fluorescent Polyphenol Sensors.

通过近红外荧光多酚传感器检测和成像植物病原体反应。

73.3D Binary Mesocrystals from Anisotropic Nanoparticles.

来自各向异性纳米颗粒的 3D 二元介晶。

74.Moderate Surface Segregation Promotes Selective Ethanol Production in CO2 Hydrogenation Reaction over CoCu Catalysts.

适度的表面偏析促进 CoCu 催化剂上 CO2 加氢反应中选择性乙醇的产生。

75.NIR-II Hydrogen-Bonded Organic Frameworks (HOFs) Used for Target-Specific Amyloid-β Photooxygenation in an Alzheimer's Disease Model.

NIR-II 氢键有机框架 (HOF) 用于阿尔茨海默病模型中目标特异性淀粉样蛋白-β 光氧合。

76.Discovery and Mechanism of Action of Small Molecule Inhibitors of Ceramidases.

神经酰胺酶小分子抑制剂的发现及其作用机制。

77.An Exceptional Thermally Induced Four-State Nonlinear Optical Switch Arising from Stepwise Molecular Dynamic Changes in a New Hybrid Salt.

由新型混合盐中的逐步分子动态变化产生的特殊热致四态非线性光开关。

78.A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene).

协同双（亚硅基）活化二硫化碳的惊人模式。

79.Highly Processable Covalent Organic Framework Gel Electrolyte Enabled by Side-Chain Engineering for Lithium-Ion Batteries.

通过锂离子电池侧链工程实现高度可加工的共价有机框架凝胶电解质。

80.C−C Coupling Is Unlikely to Be the Rate-Determining Step in the Formation of C2+ Products in the Copper-Catalyzed Electrochemical Reduction of CO.

C−C 耦合不太可能是铜催化 CO 电化学还原中 C2+ 产物形成的速率决定步骤。

81.Electrophilic Activation of [1.1.1]Propellane for the Synthesis of Nitrogen-Substituted Bicyclo[1.1.1]pentanes.

[1.1.1]丙烷的亲电活化用于合成氮取代的双环[1.1.1]戊烷。

82.Highly Ethylene-Selective Electrocatalytic CO2 Reduction Enabled by Isolated Cu−S Motifs in Metal–Organic Framework Based Precatalysts.

基于金属有机骨架的预催化剂中分离的 Cu−S 基序实现了高度乙烯选择性电催化 CO2 还原。

83.Transport of Molecular Cargo by Interaction with Virus-Like Particle RNA.

通过与病毒样颗粒 RNA 相互作用进行分子货物运输。

84.Vacancy Modulating Co3Sn2S2 Topological Semimetal for Aqueous Zinc-Ion Batteries.

用于水系锌离子电池的空位调制 Co3Sn2S2 拓扑半金属。

85.A Unified View on Varied Ultrafast Dynamics of the Primary Process in Microbial Rhodopsins.

微生物视紫红质初级过程的各种超快动力学的统一观点。

86.Dynamic Optical Visualization of Proton Transport Pathways at Water–Solid Interfaces.

水-固界面质子传输路径的动态光学可视化。

87.Cascaded Nanozyme System with High Reaction Selectivity by Substrate Screening and Channeling in a Microfluidic Device.

通过微流体装置中的底物筛选和通道形成具有高反应选择性的级联纳米酶系统。

88.Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers.

Clippane：一种基于分子镊子的机械互锁分子 (MIM)。

89.Zr(OH)4-Catalyzed Controllable Selective Oxidation of Anilines to Azoxybenzenes, Azobenzenes and Nitrosobenzenes.

Zr(OH)4-催化苯胺可控选择性氧化为偶氮苯、偶氮苯和亚硝基苯。

90.Labile Photo-Induced Free Radical in α-Ketoglutaric Acid: a Universal Endogenous Polarizing Agent for In Vivo Hyperpolarized 13C Magnetic Resonance.

α-酮戊二酸中不稳定的光诱导自由基：用于体内超极化 13C 磁共振的通用内源性极化剂。

91.Dual Nanoislands on Ni/C Hybrid Nanosheet Activate Superior Hydrazine Oxidation-Assisted High-Efficiency H2 Production.

Ni/C 混合纳米片上的双纳米岛可激活卓越的肼氧化辅助高效氢气生产。

92.Eutectic Crystallization Activates Solid-State Zinc-Ion Conduction.

共晶结晶激活固态锌离子传导。

93.Sterically Wrapped Multiple Resonance Fluorophors for Suppression of Concentration Quenching and Spectrum Broadening.

空间包裹的多重共振荧光团用于抑制浓度淬灭和光谱展宽。

94.Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters.

Cu11 模板中间隙氢化物的反应性：通往双金属簇的途中。

95.Two-Dimensional Fluorinated Covalent Organic Frameworks with Tunable Hydrophobicity for Ultrafast Oil–Water Separation.

具有可调节疏水性的二维氟化共价有机框架，用于超快油水分离。

96.Construction of NH-Unprotected Spiropyrrolidines and Spiroisoindolines by [4+1] Cyclizations of γ-Azidoboronic Acids with Cyclic N-Sulfonylhydrazones.

通过 γ-叠氮硼酸与环状 N-磺酰腙的 [4+1] 环化构建 NH-未保护的螺吡咯烷和螺异吲哚啉。