【标题速读】【Angew】【2022年】【10月】

2023-08-18 17:06 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Amorphous calcium carbonate (ACC) is a pivotal precursor in biomineralization, central to geological and industrial calcification. Some small organic molecules have the ability to affect ACC formation, composition, and stability powerfully. In their Research Article (e202208475), Asher Schmidt, Dirk Zahn, Stephan E. Wolf et al. decode the underlying molecular mechanisms that regulate both prenucleation cluster and solution composition and proceed outside the established conceptional framework.

无定形碳酸钙 (ACC) 是生物矿化的关键前体，是地质和工业钙化的核心。一些有机小分子能够强烈影响 ACC 的形成、组成和稳定性。 Asher Schmidt、Dirk Zahn、Stephan E. Wolf 等人在他们的研究文章 (e202208475) 中解码调节成核前簇和溶液组成的潜在分子机制，并在既定的概念框架之外进行。

2.Grafting N-heterocyclic carbenes (NHCs) on porous materials to realize high activity and recyclability is a challenge. In their Research Article (e202207478), Yuan-Biao Huang, Rong Cao, and co-workers describe the development of a facile method for utilizing NHC sites generated in situ from CO2-masked precursors anchored on a covalent organic framework (COF) for sustainable catalytic CO2 conversion. The NHC-CO2 moieties can be transformed into NHC sites by heating in a catalytic process, in which the CO2 molecules mask the NHC sites and reversibly form NHC-CO2 after catalysis.

在多孔材料上接枝N-杂环卡宾（NHC）以实现高活性和可回收性是一个挑战。Yuan-Biao Huang、Rong Cao 及其同事在他们的研究文章 (e202207478) 中描述了一种简便方法的开发，该方法利用锚定在共价有机框架 (COF) 上的 CO2 掩蔽前体原位生成的 NHC 位点来实现可持续发展催化二氧化碳转化。 NHC-CO2部分可以通过催化过程中的加热转化为NHC位点，其中CO2分子掩盖NHC位点并在催化后可逆地形成NHC-CO2。

3.Enter stereogradient PLA: A tripodal zirconium complex catalyzes the polymerization of L-lactide contaminated with meso-lactide to yield stereogradient poly(lactic acid) (PLA), as described by Moshe Kol and co-workers in their Research Article (e202207652). The stereogradient copolymers exhibit enhanced crystallinities relative to the stereo-random copolymers derived from tin octanoate, and may alleviate the need for L-lactide purification.

输入立体梯度 PLA：三足锆络合物催化被内消旋丙交酯污染的 L-丙交酯聚合，产生立体梯度聚乳酸 (PLA)，如 Moshe Kol 及其同事在其研究文章 (e202207652) 中所述。相对于衍生自辛酸锡的立体无规共聚物，立体梯度共聚物表现出增强的结晶度，并且可以减轻对L-丙交酯纯化的需要。

4.A palladium single-atom model catalyst was used by Ning Yan and co-workers in their Research Article (e202208237) to shed light on the kinetics and structural evolution of catalysts in hydrogen spillover, as well as the nature of participation of the spilled-over H in hydrogenation.

Ning Yan 及其同事在他们的研究文章 (e202208237) 中使用钯单原子模型催化剂来阐明氢溢出中催化剂的动力学和结构演化，以及溢出参与的本质加氢时为H。

5.Organic Semiconductors. An amine-directed B−N bond formation for the synthesis of BN-fused polycyclic aromatic multiple resonance emitters is reported by Dongdong Zhang, Lian Duan et al. in their Communication (e202207293).

有机半导体。张东东、段连等人在他们的通讯（e202207293）中报道了一种胺引导的 BN 键形成方法，用于合成 BN 稠合多环芳香族多重共振发射体。

6.Photocatalysis. The enantioselective three-component photochemical 1,4-bisalkylation of 1,3-butadiene with Pd/Cu catalysis is reported by Qinglong Zhang, Weiwei Zi, and Huimin Yu in their Research Article (e202208411).

光催化。 Qinglong Zhang、Weiwei Zi 和 Huimin Yu 在他们的研究文章 (e202208411) 中报道了 Pd/Cu 催化下 1,3-丁二烯的对映选择性三组分光化学 1,4-双烷基化反应。

7.Stimuli-Responsive Metal Complexes for Biomedical Applications.

用于生物医学应用的刺激响应金属配合物。

8.Chemically Driven Rotatory Molecular Machines.

化学驱动的旋转分子机器。

9.Design and Growth of Branched Organic Crystals: Recent Advances and Future Applications.

支化有机晶体的设计和生长：最新进展和未来应用。

10.Enantioselective Three-Component Photochemical 1,4-Bisalkylation of 1,3-Butadiene with Pd/Cu Catalysis.

Pd/Cu 催化下 1,3-丁二烯的对映选择性三组分光化学 1,4-双烷基化。

11.Atomic-Scale View of Protein-PEG Interactions that Redirect the Thermal Unfolding Pathway of PEGylated Human Galectin-3.

重定向 PEG 化人 Galectin-3 热解折叠途径的蛋白质-PEG 相互作用的原子尺度视图。

12.Formation of a Strong Heterogeneous Aluminum Lewis Acid on Silica.

在二氧化硅上形成强异质铝路易斯酸。

13.Expedient Synthesis of Ubiquitin-like Protein ISG15 Tools through Chemo-Enzymatic Ligation Catalyzed by a Viral Protease Lbpro.

通过病毒蛋白酶 Lbpro 催化的化学酶连接法便捷合成泛素样蛋白 ISG15 工具。

14.The Origin of High-Voltage Stability in Single-Crystal Layered Ni-Rich Cathode Materials.

单晶层状富镍正极材料高压稳定性的起源。

15.Phen-DC3 Induces Refolding of Human Telomeric DNA into a Chair-Type Antiparallel G-Quadruplex through Ligand Intercalation.

Phen-DC3 通过配体嵌入诱导人端粒 DNA 重折叠成椅型反平行 G-四链体。

16.Controlling the Transition of Nanospheres to Superhelices in Aqueous Media by Using a “Smart” Pyrazine Building Block.

使用“智能”吡嗪构件控制水介质中纳米球向超螺旋的转变。

17.Unblocking Ion-occluded Pore Channels in Poly(triazine imide) Framework for Proton Conduction.

疏通质子传导聚（三嗪酰亚胺）框架中离子闭塞的孔通道。

18.Stereogradient Poly(Lactic Acid) from meso-Lactide/L-Lactide Mixtures.

来自内消旋丙交酯/L-丙交酯混合物的立体梯度聚（乳酸）。

19.A CO2-Masked Carbene Functionalized Covalent Organic Framework for Highly Efficient Carbon Dioxide Conversion.

用于高效二氧化碳转化的 CO2 掩蔽卡宾功能化共价有机框架。

20.Divergent CO2 Activation by Tuning the Lewis Acid in Iron-Based Bimetallic Systems.

通过调节铁基双金属体系中的路易斯酸来实现不同的 CO2 活化。

21.Transmembrane Shuttling of Photosynthetically Produced Electrons to Propel Extracellular Biocatalytic Redox Reactions in a Modular Fashion.

光合作用产生的电子的跨膜穿梭以模块化方式推动细胞外生物催化氧化还原反应。

22.Direct Dry Synthesis of Supported Bimetallic Catalysts: A Study on Comminution and Alloying of Metal Nanoparticles.

负载型双金属催化剂的直接干法合成：金属纳米粒子粉碎和合金化的研究。

23.Unshared Pair Electrons of Zincophilic Lewis Base Enable Long-life Zn Anodes under “Three High” Conditions.

亲锌路易斯碱的不共享电子对可在“三高”条件下实现长寿命的锌阳极。

24.Modular Construction of Heterobiaryl Atropisomers and Axially Chiral Styrenes via All-Carbon Tetrasubstituted VQMs.

通过全碳四取代 VQM 构建杂联芳阻转异构体和轴向手性苯乙烯。

25.Hydrogen Spillover and Its Relation to Hydrogenation: Observations on Structurally Defined Single-Atom Sites.

氢溢出及其与氢化的关系：对结构定义的单原子位点的观察。

26.Arene Activation through Iminium Ions: Product Diversity from Intramolecular Photocycloaddition Reactions.

通过亚胺离子活化芳烃：分子内光环加成反应的产物多样性。

27.Highly Strained Bi-MOF on Bismuth Oxyhalide Support with Tailored Intermediate Adsorption/Desorption Capability for Robust CO2 Photoreduction.

卤氧化铋支撑上的高应变 Bi-MOF 具有定制的中间吸附/解吸能力，可实现稳健的 CO2 光还原。

28.Small-Molecular-Weight Additives Modulate Calcification by Interacting with Prenucleation Clusters on the Molecular Level.

小分子量添加剂通过在分子水平上与成核前簇相互作用来调节钙化。

29.Fiber-spinning Asymmetric Assembly for Janus-structured Bifunctional Nanofiber Films towards All-Weather Smart Textile.

用于全天候智能纺织品的 Janus 结构双功能纳米纤维薄膜的纤维纺丝不对称组装。

30.Crystalline Porous Organic Salt for Ultrarapid Adsorption/Desorption-Based Atmospheric Water Harvesting by Dual Hydrogen Bond System.

用于通过双氢键系统超快速吸附/解吸收集大气水的结晶多孔有机盐。

31.Aggregation-Induced Emission and Circularly Polarized Luminescence Duality in Tetracationic Binaphthyl-Based Cyclophanes.

四阳离子联萘基环烷中的聚集诱导发射和圆偏振发光二象性。

32.Enantioselective para-C(sp2)−H Functionalization of Alkyl Benzene Derivatives via Cooperative Catalysis of Gold/Chiral Brønsted Acid.

通过金/手性布朗斯台德酸的协同催化对烷基苯衍生物进行对映选择性对-C(sp2)−H 官能化。

33.Atomically Dispersed Indium-Copper Dual-Metal Active Sites Promoting C−C Coupling for CO2 Photoreduction to Ethanol.

原子分散的铟-铜双金属活性位点促进 CO2 光还原成乙醇的 C−C 耦合。

34.A Double-Helix Metal-Chain Metal-Organic Framework as a High-Output Triboelectric Nanogenerator Material for Self-Powered Anticorrosion.

双螺旋金属链金属有机骨架作为高输出摩擦纳米发电机材料，用于自供电防腐。

35.Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst.

揭示钴催化剂驱动的析氢反应的机理途径。

36.Autonomous Chiral Microswimmers with Self-mixing Capabilities for Highly Efficient Enantioselective Synthesis.

具有自混合能力的自主手性微型游泳器，可实现高效对映选择性合成。

37.Simultaneous Generation of Methyl Esters and CO in Lignin Transformation.

木质素转化中同时生成甲酯和 CO。

38.Ribbon-Type Boron-Doped Polycyclic Aromatic Hydrocarbons: Conformations, Dynamic Complexation and Electronic Properties.

带状掺硼多环芳烃：构象、动态络合和电子特性。

39.Cobaloxime Photocatalysis for the Synthesis of Phosphorylated Heteroaromatics.

钴肟光催化合成磷酸化杂芳烃。

40.Identification of a Novel Pseudo-Natural Product Type IV IDO1 Inhibitor Chemotype.

新型伪天然产品 IV 型 IDO1 抑制剂化学型的鉴定。

41.Multidentate Chelation Heals Structural Imperfections for Minimized Recombination Loss in Lead-Free Perovskite Solar Cells.

多齿螯合可以修复结构缺陷，最大限度地减少无铅钙钛矿太阳能电池的复合损失。

42.Direct Observation of Li-Ion Transport Heterogeneity Induced by Nanoscale Phase Separation in Li-rich Cathodes of Solid-State Batteries.

直接观察固态电池富锂阴极纳米级相分离引起的锂离子传输不均匀性。

43.Alloying at a Subnanoscale Maximizes the Synergistic Effect on the Electrocatalytic Hydrogen Evolution.

亚纳米级合金化可最大限度地发挥电催化析氢的协同效应。

44.Self-Propelled Initiative Collision at Microelectrodes with Vertically Mobile Micromotors.

具有垂直移动微电机的微电极自驱动主动碰撞。

45.A Single-Atom Cobalt Catalyst for the Fluorination of Acyl Chlorides at Parts-per-Million Catalyst Loading.

用于酰氯氟化的单原子钴催化剂（百万分之一催化剂负载量）。

46.An Activatable Near-Infrared Afterglow Theranostic Prodrug with Self-Sustainable Magnification Effect of Immunogenic Cell Death.

一种可激活的近红外余辉治疗诊断前药，具有免疫原性细胞死亡的自我维持放大效应。

47.A Carbon-Carbon Bond Cleavage-Based Prodrug Activation Strategy Applied to β-Lapachone for Cancer-Specific Targeting.

基于碳-碳键断裂的前药激活策略应用于 β-Lapachone，以实现癌症特异性靶向。

48.Efficient Gene Silencing in Intact Plant Cells Using siRNA Delivered By Functional Graphene Oxide Nanoparticles.

使用功能性氧化石墨烯纳米颗粒传递的 siRNA 在完整植物细胞中进行高效基因沉默。

49.Deep-Blue Electroluminescence of Perovskites with Reduced Dimensionality Achieved by Manipulating Adsorption-Energy Differences.

通过操纵吸附能差异实现降维钙钛矿的深蓝色电致发光。

50.Construction of Perylene-based Amphiphilic Micelle and Its Efficient Adsorption and In Situ Photodegradation of Bisphenol A in Aqueous Solution.

苝基两亲性胶束的构建及其对水溶液中双酚A的高效吸附和原位光降解。

51.P and Cu Dual Sites on Graphitic Carbon Nitride for Photocatalytic CO2 Reduction to Hydrocarbon Fuels with High C2H6 Evolution.

石墨碳氮化物上的 P 和 Cu 双位点用于光催化 CO2 还原为具有高 C2H6 演化的碳氢化合物燃料。

52.Bismuth-Mediated α-Arylation of Acidic Diketones with ortho-Substituted Boronic Acids.

铋介导的酸性二酮与邻位取代的硼酸的 α-芳基化。

53.Nearly-Unity Quantum Yield and 12-Hour Afterglow from a Transparent Perovskite of Cs2NaScCl6:Tb.

Cs2NaScCl6:Tb 透明钙钛矿的近乎一致的量子产率和 12 小时余辉。

54.Two-Dimensional-on-Three-Dimensional Metal-Organic Frameworks for Photocatalytic H2 Production.

用于光催化氢气生产的二维-三维金属有机框架。

55.Reconstruction of Highly Dense Cu−N4 Active Sites in Electrocatalytic Oxygen Reduction Characterized by Operando Synchrotron Radiation.

以操作同步辐射为特征的电催化氧还原中高密度 Cu−N4 活性位点的重建。

56.High-Strength Plus Reversible Supramolecular Adhesives Achieved by Regulating Intermolecular PtII⋅⋅⋅PtII Interactions.

通过调节分子间 PtII⋅⋅⋅PtII 相互作用实现高强度可逆超分子粘合剂。

57.Phase Separation of Heterogeneous Nuclear Ribonucleoprotein A1 upon Specific RNA-Binding Observed by Magnetic Resonance.

通过磁共振观察到特异性 RNA 结合时异质核核糖核蛋白 A1 的相分离。

58.A Porphyrin-Based Organic Network Comprising Sustainable Carbon Dots for Photopolymerization.

包含用于光聚合的可持续碳点的卟啉基有机网络。

59.Reductive Al−B σ-Bond Formation in Alumaboranes: Facile Scission of Polar Multiple Bonds.

Alumaborane 中还原 Al−B σ 键的形成：极性多重键的轻松断裂。

60.Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX⋅LiX (X=Cl, Br).

利用 TMPZnX·LiX (X=Cl, Br) 对二嗪进行区域选择性锌化的配位效应。

61.Amine-Directed Formation of B−N Bonds for BN-Fused Polycyclic Aromatic Multiple Resonance Emitters with Narrowband Emission.

具有窄带发射的BN稠合多环芳香族多重共振发射体的BN键的胺引导形成。

62.Transfer Hydrogenation with a Carbon-Nitride-Supported Palladium Single-Atom Photocatalyst and Water as a Proton Source.

用氮化碳支撑的钯单原子光催化剂和水作为质子源进行转移氢化。

63.Highly Efficient Electrocatalytic Oxygen Evolution Over Atomically Dispersed Synergistic Ni/Co Dual Sites.

原子分散协同镍/钴双位点高效电催化析氧。

64.Electronic Character of α,3-Dehydrotoluene Intermediates Generated from Isolable Allenyne-Containing Substrates.

由可分离的含丙炔底物生成的 α,3-脱氢甲苯中间体的电子特征。

65.pH-Induced Symmetry Conversion of DNA Origami Lattices.

pH 诱导的 DNA 折纸晶格的对称性转换。

66.Proton Chemistry Induced Long-Cycle Air Self-Charging Aqueous Batteries.

质子化学诱导长周期空气自充电水电池。

67.Integrating Light-Harvesting Ruthenium(II)-based Units into Three-Dimensional Metal Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution.

将光捕获钌（II）基单元集成到三维金属共价有机框架中，用于光催化析氢。

68.Direct Arene Trifluoromethylation Enabled by a High-Valent CuIII−CF3 Compound.

高价 CuIII−CF3 化合物实现芳烃直接三氟甲基化。

69.Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers.

羧酸的光催化直接脱羧以衍生或降解聚合物。

70.Stereoselective Three-Step One-Pot Cascade Combining Amino- and Biocatalysis to Access Chiral γ-Nitro Alcohols.

立体选择性三步一锅级联结合氨基催化和生物催化获得手性 γ-硝基醇。

71.Au⋅⋅⋅H−C Interactions Support a Robust Thermally Activated Delayed Fluorescence (TADF) Gold(I) Complex for OLEDs with Little Efficiency Roll-Off and Good Stability.

Au⋅⋅⋅H−C 相互作用支持用于 OLED 的鲁棒热激活延迟荧光 (TADF) 金 (I) 络合物，且效率滚降小且稳定性良好。

72.A Rebuilding-Free Nucleic Acid Detection Strategy Enables Ultrasensitive Genotyping, N-in-1 Logic Screening and Accurate Multiplex Assay of Dangerous Pathogens.

免重建核酸检测策略可实现超灵敏基因分型、N-in-1 逻辑筛选和危险病原体的准确多重检测。

73.1 : 1 Ca2+:Cu2+ A-site Order in a Ferrimagnetic Double Double Perovskite.

亚铁磁性双双钙钛矿中的 1 : 1 Ca2+:Cu2+ A 位顺序。

74.Selective CO2 Electroreduction to Ethanol over a Carbon-Coated CuOx Catalyst.

在碳包覆 CuOx 催化剂上选择性 CO2 电还原为乙醇。

75.Molecular Electrochemical Reductive Splitting of Dinitrogen with a Molybdenum Complex.

二氮与钼络合物的分子电化学还原裂解。

76.Fano Resonance in Single-Molecule Junctions.

单分子连接中的法诺共振。

77.Space-Confined Donor-Acceptor Strategy Enables Fast Spin-Flip of Multiple Resonance Emitters for Suppressing Efficiency Roll-Off.

空间受限的供体-受体策略可实现多个谐振发射器的快速自旋翻转，从而抑制效率滚降。

78.Solution-Phase Synthesis and Isolation of An Aza-Triangulene and Its Cation in Crystalline Form.

氮杂三角烯及其结晶形式的阳离子的溶液相合成和分离。

79.Tuning the Regioselectivity of Topochemical Polymerization through Cocrystallization of the Monomer with an Inert Isostere.

通过单体与惰性等排体的共结晶来调节拓扑化学聚合的区域选择性。

80.Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions.

来自反相乳液的明亮且光稳定的荧光金属纳米簇超粒子。

81.Novel Poxin Stable cGAMP-Derivatives Are Remarkable STING Agonists.

新型 Poxin 稳定 cGAMP 衍生物是卓越的 STING 激动剂。

82.Synthesis of α-Aryl Acrylamides via Lewis-Base-Mediated Aryl/Hydrogen Exchange.

通过路易斯碱介导的芳基/氢交换合成 α-芳基丙烯酰胺。

83.Synthesis of Non-Symmetric Azoarenes by Palladium-Catalyzed Cross-Coupling of Silicon-Masked Diazenyl Anions and (Hetero)Aryl Halides.

通过钯催化硅掩蔽的二氮烯基阴离子和（杂）芳基卤化物的交叉偶联合成非对称偶氮芳烃。

84.First explorations of binary Ge/Sb Zintl anions indicated a situation between a “matching” one and one that tends to element segregation owing to a mismatch in atom sizes. Extraction of the ternary solid K12Ge3.5Sb6 allowed access to the so far missing P4-like anion (Ge2Sb2)2−, as well as to species that show tendencies for spatial separation of Ge and Sb atoms, “incomplete” (Ge4Sb12)4− and “complete” (Ge4Sb14)4−, as confirmed by DFT calculations and described by Stefanie Dehnen et al. in their Research Article (e202207232).

对二元 Ge/Sb Zintl 阴离子的首次探索表明，存在一种介于“匹配”阴离子和由于原子尺寸不匹配而倾向于元素偏析的阴离子之间的情况。提取三元固体 K12Ge3.5Sb6 可以获取迄今为止缺失的 P4 类阴离子 (Ge2Sb2)2−，以及显示出 Ge 和 Sb 原子空间分离倾向的物质，“不完整”(Ge4Sb12)4−和“完整”(Ge4Sb14)4−，经 DFT 计算证实并由 Stefanie Dehnen 等人在他们的研究文章（e202207232）中描述。

85.A ball-milling approach allows the efficient activation of calcium metal and thus makes the direct generation of calcium-based heavy Grignard reagents feasible without complicated pre-activation processes. By using this operationally simple method, Koji Kubota, Hajime Ito, and co-workers developed a novel cross-electrophile-coupling reaction mediated by arylcalcium nucleophiles in their Research Article (e202207118), which is typically difficult using conventional Grignard reagents.

球磨方法可以有效活化钙金属，从而无需复杂的预活化过程即可直接生成钙基重格氏试剂。通过使用这种操作简单的方法，Koji Kubota、Hajime Ito 和同事在他们的研究文章 (e202207118) 中开发了一种由芳基钙亲核试剂介导的新型交叉亲电子偶联反应，这通常很难使用传统的格氏试剂实现。

86.A self-assembled glucose oxidase (GOx) nanoparticle that falls into the sea and dissociates into several enzymes is depicted in the picture illustrating the Research Article by Peng Huang and co-workers (e202208583). After dissociation, GOx regains its catalytic activity and catalyzes the oxidization of glucose into gluconic acid and H2O2. It's like someone pressing the “OFF-to-H2O2” switch that crosses the sea surface.

Peng Huang 及其同事的研究文章 (e202208583) 的图片中描绘了一种自组装的葡萄糖氧化酶 (GOx) 纳米颗粒，它落入海中并分解成多种酶。解离后，GOx恢复催化活性，催化葡萄糖氧化成葡萄糖酸和H2O2。这就像有人按下“OFF-to-H2O2”开关，穿越海面。

87.The fast and the furious: A computational DFT booster to accelerate cysteine bioconjugation: In their Research Article (202205348), Mu-Hyun Baik, Christian P. R. Hackenberger, and co-workers introduce ethynyl-triazolyl-phosphinates (ETPs) as modular electrophiles for the straightforward incorporation into complex payloads and proteins for modular protein- and antibody-modification strategies (cover picture: Barth van Rossum, FMP).

速度与激情：加速半胱氨酸生物共轭的计算 DFT 助推器：在他们的研究文章 (202205348) 中，Mu-Hyun Baik、Christian P. R. Hackenberger 及其同事介绍了乙炔基三唑基次膦酸盐 (ETP) 作为模块化亲电子试剂，用于直接融入复杂的有效负载和蛋白质中，以实现模块化蛋白质和抗体修饰策略（封面图片：Barth van Rossum，FMP）。

88.Heterogeneous Catalysis. In their Communication (e202207777), Patrick Hemberger et al. employed PEPICO spectroscopy to identify ketene and methylketene intermediates in methyl acetate conversion over the HZSM-5 zeolite.

多相催化。Patrick Hemberger 等人在他们的通讯 (e202207777) 中采用 PEPICO 光谱法鉴定 HZSM-5 沸石上乙酸甲酯转化中的乙烯酮和甲基乙烯酮中间体。

89.Membranes. In their Research Article (e202206152), Jian Xue, Jürgen Caro, Haihui Wang et al. report a bioinspired Ti3C2Tx MXene-based ionic diode membrane for osmotic energy conversion with extraordinary ionic rectification.

膜。Jian Xu、Jürgen Caro、Haihui Wang 等人在他们的研究文章 (e202206152) 中报告了一种基于 Ti3C2TX MXene 的仿生离子二极管膜，用于通过非凡的离子整流进行渗透能量转换。

90.Small-Molecule Quenchers for Förster Resonance Energy Transfer: Structure, Mechanism, and Applications.

用于福斯特共振能量转移的小分子猝灭剂：结构、机制和应用。

91.Tailoring Bond Microenvironments and Reaction Pathways of Single-Atom Catalysts for Efficient Water Electrolysis.

定制单原子催化剂的键微环境和反应途径以实现高效水电解。

92.Bioinspired Ti3C2Tx MXene-Based Ionic Diode Membrane for High-Efficient Osmotic Energy Conversion.

基于仿生 Ti3C2TX MXene 的离子二极管膜，用于高效渗透能转换。

93.DFT-Guided Discovery of Ethynyl-Triazolyl-Phosphinates as Modular Electrophiles for Chemoselective Cysteine Bioconjugation and Profiling.

DFT 引导发现乙炔基三唑基次膦酸盐作为化学选择性半胱氨酸生物共轭和分析的模块化亲电子试剂。

94.Synergistic Charge Percolation in Conducting Polymers Enables High-Performance In Vivo Sensing of Neurochemical and Neuroelectrical Signals.

导电聚合物中的协同电荷渗透可实现神经化学和神经电信号的高性能体内传感。

95.A Long-Circulating Vector for Aptamers Based upon Polyphosphodiester-Backboned Molecular Brushes.

基于多磷酸二酯主链分子刷的适配体长循环载体。

96.Tandem Electrochemical Oxidative Azidation/Heterocyclization of Tryptophan-Containing Peptides under Buffer Conditions.

缓冲条件下含色氨酸肽的串联电化学氧化叠氮化/杂环化。

97.Programming and Dynamic Control of the Circular Polarization of Luminescence from an Achiral Fluorescent Dye in a Liquid Crystal Host by Molecular Motors.

通过分子马达对液晶主体中非手性荧光染料发光的圆偏振进行编程和动态控制。