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【标题速读】【Angew】【2022年】【5月】

2023-08-17 00:07 作者:Rt_Cola  | 我要投稿

声明:本专栏主要对生命科学领域的一些期刊文章标题进行翻译,所有内容均由本人手工整理翻译。由于本人专业为生物分析相关,其他领域如果出现翻译错误请谅解。

1.Metal alloy superlattices with large volume asymmetry were constructed based on self-sorting assembly of binary giant shape amphiphiles, as reported by Zebin Su, Stephen Z. D. Cheng et al. in their Research Article (e202200637). MgZn2, NaZn13, and CaCu5 superlattices were observed in soft matters, and the thermodynamic origin of their formation was quantitatively analyzed.

Zebin Su、Stephen Z. D. Cheng 等人在他们的研究文章(e202200637)中报道,基于二元巨形两亲物的自排序组装,构建了具有大体积不对称性的金属合金超晶格。在软物质中观察到 MgZn2、NaZn13 和 CaCu5 超晶格,并定量分析了它们形成的热力学起源。

2.A molecular motor setup that allows harnessing the trajectory of directional motor rotation for an active mechanical threading process is presented by Henry Dube and co-workers in their Research Article (e202201882). The motor is embedded into a macrocycle and its indane-based rotor fragment then serves as a “revolving door” in the light-driven rotation. In this way a process akin to macroscopic threading of a needle is miniaturized to the molecular level, offering a first entry point to mechanical molecular knitting or weaving processes.

Henry Dube 及其同事在他们的研究文章 (e202201882) 中提出了一种分子电机设置,该设置允许利用定向电机旋转轨迹来实现主动机械穿线过程。电机嵌入大循环中,其基于茚满的转子碎片在光驱动旋转中充当“旋转门”。通过这种方式,类似于宏观穿针的过程被微型化到分子水平,为机械分子针织或编织过程提供了第一个切入点。

3.The Ugi four-component reaction (Ugi-4CR) was applied by Andreas Herrmann, Thorben Cordes, and co-workers in their Research Article (e202112959) to synthesize a library of linker molecules (illustrated as the ESA space gateway) to link biological targets (the space shuttle) to commercially available fluorescent dyes (the Orion service modules). The modular design of the Ugi-4CR allows the addition of different functional groups to the linkers, which in turn alter the properties of the fluorophore. Functional groups were introduced that turned a variety of fluorophores into highly stable self-healing dyes or metal-chelating dyes during biolabelling.

Andreas Herrmann、Thorben Cordes 及其同事在他们的研究文章 (e202112959) 中应用 Ugi 四组分反应 (Ugi-4CR) 来合成连接分子库(如 ESA 空间网关所示)以连接生物靶标(航天飞机)到市售荧光染料(猎户座服务模块)。 Ugi-4CR 的模块化设计允许向接头添加不同的官能团,从而改变荧光团的特性。引入官能团,在生物标记过程中将各种荧光团转化为高度稳定的自修复染料或金属螯合染料。

4.A game of two halves Direct ammonia oxidation unlocks a pathway towards affordable and efficient production of nitrous oxide, a highly promising agent for selective oxidation reactions, but necessitates the development of suitable catalysts. In their Research Article (e202200772), Javier Pérez-Ramírez and co-workers demonstrate that the synergistic interaction between Au nanoparticles and CeO2 support results in a material with unprecedented levels of N2O selectivity and productivity, far surpassing state-of-the-art systems.

两半的游戏直接氨氧化开启了一条经济高效生产一氧化二氮的途径,一氧化二氮是一种非常有前途的选择性氧化反应试剂,但需要开发合适的催化剂。 Javier Pérez-Ramírez 及其同事在他们的研究文章 (e202200772) 中证明,Au 纳米粒子和 CeO2 载体之间的协同相互作用导致材料具有前所未有的 N2O 选择性和生产率,远远超过最先进的系统。

5.RNA In their Communication (e202115481), Kevin Pagel et al. use cryogenic gas-phase infrared spectroscopy to study the key intermediate of RNA autohydrolysis.

RNA。在Kevin Pagel 等人的通讯中 (e202115481),他们利用低温气相红外光谱研究RNA自水解的关键中间体。

6.Asymmetric Catalysis Tetrasubstituted thiiranes can be synthesized by an asymmetric catalytic (2+1) cycloaddition of thioketones as reported by Xiaohua Liu, Yun-Dong Wu, Xiaoming Feng et al. in their Research Article (e202201151).

不对称催化。四取代硫杂丙环可以通过硫酮的不对称催化(2+1)环加成反应合成,如Xiaohua Liu、Yun-Dong Wu、Xiaoming Feng等人在他们的研究文章(e202201151)中报道的。

7.From Structural Design to Functional Construction: Amine Molecules in High-Performance Formamidinium-Based Perovskite Solar Cells.

从结构设计到功能构建:高性能甲脒基钙钛矿太阳能电池中的胺分子。

8.Asymmetric Catalytic (2+1) Cycloaddition of Thioketones to Synthesize Tetrasubstituted Thiiranes.

硫酮的不对称催化 (2+1) 环加成合成四取代硫杂丙环。

9.DREAMTIME NMR Spectroscopy: Targeted Multi-Compound Selection with Improved Detection Limits.

DREAMTIME NMR 光谱:具有改进的检测限的靶向多化合物选择。

10.Linker Molecules Convert Commercial Fluorophores into Tailored Functional Probes during Biolabelling.

连接分子在生物标记过程中将商业荧光团转化为定制的功能探针。

11.Asymmetrical-Dendronized TADF Emitters for Efficient Non-doped Solution-Processed OLEDs by Eliminating Degenerate Excited States and Creating Solely Thermal Equilibrium Routes.

通过消除简并激发态和创建单独的热平衡路线,用于高效非掺杂溶液加工 OLED 的不对称树枝化 TADF 发射器。

12.Construction of an Autocatalytic Hybridization Assembly Circuit for Amplified In Vivo MicroRNA Imaging.

用于放大体内 MicroRNA 成像的自催化杂交组装电路的构建。

13.Multiple Emission of Phosphonium Fluorophores Harnessed by the Pathways of Photoinduced Counterion Migration.

通过光诱导抗衡离子迁移途径利用磷荧光团的多次发射。

14.Highly Efficient Conversion of Propargylic Alcohols and Propargylic Amines with CO2 Activated by Noble-Metal-Free Catalyst Cu2O@ZIF-8.

无贵金属催化剂 Cu2O@ZIF-8 活化 CO2 高效转化丙炔醇和丙炔胺。

15.Ceria-Supported Gold Nanoparticles as a Superior Catalyst for Nitrous Oxide Production via Ammonia Oxidation.

氧化铈支持的金纳米颗粒作为氨氧化生产一氧化二氮的优质催化剂。

16.Integrated Ring-Chain Design of a New Fluorinated Ether Solvent for High-Voltage Lithium-Metal Batteries.

用于高压锂金属电池的新型氟化醚溶剂的集成环链设计。

17.Design of Near-Infrared Nonfullerene Acceptor with Ultralow Nonradiative Voltage Loss for High-Performance Semitransparent Ternary Organic Solar Cells.

用于高性能半透明三元有机太阳能电池的具有超低非辐射电压损耗的近红外非富勒烯受体设计。

18.Site-Specific Protein Modification with Reducing Carbohydrates.

通过减少碳水化合物进行位点特异性蛋白质修饰。

19.Soluble and Perfluorinated Polyelectrolyte for Safe and High-Performance Li−O2 Batteries.

用于安全高性能锂氧电池的可溶性全氟化聚电解质。

20.A Self-Serviced-Track 3D DNA Walker for Ultrasensitive Detection of Tumor Exosomes by Glycoprotein Profiling.

自助跟踪 3D DNA Walker,用于通过糖蛋白分析对肿瘤外泌体进行超灵敏检测。

21.Regio- and Enantioselective γ-Allylic Alkylation of In Situ-Generated Free Dienolates via Scandium/Iridium Dual Catalysis.

通过钪/铱双重催化原位生成的游离二烯醇盐的区域选择性和对映选择性γ-烯丙基烷基化。

22.Reversibly Photoswitching Upconversion Nanoparticles for Super-Sensitive Photoacoustic Molecular Imaging.

用于超灵敏光声分子成像的可逆光开关上转换纳米粒子。

23.A Two-Phase Approach to Fusicoccane Synthesis To Uncover a Compound That Reduces Tumourigenesis in Pancreatic Cancer Cells.

一种两阶段合成 Fusicoccane 的方法,以发现一种可减少胰腺癌细胞肿瘤发生的化合物。

24.Metal–Organic Cages with {SiW9Ni4} Polyoxotungstate Nodes.

具有 {SiW9Ni4} 多钨酸盐节点的金属有机保持架。

25.A Rational Biphasic Tailoring Strategy Enabling High-Performance Layered Cathodes for Sodium-Ion Batteries.

合理的双相定制策略可实现钠离子电池的高性能层状阴极。

26.Predicting the Solubility of Inorganic Ion Pairs in Water.

预测无机离子对在水中的溶解度。

27.A pH-Responsive Nanoparticle Library with Precise pH Tunability by Co-Polymerization with Non-Ionizable Monomers.

通过与不可电离单体共聚合而具有精确 pH 可调性的 pH 响应纳米颗粒库。

28.Characterization of Multifunctional and Non-stereoselective Oxidoreductase RubE7/IstO, Expanding the Functional Diversity of the Flavoenzyme Superfamily.

多功能和非立体选择性氧化还原酶 RubE7/IstO 的表征,扩展黄酶超家族的功能多样性。

29.Tailoring a Nanochaperone to Regulate α-Synuclein Assembly.

定制纳米伴侣来调节 α-突触核蛋白组装。

30.Selective Electrooxidation of Biomass-Derived Alcohols to Aldehydes in a Neutral Medium: Promoted Water Dissociation over a Nickel-Oxide-Supported Ruthenium Single-Atom Catalyst.

在中性介质中将生物质衍生的醇选择性电氧化为醛:在氧化镍负载的钌单原子催化剂上促进水解离。

31.Molecularly Engineered Covalent Organic Frameworks for Hydrogen Peroxide Photosynthesis.

用于过氧化氢光合作用的分子工程共价有机框架。

32.Reconfiguration and Reorganization of Bottlebrush Polymer Surfactants.

洗瓶刷聚合物表面活性剂的重新配置和重组。

33.Soft Alloys Constructed with Distinct Mesoatoms via Self-Sorting Assembly of Giant Shape Amphiphiles.

通过巨型两亲物的自排序组装,用不同的介原子构建软合金。

34.Emissive Platinum(II) Macrocycles as Tunable Cascade Energy Transfer Scaffolds.

发射性铂 (II) 大环化合物作为可调级联能量转移支架。

35.A Pair of Atypical KAS III Homologues with Initiation and Elongation Functions Program the Polyketide Biosynthesis in Asukamycin.

一对具有起始和延伸功能的非典型 KAS III 同系物编程明日香霉素中的聚酮化合物生物合成。

36.Cystine Knot Peptides with Tuneable Activity and Mechanism.

具有可调节活性和机制的胱氨酸结肽。

37.Insights into Dynamic Surface Bromide Sites in Bi4O5Br2 for Sustainable N2 Photofixation.

深入了解 Bi4O5Br2 中用于可持续 N2 光固定的动态表面溴化物位点。

38.Theoretical Optimization of Compositions of High-Entropy Oxides for the Oxygen Evolution Reaction.

用于析氧反应的高熵氧化物成分的理论优化。

39.Fluorination and Betaine Modification Augment the Blood–Brain Barrier-Crossing Ability of Cylindrical Polymer Brushes.

氟化和甜菜碱改性增强了圆柱形聚合物刷的血脑屏障穿越能力。

40.Stereoselective Synthesis of Atropisomeric Acridinium Salts by the Catalyst-Controlled Cyclization of ortho-Quinone Methide Iminiums.

通过邻醌甲基亚胺的催化剂控制环化立体选择性合成阻转异构吖啶鎓盐。

41.NIRII-HDs: A Versatile Platform for Developing Activatable NIR-II Fluorogenic Probes for Reliable In Vivo Analyte Sensing.

NIRII-HD:用于开发可激活 NIR-II 荧光探针以实现可靠的体内分析物传感的多功能平台。

42.Active Mechanical Threading by a Molecular Motor.

分子马达主动机械螺纹。

43.Superhydrophilic 2D Covalent Organic Frameworks as Broadband Absorbers for Efficient Solar Steam Generation.

超亲水二维共价有机框架作为宽带吸收剂,用于高效太阳能蒸汽产生。

44.Environmentally Benign Biosynthesis of Hierarchical MOF/Bacterial Cellulose Composite Sponge for Nerve Agent Protection.

用于神经毒剂保护的多级 MOF/细菌纤维素复合海绵的环境良性生物合成。

45.Characterization of a Nitrogenase Iron Protein Substituted with a Synthetic [Fe4Se4] Cluster.

用合成 [Fe4Se4] 簇取代的固氮酶铁蛋白的表征。

46.A Crystalline Partially Fluorinated Triazine Covalent Organic Framework for Efficient Photosynthesis of Hydrogen Peroxide.

用于过氧化氢高效光合作用的结晶部分氟化三嗪共价有机框架。

47.Pillararene-Induced Intramolecular Through-Space Charge Transfer and Single-Molecule White-Light Emission.

柱芳烯诱导的分子内空间电荷转移和单分子白光发射。

48.Structurally Disordered RuO2 Nanosheets with Rich Oxygen Vacancies for Enhanced Nitrate Electroreduction to Ammonia.

具有丰富氧空位的结构无序 RuO2 纳米片,用于增强硝酸盐电还原至氨。

49.Studying the Key Intermediate of RNA Autohydrolysis by Cryogenic Gas-Phase Infrared Spectroscopy.

利用低温气相红外光谱研究RNA自水解的关键中间体。

50.MOF Synthesis Prediction Enabled by Automatic Data Mining and Machine Learning.

自动数据挖掘和机器学习支持 MOF 合成预测。

51.Estimating Phosphorescent Emission Energies in IrIII Complexes Using Large-Scale Quantum Computing Simulations.

使用大规模量子计算模拟估算 IrIII 配合物中的磷光发射能量。

52.Organoplatinum Compounds as Anion-Tuneable Uphill Hydroxide Transporters.

有机铂化合物作为阴离子可调的上坡氢氧化物转运蛋白。

53.Designing a Network of Crystalline Polymers for a Scalable, Nonfluorinated, Healable and Amphiphobic Solid Slippery Interface.

设计用于可扩展、非氟化、可修复和双疏固体光滑界面的结晶聚合物网络。

54.Zinc-Promoted ZnMe/ZnPh Exchange in Eight-Coordinate [Ru(PPh3)2(ZnMe)4H2].

锌促进八配位 ZnMe/ZnPh 交换 [Ru(PPh3)2(ZnMe)4H2]。

55.Bioinspired Total Synthesis of Erectones A and B, and the Revised Structure of Hyperelodione D.

Electones A 和 B 的仿生全合成,以及 Hyperelodione D 的改进结构。

56.Reductant-Free Cross-Electrophile Synthesis of Di(hetero)arylmethanes by Palladium-Catalyzed Desulfinative C−C Coupling.

钯催化脱硫 C−C 偶联无还原剂交叉电试剂合成二(杂)芳基甲烷。

57.ATP-Induced Emergent Circularly Polarized Luminescence and Encryption.

ATP 诱导的紧急圆偏振发光和加密。

58.Chiral Symmetry Breaking of Monoacylated Anhydroerythritols and meso-1,2-Diols through Crystallization-Induced Deracemization.

通过结晶诱导的去消旋作用打破单酰化脱水赤藓糖醇和内消旋 1,2-二醇。

59.Iridium-Catalyzed Enantioselective C(sp3)−H Borylation of Aminocyclopropanes.

铱催化氨基环丙烷的对映选择性 C(sp3)−H 硼化。

60.Self-Regulating Colloidal Co-Assemblies That Accelerate Their Own Destruction via Chemo-Structural Feedback.

通过化学结构反馈加速自身破坏的自我调节胶体联合组件。

61.Catalytic Enantioselective Pictet–Spengler Reaction of α-Ketoamides Catalyzed by a Single H-Bond Donor Organocatalyst.

单一氢键供体有机催化剂催化 α-酮酰胺的催化对映选择性 Pictet-Spengler 反应。

62.Discovery of Two Polymorphs of TiP4N8 Synthesized from Binary Nitrides.

由二元氮化物合成的 TiP4N8 的两种多晶型物的发现。

63.A series of sulfur species prodrugs (reactive sulfur species in a capsule) that can release pure hydrogen sulfide (H2S) and hydrogen persulfide (H2S2) was used by Bowen Ke et al. in their Communication (e202201668) to compare the pharmacological differences between sulfide and persulfide. The H2S2 prodrug exhibits increased activities and reduced toxicity as compared to the H2S prodrug in vivo, indicating persulfide might represent a better therapeutic paradigm than H2S.

Bowen Ke等人使用了一系列能够释放纯硫化氢(H2S)和过硫化氢(H2S2)的硫物质前药(胶囊中的活性硫物质)。在他们的通讯(e202201668)中比较了硫化物和过硫化物之间的药理学差异。与H2S前药相比,H2S2前药在体内表现出增加的活性和降低的毒性,表明过硫化物可能代表比H2S更好的治疗范例。

64.A visible-light-promoted iterative synthesis of 2-deoxyoligosaccharides is reported by De-Cai Xiong, Xin-Shan Ye, and co-workers in their Research Article (e202114726). The rapid constructions of oligosaccharides, 20-mer deoxyglycan, and digoxin are facilitated by a bromide-based hydrogen species through an electron transfer process.

De-Cai Xiong、Xin-Shan Ye 及其同事在他们的研究文章 (e202114726) 中报道了可见光促进的 2-脱氧寡糖的迭代合成。溴化物氢物质通过电子转移过程促进寡糖、20 聚体脱氧聚糖和地高辛的快速构建。

65.Mechanical properties of nanogels influence their cellular fate. Inspired by the natural ability of the cells to sense stiffness, Smriti Singh et al. in their Research Article (e202116653) developed highly hydrophilic soft nanogels and show that the passive engulfment of the soft nanogels by the immune cells was drastically reduced compared to the stiffer counterpart. The delayed uptake resulted in an enhanced circulation time of the nanogels, an important criterion for drug delivery applications.

纳米凝胶的机械特性影响其细胞命运。受到细胞感知刚度的自然能力的启发,Smriti Singh 等人。在他们的研究文章(e202116653)中开发了高度亲水性的软纳米凝胶,并表明与较硬的对应物相比,免疫细胞对软纳米凝胶的被动吞噬大大减少。延迟吸收导致纳米凝胶的循环时间延长,这是药物输送应用的一个重要标准。

66.Sugar nucleotides are essential glycosylation donors in carbohydrate metabolism. In their Research Article (e202115696), Liuqing Wen and co-workers developed a general strategy for the efficient preparation of rare sugar nucleotides. Complex de novo biosynthesis of rare sugar nucleotides was recognized as cascade reactions. The cascade reactions were driven toward the formation of the target sugar nucleotides through a cofactor regeneration system (CRS), thus resulting in clean conversion.

糖核苷酸是碳水化合物代谢中必需的糖基化供体。在他们的研究文章(e202115696)中,刘庆文及其同事制定了有效制备稀有糖核苷酸的总体策略。稀有糖核苷酸的复杂从头生物合成被认为是级联反应。通过辅因子再生系统(CRS)驱动级联反应形成目标糖核苷酸,从而实现干净的转化。

67.Photocatalysis In their Communication (e202202079), Masaichi Saito, Stephan Kupfer, Benjamin Dietzek-Ivanšić, Wolfgang Weigand et al. utilize a precious metal-free photocatalyst consisting of a [FeFe] hydrogenase mimic for hydrogen generation under visible light.

通信中的光催化 (e202202079),Masaichi Saito、Stephan Kupfer、Benjamin Dietzek-Ivanšić、Wolfgang Weigand 等人。利用由 [FeFe] 氢化酶模拟物组成的不含贵金属的光催化剂在可见光下产生氢气。

68.Challenges, Prospects, and Emerging Applications of Inkjet-Printed Electronics: A Chemist's Point of View.

喷墨印刷电子产品的挑战、前景和新兴应用:化学家的观点。

69.Design and Synthesis of Tunable Chiral 2,2′-Bipyridine Ligands: Application to the Enantioselective Nickel-Catalyzed Reductive Arylation of Aldehydes.

可调手性 2,2'-联吡啶配体的设计与合成:在对映选择性镍催化醛还原芳基化中的应用。

70.Highly Stable and Reactive Platinum Single Atoms on Oxygen Plasma-Functionalized CeO2 Surfaces: Nanostructuring and Peroxo Effects.

氧等离子体功能化 CeO2 表面上高度稳定和反应活性的铂单原子:纳米结构和过氧化物效应。

71.Iterative Synthesis of 2-Deoxyoligosaccharides Enabled by Stereoselective Visible-Light-Promoted Glycosylation.

通过立体选择性可见光促进糖基化迭代合成 2-脱氧寡糖。

72.Cofactor-Driven Cascade Reactions Enable the Efficient Preparation of Sugar Nucleotides.

辅因子驱动的级联反应能够有效制备糖核苷酸。

73.Non-binary Encoded Nucleic Acid Barcodes Directly Readable by a Nanopore.

纳米孔可直接读取的非二进制编码核酸条形码。

74.Shell-like Xenon Nano-Traps within Angular Anion-Pillared Layered Porous Materials for Boosting Xe/Kr Separation.

角阴离子柱层状多孔材料中的壳状氙纳米陷阱可促进 Xe/Kr 分离。

75.Tuning the Elasticity of Nanogels Improves Their Circulation Time by Evading Immune Cells.

调整纳米凝胶的弹性可以通过逃避免疫细胞来改善其循环时间。

76.Spatially Resolved, Error-Robust Multiplexed MicroRNA Profiling in Single Living Cells.

单个活细胞中空间分辨、误差稳健的多重 MicroRNA 分析。

77.Reversible Three-Color Fluorescence Switching of an Organic Molecule in the Solid State via “Pump–Trigger” Optical Manipulation.

通过“泵浦触发”光学操作实现固态有机分子的可逆三色荧光切换。

78.A Heterogeneous Palladium Catalyst for the Polymerization of Olefins Prepared by Halide Abstraction Using Surface R3Si+ Species.

使用表面 R3Si+ 物质通过卤化物提取制备烯烃聚合的多相钯催化剂。

79.Structural Basis for the Prenylation Reaction of Carbazole-Containing Natural Products Catalyzed by Squalene Synthase-Like Enzymes.

角鲨烯合酶类酶催化含咔唑天然产物异戊二烯化反应的结构基础。

80.Conjugated Polyelectrolyte-Based Complex Fluids as Aqueous Exciton Transport Networks.

作为水激子传输网络的共轭聚电解质复合流体。

81.Widefield SERS for High-Throughput Nanoparticle Screening.

用于高通量纳米粒子筛选的宽场 SERS。

82.Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis.

双钯/光氧化还原催化实现二烯醇醚的区域、非对映和对映选择性脱羧氢氨烷基化。

83.Iridium-Catalyzed Asymmetric Allylic Substitution of Methyl Azaarenes.

铱催化甲基氮杂芳烃的不对称烯丙基取代。

84.Real-Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self-Assembly of Atom-Precise Cu8 Nanocluster.

原子精确 Cu8 纳米团簇动力学控制超分子自组装的实时荧光监测。

85.A New Platform of B/N-Doped Cyclophanes: Access to a π-Conjugated Block-Type B3N3 Macrocycle with Strong Dipole Moment and Unique Optoelectronic Properties.

B/N 掺杂环烷的新平台:获得具有强偶极矩和独特光电特性的 π 共轭嵌段型 B3N3 大环化合物。

86.Single-Vesicle Electrochemistry Following Repetitive Stimulation Reveals a Mechanism for Plasticity Changes with Iron Deficiency.

重复刺激后的单囊泡电化学揭示了缺铁时可塑性变化的机制。

87.Solvent-Controlled Condensation of [Mo2O5(PTC4A)2]6− Metalloligand in Stepwise Assembly of Hexagonal and Rectangular Ag18 Nanoclusters.

六角形和矩形 Ag18 纳米团簇逐步组装中 [Mo2O5(PTC4A)2]6− 金属配体的溶剂控制缩合。

88.Boosted Inner Surface Charge Transfer in Perovskite Nanodots@Mesoporous Titania Frameworks for Efficient and Selective Photocatalytic CO2 Reduction to Methane.

增强钙钛矿纳米点@介孔二氧化钛框架的内表面电荷转移,实现高效、选择性光催化二氧化碳还原为甲烷。

89.Ratiometric and Colorimetric Optical Thermometers Using Emissive Dimeric and Trimeric {[Au(SCN)2]−}n Moieties Generated in d–f Heterometallic Assemblies.

使用 d–f 异金属组件中生成的发射二聚和三聚 {[Au(SCN)2]−}n 部分的比率和比色光学温度计。

90.Modification of Nitrate Ion Enables Stable Solid Electrolyte Interphase in Lithium Metal Batteries.

硝酸根离子的修饰可实现锂金属电池中稳定的固体电解质界面。

91.Synthesis of Axially Chiral N-Arylindoles via Atroposelective Cyclization of Ynamides Catalyzed by Chiral Brønsted Acids.

手性布朗斯台德酸催化的酰胺选择性环化合成轴向手性 N-芳基吲哚。

92.Modular Generation of (Iodinated) Polyarenes Using Triethylgermane as Orthogonal Masking Group.

使用三乙基锗烷作为正交掩蔽基团模块化生成(碘化)聚芳烃。

93.A Water-Soluble Highly Oxidizing Cobalt Molecular Catalyst Designed for Bioinspired Water Oxidation.

一种水溶性高氧化性钴分子催化剂,专为仿生水氧化而设计。

94.Metal-Insulator-Semiconductor Anodes for Ultrastable and Site-Selective Upconversion Photoinduced Electrochemiluminescence.

用于超稳定和位点选择性上转换光致电化学发光的金属-绝缘体-半导体阳极。

95.Disproportionation of Nitric Oxide at a Surface-Bound Nickel Porphyrinoid.

一氧化氮在表面结合的镍卟啉上的歧化。

96.Oxidase-Type C−H/C−H Coupling Using an Isoquinoline-Derived Organic Photocatalyst.

使用异喹啉衍生的有机光催化剂进行氧化酶型 C−H/C−H 偶联。

97.Manganese-Catalyzed Asymmetric Hydrogenation of 3H-Indoles.

锰催化 3H-吲哚的不对称氢化。

98.Rhodaelectro-Catalyzed peri-Selective Direct Alkenylations with Weak O-Coordination Enabled by the Hydrogen Evolution Reaction (HER).

通过析氢反应 (HER) 实现弱 O 配位的 Rhoda 电催化近选择性直接烯基化。

99.Distal Ruthenaelectro-Catalyzed meta-C−H Bromination with Aqueous HBr.

使用 HBr 水溶液进行远端钌电催化间位 C−H 溴化。

100.A Symmetry-Based Kinematic Theory for Nanocrystal Morphology Design.

用于纳米晶体形态设计的基于对称的运动学理论。

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【标题速读】【Angew】【2022年】【5月】的评论 (共 条)

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