【标题速读】【JACS】【2022年】【12月】

2023-06-14 16:41 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

Cocaine is a time-honored local anesthetic. We report its near-complete biosynthesis and clarify the unexpected intermediate ecgonone for constructing the tropane skeleton in cocaine, which illustrates the beauty of Robison's biomimetic tropinone synthesis. The de novo biosynthesis of cocaine in tobacco is then realized, entailing significant implications for pharmaceutical production.

可卡因是一种历史悠久的局部麻醉剂。我们报告了其接近完成的生物合成，并阐明了意想不到的中间体芽子酮，用于构建可卡因中的托品酮骨架，这说明了罗宾逊仿生托品酮合成的美妙之处。然后实现了烟草中可卡因的从头生物合成，这对药物生产具有重要意义。

Design and synthesis of bench-stable 1,5-diiodobicyclo[3.1.1]heptane opens up facile access to a largely unexplored chemical species, [3.1.1]propellane. Uncovering its reactivity in turn enables convenient synthesis of various bicyclo[3.1.1]heptanes that are attracting attention in the field of drug discovery as potent bioisosteres of meta-substituted benzenes.

实验室稳定的 1,5-二碘双环 [3.1.1] 庚烷的设计和合成开辟了对很大程度上未开发的化学物种 [3.1.1] 丙烷的便捷途径。揭示其反应性反过来又可以方便地合成各种双环 [3.1.1] 庚烷，这些双环 [3.1.1] 庚烷作为间位取代苯的有效生物电子等排物在药物发现领域引起了人们的关注。

Liquid-ordered (Lo)/liquid-disordered (Ld) phase-coexisting vesicles were transferred to the solid support with microcavities for reconstructing pore-spanning lipid membranes. Accompanied by simulation, suppressed water permeation across the Lo domain was experimentally verified via spatiotemporal tracking of the fluorescent molecules under microcavities passivated by lipid membranes.

液体有序 (Lo)/液体无序 (Ld) 相共存囊泡被转移到具有微腔的固体支持物上，用于重建跨孔脂质膜。伴随着模拟，通过在脂质膜钝化的微腔下荧光分子的时空跟踪，实验验证了 Lo 域的水渗透受到抑制。

Platinum nanoclusters on a graphene catalytic condenser are programmed in their electron density via external voltage to modulate the binding energy and reactivity of molecules on the platinum surface.

石墨烯催化冷凝器上的铂纳米团簇通过外部电压对其电子密度进行编程，以调节铂表面分子的结合能和反应性。

We introduce a conditional and cell-selective genome editing system, termed enzyme-inducible CRISPR (eiCRISPR). eiCRISPR comprises Cas9 protein, a self-blocked inactive single-guide RNA (bsgRNA), and a chemically caged deoxyribozyme (DNAzyme) that activates bsgRNA and eiCRISPR in response to disease-associated enzyme for cancer cell-selective genome editing in vitro and in vivo.

我们介绍了一种条件和细胞选择性基因组编辑系统，称为酶诱导 CRISPR (eiCRISPR)。 eiCRISPR 包含 Cas9 蛋白、一种自我阻断的无活性单向导 RNA (bsgRNA) 和一种化学笼状脱氧核酶 (DNAzyme)，可激活 bsgRNA 和 eiCRISPR 以响应疾病相关酶，从而在体外和体内对癌细胞进行选择性基因组编辑。

Generation and collection of reproducible, quantitative surface-enhanced Raman scattering (SERS) signals have been major challenges for the widespread and practical use of Raman spectra. Here, we provide the multiscale perspectives on plasmonic nanoparticle systems that range from atomic to assembled nanostructure scales as well as emerging statistical and artificial intelligence approaches for analyzing SERS signals to realize quantitative SERS.

生成和收集可重现的定量表面增强拉曼散射 (SERS) 信号一直是拉曼光谱广泛和实际使用的主要挑战。在这里，我们提供了从原子到组装纳米结构尺度的等离子体纳米粒子系统的多尺度视角，以及用于分析 SERS 信号以实现定量 SERS 的新兴统计和人工智能方法。

Zhang and co-authors report the development of a selective activity-based probe for the secreted protease Kallikrein-related peptidase 6 (KLK6) by modular design. Probe IMP-2352 shows that selective inhibition of KLK6 reduces the invasiveness of pancreatic cancer cells and allows for the identification of potential KLK6 substrates.

Zhang 和合著者报告了一种基于选择性活性的探针的开发，该探针通过模块化设计用于分泌的蛋白酶激肽释放酶相关肽酶 6 (KLK6)。探针 IMP-2352 表明，选择性抑制 KLK6 可降低胰腺癌细胞的侵袭性，并允许识别潜在的 KLK6 底物。

A facile and universal strategy for the one-step synthesis of α-MoC1‒x established by introducing a trace amount of Rh. Key factors and the structural evolution during carburization in a “black box” are unlocked by plenty of in situ characterizations from different aspects, shedding light on regulating the phase transformation of carbides View the article.

通过引入痕量 Rh 建立了一种简单且通用的一步合成 α-MoC1-x 的策略。 “黑匣子”中渗碳过程中的关键因素和结构演化通过大量不同方面的原位表征得以解开，揭示了调节碳化物相变的方法查看文章。

We design a series of linear polymers with different side groups for further coordination-driven self-assembly. Such a design introduces a main-chain confinement, which effectively slows down the assembly process of metallotriangle side groups, thus allowing us to monitor the real-time evolution of non-equilibrium lychee-like nanostructures.

我们设计了一系列具有不同侧基的线性聚合物，用于进一步协调驱动的自组装。这种设计引入了主链限制，有效地减缓了金属三角形侧基的组装过程，从而使我们能够监测非平衡荔枝状纳米结构的实时演变。

A new precoordination confinement strategy has been developed to install isolated metal single atoms (M-SAs; M = Pt, Ir, Au, Ru) in the pore-confined nanospaces of the amino group grafted porphyrinic metal–organic framework (MOF) Pd-PCN-222-NH2. The resultant MOF composites M-SAs@Pd-PCN-222-NH2 display high efficiency in the photocatalytic hydrogen evolution reaction, giving a turnover number up to 21713 based on M-SAs under visible light irradiation (λ ≥ 420 nm).

开发了一种新的预配位限制策略，将孤立的金属单原子（M-SAs；M = Pt、Ir、Au、Ru）安装在氨基接枝卟啉金属有机骨架（MOF）Pd- PCN-222-NH2。由此产生的 MOF 复合材料 M-SAs@Pd-PCN-222-NH2 在光催化析氢反应中表现出高效率，在可见光照射下（λ≥420 nm），基于 M-SAs 的转换数高达 21713。

Phosphorus (P), an essential element, mainly adopts a +5 oxidation state in biomolecules on oxygen-rich Earth, while the form of biosignature PH3 gas appears in the exoplanet atmosphere. Here, we bridge the large gap between oxygen-sensitive phosphine (+3) ligands and metalloprotein chemistry based on E. coli.

磷（P）是一种必需元素，在富氧地球上的生物分子主要以+5氧化态存在，而在系外行星大气中则以生物特征PH3气体的形式出现。在这里，我们弥合了氧敏感膦 (+3) 配体和基于大肠杆菌的金属蛋白化学之间的巨大差距。

The QCaRA/AFIR method of a 52-atom natural product, endiandric acid C methyl ester, which was synthesized in a single step by Nicolaou in 1982, successfully traces the reaction back to the corresponding starting polyene only using the power of quantum chemical calculations.

Nicolaou 于 1982 年一步合成的 52 原子天然产物二苯二酸 C 甲酯的 QCaRA/AFIR 方法仅利用量子化学计算的力量成功地将反应追溯到相应的起始多烯。

Polarization-controlled coherent Raman microscopy can map 3D molecular orientations with sub-micrometer resolution. Imaging the 3D orientation of polymer chains allows for addressing the lamellar twisting mechanism in polyethylene spherulites.

偏振控制的相干拉曼显微镜可以绘制具有亚微米分辨率的 3D 分子方向。对聚合物链的 3D 方向进行成像可以解决聚乙烯球晶中的层状扭曲机制。

Sabatier principle defines the essential criteria for being an ideal catalyst in heterogeneous catalysis, while approaching the Sabatier optimal is a major pursuit in catalyst design. The ferromagnetic catalysts are able to be the Sabatier optimal of the Haber-Bosch process via a second-order ferromagnetic–paramagnetic phase transition.

Sabatier 原理定义了在多相催化中成为理想催化剂的基本标准，而接近 Sabatier 最优是催化剂设计的主要追求。铁磁催化剂能够通过二阶铁磁-顺磁相变成为 Haber-Bosch 过程的 Sabatier 最优。

A new class of discrete, chiral polymer–insulin conjugates is reported. These conjugates display composition and chirality-dependent blood glucose lowering effects in diabetic mice, suggesting that these molecular features of synthetic polymers can be tailored to optimize future polymer–protein conjugates.

报道了一类新的离散手性聚合物-胰岛素偶联物。这些结合物在糖尿病小鼠中显示出成分和手性依赖性血糖降低作用，表明可以定制合成聚合物的这些分子特征以优化未来的聚合物-蛋白质结合物。

Anion-binding catalytic system combining tripodal trithiourea with sodium thiophenolate enables the fast and selective anionic ring-opening polymerization of N-Carboxyanhydrides, leading to the precision construction of various polypeptides with living polymerization behavior. The high selectivity for propagation over deleterious side reactions correlates with enhanced stabilization of propagating carbamate anion.

结合三足三硫脲和苯硫酚钠的阴离子结合催化体系使 N-羧酸氢化物的快速和选择性阴离子开环聚合成为可能，从而精确构建具有活性聚合行为的各种多肽。对有害副反应的传播的高选择性与传播的氨基甲酸酯阴离子的稳定性增强相关。

This study exhibits a pathway for jet fuel production from renewable lignocellulose biomass derivatives. An anodic electrocatalysis route was employed to produce jet fuel precursors from biomass platform chemicals on Ni-based electrocatalysts in an aqueous electrolyte at room temperature and atmospheric pressure.

本研究展示了从可再生木质纤维素生物质衍生物生产喷气燃料的途径。在室温和大气压力下，采用阳极电催化途径在水性电解质中通过镍基电催化剂从生物质平台化学品生产喷气燃料前体。

A new class of BF2 formazanate dyes that can cross the blood–brain barrier has been developed for the NIR-II imaging of deep brain areas through the intact scalp and skull. These new NIR-II dyes will provide a new scaffold for the design of probes for brain imaging and therapy.

已经开发出一类可以穿过血脑屏障的新型 BF2 甲酸染料，用于通过完整的头皮和颅骨对深部脑区域进行 NIR-II 成像。这些新的 NIR-II 染料将为脑成像和治疗探针的设计提供新的支架。

The chiral seed, corannulene, and the chiral wall, pillar[5]arene, are docked and their chirality is fixed. All the subcomponents tilt in the same direction, generating the twisted cavitand with five-fold symmetry as a pair of enantiomers.

手性种子、环烯和手性壁、柱 [5] 芳烃对接，它们的手性是固定的。所有的子组分都向同一方向倾斜，从而产生具有五重对称性的扭曲空穴作为一对对映体。

1.Could the Quantum Internet Be Comprised of Molecular Spins with Tunable Optical Interfaces?.

量子互联网能否由具有可调光学界面的分子自旋组成？

2.Native Top-Down Mass Spectrometry with Collisionally Activated Dissociation Yields Higher-Order Structure Information for Protein Complexes.

具有碰撞激活解离的天然自上而下质谱法产生蛋白质复合物的高阶结构信息。

3.Bifunctional Compounds as Molecular Degraders for Integrin-Facilitated Targeted Protein Degradation.

双功能化合物作为整合素促进靶向蛋白质降解的分子降解剂。

4.From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid.

从生物质到功能性结晶金刚石纳米线：2,5-呋喃二甲酸的压力诱导聚合。

5.Pentosinane, a Post-Translational Modification of Human Proteins with Underappreciated Stability.

Pentosinane，一种稳定性被低估的人类蛋白质的翻译后修饰。

6.Practical and Facile Access to Bicyclo[3.1.1]heptanes: Potent Bioisosteres of meta-Substituted Benzenes.

双环 [3.1.1] 庚烷的实用和简便获取：间位取代苯的有效生物电子等排体。

7.Diazophosphane HPN2.

重氮磷 HPN2。

8.Iron-Catalyzed Intermolecular Amination of Benzylic C(sp3)–H Bonds.

铁催化的苄基 C(sp3)–H 键的分子间胺化。

9.Chemical Emulation of the Biosynthetic Route to Anthrasteroids: Synthesis of Asperfloketal A.

蒽甾类生物合成途径的化学模拟：Asperfloketal A 的合成。

10.Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN22– and CN2– Radical Ligands.

稳定双重去质子化的重氮甲烷：具有 CN22– 和 CN2– 自由基配体的可分离复合物。

11.Photochemical Ring-Opening Reaction of 1,3-Cyclohexadiene: Identifying the True Reactive State.

1,3-环己二烯的光化学开环反应：识别真实的反应状态。

12.In Vitro Membrane Platform for the Visualization of Water Impermeability across the Liquid-Ordered Phase under Hypertonic Conditions.

用于在高渗条件下通过液体有序相可视化水渗透性的体外膜平台。

13.Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs.

Conformer Ring Flip 增强了 ansa-Donor-Acceptor-Donor 机械变色扭转弹簧的机械变色性能。

14.Au Atoms Anchored on Amorphous C3N4 for Single-Site Raman Enhancement.

锚定在无定形 C3N4 上的 Au 原子用于单点拉曼增强。

15.AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units.

AIB3IIC3IIIQ8VI：通过耦合八面体和四面体单元设计红外非线性光学材料的新系列。

16.Controlling the Size of Au Nanoparticles on Reducible Oxides with the Electrochemical Potential.

用电化学势控制可还原氧化物上 Au 纳米粒子的尺寸。

17.Regulating DNA-Hybridization Using a Chemically Fueled Reaction Cycle.

使用化学燃料反应循环调节 DNA 杂交。

18.Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel(II) Complexes.

延长方形平面镍 (II) 配合物的金属到配体电荷转移激发态寿命的分子设计原则。

19.Clarifying the Relationship between the Lithium Deposition Coverage and Microstructure in Lithium Metal Batteries.

阐明锂金属电池中锂沉积覆盖率与微观结构之间的关系。

20.Study of an RNA-Focused DNA-Encoded Library Informs Design of a Degrader of a r(CUG) Repeat Expansion.

以 RNA 为中心的 DNA 编码文库的研究为r(CUG) 重复扩增降解剂的设计提供了信息。

21.Partially Oxidized Purely Organic Zwitterionic Neutral Radical Conductor: Multi-step Phase Transitions and Crossover Caused by Intra- and Intermolecular Electronic Interactions.

部分氧化的纯有机两性离子中性自由基导体：由分子内和分子间电子相互作用引起的多步相变和交叉。

22.Long-Wavelength Photoconvertible Dimeric BODIPYs for Super-Resolution Single-Molecule Localization Imaging in Near-Infrared Emission.

用于近红外发射超分辨率单分子定位成像的长波长光转换二聚体 BODIPY。

23.Discovery and Engineering of the Cocaine Biosynthetic Pathway.

可卡因生物合成途径的发现和工程。

24.Surface-Clean Au25 Nanoclusters in Modulated Microenvironment Enabled by Metal–Organic Frameworks for Enhanced Catalysis.

表面清洁的 Au25 纳米团簇在调制微环境中由金属有机框架启用以增强催化作用。

25.Surface Anion Promotes Pt Electrocatalysts with High CO Tolerance in Fuel-Cell Performance.

表面阴离子促进 Pt 电催化剂在燃料电池性能中具有高 CO 耐受性。

26.Photochemically Mediated Polymerization of Molecular Furan and Pyridine: Synthesis of Nanothreads at Reduced Pressures.

分子呋喃和吡啶的光化学介导聚合：在减压下合成纳米线。

27.Functional Water Networks in Fully Hydrated Photosystem II.

完全水化光系统 II 中的功能性水网络。

28.Photomechanical Motions in Organoboron-Based Phosphorescent Molecular Crystals Driven by a Crystal-State [2 + 2] Cycloaddition Reaction.

晶态 [2 + 2] 环加成反应驱动的有机硼基磷光分子晶体中的光机械运动。

29.Mesoscale Polymer Surfactants: Photolithographic Production and Localization at Droplet Interfaces.

中尺度聚合物表面活性剂：液滴界面的光刻生产和定位。

30.Discovery, Structure, and Mechanism of a Class II Sesquiterpene Cyclase.

II 类倍半萜环化酶的发现、结构和机制。

31.Atomically Dispersed Au-Assisted C–C Coupling on Red Phosphorus for CO2 Photoreduction to C2H6.

用于将 CO2 光还原为 C2H6 的红磷原子分散 Au 辅助 C-C 偶联。

32.Ultrafast Two-Dimensional Infrared Spectroscopy Resolved a Structured Lysine 159 on the Cytoplasmic Surface of the Microbial Photoreceptor Bacteriorhodopsin.

超快二维红外光谱法解析了微生物光感受器细菌视紫红质细胞质表面上的结构化赖氨酸 159。

33.Bridging Electrochemistry and Photoelectron Spectroscopy in the Context of Birch Reduction: Detachment Energies and Redox Potentials of Electron, Dielectron, and Benzene Radical Anion in Liquid Ammonia.

中电子、双电子和苯自由基阴离子的分离能和氧化还原电位。

34.Role of Serine Coordination in the Structural and Functional Protection of the Nitrogenase P-Cluster.

丝氨酸协调在固氮酶 P 簇的结构和功能保护中的作用。

35.Platinum Graphene Catalytic Condenser for Millisecond Programmable Metal Surfaces.

用于毫秒级可编程金属表面的铂金石墨烯催化冷凝器。

36.Gas-Phase Unfolding of Protein Complexes Distinguishes Conformational Isomers.

蛋白质复合物的气相展开区分构象异构体。

37.Enantioselective Radical Addition to Ketones through Lewis Acid-Enabled Photoredox Catalysis.

通过路易斯酸启用的光氧化还原催化对酮的对映选择性自由基加成。

38.Uncovering the Electrolyte-Dependent Transport Mechanism of LiO2 in Lithium-Oxygen Batteries.

揭示锂氧电池中 LiO2 依赖于电解质的传输机制。

39.Rhodium-Catalyzed Diastereo- and Enantioselective Divergent Annulations between Cyclobutanones and 1,5-Enynes: Rapid Construction of Complex C(sp3)-Rich Scaffolds.

铑催化的环丁酮和 1,5-烯炔之间的非对映和对映选择性发散环化：快速构建复杂的 C(sp3)-富支架。

40.Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal–Organic Frameworks.

网状化学与艺术：以奥林匹克五环为灵感的金属有机骨架案例研究。

41.Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li6+xP1–xSixO5Cl.

通过锂在立方氧化物亚银石 Li6+xP1–xSixO5Cl 中的分布控制离子电导率。

42.Divalent Lanthanide Metallocene Complexes with a Linear Coordination Geometry and Pronounced 6s–5d Orbital Mixing.

具有线性配位几何结构和显着 6s–5d 轨道混合的二价镧系茂金属配合物。

43.Correlating CO Coverage and CO Electroreduction on Cu via High-Pressure in Situ Spectroscopic and Reactivity Investigations.

通过高压原位光谱和反应性研究关联铜上的 CO 覆盖率和 CO 电还原。

44.Mn2+ Bispidine Complex Combining Exceptional Stability, Inertness, and MRI Efficiency.

Mn2+ Bispidine 络合物兼具出色的稳定性、惰性和 MRI 效率。

45.Synthesis of Carborane-Backbone Metallacycles for Highly Selective Capture of n-Pentane.

用于高选择性捕获正戊烷的碳硼烷骨架金属环的合成。

46.Molecular Mechanisms of Mercury-Sensitive Aquaporins.

汞敏感性水通道蛋白的分子机制。

47.Revealing the Intrinsic Chiroptical Activity in Chiral Metal-Halide Semiconductors.

揭示手性金属卤化物半导体的固有手性光学活性。

48.Ambimodal Bispericyclic [6 + 4]/[4 + 6] Transition State Competes with Diradical Pathways in the Cycloheptatriene Dimerization: Dynamics and Experimental Characterization of Thermal Dimers.

双峰双周环 [6 + 4]/[4 + 6] 过渡态与环庚三烯二聚化中的双自由基途径竞争：热二聚体的动力学和实验表征。

49.Designing Glass and Crystalline Phases of Metal–Bis(acetamide) Networks to Promote High Optical Contrast.

设计金属-双（乙酰胺）网络的玻璃相和晶相以促进高光学对比度。

50.Orthogonal Chemical Activation of Enzyme-Inducible CRISPR/Cas9 for Cell-Selective Genome Editing.

用于细胞选择性基因组编辑的酶诱导型 CRISPR/Cas9 的正交化学激活。

51.Regioselective Aromatic Perfluoro-tert-butylation Using Perfluoro-tert-butyl Phenyl Sulfone and Arynes.

使用全氟叔丁基苯基砜和芳烃的区域选择性芳族全氟叔丁基化。

52.β-Lactamases Evolve against Antibiotics by Acquiring Large Active-Site Electric Fields.

β-内酰胺酶通过获得大的活性位点电场来对抗抗生素。

53.Ultrafast and Multicolor Luminescence Switching in a Lanthanide-Based Hydrochromic Perovskite.

基于镧系元素的水致变色钙钛矿中的超快和多色发光切换。

54.Fast Sulfate Formation Initiated by the Spin-Forbidden Excitation of SO2 at the Air–Water Interface.

空气-水界面处 SO2 的自旋禁止激发引发的快速硫酸盐形成。

55.Skeletal Editing of Pyrimidines to Pyrazoles by Formal Carbon Deletion.

通过形式碳删除将嘧啶骨架编辑为吡唑。

56.Electrophilic C–H Borylation of Aza[5]helicenes Leading to Bowl-Shaped Quasi-[7]Circulenes with Switchable Dynamics.

Aza[5]helicenes 的亲电 C-H 硼酸化导致具有可切换动力学的碗状准 [7]Circulenes。

57.Inch-Size Molecular Ferroelectric Crystal with a Large Electromechanical Coupling Factor on Par with Barium Titanate.

具有与钛酸钡相当的大机电耦合系数的英寸尺寸分子铁电晶体。

58.Correction to “Synthesis and Chiral Resolution of Twisted Carbon Nanobelts”.

对“扭曲碳纳米带的合成和手性拆分”的更正。

59.Toward Quantitative Surface-Enhanced Raman Scattering with Plasmonic Nanoparticles: Multiscale View on Heterogeneities in Particle Morphology, Surface Modification, Interface, and Analytical Protocols.

用等离子体纳米粒子进行定量表面增强拉曼散射：粒子形态学、表面改性、界面和分析协议中异质性的多尺度视图。

60.The Protein Unfolded State: One, No One and One Hundred Thousand.

蛋白质展开状态：一、没有一和十万。

61.Structure–Reactivity–Property Relationships in Covalent Adaptable Networks.

共价适应网络中的结构-反应-性质关系。

62.Reading Information Stored in Synthetic Macromolecules.

读取存储在合成大分子中的信息。

63.Mechanical Force Enables an Anomalous Dual Ring-Opening Reaction of Naphthodipyran.

机械力使萘并双吡喃发生异常双开环反应。

64.A General Strategy to Install Amidine Functional Groups Along the Peptide Backbone.

沿肽主链安装脒官能团的一般策略。

65.Zwitterions in 3D Perovskites: Organosulfide-Halide Perovskites.

3D 钙钛矿中的两性离子：有机硫化物-卤化物钙钛矿。

66.Overcoming Photochemical Limitations in Metallaphotoredox Catalysis: Red-Light-Driven C–N Cross-Coupling.

克服金属光氧化还原催化中的光化学限制：红光驱动的 C-N 交叉偶联。

67.Polymer Molecular Weight Determination via Fluorescence Lifetime.

通过荧光寿命测定聚合物分子量。

68.Spinolate Lanthanide Complexes for High Circularly Polarized Luminescence Metrics in the Visible and Near-Infrared.

用于可见光和近红外高圆偏振发光指标的多旋酸镧系配合物。

69.Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents.

以二恶唑酮作为酰胺化试剂，铑 (III) 催化未活化烯烃的反马尔可夫尼科夫氢化酰胺化反应。

70.Cobalt-Catalyzed Nitrogen Atom Insertion in Arylcycloalkenes.

芳基环烯烃中钴催化的氮原子插入。

71.Plate-like Guanine Biocrystals Form via Templated Nucleation of Crystal Leaflets on Preassembled Scaffolds.

板状鸟嘌呤生物晶体通过预组装支架上的晶体小叶的模板化成核形成。

72.Neutral Homoaromatic Diboradisilacyclobutene: Synthesis, Structure, and Reactivity.

中性高芳香族二硼硅杂环丁烯：合成、结构和反应性。

73.Enantioselective Giese Additions of Prochiral α-Amino Radicals.

前手性 α-氨基自由基的对映选择性 Giese 加成。

74.Nano-Biohybrid DNA Engager That Reprograms the T-Cell Receptor.

重新编程 T 细胞受体的纳米生物杂交 DNA 接合剂。

75.Gas-Phase Formation of 1,3,5,7-Cyclooctatetraene (C8H8) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C8H9•) Transient.

1,3,5,7-环辛四烯 (C8H8) 通过芳族 1,3,5-环辛三烯-7-基自由基 (C8H9•) 瞬变环扩展形成气相。

76.Impact of Hydrophobic/Hydrophilic Balance on Aggregation Pathways, Morphologies, and Excited-State Dynamics of Amphiphilic Diketopyrrolopyrrole Dyes in Aqueous Media.

疏水/亲水平衡对水性介质中两亲性二酮吡咯并吡咯染料的聚集途径、形态和激发态动力学的影响。