【标题速读】【Angew】【2022年】【12月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Crownphyrins are macrocycles combining the structural features of porphyrin and crown ethers. The molecular architecture renders them an intriguing class of hosts capable of binding neutral and ionic guests. The presence of imine linkages connecting the dipyrrin segment with the ether chain enables the unusual coordination behavior of crownphyrins, as demonstrated by the formation of two classes of strikingly different complexes reported by Bartosz Szyszko and co-workers in their Research Article (e202211671).

冠卟啉是结合了卟啉和冠醚结构特征的大环化合物。分子结构使它们成为一类有趣的主体，能够结合中性和离子客体。连接二吡啉片段与醚链的亚胺键的存在使得冠菲林具有不寻常的配位行为，Bartosz Szyszko 及其同事在他们的研究文章 (e202211671) 中报道了两类截然不同的复合物的形成，证明了这一点。

2.Sequential electron transfer leading to the generation of long-lived charge-separated states in the order of 20 ms is demonstrated in multimodular electron donor–acceptor hybrids by Francis D'Souza and co-workers in their Research Article (e202212474), as a promising functional material for light energy conversion. Strategic positioning of diameter-sorted, single-wall carbon nanotubes, BODIPY, and C60 promoted electron and hole transfer events, slowing down the process of charge recombination, as demonstrated by pump–probe studies covering wide temporal and spatial time scales.

Francis D'Souza 及其同事在其研究文章 (e202212474) 中在多模块电子供体-受体混合体中证明了顺序电子转移可导致产生约 20 ms 的长寿命电荷分离态，这是一种很有前途的方法光能转换功能材料。直径排序的单壁碳纳米管、BODIPY 和 C60 的战略定位促进了电子和空穴转移事件，减慢了电荷复合的过程，涵盖广泛时空时间尺度的泵浦探针研究证明了这一点。

3.A sensitive and reversible labeling strategy enabling global mapping of the core-fucosylated glycoproteome on cell surfaces is presented in the Research Article (e202206802) by Hu Zhou, Liuqing Wen, and co-workers. The labeled probe can be further cleaved enzymatically after capture by affinity resin. The on-bead traceless cleavage allowed the global mapping of core-fucosylated glycoproteins and glycosylation sites by mass spectrometry.

Hu Zhou、Liuqing Wen 及其同事在研究文章 (e202206802) 中提出了一种敏感且可逆的标记策略，能够对细胞表面的核心岩藻糖基化糖蛋白组进行全局绘图。标记的探针在被亲和树脂捕获后可以进一步酶切。珠上无痕切割允许通过质谱法对核心岩藻糖基化糖蛋白和糖基化位点进行全局定位。

4.Glycan heterogeneity and subunit composition of therapeutic glycoprotein complexes are challenging to define. In their Communication (e202213170), Di Wu and Carol V. Robinson present a native top-down mass spectrometry approach, together with in silico modelling, to reveal the stabilization effect of interfacial N-glycans on therapeutic cytokine and hormone assemblies.

治疗性糖蛋白复合物的聚糖异质性和亚基组成很难定义。Di Wu 和 Carol V. Robinson 在他们的通讯 (e202213170) 中提出了一种天然的自上而下的质谱方法以及计算机建模，以揭示界面 N-聚糖对治疗性细胞因子和激素组装的稳定作用。

5.Chemical Approaches to Synthetic Drug Delivery Systems for Systemic Applications.

用于全身应用的合成药物输送系统的化学方法。

6.Challenges and Opportunities in Electrocatalytic CO2 Reduction to Chemicals and Fuels.

电催化二氧化碳还原为化学品和燃料的挑战和机遇。

7.Hydrogen-Bond-Modulated Nucleofugality of SeIII Species to Enable Photoredox-Catalytic Semipinacol Manifolds.

SeIII 物质的氢键调节离核性可实现光氧化还原催化赛米那醇流形。

8.Steering the Ultrafast Opening and Closure Dynamics of a Photochromic Coordination Cage by Guest Molecules.

通过客体分子控制光致变色配位笼的超快打开和关闭动力学。

9.Chromium/Photoredox Dual Catalyzed Synthesis of α-Benzylic Alcohols, Isochromanones, 1,2-Oxy Alcohols and 1,2-Thio Alcohols.

铬/光氧化还原双催化合成 α-苄醇、异色满酮、1,2-氧基醇和 1,2-硫代醇。

10.Confinement of the Triplet States in π-Conjugated BODIPY Dimers Linked with Ethynylene or Butadiynylene Bridges: A Different View on the Effect of Symmetry.

与乙炔基或丁二炔基桥连接的 π 共轭 BODIPY 二聚体中三重态的限制：对称性影响的不同观点。

11.A Sensitive and Reversible Labeling Strategy Enables Global Mapping of the Core-Fucosylated Glycoproteome on Cell Surfaces.

敏感且可逆的标记策略可实现细胞表面核心岩藻糖基化糖蛋白组的全局绘图。

12.Engineering Transport Properties in Interconnected Enargite-Stannite Type Cu2+xMn1−xGeS4 Nanocomposites.

互连 Enargite-Stanite 型 Cu2+xMn1−xGeS4 纳米复合材料的工程输运特性。

13.Photo-Facilitated Detection and Sequencing of 5-Formylcytidine RNA.

5-甲酰胞苷 RNA 的光促进检测和测序。

14.Supramolecular Assembly of Organoplatinum(II) Complexes for Subcellular Distribution and Cell Viability Monitoring with Differentiated Imaging.

有机铂 (II) 复合物的超分子组装，用于通过差异成像进行亚细胞分布和细胞活力监测。

15.Microhydrated 3-Methyl-3-oxetanemethanol: Evolution of the Hydrogen-Bonding Network from Chains to Cubes.

微水合 3-甲基-3-氧杂环丁烷甲醇：氢键网络从链到立方体的演变。

16.Combination Cancer Treatment: Using Engineered DNAzyme Molecular Machines for Dynamic Inter- and Intracellular Regulation.

组合癌症治疗：使用工程 DNAzyme 分子机器进行动态细胞间和细胞内调节。

17.Deracemization through Sequential Photoredox-Neutral and Chiral Brønsted Acid Catalysis.

通过顺序光氧化还原中性和手性布朗斯台德酸催化进行去消旋化。

18.Hierarchical Supramolecular Self-Assembly: Fabrication and Visualization of Multiblock Microstructures.

分层超分子自组装：多块微结构的制造和可视化。

19.Glycan Modulation of Insulin-like Growth Factor-1 Receptor.

胰岛素样生长因子-1 受体的聚糖调节。

20.Spin Effect to Promote Reaction Kinetics and Overall Performance of Lithium-Sulfur Batteries under External Magnetic Field.

自旋效应促进外部磁场下锂硫电池的反应动力学和整体性能。

21.Photo-Induced Homologation of Carbonyl Compounds for Iterative Syntheses.

用于迭代合成的羰基化合物的光诱导同系化。

22.Deciphering Ligand Controlled Structural Evolution of Prussian Blue Analogues and Their Electrochemical Activation during Alkaline Water Oxidation.

破译配体控制的普鲁士蓝类似物的结构演化及其在碱性水氧化过程中的电化学活化。

23.Crownphyrins: Metal-Mediated Transformations of the Porphyrin-Crown Ether Hybrids.

冠卟啉：金属介导的卟啉-冠醚杂化物的转化。

24.The Excited-State Creutz–Taube Ion.

激发态克罗伊茨-陶伯离子。

25.Semisynthetic Viral Inhibitor for Light Control of the MHC I Peptide Loading Complex.

用于光控制 MHC I 肽加载复合物的半合成病毒抑制剂。

26.N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins.

N-杂环卡宾：表面安装的 Ru-卟啉的分子搬运工。

27.Heterogeneous Hollow Multi-Shelled Structures with Amorphous-Crystalline Outer-Shells for Sequential Photoreduction of CO2.

具有非晶态结晶外壳的异质中空多壳结构，用于 CO2 的连续光还原。

28.Π–Π Stacking Complex Induces Three-Component Coupling Reactions To Synthesize Functionalized Amines.

Π–Π堆积配合物诱导三组分偶联反应合成功能化胺。

29.Interfacial Designing of MnO2 Half-Wrapped by Aromatic Polymers for High-Performance Aqueous Zinc-Ion Batteries.

高性能水系锌离子电池芳香族聚合物半包裹二氧化锰的界面设计。

30.The Role of Metal Adatoms in a Surface-Assisted Cyclodehydrogenation Reaction on a Gold Surface.

金属吸附原子在金表面表面辅助环脱氢反应中的作用。

31.A Carbon Nanotube Binding BODIPY-C60 Nano Tweezer: Charge Stabilization through Sequential Electron Transfer.

碳纳米管结合 BODIPY-C60 纳米镊子：通过顺序电子转移实现电荷稳定。

32.Isotropic Anhydrous Superprotonic Conductivity Cooperated with Installed Imidazolium Molecular Motions in a 3D Hydrogen-Bonded Phosphate Network.

各向同性无水超质子电导率与 3D 氢键磷酸盐网络中安装的咪唑分子运动相配合。

33.Stereo- and Site-Selective Crotylation of Alcohol Proelectrophiles via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by Methylallene and Butadiene.

通过甲基丙二烯和丁二烯介导的钌催化氢自动转移对醇亲电体进行立体和位点选择性巴酰化。

34.Efficient Removal of Perfluorinated Chemicals from Contaminated Water Sources Using Magnetic Fluorinated Polymer Sorbents.

使用磁性氟化聚合物吸附剂有效去除受污染水源中的全氟化化学品。

35.Acceleration of Cathode Interfacial Kinetics by Liquid Organosulfides in Lithium Metal Batteries.

锂金属电池中液态有机硫化物加速阴极界面动力学。

36.Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes.

通过钠介导的氟化芳烃钴化构建方形平面钴 (II) 配合物。

37.High-Efficiency CO2/N2 Separation Enabled by Rotation of Electrostatically Anchored Flexible Ligands in Metal–Organic Framework.

通过静电锚定柔性配体在金属有机框架中的旋转实现高效 CO2/N2 分离。

38.Substrate Induced Movement of the Metal Cofactor between Active and Resting State.

底物诱导金属辅因子在活性状态和静止状态之间的移动。

39.A Deep-Learning Framework for the Automated Recognition of Molecules in Scanning-Probe-Microscopy Images.

用于自动识别扫描探针显微镜图像中的分子的深度学习框架。

40.Side-Chain Control of Topochemical Polymer Single Crystals with Tunable Elastic Modulus.

弹性模量可调的拓扑化学聚合物单晶的侧链控制。

41.Energy-Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal.

分子主体·客体晶体高效吸收碘。

42.Assembling Phenothiazine into a Porous Coordination Cage to Improve Its Photocatalytic Efficiency for Organic Transformations.

将吩噻嗪组装到多孔配位笼中以提高其有机转化的光催化效率。

43.Controlling Intermolecular Interaction and Interphase Chemistry Enabled Sustainable Water-tolerance LiMn2O4||Li4Ti5O12 Batteries.

控制分子间相互作用和相间化学可实现可持续的耐水性 LiMn2O4||Li4Ti5O12 电池。

44.Discerning the Contributions of Gold Species in Butadiene Hydrogenation: From Single Atoms to Nanoparticles.

辨别金物质在丁二烯氢化中的贡献：从单原子到纳米颗粒。

45.Spatially Directed Biosynthesis of Quantum Dots via Spidroin Templating in Escherichia coli.

在大肠杆菌中通过蛛丝蛋白模板进行量子点的空间定向生物合成。

46.A Facile Strategy to Obtain Low-Cost and High-Performance Gold-Based Catalysts from Artificial Electronic Waste by [Zr48Ni6] Nano-Cages in MOFs for CO2 Electroreduction to CO.

通过 MOF 中的 [Zr48Ni6] 纳米笼从人造电子废物中获得低成本和高性能金基催化剂的简便策略，用于 CO2 电还原为 CO。

47.Graphene Nanoribbon Hybridization of Zeolitic Imidazolate Framework Membranes for Intrinsic Molecular Separation.

用于本征分子分离的沸石咪唑酯框架膜的石墨烯纳米带杂交。

48.Copper-Catalyzed 1,2-Dicarbonylative Cyclization of Alkenes with Alkyl Bromides via Radical Cascade Process.

通过自由基级联过程铜催化烯烃与烷基溴的 1,2-二羰基环化。

49.Native Top-Down Mass Spectrometry Reveals a Role for Interfacial Glycans on Therapeutic Cytokine and Hormone Assemblies.

天然自上而下质谱揭示了界面聚糖在治疗性细胞因子和激素组装中的作用。

50.Vinylene-Linked 2D Conjugated Covalent Organic Frameworks by Wittig Reactions.

通过 Wittig 反应制备亚乙烯基连接的二维共价有机框架。

51.Fluorine-18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation.

通过单选择性 C−F 键激活对二氟甲基和三氟甲基进行 Fluorine-18 标记。

52.Directing Group-Free Formal Suzuki–Miyaura Coupling of Simple Ketones Enabled by Activation of Unstrained C−C Bonds.

通过激活无应变 C−C 键实现简单酮的无基团形式铃木-宫浦偶联。

53.A Triplet Label Extends Two-Dimensional Infrared Spectroscopy from Pico- to Microseconds.

三重标签将二维红外光谱从皮秒扩展到微秒。

54.Total Synthesis of Spiro[cyclohexane-2-indoline] Alkaloids: A Regio- and Diastereoselective Spirocyclization Approach.

螺[环己烷-2-二氢吲哚]生物碱的全合成：区域选择性和非对映选择性螺环化方法。

55.General Access to N−CF3 Secondary Amines and Their Transformation to N−CF3 Sulfonamides.

N−CF3 仲胺的一般获取及其向 N−CF3 磺酰胺的转化。

56.Electrochemical Palladium-Catalyzed Oxidative Carbonylation-Cyclization of Enallenols.

电化学钯催化氧化羰基化-烯烯醇环化。

57.Rhodium-Catalyzed Divergent Arylation of Alkenylsulfonium Salts with Arylboroxines.

铑催化烯基锍盐与芳基环硼氧烷的发散芳基化。

58.Sequential and Reversible Phase Transformations in Zero-Dimensional Organic-Inorganic Hybrid Sb-based Halides towards Multiple Emissions.

零维有机-无机杂化锑基卤化物的连续和可逆相变向多重发射。

59.Atroposelective Synthesis of N-Arylated Quinoids by Organocatalytic Tandem N-Arylation/Oxidation.

通过有机催化串联 N-芳基化/氧化反应选择性合成 N-芳基化醌类化合物。

60.Construction of Ni-Co-Fe Hydr(oxy)oxide@Ni-Co Layered Double Hydroxide Yolk-Shelled Microrods for Enhanced Oxygen Evolution.

用于增强析氧的Ni-Co-Fe羟基氧化物@Ni-Co层状双氢氧化物蛋黄壳微棒的构建。

61.Low-Toxicity ZnSe/ZnS Quantum Dots as Potent Photoreductants and Triplet Sensitizers for Organic Transformations.

低毒性 ZnSe/ZnS 量子点作为有机转化的有效光还原剂和三线态敏化剂。

62.Complexed Semiconductor Cores Activate Hexaniobate Ligands as Nucleophilic Sites for Solar-Light Reduction of CO2 by Water.

复合半导体核心激活六铌酸盐配体作为亲核位点，用于通过水进行太阳光还原二氧化碳。

63.Biosynthesis of Nodulisporic Acids: A Multifunctional Monooxygenase Delivers a Complex and Highly Branched Array.

球孢酸的生物合成：多功能单加氧酶提供复杂且高度支化的阵列。

64.Construction of Catalytic Covalent Organic Frameworks with Redox-Active Sites for the Oxygen Reduction and the Oxygen Evolution Reaction.

用于氧还原和析氧反应的具有氧化还原活性位点的催化共价有机框架的构建。

65.A Dislocated Twin-Locking Acceptor-Donor-Acceptor Configuration for Efficient Delayed Fluorescence with Multiple Through-Space Charge Transfer.

一种错位双锁受体-供体-受体结构，可实现高效延迟荧光和多重空间电荷转移。

66.Singlet-Triplet Energy Gap as a Critical Molecular Descriptor for Predicting Organic Photovoltaic Efficiency.

单线态-三线态能隙作为预测有机光伏效率的关键分子描述符。

67.Pyrogallate-Based Metal-Organic Framework with a Two-Dimensional Secondary Building Unit.

具有二维二级建筑单元的焦性没食子酸盐基金属有机框架。

68.Engineering of Pyroelectric Crystals Decoupled from Piezoelectricity as Illustrated by Doped α-Glycine.

掺杂 α-甘氨酸所示的与压电解耦的热释电晶体工程。

69.A Cation Concentration Gradient Approach to Tune the Selectivity and Activity of CO2 Electroreduction.

调节 CO2 电还原选择性和活性的阳离子浓度梯度方法。

70.Modular and Fast Synthesis of Versatile Secondary α,α-Dialkyl Boronates via Deoxygenative Alkylboration of Aldehydes.

通过醛的脱氧烷基硼化反应模块化快速合成多功能二级 α,α-二烷基硼酸酯。

71.Vibrational circular dichroism (VCD) spectroscopy was used by Boris J. Nachtsheim, Christian Merten et al. in their Communication (e202204624) to verify DFT-calculated chiral iodane structures. Based on a chiral triazole-substituted iodoarene catalyst, a yet undescribed cationic chiral iodane was elucidated as the most populated intermediate under oxidative conditions with a significant intermolecular N–I interaction.

Boris J. Nachtsheim、Christian Merten 等人在他们的通讯 (e202204624) 中使用振动圆二色性 (VCD) 光谱验证 DFT 计算的手性碘结构。基于手性三唑取代的碘芳烃催化剂，一种尚未描述的阳离子手性碘被阐明为氧化条件下最常见的中间体，具有显着的分子间 N-I 相互作用。

72.An all-solid-state proton rectifier , which was fabricated using a heterogeneous membrane composed of a proton-conducting coordination polymer, Cu2(CuTCPP), and a hydroxide-ion-conducting layered double hydroxide, Mg-Al-LDH(NO3), is presented by Yukihiro Yoshida, Hiroshi Kitagawa, and co-workers in their Research Article (e202213077). The device demonstrated a proton rectification ratio greater than 200, which is the highest among the reported all-solid-state H+–OH− rectifiers.

全固态质子整流器，采用由质子传导配位聚合物 Cu2(CuTCPP) 和氢氧根离子传导层状双氢氧化物 Mg-Al-LDH(NO3) 组成的异质膜制成，由 Yukihiro Yoshida、Hiroshi Kitakawa 及其同事在他们的研究文章 (e202213077) 中提出。该装置的质子整流比大于200，是已报道的全固态H+–OH−整流器中最高的。

73.A bimodal imaging probe FCy7-NO2 was applied to image nitroreductase overexpressed by lung cancer in vivo, as reported by Xin Zhou and co-workers in their Research Article (e202213495). Integrating two complementary imaging technologies into FCy7-NO2 enables sensitive detection of nitroreductase over a broad concentration range without tissue-depth limit.

正如 Xin Zhou 及其同事在他们的研究文章 (e202213495) 中报道的那样，双峰成像探针 FCy7-NO2 用于对肺癌体内过表达的硝基还原酶进行成像。将两种互补的成像技术集成到 FCy7-NO2 中，可以在广泛的浓度范围内灵敏地检测硝基还原酶，而不受组织深度限制。

74.Helical molecular springs built from chiral ladder polymers expand and contract without unfolding at room temperature. In their Communication (e202209772), Severin T. Schneebeli and co-workers show that in solution such helical ladder polymers can act like classical Hookean springs with adjustable spring constants.

由手性梯形聚合物制成的螺旋分子弹簧在室温下膨胀和收缩而不展开。 Severin T. Schneebeli 及其同事在他们的通讯 (e202209772) 中表明，在溶液中，这种螺旋梯聚合物可以像经典的胡克弹簧一样发挥作用，具有可调节的弹簧常数。

75.Dynamic Bonds: Adaptable Timescales for Responsive Materials.

动态键：响应材料的适应性时间尺度。

76.Zirconium Carbide Mediates Coke-Resistant Methane Dry Reforming on Nickel-Zirconium Catalysts.

碳化锆介导镍锆催化剂上的抗焦甲烷干重整。

77.In Vivo Nitroreductase Imaging via Fluorescence and Chemical Shift Dependent 19F NMR.

通过荧光和化学位移相关的 19F NMR 进行体内硝基还原酶成像。

78.Design of a Protein with Improved Thermal Stability by an Evolution-Based Generative Model.

通过基于进化的生成模型设计具有改进的热稳定性的蛋白质。

79.Unusual Scaffold Rearrangement in Polyaromatic Hydrocarbons Driven by Concerted Action of Single Gold Atoms on a Gold Surface.

金表面上单个金原子的协同作用驱动多芳烃中不寻常的支架重排。

80.Cu Single Atom Nanozyme Based High-Efficiency Mild Photothermal Therapy through Cellular Metabolic Regulation.

基于铜单原子纳米酶的通过细胞代谢调节的高效温和光热疗法。

81.Ultrafast Dynamics and Catalytic Mechanism of Fatty Acid Photodecarboxylase.

脂肪酸光脱羧酶的超快动力学和催化机制。

82.Unveiling the Protonation Kinetics-Dependent Selectivity in Nitrogen Electroreduction: Achieving 75.05 % Selectivity.

揭示氮电还原中质子化动力学相关的选择性：实现 75.05% 的选择性。

83.Cobalt-Catalyzed Deaminative Amino- and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light.

可见光促进芳基三烷基铵盐的钴催化脱氨氨基和烷氧基羰基化。

84.Light-Induced Divergent Cyanation of Alkynes Enabled by Phosphorus Radicals.

磷自由基引起的光诱导炔烃发散氰化。

85.A Redox-Controlled Substrate Engineering Strategy for Site-Specific Enzymatic Fucosylation.

用于位点特异性酶促岩藻糖基化的氧化还原控制底物工程策略。

86.Rational Design of Carbon Nitride Photoelectrodes with High Activity Toward Organic Oxidations.

具有高有机氧化活性的氮化碳光电极的合理设计。

87.Actinide Pnictinidene Chemistry: A Terminal Thorium Parent-Arsinidene Complex Stabilised by a Super-Bulky Triamidoamine Ligand.

Actinide Pnictinidene 化学：由超大型三酰氨基胺配体稳定的末端钍母体-胂络合物。

88.Ruthenium-Based Metal–Organic Nanoradiosensitizers Enhance Radiotherapy by Combining ROS Generation and CO Gas Release.

钌基金属有机纳米放射增敏剂通过结合 ROS 生成和 CO 气体释放来增强放射治疗。

89.A Vitamin B2-Photocatalysed Approach to Methionine Analogues.

维生素 B2 光催化制备蛋氨酸类似物的方法。

90.Light, Heat and Electricity Integrated Energy Conversion System: Photothermal-Assisted Co-Electrolysis of CO2 and Methanol.

光、热、电一体化能源转换系统：光热辅助CO2和甲醇共电解。

91.Bioactive Ion-Based Switchable Supercapacitors.

基于生物活性离子的可切换超级电容器。

92.Porous Liquids Responsive to Light.

对光敏感的多孔液体。

93.Facet-specific Active Surface Regulation of BixMOy (M=Mo, V, W) Nanosheets for Boosted Photocatalytic CO2 reduction.

BixMOy (M=Mo、V、W) 纳米片的小面特异性活性表面调节可增强光催化 CO2 还原。

94.Programmed Iteration Controls the Assembly of the Nonanoic Acid Side Chain of the Antibiotic Mupirocin.

程序化迭代控制抗生素莫匹罗星壬酸侧链的组装。

95.Nanoporous Single-Crystalline Oxide Catalysts for Preferential Oxidation of CO in H2 with an Ultra-wide Temperature Window.

纳米多孔单晶氧化物催化剂在超宽温度窗口下优先氧化 H2 中的 CO。

96.Ultra-Tough and Recyclable Ionogels Constructed by Coordinated Supramolecular Solvents.

由协调超分子溶剂构建的超坚韧且可回收的离子凝胶。

97.o-Quinodimethane Atropisomers: Enantioselective Synthesis and Stereospecific Transformation.

邻醌二甲烷阻转异构体：对映选择性合成和立体定向转化。

98.Host Spin-Crossover Thermodynamics Indicate Guest Fit.

宿主自旋交叉热力学表明客体拟合。

99.A Facile Structural Isomerization-Induced 3D Spatial D-A Interlocked Network for Achieving NIR-II Phototheranostic Agents.

一种简单的结构异构化诱导的 3D 空间 DA 互锁网络，用于实现 NIR-II 光治疗剂。

100.Room-Temperature Ring-Opening Polymerization of δ-Valerolactone and ϵ-Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals.

吸收到多孔柱[5]芳烃晶体中引起δ-戊内酯和ε-己内酯的室温开环聚合。

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