【标题速读】【JACS】【2022年】【11月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

Biodegradable ferrous sulfide-based nanocomposites with hydrogen sulfide gas, carbonic anhydrase inhibitor, and Fenton agents releasing capacity were designed and constructed to cause intratumoral acidosis-induced metabolic symbiosis disruption. Upon laser irradiation, the formed nanocomposites can eliminate tumors through photoacoustic and magnetic resonance imaging-guided specific chemodynamic/photothermal/gas therapy.

设计并构建了具有硫化氢气体、碳酸酐酶抑制剂和芬顿剂释放能力的可生物降解硫化亚铁基纳米复合材料，以引起肿瘤内酸中毒诱导的代谢共生破坏。 在激光照射下，形成的纳米复合材料可以通过光声和磁共振成像引导的特定化学动力学/光热/气体疗法消除肿瘤。

Live cell Raman imaging is an emerging technique. A tiny alkyne can be introduced into small molecules without the loss of biological activity and is an excellent Raman tag for detection in living cells and tissues. EdU, an alkyne-tagged nucleoside, is incorporated into DNA and accumulated in the nucleus.

活细胞拉曼成像是一项新兴技术。 微小的炔烃可以被引入小分子而不损失生物活性，是用于活细胞和组织检测的极佳拉曼标签。 EdU 是一种带有炔烃标记的核苷，被掺入 DNA 并在细胞核中积累。

The off/on-type fluorescent probe for the HaloTag, Halo SiR-5, showed a strong fluorescence upon conjugating to HaloTag protein by controlling the twisted intramolecular charge transfer (TICT) process.

HaloTag 的关/开型荧光探针 Halo SiR-5 在通过控制扭曲分子内电荷转移 (TICT) 过程与 HaloTag 蛋白结合后显示出强烈的荧光。

Temporal control of DNA strand displacement reactions (SDRs) is achieved using blocker strands and specific enzymes. The blocker binds to the toehold domain of the target DNA and efficiently inhibits SDR. Enzymatic degradation of the blocker strand enables SDR with highly controllable kinetics.

DNA 链置换反应 (SDR) 的时间控制是使用阻断链和特定酶实现的。 阻断剂与目标 DNA 的立足点域结合并有效抑制 SDR。 阻断链的酶促降解使 SDR 具有高度可控的动力学。

This work provides an exemplification of the switchable catalysis concept whereby a single organoboron catalyst is triggered to enter ring-opening polymerization or ring-opening copolymerization cycles through thermodynamically and kinetically preferential ring opening of terminal epoxides or internal epoxides under different atmosphere (CO2 or N2).

这项工作提供了可切换催化概念的示例，即通过在不同气氛（CO2 或 N2）下末端环氧化物或内部环氧化物的热力学和动力学优先开环，触发单一有机硼催化剂进入开环聚合或开环共聚循环 .

A eutectic LiI–LiOH salt with the lowest eutectic point among binary eutectic lithium salt systems was selected to provide a Li-rich molten environment, not only offering excess lithium but benefiting ion diffusion compared to that in the solid environment. Hence, the highly degraded layer cathodes in spent lithium ion batteries are directly regenerated.

选择二元共晶锂盐体系中共晶点最低的共晶 LiI-LiOH 盐来提供富含锂的熔融环境，与固体环境相比，不仅提供过量的锂，而且有利于离子扩散。 因此，废旧锂离子电池中高度退化的正极层被直接再生。

Mucus, a biologically dynamic hydrogel, covers the surface of epithelial cells and presents the human body's first line of defense against foreign particles. The unique biophysical properties and selective biological functions of mucus have inspired scientists to synthesize artificial versions (synthetic mucus) in the laboratory to advance mucus-related research.

粘液是一种生物动态水凝胶，覆盖在上皮细胞表面，是人体抵御外来颗粒的第一道防线。 粘液独特的生物物理学特性和选择性生物学功能激发了科学家们在实验室中合成人工版本（合成粘液）以推进与粘液相关的研究。

Small extracellular vesicles (sEVs) from cells of different malignant degrees carry different functional proteins. Nano-FTIR identifies malignancy-related protein heterogeneity at the single sEV level, including an increased amide I/II absorption ratio and a reduced proportion of α-helix + random coil. These spectral signatures provide a noninvasive solution for tumor diagnosis.

来自不同恶性程度的细胞的小细胞外囊泡（sEVs）携带不同的功能蛋白。 Nano-FTIR 在单个 sEV 水平上识别恶性肿瘤相关的蛋白质异质性，包括增加的酰胺 I/II 吸收率和减少的 α-螺旋 + 无规卷曲比例。 这些光谱特征为肿瘤诊断提供了一种无创解决方案。

Corral[5]arene--a conjugated tubular macrocycle--manifests bright fluorescent emission, dynamic chirality, and induced-fit guest-binding behaviors. Its deep and adaptive cavity allows it to accommodate a wide range of guests with different molecular sizes and shapes.

Corral[5]arene——一种共轭管状大环化合物——表现出明亮的荧光发射、动态手性和诱导适合的客体结合行为。 其深而适应性强的腔使其能够容纳具有不同分子大小和形状的各种客人。

The first examples of d0 transition-metal-based deep-UV transparent nonlinear optical crystals, MOF4H2 (M = Zr (ZOF), Hf (HOF)), have been obtained by employing an isoreticular node substitution strategy. The KTiOPO4-like ZOH and HOF exhibit exceptionally short UV absorption edges and strong second-harmonic generation, highlighting the promise of d0 transition-metal oxyfluorides as a new source of deep-UV transparent nonlinear optical material.

d0 过渡金属基深紫外透明非线性光学晶体 MOF4H2（M = Zr（ZOF），Hf（HOF））的第一个例子是通过采用等网状节点替换策略获得的。 类 KTiOPO4 的 ZOH 和 HOF 表现出极短的紫外吸收边缘和强烈的二次谐波产生，突出了 d0 过渡金属氟氧化物作为深紫外透明非线性光学材料新来源的前景。

This cover art illustrates palladium hydride-enabled hydroalkenylation of strained molecules, bicyclo[1.1.0]butanes (BCBs) and cyclopropenes. The in situ generated PdH species adds onto strained molecules in a chemoselective manner. The resulting alkyl Pd(II) complex, upon visible-light-induced homolysis of the Pd–C bond, generates the key reaction intermediates, hybrid Pd(I) cyclobutyl or cyclopropyl radical species.

此封面艺术展示了钯氢化物对应变分子、双环[1.1.0]丁烷 (BCB) 和环丙烯的加氢烯基化作用。 原位生成的 PdH 物质以化学选择性方式添加到应变分子上。 由此产生的烷基 Pd(II) 络合物，在可见光诱导的 Pd-C 键均裂后，生成关键的反应中间体，杂化 Pd(I) 环丁基或环丙基自由基物种。

A sequence-controlled one-pot tandem copolymerization was achieved to produce degradable high-molecular-weight functionalized block poly(ester-b-carbonates) with mechanical properties comparable to those of commodity polyolefins.

实现了顺序控制的一锅串联共聚，以生产可降解的高分子量功能化嵌段聚（酯-b-碳酸酯），其机械性能可与商品聚烯烃相媲美。

Through energy band engineering, a PNP-type single-molecule junction is constructed, whose properties prove that the opposite intrinsic dipole moments are effective in regulating the charge transport mechanism of single-molecule devices.

通过能带工程，构建了PNP型单分子结，其性质证明相反的本征偶极矩可有效调节单分子器件的电荷传输机制。

Superatomic crystal is a class of hierarchical materials composed of atomically precise clusters assembled via van der Waals or covalent-like interactions. Au6Te12Se8, an all-inorganic superatomic superconductor exhibiting superatomic charge-density wave (S-CDW), shows the lowest threshold toward external pressure. Moreover, a second superconducting phase emerges with a 3-fold enhancement of the transition temperature (Tc), which is accompanied by a channel switch of conductivity from the a- to the b-axis.

超原子晶体是一类分层材料，由通过范德华力或类共价相互作用组装的原子级精确簇组成。 Au6Te12Se8 是一种全无机超原子超导体，具有超原子电荷密度波 (S-CDW)，显示出对外部压力的最低阈值。 此外，第二个超导相随着转变温度 (Tc) 的 3 倍增强而出现，伴随着从 a 轴到 b 轴的电导率通道转换。

Vertically aligned sub-10 nm corrugated TiO2 nanowire arrays with controllable concave walls have been synthesized by a unique mono-micelle-directed assembly method. An underlying mechanism of the hole extraction effect for concave walls is clarified, demonstrating the exact role of concave walls as the hole collection centers for efficient water splitting.

通过独特的单胶束定向组装方法合成了具有可控凹壁的垂直排列的亚 10 nm 波纹状 TiO2 纳米线阵列。 阐明了凹壁空穴提取效应的潜在机制，证明了凹壁作为高效水分解的空穴收集中心的确切作用。

This study reveals the facet-dependent trapped state of the photogenerated electrons over anatase TiO2. Controlling the shallow or deep electron trap states via selective exposure of the (101) or (001) facet enables the selective photocatalytic conversion of biopolyols to formic acid or CO under irradiation, respectively.

这项研究揭示了光生电子在锐钛矿 TiO2 上的小平面依赖捕获态。 通过 (101) 或 (001) 面的选择性曝光来控制浅层或深层电子陷阱状态，能够分别在辐照下将生物多元醇选择性光催化转化为甲酸或 CO。

Py-2, a molecular platform integrating the rhodamine 6G scaffold and polymethine, can be conveniently developed for various activatable ratiometric NIR-II molecular fluorescent probes, offering a wide range of attractive tools for the reliable detection of specific targets within deep tissue with high resolution.

Py-2 是一个集成了罗丹明 6G 支架和聚甲炔的分子平台，可方便地开发用于各种可激活的比例 NIR-II 分子荧光探针，为以高分辨率可靠检测深层组织内的特定靶标提供广泛的有吸引力的工具 .

A bio-inspired Cu MOF achieves simultaneous hydrolysis of the nerve agent simulant and oxidization of the sulfur mustard simulant. The cooperative catalysis of dual copper sites in the MOF greatly promotes the catalytic performance.

受生物启发的 Cu MOF 实现了神经毒剂模拟物的同时水解和硫芥模拟物的氧化。 MOF中双铜位的协同催化极大地提升了催化性能。

Local coordination environment of metal sites essentially determines their catalytic performance. On the surface-defect-enriched CeO2, the lattice-embedded Pt atomic single-layer structure derived from embedded Pt single atoms significantly outperforms the surface-adsorbed Pt atomic single-layer structure derived from adsorbed Pt single atoms on the conventional CeO2 for CO oxidation.

金属位点的局部配位环境本质上决定了它们的催化性能。 在表面缺陷富集的 CeO2 上，嵌入 Pt 单原子衍生的晶格嵌入 Pt 原子单层结构明显优于传统 CeO2 上吸附 Pt 单原子衍生的表面吸附 Pt 原子单层结构用于 CO 氧化 .

A feasible strategy combining precoking and steaming to directionally construct the active naphthalenic species within the crystal center of the SAPO-34 catalyst has been developed, which can not only promote the lower olefin selectivity to ~89% (ethylene and propylene) but also prolong the catalyst lifetime by ~3.7-fold in the methanol-to-olefin conversion.

开发了一种可行的预焦化和汽蒸相结合的策略，将活性萘物种定向构建在 SAPO-34 催化剂的晶心内，不仅可以将低烯烃选择性提高到~89%（乙烯和丙烯），而且可以延长 在甲醇转化为烯烃的过程中，催化剂寿命提高了约 3.7 倍。

This cover illustrates the dynamic process of nitrogen substitution of one carbon atom of a fullerene cage containing a metal atom. The nitrogen atom is from the decomposition of a N2 molecule, which is decomposed by DC-arc discharge (mimicked by strong lightning). The high-energy nitrogen atom then attacks the fullerene cage, resulting in substitution/removal of one carbon atom.

本封面说明了氮取代含有金属原子的富勒烯笼中一个碳原子的动态过程。 氮原子来自 N2 分子的分解，N2 分子被直流电弧放电（模仿强闪电）分解。 然后高能氮原子攻击富勒烯笼，导致一个碳原子的取代/去除。

Here we report the ultrathin conjugated metalloporphyrin covalent organic framework epitaxially grown on graphene as a two-dimensional van der Waals heterostructure to achieve high-efficiency electrochemical CO2 to CO conversion. Operando spectroscopic and theoretical studies disclosed that the strong interlayer coupling leads to electron-deficient metal centers and speeds up electrocatalysis.

在这里，我们报告了在石墨烯上外延生长的超薄共轭金属卟啉共价有机框架作为二维范德瓦尔斯异质结构，以实现高效电化学 CO2 到 CO 的转化。 原位光谱和理论研究表明，强层间耦合导致金属中心缺电子并加速电催化。

Alkyl-substituted N,S-embedded heterocycloarenes with a planar aromatic configuration were synthesized, and it was found that the charge transport characteristics can be effectively manipulated by the engineering of the molecular geometry and the alkyl chain branching position.

合成了具有平面芳族构型的烷基取代的 N,S-嵌入杂环芳烃，发现通过分子几何结构和烷基链支化位置的工程可以有效地控制电荷传输特性。

Built on 8-connected Zr6/Y6 clusters and a flexible tetracarboxylate, a series of three MOF structures with different topologies are achieved, with different ligand and/or SBU geometries. One of the compounds, HIAM-402, exhibits large porosity and high stability and is capable of one-step purification of propylene from propane/propylene/propyne mixtures.

Porphyrin-based π-electronic ion pairs exhibit solid-state and solution-state stacked assemblies according to the peripheral substituents, resulting in a stacked radical pair with antiferromagnetic spin–spin interactions for the "activated" pair that has electron-withdrawing and electron-donating groups in the constituent cation and anion, respectively.

基于卟啉的 π 电子离子对根据外围取代基表现出固态和溶液态堆叠组件，导致具有反铁磁自旋 - 自旋相互作用的堆叠自由基对具有吸电子和电子 - 的“激活”对 分别在组成阳离子和阴离子中的供体基团。

1.Raman Spectroscopy for Chemical Biology Research.

用于化学生物学研究的拉曼光谱。

2.Evidence for Water Antibonding Orbital Mixing in the Hydrated Electron from Its Oxygen 1s X-ray Absorption Spectrum.

从其氧 1s X 射线吸收光谱中水合电子中水反键合轨道混合的证据。

3.Recycling Upstream Redox Enzymes Expands the Regioselectivity of Cycloaddition in Pseudo-Aspidosperma Alkaloid Biosynthesis.

回收上游氧化还原酶可扩大环加成在拟无子植物生物碱生物合成中的区域选择性。

4.Efficient Red-Light-Driven Hydrogen Evolution with an Anthraquinone Organic Dye.

用蒽醌有机染料进行高效的红光驱动氢析出。

5.Au as a Surrogate for F: The Case of UAu6 vs UF6.

Au 作为 F 的替代品：UAu6 与 UF6 的案例。

6.Aqueous Amine-Tolerant [2+2] Photocycloadditions of Unactivated Olefins.

未活化烯烃的耐水性 [2+2] 光环加成。

7.Total Synthesis of Matrine Alkaloids.

苦参碱类生物碱的全合成。

8.Catalysis-Enabled 13-Step Total Synthesis of (−)-Peyssonnoside A.

(−)-Peyssonnoside A 的催化启用 13 步全合成。

9.Total Synthesis of the Dihydrooxepine-Spiroisoxazoline Natural Product Psammaplysin A.

Dihydrooxepine-Spiroisoxazoline 天然产物 Psammaplysin A 的全合成。

10.Direct C(sp3)–N Bond Formation between Toluene and Amine in Water Microdroplets.

水微滴中甲苯和胺之间的直接 C(sp3)–N 键形成。

11.Electrochemically Switchable Circularly Polarized Photoluminescence within Self-Assembled Conducting Polymer Helical Microfibers.

自组装导电聚合物螺旋微纤维内的电化学可切换圆偏振光致发光。

12.Migratory Insertion of CO into a Au–C Bond.

CO 迁移插入 Au-C 键。

13.Nature of Cations Critically Affects Water at the Negatively Charged Silica Interface.

阳离子的性质严重影响带负电的二氧化硅界面处的水。

14.Achiral-Core-Metal Change in Isomorphic Enantiomeric Ag12Ag32 and Au12Ag32 Clusters Triggers Circularly Polarized Phosphorescence.

同构对映体 Ag12Ag32 和 Au12Ag32 簇中的非手性核心金属变化触发圆偏振磷光。

15.Stimuli-Induced Reversible Transformation between Decanuclear and Pentanuclear Gold(I) Sulfido Complexes.

十核和五核金 (I) 硫化物配合物之间的刺激诱导可逆转变。

16.Two-Dimensional Wedge-Shaped Magnetic EuS: Insight into the Substrate Step-Guided Epitaxial Synthesis on Sapphire.

二维楔形磁性 EuS：深入了解蓝宝石上的衬底步进引导外延合成。

17.Bromide-Mediated Photoelectrochemical Epoxidation of Alkenes Using Water as an Oxygen Source with Conversion Efficiency and Selectivity up to 100%.

以水为氧源溴化物介导的烯烃光电化学环氧化反应，转化效率和选择性高达100%。

18.General Design Strategy to Precisely Control the Emission of Fluorophores via a Twisted Intramolecular Charge Transfer (TICT) Process.

通过扭曲分子内电荷转移 (TICT) 过程精确控制荧光团发射的一般设计策略。

19.Orthogonal Enzyme-Driven Timers for DNA Strand Displacement Reactions.

用于 DNA 链置换反应的正交酶驱动计时器。

20.Length-Controlled Nanofiber Micelleplexes as Efficient Nucleic Acid Delivery Vehicles.

长度可控的纳米纤维胶束复合物作为高效的核酸运载工具。

21.Single-Crystalline Imine-Linked Two-Dimensional Covalent Organic Frameworks Separate Benzene and Cyclohexane Efficiently.

单晶亚胺连接的二维共价有机骨架可有效分离苯和环己烷。

22.Spatially Resolved Janus Patterning of Graphene by Direct Laser Writing.

通过直接激光写入对石墨烯进行空间分辨的 Janus 图案化。

23.VaporSPOT: Parallel Synthesis of Oligosaccharides on Membranes.

VaporSPOT：寡糖在膜上的平行合成。

24.Unraveling the Nature and Role of Layered Cation Ordering in Cation-Disordered Rock-Salt Cathodes.

揭示阳离子无序岩盐阴极中层状阳离子有序的性质和作用。

25.Evaluation of the Stability of Diamine-Appended Mg2(dobpdc) Frameworks to Sulfur Dioxide.

二胺附加 Mg2(dobpdc) 框架对二氧化硫的稳定性评估。

26.Tilting the Balance: London Dispersion Systematically Enhances Enantioselectivities in Brønsted Acid Catalyzed Transfer Hydrogenation of Imines.

倾斜天平：伦敦分散体系统地增强了亚胺布朗斯台德酸催化转移氢化中的对映选择性。

27.Indirect Band Gap Semiconductors for Thin-Film Photovoltaics: High-Throughput Calculation of Phonon-Assisted Absorption.

用于薄膜光伏的间接带隙半导体：声子辅助吸收的高通量计算。

28.Biodegradable Ferrous Sulfide-Based Nanocomposites for Tumor Theranostics through Specific Intratumoral Acidosis-Induced Metabolic Symbiosis Disruption.

可生物降解的基于硫化亚铁的纳米复合材料通过特定的肿瘤内酸中毒诱导的代谢共生破坏用于肿瘤治疗。

29.Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalysts.

有机硼催化剂从环氧化物混合物中顺序可逆构建富氧嵌段共聚物。

30.Quantitative Kinetics of HO2 Reactions with Aldehydes in the Atmosphere: High-Order Dynamic Correlation, Anharmonicity, and Falloff Effects Are All Important.

HO2 与大气中醛类反应的定量动力学：高阶动态相关性、非谐性和衰减效应都很重要。

31.Monolayer Fullerene Networks as Photocatalysts for Overall Water Splitting.

单层富勒烯网络作为全水分解光催化剂。

32.De Novo Construction of Chiral Aminoindolines by Cu-Catalyzed Asymmetric Cyclization and Subsequent Discovery of an Unexpected Sulfonyl Migration.

通过 Cu 催化的不对称环化从头构建手性氨基吲哚并随后发现意外的磺酰基迁移。

33.Photoinduced Ion-Pair Inner-Sphere Electron Transfer-Reversible Addition–Fragmentation Chain Transfer Polymerization.

光致离子对内球电子转移-可逆加成-断裂链转移聚合。

34.Total Synthesis of Aflastatin A.

黄曲霉素 A 的全合成。

35.Conductive and Ultrastable Covalent Organic Framework/Carbon Hybrid as an Ideal Electrocatalytic Platform.

作为理想电催化平台的导电和超稳定共价有机骨架/碳杂化物。

36.Universal Concept for Bright, Organic, Solid-State Emitters─Doping of Small-Molecule Ionic Isolation Lattices with FRET Acceptors.

明亮、有机、固态发射器的通用概念─用 FRET 受体掺杂小分子离子隔离晶格。

37.Elucidating the Roles of Local and Nonlocal Rate Enhancement Mechanisms in Plasmonic Catalysis.

阐明局部和非局部速率增强机制在等离子体催化中的作用。

38.A Multi-Objective Active Learning Platform and Web App for Reaction Optimization.

用于反应优化的多目标主动学习平台和 Web 应用程序。

39.Isolation and Characterization of Heteroleptic Mononuclear Palladium(I) Complexes.

杂配单核钯 (I) 配合物的分离和表征。

40.Alternating Isotactic Polyhydroxyalkanoates via Site- and Stereoselective Polymerization of Unsymmetrical Diolides.

通过不对称二醇的位点选择性和立体选择性聚合交替等规聚羟基链烷酸酯。

41.Iridium-Catalyzed Asymmetric Cascade Allylation/Retro-Claisen Reaction.

铱催化的不对称级联烯丙基化/逆克莱森反应。

42.High-Throughput Inverse Design for 2D Ferroelectric Rashba Semiconductors.

二维铁电 Rashba 半导体的高吞吐量逆向设计。

43.Defining Stereochemistry in the Polymerization of Lactide by Aluminum Catalysts: Insights into the Dual-Stereocontrol Mechanism.

定义铝催化剂丙交酯聚合中的立体化学：对双立体控制机制的洞察。

44.Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques.

使用电分析和数据科学技术研究烯丙基亲电试剂与低价 Ni/Co 催化剂的氧化加成机制。

45.Ni/Photoredox-Catalyzed C(sp3)–C(sp3) Coupling between Aziridines and Acetals as Alcohol-Derived Alkyl Radical Precursors.

Ni/Photoredox 催化的 C(sp3)–C(sp3) 偶联氮丙啶和缩醛作为醇衍生的烷基自由基前体。

46.Rh-Catalyzed Sequential Asymmetric Hydrogenations of 3-Amino-4-Chromones Via an Unusual Dynamic Kinetic Resolution Process.

Rh 催化的 3-Amino-4-Chromones 通过不寻常的动态动力学拆分过程连续不对称氢化。

47.A General Stereoselective Synthesis of [4]Dendralenes.

[4]Dendralenes 的一般立体选择性合成。

48.Reassigning the Pressure-Induced Phase Transitions of Methylammonium Lead Bromide Perovskite.

重新分配甲基铵溴化铅钙钛矿的压力诱导相变。

49.Asymmetric Photochemical [2 + 2]-Cycloaddition of Acyclic Vinylpyridines through Ternary Complex Formation and an Uncontrolled Sensitization Mechanism.

不对称光化学 [2 + 2]-无环乙烯基吡啶通过三元复合物形成和不受控制的敏化机制的环加成。

50.Use of a PCET Mediator Enables a Ni-HER Electrocatalyst to Act as a Hydride Delivery Agent.

使用 PCET 介体可使 Ni-HER 电催化剂充当氢化物输送剂。

51.Probing the Synergistic Effects of Mg2+ on CO2 Reduction Reaction on CoPc by In Situ Electrochemical Scanning Tunneling Microscopy.

通过原位电化学扫描隧道显微镜探讨 Mg2+ 对 CoPc CO2 还原反应的协同作用。

52.Mucus-Inspired Dynamic Hydrogels: Synthesis and Future Perspectives.

受粘液启发的动态水凝胶：合成和未来展望。

53.Using Catalysis to Drive Chemistry Away from Equilibrium: Relating Kinetic Asymmetry, Power Strokes, and the Curtin–Hammett Principle in Brownian Ratchets.

使用催化作用使化学远离平衡：将动力学不对称性、动力冲程和布朗棘轮中的科廷-哈米特原理联系起来。

54.Amplification, Enrichment, and Sequencing of Mutagenic Methylated DNA Adduct through Specifically Pairing with Unnatural Nucleobases.

通过与非天然核碱基特异性配对，对诱变甲基化 DNA 加合物进行扩增、富集和测序。

55.Chemoproteomic Identification of Blue-Light-Damaged Proteins.

蓝光损伤蛋白质的化学蛋白质组学鉴定。

56.Acetonitrile Ligand Photosubstitution in Ru(II) Complexes Directly from the 3MLCT State.

直接来自 3MLCT状态的 Ru(II) 复合物中的乙腈配体光取代。

57.Plasmon-Generated Solvated Electrons for Chemical Transformations.

用于化学转化的等离子体产生的溶剂化电子。

58.Enantioselective Synthesis of N-Benzylic Heterocycles by Ni/Photoredox Dual Catalysis.

Ni/Photoredox 双催化对映选择性合成 N-苄基杂环。

59.Total Synthesis of (−)-Principinol C.

(−)-Principinol C 的全合成。

60.Photoelectrochemical Asymmetric Catalysis Enables Direct and Enantioselective Decarboxylative Cyanation.

光电化学不对称催化可实现直接和对映选择性脱羧氰化。

61.Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer.

通过可见光诱导能量转移合成多取代 2-氧杂双环 [2.1.1] 己烷。

62.Single-Handed Helicene Nanoribbons via Transfer of Chiral Information.

通过手性信息转移的单手螺旋纳米带。

63.Optimization of Pore-Space-Partitioned Metal–Organic Frameworks Using the Bioisosteric Concept.

使用生物等排概念优化孔隙空间分隔的金属-有机框架。

64.Water Dimer-Driven DNA Base Superstructure with Mismatched Hydrogen Bonding.

具有错配氢键的水二聚体驱动的 DNA 碱基超结构。

65.Asymmetric Total Synthesis of Havellockate.

Havellockate 的不对称全合成。

66.Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA.

芳烃的全氘化通过氢同位素交换催化的超碱性氨基钠供体物质 NaTMP·PMDETA。

67.Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand.

具有非旁观者三配位磷配体的铱络合物的两点 O–H 加成。

68.Nickel-Catalyzed Enantioselective Reductive Conjugate Arylation and Heteroarylation via an Elementary Mechanism of 1,4-Addition.

通过 1,4-加成的基本机制进行镍催化的对映选择性还原共轭芳基化和杂芳基化。

69.The Influence of the Electron Density in Acyl Protecting Groups on the Selectivity of Galactose Formation.

酰基保护基团中电子密度对半乳糖形成选择性的影响。

70.Electrochemical Strategy for Proton Relay Installation Enhances the Activity of a Hydrogen Evolution Electrocatalyst.

质子继电器装置的电化学策略增强了析氢电催化剂的活性。

71.Single-Vesicle Infrared Nanoscopy for Noninvasive Tumor Malignancy Diagnosis.

用于无创肿瘤恶性诊断的单囊泡红外纳米镜检查。

72.Hydroxyl-Rich Hydrophilic Endocytosis-Promoting Peptide with No Positive Charge.

富含羟基的亲水性内吞作用促进肽，不带正电荷。

73.Local Structure Insight into Hydrogen Evolution Reaction with Bimetal Nanocatalysts.

双金属纳米催化剂对析氢反应的局部结构洞察。

74.Adaptable Eutectic Salt for the Direct Recycling of Highly Degraded Layer Cathodes.

用于直接回收高度退化层阴极的适应性共晶盐。

75.Soft Multiaxial Molecular Ferroelectric Thin Films with Self-Powered Broadband Photodetection.

具有自供电宽带光电检测功能的软多轴分子铁电薄膜。

76.Spectroscopic and Kinetic Studies of the ClSO Radical from Cl2SO Photolysis.

来自 Cl2SO 光解的 ClSO 自由基的光谱和动力学研究。

77.De Novo Discovery of Thiopeptide Pseudo-natural Products Acting as Potent and Selective TNIK Kinase Inhibitors.

从头发现作为有效和选择性 TNIK 激酶抑制剂的硫肽伪天然产物。

78.Photocatalytic Overall Water Splitting over PbTiO3 Modulated by Oxygen Vacancy and Ferroelectric Polarization.

氧空位和铁电极化调制的 PbTiO3 上的光催化全水分解。

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