【标题速读】【JACS】【2022年】【1月】

2023-06-05 16:52 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

Lithium (Li) metal anode is attractive for high-energy-density batteries. In this work, a successive conversion–de-intercalation delithiation mechanism, visually illustrated in the cover art, is proposed by manipulating the overpotential evolution of anode to restrain the generation of inactive Li.

锂 (Li) 金属负极对于高能量密度电池具有吸引力。在这项工作中，通过操纵阳极的过电位演化来抑制惰性锂的产生，提出了一种连续的转化-脱嵌脱锂机制，如封面艺术所示。

This study introduces a NIR-light-initiated conditionally activatable photoredox catalysis (ConAPC) in living systems, allowing O2-independent photocatalytic cellular electron flow disruption to be selectively confined within cancer cells.

本研究在生命系统中引入了近红外光引发的条件激活光氧化还原催化 (ConAPC)，允许将不依赖 O2 的光催化细胞电子流中断选择性地限制在癌细胞内。

A composite nanocarrier has been constructed to load porphyrin molecules for catalytic rheumatoid arthritis treatment, which is achieved by releasing Mn ions and porphyrin ligands in situ for synthesizing a manganese porphyrin, a mimic of superoxide dismutase and catalase that can catalyze the depletion of reactive oxygen species and mitigate oxidative stress.

已构建复合纳米载体负载卟啉分子用于催化类风湿性关节炎治疗，这是通过原位释放锰离子和卟啉配体以合成锰卟啉实现的，锰卟啉是超氧化物歧化酶和过氧化氢酶的模拟物，可催化活性氧的消耗并减轻氧化应激。

As a unique 3d-5f-governing electrocatalyst, UCoO4 exhibited excellent water-splitting performance. Operando X-ray spectroscopy revealed that strong U 5f–O 2p covalence can synergistically accelerate Co sites' OER activity via a perfectly ordered U–O–Co network.

作为一种独特的 3d-5f 调控电催化剂，UCoO4 表现出优异的水分解性能。Operando X 射线光谱表明，强 U 5f–O 2p 共价可以通过完美有序的 U–O–Co 网络协同加速 Co 位点的 OER 活性。

Highly dispersed dual Au and Cu species enable efficient and selective photocatalytic conversion of methane to methanol and oxygenates on ZnO using O2 as the oxidant operated at ambient temperature, resulting in a nearly 100% selectivity and 14.1% apparent quantum yield at 365 nm.

高度分散的双 Au 和 Cu 物种能够在环境温度下使用 O2 作为氧化剂，在 ZnO 上将甲烷高效、选择性地光催化转化为甲醇和含氧化合物，从而在 365 nm 处产生近 100% 的选择性和 14.1% 的表观量子产率。

The first photoactivatable Raman imaging was demonstrated with biological-stable cyclopropenones. A series of organelle-targeting probes enable multiplex subcellular imaging and tracking in live cells.

第一个可光激活的拉曼成像是用生物稳定的环丙烯酮证明的。一系列细胞器靶向探针可在活细胞中实现多重亚细胞成像和跟踪。

The image represents the structure of figure-eight polycyclic aromatic hydrocarbon “infinitene” as a new topoisomer of kekulene (C48H24). Infinitene showed interesting physical and chiroptical properties unlike kekulene, and a simple and beautiful structure was revealed by X-ray crystallographic analysis. The image was illustrated by Dr. Issey Takahashi in Nagoya University.

该图像表示作为凯库烯 (C48H24) 的新拓扑异构体的 8 字形多环芳烃“无限烯”的结构。Infinitene 显示出与凯库烯不同的有趣的物理和手性光学性质，并且通过 X 射线晶体学分析揭示了一种简单而美丽的结构。该图像由名古屋大学的 Issey Takahashi 博士绘制插图。

We propose, for the first time, the concept of mechanically interlocked vitrimers (MIVs), which represents a new generation of mechanically interlocked networks by coupling mechanical bonds with dynamic covalent bonds. An unexpected synergistic effect between the dual dynamic entities highlights the importance of our design beyond the combination of mechanical and malleable properties.

我们首次提出了机械互锁 vitrimers (MIV) 的概念，它通过将机械键与动态共价键耦合来代表新一代机械互锁网络。双动态实体之间意想不到的协同效应突出了我们设计的重要性，超越了机械和可塑性的结合。

In MgVO3 with a 3d1 honeycomb lattice system, the neighboring 3dxy orbitals form a new bonding state (V–V dimers, a spin-singlet state), and they are arranged in a ladder-type manner.

在具有3d1蜂窝晶格系统的MgVO3中，相邻的3dxy轨道形成新的成键态（V-V二聚体，自旋单态），呈阶梯状排列。

The cover depicts single-atom dispersed catalysts decorating atomically dispersed Ru onto a nickel-vanadium layered double hydroxide, which can exhibit both excellent hydrogen evolution reaction and oxygen evolution reaction activities through a strong atomic metal–support interaction.

封面描绘了单原子分散催化剂将原子分散的 Ru 修饰到镍-钒层状双氢氧化物上，通过强原子金属-载体相互作用，它可以表现出优异的析氢反应和析氧反应活性。查看文章。

A series of poly(1,4-dihydropyridine)s without traditional luminescent units were developed and showed a bright fluorescence and long-emission wavelength phosphorescence. The emission wavelength can be simply tuned by the variation of the cluster sizes and molecular weight of the polymers due to the through-space conjugation between the heteroatoms and electronically unsaturated units.

开发了一系列没有传统发光单元的聚（1,4-二氢吡啶），并显示出明亮的荧光和长发射波长的磷光。由于杂原子和电子不饱和单元之间的空间共轭，聚合物的簇大小和分子量的变化可以简单地调节发射波长。

Electrochemical epoxide hydrogenation is reported. Various anti-Markovnikov and Markovnikov alcohols can be generated using electrons and protons as the hydrogen source. Of note, this protocol can serve as a modular synthetic route for electrohydrogenation of more challenging and inert oxetane, tetrahydrofuran, tetrahydropyran, and even larger oxepane derivatives.

报道了电化学环氧化物加氢。使用电子和质子作为氢源可以生成各种反马尔可夫尼科夫醇和马尔可夫尼科夫醇。值得注意的是，该协议可以作为模块化合成路线，用于更具挑战性和惰性的氧杂环丁烷、四氢呋喃、四氢吡喃，甚至更大的氧杂环丁烷衍生物的电氢化。

1.Polymerizations with Elemental Sulfur: From Petroleum Refining to Polymeric Materials.

用元素硫进行聚合：从石油炼制到聚合物材料。

2.Electrochemistry for the Chemoselective Modification of Peptides and Proteins.

肽和蛋白质的化学选择性修饰的电化学。

3.High-Performance Organic Electronic Materials by Contorting Perylene Diimides.

弯曲的苝二酰亚胺的高性能有机电子材料。

4.Single-molecule Detection of Ultrafast Biomolecular Dynamics with Nanophotonics.

用纳米光子技术对超快生物分子动力学的单分子检测。

5.Superfast Tetrazole–BCN Cycloaddition Reaction for Bioorthogonal Protein Labeling on Live Cells.

用于活细胞生物正交蛋白标记的超快四唑-BCN环化反应。

6.Medium and Large N-Heterocycle Formation via Allene Hydroamination with a Bimetallic Rh(II) Catalyst.

双金属Rh(II)催化剂通过烯烃水解形成大中型N-杂环。

7.Light Driven Ultrafast Bioinspired Molecular Motors: Steering and Accelerating Photoisomerization Dynamics of Retinal.

光驱动的超快生物启发分子马达：指导和加速视网膜的光异构化动态。

8.Site-Selective Surface Modification of 2D Superatomic Re6Se8.

二维超原子Re6Se8的位点选择性表面修饰.

9.An Enzymatic Platform for Primary Amination of 1-Aryl-2-alkyl Alkynes.

1-Aryl-2-alkyl Alkynes初级胺化的酶学平台.

10.Homologation of Electron-Rich Benzyl Bromide Derivatives via Diazo C–C Bond Insertion.

通过重氮C-C键插入实现富电子苄基溴化物的同源化.

11.Selective Isomerization via Transient Thermodynamic Control: Dynamic Epimerization of trans to cis Diols.

通过瞬时热力学控制的选择性异构化：反式与顺式二元醇的动态外嵌化。

12.Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids.

双环[3.2.1]辛烷的还原自由基环化策略：ent-Kaurane和Beyerane二萜化合物的合成。

13.One-Shot Synthesis of Expanded Heterohelicene Exhibiting Narrowband Thermally Activated Delayed Fluorescence.

一次性合成具有窄带热激活延迟荧光的膨胀异构体。

14.Reversible Iodine Capture by Nonporous Adaptive Crystals of a Bipyridine Cage.

双吡啶笼的无孔自适应晶体的可逆碘捕获。

15.A Concise Enantioselective Approach to Quassinoids.

喹诺酮类化合物的简明对映选择性方法。

16.Distal Ionic Substrate–Catalyst Interactions Enable Long-Range Stereocontrol: Access to Remote Quaternary Stereocenters through a Desymmetrizing Suzuki–Miyaura Reaction.

远端离子底物-催化剂的相互作用使远距离立体控制成为可能：通过去对称化的铃木-米亚乌拉反应获得遥远的季相立体中心。

17.Enantioselective Ni/N-Heterocyclic Carbene-Catalyzed Redox-Economical Coupling of Aldehydes, Alkynes, and Enones for Rapid Construction of Acyclic All-Carbon Quaternary Stereocenters.

烯烃、炔烃和烯烃的对映选择性Ni/N-杂环碳催化氧化还原经济耦合，快速构建无环的全碳四元立体中心。

18.Contra-Thermodynamic Positional Isomerization of Olefins.

烯烃的反热力学位置异构化。

19.Catalytic, contra-Thermodynamic Positional Alkene Isomerization.

催化、反热力学条件下的烯烃异构化。

20.Solar Energy Storage: Competition between Delocalized Charge Transfer and Localized Excited States in the Norbornadiene to Quadricyclane Photoisomerization.

太阳能储存：降冰片二烯到四环烷光致异构化中非局部电荷转移和局部激发态之间的竞争。

21.Conditionally Activatable Photoredox Catalysis in Living Systems.

活体系统中的条件性可激活光氧化催化。

22.Dual-Channel Fluorescent Probe for the Simultaneous Monitoring of Peroxynitrite and Adenosine-5′-triphosphate in Cellular Applications.

双通道荧光探针在细胞应用中同时监测过硫酸盐和腺苷-5′-三磷酸。

23.A Night-Time Edge Site Intermediate in the Cyanobacterial Circadian Clock Identified by EPR Spectroscopy.

EPR光谱法确定的蓝藻昼夜钟中的夜间边缘位点中间体。

24.Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling.

具有巨大磁电耦合作用的铁弹性自旋交叉复合物的域壁动力学。

25.A Successive Conversion–Deintercalation Delithiation Mechanism for Practical Composite Lithium Anodes.

实用复合锂电阳极的连续转化-去插层-脱硫机制。

26.Spiropyran Photoisomerization Dynamics in Multiresponsive Hydrogels.

多反应水凝胶中的斯皮罗吡喃光异构化动力学。

27.Cove-Edged Graphene Nanoribbons with Incorporation of Periodic Zigzag-Edge Segments.

含有周期性Zigzag边缘段的凹凸不平的石墨烯纳米带.

28.Reaction Mechanism of Li2MnO3 Electrodes in an All-Solid-State Thin-Film Battery Analyzed by Operando Hard X-ray Photoelectron Spectroscopy.

全固态薄膜电池中Li2MnO3电极的反应机制，通过操作性硬X射线光电子能谱分析。

29.Interface Dynamics in Ag–Cu3P Nanoparticle Heterostructures.

Ag-Cu3P纳米粒子异质结构中的界面动力学。

30.Identification of Cu(100)/Cu(111) Interfaces as Superior Active Sites for CO Dimerization During CO2 Electroreduction.

确定Cu(100)/Cu(111)界面为二氧化碳电还原过程中CO二聚体的最佳活性点。

31.Modulating Angiogenesis by Proteomimetics of Vascular Endothelial Growth Factor.

血管内皮生长因子的拟态物调节血管生成。

32.Temperature Cycling Enables Efficient 13C SABRE-SHEATH Hyperpolarization and Imaging of [1-13C]-Pyruvate.

温度循环使13C SABRE-SHEATH超极化和[1-13C]-丙酮酸的成像变得有效。

33.Total Synthesis and Biological Evaluation of Paenilamicins from the Honey Bee Pathogen Paenibacillus larvae.

来自蜜蜂病原体Paenibacillus larvae的Paenilamicins的全合成和生物学评价。

34.Enhanced Light Emission through Symmetry Engineering of Halide Perovskites.

通过卤化物过氧化物的对称性工程增强光发射。

35.Controlling Ligand Coordination Spheres and Cluster Fusion in Superatoms.

控制配体配位球和超原子中的团簇融合.

36.In Situ Synthesis of Natural Antioxidase Mimics for Catalytic Anti-Inflammatory Treatments: Rheumatoid Arthritis as an Example.

用于催化抗炎治疗的天然抗氧化酶模拟物的原位合成：以类风湿性关节炎为例.

37.Photomodulation of Transmembrane Transport and Potential by Stiff-Stilbene Based Bis(thio)ureas.

基于硬苯乙烯的双(硫)脲类物质对跨膜运输和电位的光调控.

38.Intermolecular 1,2-Difunctionalization of Alkenes Enabled by Fluoroamide-Directed Remote Benzyl C(sp3)–H Functionalization.

氟酰胺定向远程苄基 C(sp3)–H 官能化实现烯烃的分子间 1,2-双官能化。

39.Total Chemical Synthesis of Correctly Folded Disulfide-Rich Proteins Using a Removable O-Linked β-N-Acetylglucosamine Strategy.

使用可移除的O型链接β-N-乙酰葡糖胺策略进行正确折叠的富二硫化物蛋白质的全化学合成。

40.Versatile Fe–Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C–H Bond Activation.

金属卤素系统中多功能的Fe-Sn键相互作用：多重键和C-H键的激活。

41.Deoxyribonucleic Acid Encoded and Size-Defined π-Stacking of Perylene Diimides.

脱氧核糖核酸编码和尺寸定义的苝二酰亚胺的π-堆积。

42.End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy.

通过低温诱导/退火产生的端面铜(I)超氧化物和铜(II)过氧化物及氢过氧化物复合物，并通过EPR/ENDOR光谱学进行表征。

43.Fast Photoswitchable Order–Disorder Transitions in Liquid-Crystalline Block Co-oligomers.

液晶块状共混物中的快速光开关秩序-失序转换。

44.Dual Nanomechanics in Anisotropic Porous Covalent Organic Framework Janus-Type Thin Films.

各向异性多孔共价有机框架Janus型薄膜中的双重纳米力学。

45.Chemically Fueled Self-Sorted Hydrogels.

化学燃料的自排序水凝胶.

46.5f Covalency Synergistically Boosting Oxygen Evolution of UCoO4 Catalyst.

5f共价性协同促进UCoO4催化剂的氧进化。

47.Synthetic O-Acetylated Sialosides and their Acetamido-deoxy Analogues as Probes for Coronaviral Hemagglutinin-esterase Recognition.

作为冠状病毒血凝素酯酶识别探针的合成O-乙酰化唾液腺苷及其乙酰化脱氧类似物。

48.Superior Hard but Quickly Reversible Si–O–Si Network Enables Scalable Fabrication of Transparent, Self-Healing, Robust, and Programmable Multifunctional Nanocomposite Coatings.

坚硬而快速可逆的Si-O-Si网络使透明、自愈、稳健和可编程的多功能纳米复合涂层的可扩展制造成为可能。

49.Au and Pt Remain Unoxidized on a CeO2-Based Catalyst during the Water–Gas Shift Reaction.

水气变换反应中基于CeO2的催化剂上的金和铂保持未氧化状态。

50.DNA–Protein Cross-Linking Sequencing for Genome-Wide Mapping of Thymidine Glycol.

DNA-蛋白质交联测序用于胸苷二醇的全基因组测绘。

51.Alkanes versus Oligosilanes: Conformational Effects on σ-Electron Delocalization.

烷烃与低聚硅氧烷：σ-电子脱焦的构型影响。

52.Crystal Structure and Optical Properties of a Chiral Mixed Thiolate/Stibine-Protected Au18 Cluster.

手性混合硫酸盐/硫酸盐保护的Au18簇的晶体结构和光学特性。

53.It’s Complicated: On Relativistic Effects and Periodic Trends in the Melting and Boiling Points of the Group 11 Coinage Metals.

情况很复杂：论相对论的影响和第11组硬币金属熔点和沸点的周期性趋势。

54.Tris(4-bromophenyl)aminium Hexachloroantimonate-Mediated Intermolecular C(sp2)–C(sp3) Free Radical Coupling of Vindoline with β-Ketoesters and Related Compounds.

三（4-溴苯基）铵六氯锑酸盐介导的分子间 C(sp2)–C(sp3) 文多灵与 β-酮酯和相关化合物的自由基偶联。

55.Macromolecular Engineering of Thermoresponsive Metal–Phenolic Networks.

大分子工程的热敏性金属-酚醛网络。

56.Iron-Catalyzed Vinylzincation of Terminal Alkynes.

铁催化的末端炔的乙烯基锌化。

57.An Isolable Azide Adduct of Titanium(II) Follows Bifurcated Deazotation Pathways to an Imide.

钛(II)的一个可隔离的叠加物遵循分岔的脱氮途径，成为一个酰亚胺。

58.Molecular-Level Insights on Reactive Arrangement in On-Surface Photocatalytic Coupling Reactions Using Tip-Enhanced Raman Spectroscopy.

使用针尖增强拉曼光谱对表面光催化耦合反应中的活性排列的分子水平的洞察。

59.Preparation of Au@Pd Core–Shell Nanorods with fcc-2H-fcc Heterophase for Highly Efficient Electrocatalytic Alcohol Oxidation.

具有fcc-2H-fcc异相的Au@Pd核壳纳米棒的制备用于高效电催化酒精氧化.

60.Designing Tetraoxa[8]circulenes To Serve as Hosts and Sensors.

设计四氧[8]环烯作为宿主和传感器.

61.Pd/Fe2O3 with Electronic Coupling Single-Site Pd–Fe Pair Sites for Low-Temperature Semihydrogenation of Alkynes.

具有电子耦合单点Pd-Fe对位点的Pd/Fe2O3用于低温半氢化的炔类化合物。

62.Modulations of a Metal–Ligand Interaction and Photophysical Behaviors by Hückel–Möbius Aromatic Switching.

Hückel-Möbius 芳烃转换对金属-配体相互作用和光物理行为的调控。

63.Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions.

空气稳定的热发光碳二碳-氟硼离子。

64.A Change from Kinetic to Thermodynamic Control Enables trans-Selective Stereochemical Editing of Vicinal Diols.

从动力学控制到热力学控制的变化使维基尔二元醇的反选择立体化学编辑成为可能。

65.Development of Photolenalidomide for Cellular Target Identification.

用于细胞目标识别的光来那度胺的开发。

66.Oxide Ion and Proton Conductivity in a Family of Highly Oxygen-Deficient Perovskite Derivatives.

高缺氧过氧化物衍生物家族的氧离子和质子导电性。

67.Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis?.

电子和自旋电子开壳大分子，何去何从？

68.Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes.

亲电胺化试剂的氢化、氨基化和羧化：翁波龙促成的烯和炔的含N分子的调节和立体选择性合成。

69.Nickel-Catalyzed Addition of C–C Bonds of Amides to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction.

镍催化的酰胺类C-C键与受限烯烃的加成：1,2-氨基羰基化反应。

70.Reversible Methanolation of Metal Halide Perovskites.

金属卤化钙钛矿的可逆甲醇化。

71.Nonequilibrium Catalytic Supramolecular Assemblies of Melamine- and Imidazole-Based Dynamic Building Blocks.

基于三聚氰胺和咪唑的动态构件的非平衡催化超分子组合。

72.Organocatalytic, Stereoselective, Cationic Reversible Addition–Fragmentation Chain-Transfer Polymerization of Vinyl Ethers.

乙烯基醚的有机催化、立体选择性、阳离子可逆加成-断裂链转移聚合。

73.Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal–Organic Framework.

中多孔金属有机框架中均匀催化剂的表面密封封装。

74.A 59-Electron Non-Magic-Number Gold Nanocluster Au99(C≡CR)40 Showing Unexpectedly High Stability.

一种59电子的非魔数金纳米簇Au99(C≡CR)40表现出意想不到的高稳定性。

75.Molecular Photocatalytic Water Splitting by Mimicking Photosystems I and II.

模仿光系统I和II的分子光催化水分离。

76.Discovery of a Covalent FEM1B Recruiter for Targeted Protein Degradation Applications.

发现一种共价的FEM1B招募剂用于靶向蛋白降解应用。

77.Evidence for a Long-Lived, Cu-Coupled and Oxygen-Inert Disulfide Radical Anion in the Assembly of Metallothionein-3 Cu(I)4-Thiolate Cluster.

在金属硫蛋白-3 Cu(I)4-硫醇盐簇的组装中发现了长寿命、Cu-耦合和氧惰性二硫化物自由基阴离子的证据。

78.Chemisorption-Induced Formation of Biphenylene Dimer on Ag(111).

Ag(111)上化学吸附诱导的联苯二聚体的形成。

79.Quantification of the Effect of an External Magnetic Field on Water Oxidation with Cobalt Oxide Anodes.

外部磁场对氧化钴阳极水氧化作用的量化。

80.Binary Au–Cu Reaction Sites Decorated ZnO for Selective Methane Oxidation to C1 Oxygenates with Nearly 100% Selectivity at Room Temperature.

二元金-铜反应点装饰的氧化锌在室温下以近100%的选择性将甲烷氧化为C1含氧化合物。

81.Direct Observation of Anthracene Clusters at Ice Surfaces.

直接观察冰面上的蒽簇。

82.Machine Learning Assisted Simultaneous Structural Profiling of Differently Charged Proteins in a Mycobacterium smegmatis Porin A (MspA) Electroosmotic Trap.

机器学习辅助下的不同电荷蛋白的同步结构剖析--烟曲霉菌Porin A (MspA)电渗陷阱。