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【标题速读】【Angew】【2022年】【2月】

2023-08-15 00:30 作者:Rt_Cola  | 我要投稿

声明:本专栏主要对生命科学领域的一些期刊文章标题进行翻译,所有内容均由本人手工整理翻译。由于本人专业为生物分析相关,其他领域如果出现翻译错误请谅解。

1.SO2 and NO2 are important air pollutants, and understanding the mechanism of capture materials drives the development of new clean-up technologies. In situ synchrotron X-ray crystallographic and spectroscopic experiments were used by Sihai Yang, Wei Shi et al. in their Research Article (e202115585) to establish a detailed molecular mechanism consisting of reversible coordination of SO2 and NO2 at the six open NiII sites on the unprecedented {Ni12}-wheel of a robust metal–organic framework material (NKU-100) at crystallographic resolution.

SO2 和 NO2 是重要的空气污染物,了解捕获材料的机制推动了新清洁技术的发展。杨四海、石伟等人采用原位同步加速器X射线晶体学和光谱实验。在他们的研究文章 (e202115585) 中,建立了一种详细的分子机制,该机制由 SO2 和 NO2 在晶体学上坚固的金属有机骨架材料 (NKU-100) 的前所未有的 {Ni12} 轮上的六个开放 NiII 位点上的可逆配位组成解决。

2.Dianion and dication of a tetracyclopentatetraphenylene derivative were generated and characterized by spectroscopic methods and X-ray crystallography to reveal that the outer and inner conjugation circuits are significantly decoupled as theoretically predicted. The magnetically induced ring currents of the outer and inner circuits flow clockwise and counterclockwise, respectively, in the same direction as the trains run on the outer and inner loops of Osaka Loop Line, as reported by Ichiro Hisaki, Marina A. Petrukhina, Tohru Nishinaga, Masayoshi Nakano, Yoshito Tobe, and co-workers in their Research Article (e202115316).

生成了四环戊四亚苯基衍生物的二价阴离子和二价阳离子,并通过光谱方法和 X 射线晶体学进行了表征,揭示了外部和内部共轭电路按照理论预测显着解耦。据 Ichiro Hisaki、Marina A. Petrukhina、Tohru Nishinaga 报道,外环线和内环线的磁感应环电流分别顺时针和逆时针流动,与大阪环线外环线和内环线的列车运行方向相同。 、Masayoshi Nakano、Yoshito Tobe 及其同事在他们的研究文章 (e202115316) 中。

3.An atomic bridging structure of nickel–nitrogen–carbon active sites confined in porous carbon was revealed by Jintao Zhang and co-workers in their Research Article (e202113918). Uncovering the fundamental mechanism reveals a high potential for modulating bridging structures to enhance interfacial electrocatalytic reactions beyond carbon dioxide reduction.

Jintao Zhang 及其同事在他们的研究文章 (e202113918) 中揭示了限制在多孔碳中的镍-氮-碳活性位点的原子桥结构。揭示基本机制揭示了调节桥接结构以增强二氧化碳还原之外的界面电催化反应的巨大潜力。

4.Aromatics-permeable membranes made from polydimethylsiloxane with tunable side group mobilities are reported by Gongping Liu and co-workers in their Research Article (e202111810). Phenyl groups were introduced as rigid molecular spacers to endow the methyl groups with high mobility and reconstruct the polymer conformation, creating a highway for the fast transport of aromatic molecules, and thus realizing efficient removal of aromatic compounds from aqueous solution.

Gangping Liu 及其同事在他们的研究文章 (e202111810) 中报道了由聚二甲基硅氧烷制成的具有可调侧基迁移率的芳烃渗透膜。引入苯基作为刚性分子间隔基,赋予甲基高流动性并重构聚合物构象,为芳香分子的快速传输创造一条高速公路,从而实现从水溶液中高效去除芳香化合物。

5.Electrochemistry. An electrochemical desaturative α-acylation of cyclic N-aryl amines to access α-substituted enamines is reported in the Communication by Youai Qiu et al. (e202115178).

电化学。 Youai Qiu 等人在通讯中报道了环状 N-芳基胺的电化学去饱和 α-酰化反应以得到 α-取代的烯胺。 (e202115178)。

6.Microwave Chemistry. In their Research Article (e202114340), Hong Li, Xin Gao et al. report the detection of microwave-induced hot spots in liquid solutions with a fluorescence thermometer attached on microwave-absorbing carbon particles.

微波化学。 Hong Li、Xin Gaut 等人在他们的研究文章 (e202114340) 中。报告用附着在微波吸收碳颗粒上的荧光温度计检测液体溶液中微波引起的热点。

7.The Mechanism of Piezocatalysis: Energy Band Theory or Screening Charge Effect?.

压电催化机制:能带理论还是屏蔽电荷效应?

8.Quantifying Mechanical Properties of Molecular Crystals: A Critical Overview of Experimental Elastic Tensors.

量化分子晶体的力学性质:实验弹性张量的重要概述。

9.Watching Microwave-Induced Microscopic Hot Spots via the Thermosensitive Fluorescence of Europium/Terbium Mixed-Metal Organic Complexes.

通过铕/铽混合金属有机络合物的热敏荧光观察微波引起的微观热点。

10.A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization.

带有刚性二齿硼烷/膦配体的 Ni0 σ-硼烷配合物:通过氧化脱氢氯硼化形成硼基配合物以及乙烯聚合的催化活性。

11.PDMS with Tunable Side Group Mobility and Its Highly Permeable Membrane for Removal of Aromatic Compounds.

具有可调侧基迁移率的 PDMS 及其用于去除芳香族化合物的高渗透膜。

12.Atomic Bridging Structure of Nickel–Nitrogen–Carbon for Highly Efficient Electrocatalytic Reduction of CO2.

用于高效电催化还原二氧化碳的镍-氮-碳原子桥结构。

13.Low-Symmetry MOF-Based Patchy Colloids and Their Precise Linking via Site-Selective Liquid Bridging to Form Supra-Colloidal and Supra-Framework Architectures.

基于 MOF 的低对称性片状胶体及其通过位点选择性液体桥接的精确连接,形成超胶体和超框架结构。

14.Tunable Second-Level Room-Temperature Phosphorescence of Solid Supramolecules between Acrylamide–Phenylpyridium Copolymers and Cucurbit[7]uril.

丙烯酰胺-苯基吡啶共聚物和葫芦[7]脲之间固体超分子的可调谐二级室温磷光。

15.Dianion and Dication of Tetracyclopentatetraphenylene as Decoupled Annulene-within-an-Annulene Models.

四环戊四亚苯基的双阴离子和双阳离子作为环烯内解耦的环烯模型。

16.Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction.

金属化促进的稳健的基于卟啉的氢键有机框架用于光催化二氧化碳还原。

17.Scalable Molten Salt Synthesis of Platinum Alloys Planted in Metal–Nitrogen–Graphene for Efficient Oxygen Reduction.

金属-氮-石墨烯中种植的铂合金的可扩展熔盐合成,用于有效的氧还原。

18.A {Ni12}-Wheel-Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide.

用于二氧化硫和二氧化氮配位结合的{Ni12}-轮基金属有机框架。

19.Circular Permutated PQQ-Glucose Dehydrogenase as an Ultrasensitive Electrochemical Biosensor.

圆形排列 PQQ-葡萄糖脱氢酶作为超灵敏电化学生物传感器。

20.Assembly of Hexagonal Column Interpenetrated Spheres from Plant Polyphenol/Cationic Surfactants and Their Application as Antimicrobial Molecular Banks.

植物多酚/阳离子表面活性剂六角柱互穿球的组装及其作为抗菌分子库的应用。

21.Heteroatom-Embedded Approach to Vinylene-Linked Covalent Organic Frameworks with Isoelectronic Structures for Photoredox Catalysis.

用于光氧化还原催化的具有等电子结构的亚乙烯基连接的共价有机框架的杂原子嵌入方法。

22.Azaphilones as Activation-Free Primary-Amine-Specific Bioconjugation Reagents for Peptides, Proteins and Lipids.

氮杂菲酮作为肽、蛋白质和脂质的免活化伯胺特异性生物共轭试剂。

23.Fluorescence Imaging of Mitochondrial DNA Base Excision Repair Reveals Dynamics of Oxidative Stress Responses.

线粒体 DNA 碱基切除修复的荧光成像揭示了氧化应激反应的动态。

24.Bioorthogonal Ligation-Activated Fluorogenic FRET Dyads.

生物正交连接激活的荧光 FRET 二元组。

25.Imaging Membrane Order and Dynamic Interactions in Living Cells with a DNA Zipper Probe.

使用 DNA 拉链探针对活细胞中的膜秩序和动态相互作用进行成像。

26.Radiation Chemistry Provides Nanoscopic Insights into the Role of Intermediate Phases in CeO2 Mesocrystal Formation.

辐射化学为 CeO2 介晶形成中中间相的作用提供了纳米视角的见解。

27.Stabilizing Interface pH by N-Modified Graphdiyne for Dendrite-Free and High-Rate Aqueous Zn-Ion Batteries.

通过 N-改性石墨炔稳定界面 pH 值,用于无枝晶和高倍率水性锌离子电池。

28.Design and Development of a Bioorthogonal, Visualizable and Mitochondria-Targeted Hydrogen Sulfide (H2S) Delivery System.

生物正交、可视化和线粒体靶向的硫化氢 (H2S) 输送系统的设计和开发。

29.Highly Durable and Fully Dispersed Cobalt Diatomic Site Catalysts for CO2 Photoreduction to CH4.

高度耐用且完全分散的钴双原子位点催化剂,用于 CO2 光还原生成 CH4。

30.Oriented Two-Dimensional Covalent Organic Framework Membranes with High Ion Flux and Smart Gating Nanofluidic Transport.

具有高离子通量和智能门控纳流体传输的定向二维共价有机框架膜。

31.Unraveling the Electrical and Magnetic Properties of Layered Conductive Metal-Organic Framework With Atomic Precision.

以原子精度揭示层状导电金属有机框架的电学和磁性。

32.A DNA Nanocomplex Containing Cascade DNAzymes and Promoter-Like Zn-Mn-Ferrite for Combined Gene/Chemo-dynamic Therapy.

一种含有级联 DNAzymes 和启动子样 Zn-Mn-Ferrite 的 DNA 纳米复合物,用于基因/化学动力学联合治疗。

33.Bimetallic Two-Dimensional Metal–Organic Frameworks for the Chemiresistive Detection of Carbon Monoxide.

用于一氧化碳化学电阻检测的双金属二维金属有机框架。

34.Synthetic Silica Nano-Organelles for Regulation of Cascade Reactions in Multi-Compartmentalized Systems.

用于调节多室系统中级联反应的合成二氧化硅纳米细胞器。

35.Möbius ZnII-Hexaphyrins Bearing a Chiral Coordinating Arm: A Chiroptical Switch Featuring P/M Twist Inversion Controlled by Achiral Effectors.

带有手性协调臂的莫比乌斯 ZnII-六菲林:一种手性光学开关,具有由非手性效应器控制的 P/M 扭转反转。

36.Altering Chain Flexibility of Aliphatic Polyesters for Yellow-Green Clusteroluminescence in 38 % Quantum Yield.

改变脂肪族聚酯的链柔韧性以实现 38% 量子产率的黄绿色簇发光。

37.Titanocene(III)-Catalyzed Precision Deuteration of Epoxides.

二茂钛 (III) 催化环氧化物的精密氘化。

38.A Supramolecular Polymer Constituted of Antiaromatic NiII Norcorroles.

一种由抗芳香族 NiII Norcorroles 组成的超分子聚合物。

39.Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen.

砷和氮的高压高温化学反应生成单键立方 AsN。

40.A Phenanthrocarbazole-Based Dopant-Free Hole-Transport Polymer with Noncovalent Conformational Locking for Efficient Perovskite Solar Cells.

一种基于菲咔唑的无掺杂空穴传输聚合物,具有非共价构象锁定,用于高效钙钛矿太阳能电池。

41.SnF2-Catalyzed Formation of Polymerized Dioxolane as Solid Electrolyte and its Thermal Decomposition Behavior.

SnF2 催化聚合二氧戊环固体电解质的形成及其热分解行为。

42.A Hydrogen-Bonded Ravel Assembled by Anion Coordination.

通过阴离子配位组装的氢键拉维尔。

43.One-Pot Synthesis of Melt-Processable Supramolecular Soft Actuators.

可熔融加工的超分子软执行器的一锅法合成。

44.Stereoselective O-Glycosylations by Pyrylium Salt Organocatalysis.

通过吡喃鎓盐有机催化进行立体选择性 O-糖基化。

45.Electrochemical Desaturative β-Acylation of Cyclic N-Aryl Amines.

环状 N-芳基胺的电化学去饱和 β-酰化。

46.Detection of Bacterial Rhamnolipid Toxin by Redox Liposome Single Impact Electrochemistry.

氧化还原脂质体单次冲击电化学检测细菌鼠李糖脂毒素。

47.Nickel-Catalyzed Stereo- and Enantioselective Cross-Coupling of gem-Difluoroalkenes with Carbon Electrophiles by C−F Bond Activation.

通过 C−F 键活化,镍催化偕二氟烯烃与碳亲电子试剂的立体和对映选择性交叉偶联。

48.Highly Efficient Light-Emitting Diodes Based on an Organic Antimony(III) Halide Hybrid.

基于有机卤化锑 (III) 混合物的高效发光二极管。

49.Biosynthesis of Gut-Microbiota-Derived Lantibiotics Reveals a Subgroup of S8 Family Proteases for Class III Leader Removal.

肠道微生物群衍生的羊毛硫抗生素的生物合成揭示了用于去除 III 类前导序列的 S8 家族蛋白酶亚组。

50.Enantioselective Synthesis of Dithia[5]helicenes and their Postsynthetic Functionalization to Access Dithia[9]helicenes.

Dithia[5]helicenes 的对映选择性合成及其合成后官能化以获取 Dithia[9]helicenes。

51.Catalytic Asymmetric Homologation of 4-Substituted Cyclohexanones with CF3CHN2: Enantioselective Synthesis of α-Trifluoromethyl Cycloheptanones.

4-取代环己酮与 CF3CHN2 的催化不对称同系化:α-三氟甲基环庚酮的对映选择性合成。

52.Site-Specific Conjugation of a Selenopolypeptide to Alpha-1-antitrypsin Enhances Oxidation Resistance and Pharmacological Properties.

硒多肽与 Alpha-1-抗胰蛋白酶的位点特异性结合可增强氧化抗性和药理学特性。

53.Expeditious and Efficient ortho-Selective Trifluoromethane-sulfonylation of Arylhydroxylamines.

芳基羟胺的快速高效的邻位选择性三氟甲烷磺酰化。

54.A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep-UV Transparency.

具有强烈 SHG 响应和宽深紫外透明度的硫酸镧铵复盐。

55.Characterization of Mannosyl Dioxanium Ions in Solution Using Chemical Exchange Saturation Transfer NMR Spectroscopy.

使用化学交换饱和转移核磁共振波谱表征溶液中的甘露糖基二氧根离子。

56.Indomethacin is an anti-inflammatory drug that has been marketed since 1965. The third polymorph, Form δ, was discovered by both melt and solution crystallization in 1974. By using a combination of 3D electron diffraction (3D ED or MicroED) and microdroplet melt crystallization, Ming Lu, Hongyi Xu et al. reveal in their Research Article (e202114985) that Form δ consists of two plastically bendable crystal forms. This discovery and the correction of a 47-year-old misunderstanding signify that MicroED diffraction has become a powerful tool for polymorphic structural studies.

吲哚美辛是一种抗炎药,自 1965 年起上市。第三种多晶型物 δ 型于 1974 年通过熔融结晶和溶液结晶发现。通过结合使用 3D 电子衍射(3D ED 或 MicroED)和微滴熔融结晶,卢明,徐宏毅等。在他们的研究文章 (e202114985) 中揭示,δ 型由两种可塑性弯曲的晶体形式组成。这一发现以及对长达47年的误解的纠正,标志着MicroED衍射已成为多晶型结构研究的有力工具。

57.A loop deletion mutant of outer membrane protein F (OmpF) that facilitates the cellular uptake of decoy molecules into Escherichia coli has been developed. In their Communication (e202111612), Osami Shoji and co-workers report that co-expression of the OmpF mutant with wild-type CYP102A1 enables an E. coli-based whole-cell biocatalyst to efficiently oxidise benzene, alkyl- and cycloalkylbenzenes with the help of decoy molecules, bringing this system a significant step closer to practical applications.

外膜蛋白 F (OmpF) 的环缺失突变体可促进大肠杆菌将诱饵分子摄取。 Osami Shoji 及其同事在他们的通讯 (e202111612) 中报告说,OmpF 突变体与野生型 CYP102A1 的共表达使得基于大肠杆菌的全细胞生物催化剂能够有效氧化苯、烷基苯和环烷基苯。诱饵分子,使该系统更接近实际应用。

58.The purple cloud (HasA; a heme acquisition protein) delivers cobalt oxaporphyrinium (orange porphyrin and red oxygen) to Pseudomonas aeruginosa (green). Reconstructed HasA has the ability to combat Pseudomonas aeruginosa. The willow shown in the picture is associated with death, symbolizing growth inhibition of Pseudomonas aeruginosa by reconstructed HasA, as detailed in the Communication by Osami Shoji, Hiroshi Shinokubo, and co-workers (e202112456).

紫色云(HasA;一种血红素获取蛋白)将氧卟啉钴(橙色卟啉和红色氧)传递给铜绿假单胞菌(绿色)。重建的HasA具有对抗铜绿假单胞菌的能力。图中显示的柳树与死亡相关,象征着重建的 HasA 对铜绿假单胞菌的生长抑制,如 Osami Shoji、Hiroshi Shinokubo 和同事的通讯 (e202112456) 中详细介绍的。

59.The concept of self-expanding lithium-ion transport channels to construct a fast-charging anode is proposed by Guoxing Li, Yuliang Li, and co-workers in their Research Article (e202113313). The self-expanding lithium-ion transport channels can be achieved by a self-reversible conversion of chemical bonds with different bond lengths in the anode driven by the interactions with lithium ions during cycling. They reduce the energy barrier of lithium-ion transport, accelerate lithium-ion solid-state diffusion, and thus enable an excellent fast-charging performance.

李国兴、李玉良等人在他们的研究文章(e202113313)中提出了通过自扩展锂离子传输通道构建快速充电阳极的概念。自膨胀的锂离子传输通道可以通过循环过程中与锂离子的相互作用驱动的阳极中不同键长的化学键的自可逆转换来实现。它们降低了锂离子传输的能垒,加速了锂离子固态扩散,从而实现了优异的快速充电性能。

60.Nanomotors 2D nanobots based on soft nanoarchitectonics powered by an ultralow fuel concentration are reported in the Communication by Motilal Mathesh, Elisha Bhattarai, and Wenrong Yang (e202113801).

Motilal Mathesh、Elisha Bhattarai 和 Wenrong Yang 的通讯 (e202113801) 报道了基于软纳米结构、由超低燃料浓度驱动的纳米电机 2D 纳米机器人。

61.Li–S Batteries In their Research Article (e202114671), Bo-Quan Li, Qiang Zhang et al. identify the surface gelation on disulfide electrocatalysts in Li–S batteries for the first time.

锂硫电池 在他们的研究文章 (e202114671) 中,Bo-Quan Li、Qiang Zhu 等人。首次确定锂硫电池中二硫化物电催化剂的表面凝胶化。

62.Chemical Batteries with CO2.

含有二氧化碳的化学电池。

63.Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C−C Bond Formation.

过渡金属催化的单氟烷基化:通过 C−C 键形成合成烷基氟化物的策略。

64.Surface Gelation on Disulfide Electrocatalysts in Lithium–Sulfur Batteries.

锂硫电池中二硫化物电催化剂的表面凝胶化。

65.Indomethacin Polymorph δ Revealed To Be Two Plastically Bendable Crystal Forms by 3D Electron Diffraction: Correcting a 47-Year-Old Misunderstanding.

3D 电子衍射显示吲哚美辛多晶型 δ 是两种可塑性弯曲的晶型:纠正 47 年的误解。

66.Manipulation of Multiple Cell–Cell Interactions by Tunable DNA Scaffold Networks.

通过可调谐 DNA 支架网络操纵多个细胞间相互作用。

67.A Universal Boronate-Affinity Crosslinking-Amplified Dynamic Light Scattering Immunoassay for Point-of-Care Glycoprotein Detection.

用于护理点糖蛋白检测的通用硼酸盐亲和交联放大动态光散射免疫测定。

68.An Activatable Hybrid Organic–Inorganic Nanocomposite as Early Evaluation System of Therapy Effect.

一种可激活的杂化有机-无机纳米复合材料作为治疗效果的早期评估系统。

69.Dual-Regulation of Defect Sites and Vertical Conduction by Spiral Domain for Electrocatalytic Hydrogen Evolution.

电催化析氢的螺旋域对缺陷位点和垂直传导的双重调节。

70.Highly Efficient Synthesis of Poly(silylether)s: Access to Degradable Polymers from Renewable Resources.

聚(甲硅烷基醚)的高效合成:从可再生资源中获取可降解聚合物。

71.The Crystal Plane is not the Key Factor for CO2-to-Methane Electrosynthesis on Reconstructed Cu2O Microparticles.

晶面并不是重构 Cu2O 微粒上 CO2 电合成甲烷的关键因素。

72.Branched Poly(Aryl Piperidinium) Membranes for Anion-Exchange Membrane Fuel Cells.

用于阴离子交换膜燃料电池的支化聚(芳基哌啶鎓)膜。

73.Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst.

远程氨基酸识别能够在锰氧化催化剂上有效激活过氧化氢。

74.Reversible Covalent Headpiece Enables Interconversion between Double- and Single-Stranded DNA-Encoded Chemical Libraries.

可逆共价头能够实现双链和单链 DNA 编码化学文库之间的相互转换。

75.One-Pot Construction of Sulfur-Rich Thermoplastic Elastomers Enabled by Metal-Free Self-Switchable Catalysis and Air-Assisted Coupling.

通过无金属自切换催化和空气辅助耦合实现富硫热塑性弹性体的一锅法构建。

76.Copper-Catalyzed Asymmetric Diyne Cyclization via [1,2]-Stevens-Type Rearrangement for the Synthesis of Chiral Chromeno[3,4-c]pyrroles.

通过[1,2]-Stevens型重排的铜催化不对称二炔环化合成手性色并[3,4-c]吡咯。

77.Transformation of Crowded Oligoarylene into Perylene-Cored Chiral Nanographene by Sequential Oxidative Cyclization and 1,2-Phenyl Migration.

通过连续氧化环化和 1,2-苯基迁移将拥挤的低聚亚芳基转化为苝核手性纳米石墨烯。

78.Regio- and Diastereoselective [3+2] Annulation of Aliphatic Aldimines with Alkenes by Scandium-Catalyzed β-C(sp3)−H Activation.

通过钪催化的 β-C(sp3)−H 活化,脂肪族醛亚胺与烯烃的区域和非对映选择性 [3+2] 成环。

79.WSe2 Flakelets on N-Doped Graphene for Accelerating Polysulfide Redox and Regulating Li Plating.

N掺杂石墨烯上的WSe2薄片用于加速多硫化物氧化还原和调节锂镀层。

80.A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones.

氟代烷基酮的渐进式(氘代)加氢脱氟的卡宾策略。

81.A General Approach to Design Dual Ratiometric Fluorescent and Photoacoustic Probes for Quantitatively Visualizing Tumor Hypoxia Levels In Vivo.

设计双比率荧光和光声探针用于定量可视化体内肿瘤缺氧水平的通用方法。

82.Self-Expanding Ion-Transport Channels on Anodes for Fast-Charging Lithium-Ion Batteries.

用于快速充电锂离子电池的阳极上的自扩展离子传输通道。

83.Unexpected Role of a Short-Chain Dehydrogenase/Reductase Family Protein in Type II Polyketide Biosynthesis.

短链脱氢酶/还原酶家族蛋白在 II 型聚酮化合物生物合成中的意外作用。

84.Refining of Particulates at Stimuli-Responsive Interfaces: Label-Free Sorting and Isolation.

刺激响应界面处的颗粒精炼:无标记分选和分离。

85.Single-Cell Visualization of Monogenic RNA G-quadruplex and Occupied G-quadruplex Ratio through a Module-Assembled Multifunctional Probes Assay (MAMPA).

通过模块组装多功能探针测定 (MAMPA) 实现单基因 RNA G 四链体和占用 G 四链体比率的单细胞可视化。

86.Promoting CO2 Electroreduction Kinetics on Atomically Dispersed Monovalent ZnI Sites by Rationally Engineering Proton-Feeding Centers.

通过合理设计质子供给中心促进原子分散的单价 ZnI 位点上的 CO2 电还原动力学。

87.Rational Design of Axially Chiral Styrene-Based Organocatalysts and Their Application in Catalytic Asymmetric (2+4) Cyclizations.

轴向手性苯乙烯基有机催化剂的合理设计及其在催化不对称(2+4)环化中的应用。

88.Initiating Electron Transfer in Doubly Curved Nanographene Upon Supramolecular Complexation of C60.

C60 超分子络合引发双曲纳米石墨烯中的电子转移。

89.Lactone Backbone Density in Rigid Electron-Deficient Semiconducting Polymers Enabling High n-type Organic Thermoelectric Performance.

刚性缺电子半导体聚合物中的内酯主链密度可实现高 n 型有机热电性能。

90.Preparing Two-Dimensional Ordered Li0.33La0.557TiO3 Crystal in Interlayer Channel of Thin Laminar Inorganic Solid-State Electrolyte towards Ultrafast Li+ Transfer.

在薄层状无机固态电解质的层间通道中制备二维有序 Li0.33La0.557TiO3 晶体以实现超快 Li+ 传输。

91.Transformation Pathways in Colloidal CdTeSe Magic-Size Clusters.

胶体 CdTeSe 神奇大小团簇的转化途径。

92.2D Active Nanobots Based on Soft Nanoarchitectonics Powered by an Ultralow Fuel Concentration.

基于软纳米结构的二维主动纳米机器人,由超低燃料浓度提供动力。

93.Collateral Damage Occurs When Using Photosensitizer Probes to Detect or Modulate Nucleic Acid Modifications.

使用光敏剂探针检测或调节核酸修饰时会发生附带损害。

94.A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa.

用钴 5-氧代卟啉鎓阳离子重建的血红素获取蛋白及其对多重耐药铜绿假单胞菌的生长抑制活性。

95.Identification of Cyclopropane Formation in the Biosyntheses of Hormaomycins and Belactosins: Sequential Nitration and Cyclopropanation by Metalloenzymes.

激素和贝乳糖素生物合成中环丙烷形成的鉴定:金属酶的连续硝化和环丙烷化。

96.Two Giant Calixarene-Like Polyoxoniobate Nanocups {Cu12Nb120} and {Cd16Nb128} Built from Mixed Macrocyclic Cluster Motifs.

由混合大环簇基序构建的两个巨型杯芳烃类聚氧铌酸盐纳米杯{Cu12Nb120}和{Cd16Nb128}。

97.Enantioselective Synthesis of Oxazaborolidines by Palladium-Catalyzed N−H/B−H Double Activation of 1,2-Azaborines.

钯催化 1,2-氮杂硼烷的 N−H/B−H 双重活化对映选择性合成 Oxazaborolidines。

98.Optical Cell Tagging for Spatially Resolved Single-Cell RNA Sequencing.

用于空间分辨单细胞 RNA 测序的光学细胞标记。

99.Single-Ion Lithium Conducting Polymers with High Ionic Conductivity Based on Borate Pendant Groups.

基于硼酸盐侧基的具有高离子电导率的单离子锂导电聚合物。

100.Mechanochemical Solvent-Free Suzuki–Miyaura Cross-Coupling of Amides via Highly Chemoselective N−C Cleavage.

通过高度化学选择性 N−C 裂解进行酰胺的机械化学无溶剂 Suzuki-Miyaura 交叉偶联。

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【标题速读】【Angew】【2022年】【2月】的评论 (共 条)

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