【标题速读】【Angew】【2022年】【6月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Operando spectroscopy captures the dynamic behavior of ceria-supported Pd single atoms, clusters, and nanoparticles during CO oxidation. In their Research Article (e202200434), Emiel J. M. Hensen et al. elucidate the catalytic role of different Pd species using a combination of in situ spectroscopy with transient and steady-state kinetic analysis. Highly dispersed Pd–oxo species and interfacial Pd sites catalyze low-temperature CO oxidation, while metallic Pd contributes to the activity at elevated temperature.

Operando 光谱捕获二氧化铈支撑的 Pd 单原子、簇和纳米颗粒在 CO 氧化过程中的动态行为。 Emiel J. M. Hensen 等人在他们的研究文章 (e202200434) 中利用原位光谱与瞬态和稳态动力学分析相结合，阐明了不同 Pd 物种的催化作用。高度分散的 Pd-oxo 物种和界面 Pd 位点催化低温 CO 氧化，而金属 Pd 则有助于高温下的活性。

2.The precursor 4,5,9,10-tetrakis(3-methylnaphthalen-2-yl)pyrene is synthesized in solution, sublimed on an Au(111) substrate under ultrahigh vacuum conditions, and converted into the peri-heptacene molecule by thermal activation via surface-assisted oxidative ring-closure and cyclodehydrogenation reactions. Details of this research can be found in the Communication by José I. Urgel, Pavel Jelínek, Xinliang Feng, David Écija, and co-workers (e202114983).

在溶液中合成前体 4,5,9,10-四(3-甲基萘-2-基)芘，在超高真空条件下在 Au(111) 基底上升华，并通过热活化转化为近庚苯分子通过表面辅助的氧化闭环和环脱氢反应。有关这项研究的详细信息，请参阅 José I. Urgel、Pavel Jelínek、Xinliang Feng、David Écija 及其同事的通讯 (e202114983)。

3.Breslow intermediates (BIs) are pivotal species in Umpolung catalysis effected by N-heterocyclic carbenes (NHCs). For their formation from aldehydes and NHCs, a long-standing riddle has been the mechanism by which the zwitterionic primary intermediate is converted into the BI, as the C-to-O 1,2-H-shift involved is kinetically highly disfavored. The kinetic study described by Albrecht Berkessel and co-workers in their Research Article (e202117682) shows that under aprotic conditions, the BI itself effects this critical H-shift in an autocatalytic fashion. Cover art: Andrea Bertl.

Breslow 中间体 (BI) 是 N-杂环卡宾 (NHC) 影响的 Umpolung 催化中的关键物质。对于它们从醛和 NHC 的形成，两性离子主要中间体转化为 BI 的机制一直是一个长期存在的谜团，因为所涉及的 C-to-O 1,2-H-转变在动力学上是非常不利的。 Albrecht Berkessel 及其同事在其研究文章 (e202117682) 中描述的动力学研究表明，在非质子条件下，BI 本身以自催化方式影响这一关键的 H 转变。封面艺术：安德里亚·伯特尔。

4.The vortex fluidic device accelerated immunoblot assay (VAIA) is a new method that reduces immunoblot processing time from nearly 2 h to less than 5 min. In their Communication (e202202021), Gregory A. Weiss and co-workers demonstrate the broad applicability and potential of VAIA. In the picture, the artistic interpretation of VAIA demonstrates how the unique thin film microfluidics of the vortex fluidic device can accelerate immunoblot processing.

涡流流体装置加速免疫印迹测定 (VAIA) 是一种新方法，可将免疫印迹处理时间从近 2 小时缩短至不到 5 分钟。 Gregory A. Weiss 和同事在他们的通讯 (e202202021) 中展示了 VAIA 的广泛适用性和潜力。图中，VAIA 的艺术诠释展示了涡流流体装置独特的薄膜微流体如何加速免疫印迹处理。

5.Asymmetric Catalysis An enantio- and diastereoselective copper-catalyzed allylboration of alkynes with allylic gem-dichlorides is reported by Martín Fañanás-Mastral et al. in their Communication (e202117696).

不对称催化 Martín Fañanás-Mastral 等人在他们的通讯（e202117696）中报道了炔烃与烯丙基偕二氯化物的对映和非对映选择性铜催化烯丙基硼化反应。

6.Polymorphism In their Research Article (e202200954), Kana M. Sureshan et al. report a topochemical reaction yielding polymorphs of triazolyl-linked polyinositol.

多态性。在他们的研究文章 (e202200954) 中，Kana M. Sureshan 等人报道了一种拓扑化学反应，产生了三唑基连接的聚肌醇的多晶型物。

7.Photoinduced Controlled/Living Polymerizations.

光诱导的受控/活性聚合。

8.Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?.

拓扑化学假设：它们与高温下发生的拓扑化学反应相关吗？

9.Operando Spectroscopy Unveils the Catalytic Role of Different Palladium Oxidation States in CO Oxidation on Pd/CeO2 Catalysts.

原位光谱揭示了不同钯氧化态在 Pd/CeO2 催化剂上 CO 氧化中的催化作用。

10.Redox-Addressable Single-Molecule Junctions Incorporating a Persistent Organic Radical.

包含持久性有机自由基的氧化还原可寻址单分子结。

11.Realizing Fast Synthesis of High-Silica Zeolite Y with Remarkable Catalytic Performance.

实现催化性能优异的高硅Y沸石的快速合成。

12.Hierarchically Nanostructured Solid-State Electrolyte for Flexible Rechargeable Zinc–Air Batteries.

用于柔性可充电锌空气电池的分层纳米结构固态电解质。

13.Metal- and Strain-Free Bioorthogonal Cycloaddition of o-Diones with Furan-2(3H)-one as Anionic Cycloaddend.

邻二酮与呋喃-2(3H)-酮作为阴离子环加成物的无金属和无应变生物正交环加成。

14.Achieving 37.1% Green Electroluminescent Efficiency and 0.09 eV Full Width at Half Maximum Based on a Ternary Boron-Oxygen-Nitrogen Embedded Polycyclic Aromatic System.

基于三元硼-氧-氮嵌入多环芳香族系统，实现 37.1% 的绿色电致发光效率和 0.09 eV 半高宽。

15.Controllable Disulfide Exchange Polymerization of Polyguanidine for Effective Biomedical Applications by Thiol-Mediated Uptake.

聚胍的可控二硫键交换聚合，通过硫醇介导的摄取实现有效的生物医学应用。

16.A Bacteria-Responsive Porphyrin for Adaptable Photodynamic/Photothermal Therapy.

用于适应性光动力/光热疗法的细菌响应性卟啉。

17.Rational Design of Silicon-Based Zinc Ionophores.

硅基锌离子载体的合理设计。

18.Gold-Catalyzed Desymmetric Lactonization of Alkynylmalonic Acids Enabled by Chiral Bifunctional P,N ligands.

手性双功能 P,N 配体实现金催化的炔基丙二酸的不对称内酯化。

19.Efficient and Color-Tunable Dual-Mode Afterglow from Large-Area and Flexible Polymer-Based Transparent Films for Anti-Counterfeiting and Information Encryption.

大面积柔性聚合物透明薄膜的高效且颜色可调的双模式余辉，用于防伪和信息加密。

20.Oligomeric Acceptor: A “Two-in-One” Strategy to Bridge Small Molecules and Polymers for Stable Solar Devices.

寡聚受体：桥接小分子和聚合物以实现稳定太阳能器件的“二合一”策略。

21.Dissipative Control over the Toehold-Mediated DNA Strand Displacement Reaction.

对立足点介导的 DNA 链置换反应的耗散控制。

22.Single-Cell Quantification of a Highly Biocompatible Dinuclear Iridium(III) Complex for Photocatalytic Cancer Therapy.

用于光催化癌症治疗的高度生物相容性双核铱 (III) 复合物的单细胞定量。

23.Self-Reporting Activated Ester-Amine Reaction for Enantioselective Multi-Channel Visual Detection of Chiral Amines.

用于手性胺对映选择性多通道视觉检测的自报告活化酯胺反应。

24.In Situ Spectroscopic Characterization and Theoretical Calculations Identify Partially Reduced ZnO1−x/Cu Interfaces for Methanol Synthesis from CO2.

原位光谱表征和理论计算确定了用于从 CO2 合成甲醇的部分还原的 ZnO1−x/Cu 界面。

25.Protein-Mediated Biosynthesis of Semiconductor Nanocrystals for Photocatalytic NAD(P)H Regeneration and Chiral Amine Production.

用于光催化 NAD(P)H 再生和手性胺生产的蛋白质介导的半导体纳米晶体生物合成。

26.Enantioselective Synthesis of Axially Chiral Styrene-Carboxylic Esters by Rhodium-Catalyzed Chelation-Controlled [2+2+2] Cycloaddition.

通过铑催化螯合控制的 [2+2+2] 环加成对映选择性合成轴向手性苯乙烯-羧酸酯。

27.Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts.

使用铜负载铑簇和单原子催化剂高效电化学将硝酸盐还原为氨。

28.Slow Synthesis Methodology-Directed Immiscible Octahedral PdxRh1−x Dual-Atom-Site Catalysts for Superior Three-Way Catalytic Activities over Rh.

慢速合成方法指导的不混溶八面体 PdxRh1−x 双原子位催化剂，具有优于 Rh 的三向催化活性。

29.Boosting the Productivity of Electrochemical CO2 Reduction to Multi-Carbon Products by Enhancing CO2 Diffusion through a Porous Organic Cage.

通过多孔有机笼增强二氧化碳扩散，提高电化学二氧化碳还原生产多碳产品的生产率。

30.Beyond a Linker: The Role of Photochemistry of Crosslinkers in the Direct Optical Patterning of Colloidal Nanocrystals.

超越连接剂：交联剂光化学在胶体纳米晶体直接光学图案化中的作用。

31.Amplified Circularly Polarized Electroluminescence Behavior Triggered by Helical Nanofibers from Chiral Co-assembly Polymers.

由手性共组装聚合物的螺旋纳米纤维触发的放大圆偏振电致发光行为。

32.Remote Site-Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis.

双金属中继催化实现未活化烯烃的远程位点选择性不对称原硼化。

33.Surface Engineering of Palladium Nanocrystals: Decoupling the Activity of Different Surface Sites on Nanocrystal Catalysts.

钯纳米晶体的表面工程：解耦纳米晶体催化剂上不同表面位点的活性。

34.Euglenatides, Potent Antiproliferative Cyclic Peptides Isolated from the Freshwater Photosynthetic Microalga Euglena gracilis.

眼虫素，从淡水光合微藻眼虫中分离出的有效抗增殖环肽。

35.Constructing Cu−C Bonds in a Graphdiyne-Regulated Cu Single-Atom Electrocatalyst for CO2 Reduction to CH4.

在石墨炔调控的 Cu 单原子电催化剂中构建 Cu−C 键，用于将 CO2 还原为 CH4。

36.Palladium-Catalyzed Regiodivergent Synthesis of 1,3-Dienyl and Allyl Esters from Propargyl Esters.

钯催化从炔丙酯区域发散合成 1,3-二烯酯和烯丙酯。

37.Halogen⋅⋅⋅Halogen and Halogen⋅⋅⋅π Interactions Enabled Reversible Photo-oligomerization of Conjugated Dienones: Visible Light Triggered Single-Crystal-to-Single-Crystal Transformation.

卤素···卤素和卤素···π相互作用实现了共轭二烯酮的可逆光齐聚：可见光触发单晶到单晶的转变。

38.Formation of Breslow Intermediates from N-Heterocyclic Carbenes and Aldehydes Involves Autocatalysis by the Breslow Intermediate, and a Hemiacetal.

由 N-杂环卡宾和醛形成 Breslow 中间体涉及 Breslow 中间体和半缩醛的自催化作用。

39.Enantio- and Diastereoselective Copper-Catalyzed Allylboration of Alkynes with Allylic gem-Dichlorides.

对映体和非对映选择性铜催化炔烃与烯丙基宝石二氯化物的烯丙基硼化。

40.Small Molecules Modulate Liquid-to-Solid Transitions in Phase-Separated Tau Condensates.

小分子调节相分离 Tau 凝聚物中的液体到固体的转变。

41.Synthesis and Characterization of peri-Heptacene on a Metallic Surface.

金属表面上近庚苯的合成和表征。

42.A Nonenzymatic Analog of Pyrimidine Nucleobase Biosynthesis.

嘧啶核碱基生物合成的非酶类似物。

43.Endo-M Mediated Chemoenzymatic Approach Enables Reversible Glycopeptide Labeling for O-GlcNAcylation Analysis.

Endo-M 介导的化学酶法可实现 O-GlcNAc 酰化分析的可逆糖肽标记。

44.Circularly Polarized White Organic Light-Emitting Diodes Based on Spiro-Type Thermally Activated Delayed Fluorescence Materials.

基于螺环型热激活延迟荧光材料的圆偏振白色有机发光二极管。

45.Organophotocatalytic Regioselective C−H Alkylation of Electron-Rich Arenes Using Activated and Unactivated Alkenes.

使用活化和未活化的烯烃对富电子芳烃进行有机光催化区域选择性 C−H 烷基化。

46.Metal-Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes.

三氟甲磺酸硅烷基酯和卤化物的无金属催化氢解成氢硅烷。

47.Visualizing Proteins in Mammalian Cells by 19F NMR Spectroscopy.

通过 19F NMR 光谱可视化哺乳动物细胞中的蛋白质。

48.Reducing Energy Disorder for Efficient and Stable Sn−Pb Alloyed Perovskite Solar Cells..

减少能量无序，实现高效稳定的锡铅合金钙钛矿太阳能电池。

49.Temperature-Reliable Low-Dimensional Perovskites Passivated Black-Phase CsPbI3 toward Stable and Efficient Photovoltaics.

温度可靠的低维钙钛矿钝化黑相 CsPbI3，实现稳定高效的光伏发电。

50.A Class of Readily Tunable Planar-Chiral Cyclopentadienyl Rhodium(III) Catalysts for Asymmetric C–H Activation.

一类用于不对称 C-H 活化的易于调节的平面手性环戊二烯基铑 (III) 催化剂。

51.Nitrate-to-Ammonia Conversion at an InSn-Enriched Liquid-Metal Electrode.

富含 InSn 的液态金属电极将硝酸盐转化为氨。

52.Light-Triggered High-Affinity Binding of Tetramethylammonium over Potassium Ions by [18]crown-6 in a Tetrahedral Anion Cage.

四面体阴离子笼中 [18]crown-6 光触发四甲基铵与钾离子的高亲和力结合。

53.Under-5-Minute Immunoblot Assays by Vortex Fluidic Device Acceleration.

通过涡流流体装置加速进行 5 分钟内的免疫印迹测定。

54.Enantioselective Seleno-Michael Addition Reactions Catalyzed by a Chiral Bifunctional N-Heterocyclic Carbene with Noncovalent Activation.

手性双功能 N-杂环卡宾非共价活化催化的对映选择性硒-迈克尔加成反应。

55.Palladium-Catalyzed Enantioselective γ-Arylation of β,γ-Unsaturated Butenolides.

钯催化 β,γ-不饱和丁烯酸内酯的对映选择性 γ-芳基化。

56.Benzo-Extended Cyclohepta[def]fluorene Derivatives with Very Low-Lying Triplet States.

具有极低位三重态的苯并扩展环庚[def]芴衍生物。

57.A High-Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling.

重新利用烯烃聚合催化剂进行聚合物升级循环的高通量方法。

58.Isolation of Stable Borepin Radicals and Anions.

稳定的 Borepin 自由基和阴离子的分离。

59.Diastereo- and Enantioselective Silver-Catalyzed [3+3] Cycloaddition and Kinetic Resolution of Azomethine Imines with Activated Isocyanides.

非对映和对映选择性银催化的 [3+3] 环加成反应以及活化异氰化物对甲亚胺亚胺的动力学拆分。

60.Efficient Generation of Hydrogen Peroxide and Formate by an Organic Polymer Dots Photocatalyst in Alkaline Conditions.

有机聚合物点光催化剂在碱性条件下有效产生过氧化氢和甲酸盐。

61.Nickel/Copper-Cocatalyzed Asymmetric Benzylation of Aldimine Esters for the Enantioselective Synthesis of α-Quaternary Amino Acids.

镍/铜助催化醛亚胺酯的不对称苯甲基化用于对映选择性合成 α-季氨基酸。

62.Cobalt-Catalyzed Direct Aminocarbonylation of Ethers: Efficient Access to α-Amide Substituted Ether Derivatives.

钴催化醚的直接氨基羰基化：有效获得 α-酰胺取代的醚衍生物。

63.Enhancement of the enzymatic activity of cell-membrane-coated metal–organic framework nanoparticles by depleting membrane cholesterol is demonstrated by Weiwei Gao, Liangfang Zhang et al. in their Communication (e202203115). Increased membrane permeability, caused by the reduction in cholesterol level, is likely responsible for the increased enzymatic activity. This discovery broadens the use of these biomimetic nanoparticles in drug delivery and biodetoxification.

Weiwei Gau、Liangfang Zhu 等人在他们的通讯（e202203115）中证明，通过消耗膜胆固醇，可以增强细胞膜包被的金属有机框架纳米颗粒的酶活性。由胆固醇水平降低引起的膜通透性增加可能是酶活性增加的原因。这一发现拓宽了这些仿生纳米粒子在药物输送和生物解毒中的用途。

64.Using water as a hydrogen source to perform chemical reactions is fascinating but challenging because of the high H−O bond dissociation energy of water (ca. 5 eV). Tingbin Lim, Ren Su, and co-workers show in their Research Article (e202204256) that surface-hydroxylated graphitic carbon nitride only requires 2.25 eV to activate water for reactions involving a hydrogen atom transfer step, allowing solar-driven eco-friendly synthetic chemistry.

使用水作为氢源进行化学反应是令人着迷的，但也具有挑战性，因为水的 H−O 键解离能很高（约 5 eV）。 Tingbin Lim、Ren Su 和同事在他们的研究文章 (e202204256) 中表明，表面羟基化石墨碳氮化物仅需要 2.25 eV 即可激活水以进行涉及氢原子转移步骤的反应，从而实现太阳能驱动的环保合成化学。

65.The global atlas of bacterial aromatic polyketides is reported by Lihan Zhang and co-workers in their Research Article (e202202286). By pan-genomic analysis of the biosynthetic gene clusters of type II polyketide synthases, the global distribution, abundance, and structural diversity of the aromatic polyketides were assessed. The study also provides insight for the molecular evolution of aromatic polyketides and serves as a compass for future discoveries of this class of natural products.

Lihan Zhang 及其同事在他们的研究文章 (e202202286) 中报道了细菌芳香族聚酮化合物的全球图谱。通过对 II 型聚酮合酶生物合成基因簇进行泛基因组分析，评估了芳香族聚酮化合物的全球分布、丰度和结构多样性。该研究还为芳香族聚酮化合物的分子进化提供了见解，并为此类天然产物的未来发现提供了指南针。

66.Are photoproteins stable enough for operation in real world technologies? The Research Article (e202201148) by Vincent M. Friebe, Raoul N. Frese, and co-workers pushes the operation of a biohybrid photoelectrode to new lengths. By stabilizing the pathways crucial for electron transfer, it was possible to prolong electrode operation to the equivalent of a full year of solar insolation in the Netherlands, as well as to maintain output after storage for 2.5 years. These findings will be instrumental for realizing photoprotein-based technologies such as biosensors or biophotovoltaics.

发光蛋白是否足够稳定，可以在现实世界的技术中运行？ Vincent M. Friebe、Raoul N. Frese 及其同事的研究文章 (e202201148) 将生物混合光电极的操作推向了新的高度。通过稳定对电子转移至关重要的路径，可以将电极的运行时间延长到相当于荷兰一整年的日照时间，并在存储 2.5 年后保持输出。这些发现将有助于实现基于发光蛋白的技术，例如生物传感器或生物光伏技术。

67.Photocatalytic CO2 Reduction Aqueous CO2 reduction on silicon photocathodes functionalized with cobalt molecular catalysts/carbon nanotubes is reported by Fei Li et al. in their Communication (e202201086).

光催化 CO2 还原。Fei Li 等人在他们的通讯（e202201086）中报道了在用钴分子催化剂/碳纳米管功能化的硅光电阴极上水相 CO2 还原。

68.Coordination Compounds In their Research Article (e202201884), Lili Zhao, Tiow-Gan Ong et al. report a bis-(carbone) pincer ligand and its coordinative behavior toward multi-metallic configurations.

配位化合物 在他们的研究文章 (e202201884) 中，Lili Zhu、Tiow-Gan Ong 等人报告双（碳）钳配体及其对多金属构型的配位行为。

69.Metal Halide Perovskite Based Heterojunction Photocatalysts.

基于金属卤化物钙钛矿的异质结光催化剂。

70.A Bis-(carbone) Pincer Ligand and Its Coordinative Behavior toward Multi-Metallic Configurations.

双（碳）钳配体及其对多金属构型的配位行为。

71.Inorganic Chiral Hybrid Nanostructures for Tailored Chiroptics and Chirality-Dependent Photocatalysis.

用于定制手性光学和手性依赖性光催化的无机手性混合纳米结构。

72.Catalytic DNA Polymerization Can Be Expedited by Active Product Release.

活性产品的释放可以加速催化 DNA 聚合。

73.Digitizing Chemical Synthesis in 3D Printed Reactionware.

3D 打印反应器中的数字化化学合成。

74.Activatable Persistent Luminescence from Porphyrin Derivatives and Supramolecular Probes with Imaging-Modality Transformable Characteristics for Improved Biological Applications.

卟啉衍生物和超分子探针的可激活持续发光，具有成像模态可转换特性，可改善生物应用。

75.Catalytic Degradation of Polyethylene Terephthalate Using a Phase-Transitional Zirconium-Based Metal–Organic Framework.

使用相变锆基金属有机骨架催化降解聚对苯二甲酸乙二醇酯。

76.Enantio-, Diastereo- and Regioselective Synthesis of Chiral Cyclic and Acyclic gem-Difluoromethylenes by Palladium-Catalyzed [4+2] Cycloaddition.

钯催化的 [4+2] 环加成对映体、非对映体和区域选择性合成手性环状和无环偕二氟亚甲基。

77.Palladium-Catalyzed Stagewise Strain-Release-Driven C−C Activation of Bicyclo[1.1.1]pentanyl Alcohols.

钯催化分阶段应变释放驱动的 CC 活化双环[1.1.1]戊醇。

78.Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N-Heterocyclic Carbene Ligand: Improved Stability and Activity.

带有大环 N-杂环卡宾配体的钌烯烃复分解催化剂：提高稳定性和活性。

79.Enantioselective Total Synthesis of [3]-Ladderanol through Late-Stage Organocatalytic Desymmetrization.

通过后期有机催化去对称对映选择性全合成[3]-Ladderanol。

80.Sustained Release of a Synthetic Autoinducing Peptide Mimetic Blocks Bacterial Communication and Virulence In Vivo..

合成自诱导肽模拟物的持续释放可阻断体内细菌通讯和毒力。

81.Pyrene-Based Dopant-Free Hole-Transport Polymers with Fluorine-Induced Favorable Molecular Stacking Enable Efficient Perovskite Solar Cells.

芘基无掺杂空穴传输聚合物具有氟诱导的有利分子堆积，可实现高效钙钛矿太阳能电池。

82.Extended Conjugation Attenuates the Quenching of Aggregation-Induced Emitters by Photocyclization Pathways.

延长的共轭减弱了光环化途径对聚集诱导发射体的猝灭。

83.Tuning an Imine Reductase for the Asymmetric Synthesis of Azacycloalkylamines by Concise Structure-Guided Engineering.

通过简洁的结构引导工程调整亚胺还原酶用于氮杂环烷基胺的不对称合成。

84.Fusion of Multi-Resonance Fragment with Conventional Polycyclic Aromatic Hydrocarbon for Nearly BT.2020 Green Emission.

多共振片段与传统多环芳烃的融合，实现近BT.2020绿色排放。

85.Investigation of the Molecular Landscape of Bacterial Aromatic Polyketides by Global Analysis of Type II Polyketide Synthases.

通过 II 型聚酮化合物合成酶的整体分析研究细菌芳香族聚酮化合物的分子景观。

86.Palladium-Catalyzed Tandem Cycloisomerization/Cross-Coupling of Carbonyl- and Imine-Tethered Alkylidenecyclopropanes.

钯催化的羰基和亚胺连接的亚烷基环丙烷的串联环异构化/交叉偶联。

87.Single-Step Expeditious Synthesis of Diblock Copolymers with Different Morphologies by Lewis Pair Polymerization-Induced Self-Assembly.

通过路易斯对聚合诱导自组装一步快速合成不同形貌的二嵌段共聚物。

88.Selective Extraction of Transition Metals from Spent LiNixCoyMn1−x−yO2 Cathode via Regulation of Coordination Environment.

通过调节配位环境从废 LiNixCoyMn1−x−yO2 阴极中选择性萃取过渡金属。

89.Surface-Adaptive Capillarity Enabling Densified 3D Printing for Ultra-High Areal and Volumetric Energy Density Supercapacitors.

表面自适应毛细管现象可实现超高面积和体积能量密度超级电容器的致密 3D 打印。

90.Hydrophobization Engineering of the Air–Cathode Catalyst for Improved Oxygen Diffusion towards Efficient Zinc–Air Batteries.

空气阴极催化剂的疏水化工程，用于改善高效锌空气电池的氧扩散。

91.Electrocatalysis for Continuous Multi-Step Reactions in Quasi-Solid-State Electrolytes Towards High-Energy and Long-Life Aluminum–Sulfur Batteries.

准固态电解质中连续多步反应的电催化以实现高能和长寿命的铝硫电池。

92.Highly Chemoselective Transamidation of Unactivated Tertiary Amides by Electrophilic N−C(O) Activation by Amide-to-Acyl Iodide Re-routing.

通过酰胺到酰基碘重新路由的亲电 N−C(O) 活化对未活化的叔酰胺进行高度化学选择性的转酰胺基化。

93.Anionic Cyanine J-Type Aggregate Nanoparticles with Enhanced Photosensitization for Mitochondria-Targeting Tumor Phototherapy.

具有增强光敏性的阴离子花青 J 型聚集纳米粒子，用于线粒体靶向肿瘤光疗。

94.Surface-Plasmon-Enhanced Transmetalation between Copper and Palladium Nanoparticle Catalyst.

铜和钯纳米粒子催化剂之间的表面等离子体增强金属转移。

95.A Strategy Based on Aggregation-Induced Ratiometric Emission to Differentiate Molecular Weight of Supramolecular Polymers.

基于聚集诱导比率发射来区分超分子聚合物分子量的策略。

96.Direct Amination of Benzene with Molecular Nitrogen Enabled by Plasma-Liquid Interactions.

通过等离子体-液体相互作用实现苯与分子氮的直接胺化。

97.Tandem Catalysis for Selective Oxidation of Methane to Oxygenates Using Oxygen over PdCu/Zeolite.

使用 PdCu/沸石上的氧气将甲烷选择性氧化为氧化物的串联催化。

98.Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions.

使用羟基石墨碳氮化物进行氢偶联反应光催化从水中提取氢原子。

99.Unprecedented Mushroom Polyketide Synthases Produce the Universal Anthraquinone Precursor.

前所未有的蘑菇聚酮化合物合成酶可生产通用蒽醌前体。

100.Tailored Pyridoxal Probes Unravel Novel Cofactor-Dependent Targets and Antibiotic Hits in Critical Bacterial Pathogens.

定制的吡哆醛探针揭示了关键细菌病原体中新的辅因子依赖性靶点和抗生素命中。

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