【标题速读】【JACS】【2022年】【9月】

2023-06-11 18:41 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

An electrochemical strategy is reported to upgrade CO2-derived formic acid into high-valued formamide by the co-reduction of CO2 and nitrite pollutants. Low-coordinated Cu exhibits a remarkable economic advantage for formamide electrosynthesis over conventional manufacture.

据报道，一种电化学策略通过 CO2 和亚硝酸盐污染物的共同还原将 CO2 衍生的甲酸升级为高价值的甲酰胺。与传统制造相比，低配位铜在甲酰胺电合成方面具有显着的经济优势。

Synthetic biodegradable polyesters, e.g., PBAT, suffer from a slow biodegradability under ambient conditions, tending to be biodegradable only under harsh industrial composting conditions. Here, it is demonstrated how the biodegradability of such polyesters can be enhanced under ambient conditions of soils without sacrificing the desirable rheological and mechanical properties.

合成的可生物降解聚酯，例如 PBAT，在环境条件下生物降解缓慢，只有在恶劣的工业堆肥条件下才能生物降解。在这里，展示了如何在土壤环境条件下增强此类聚酯的生物降解性，而不牺牲所需的流变学和机械性能。

Biphase catalyst of anatase and rutile TiO2 with optimal phase interface concentration enables efficient and selective photooxidation of methane to formaldehyde under the reaction condition of water solvent, oxygen atmosphere, and full-spectrum light irradiation. More importantly, the feasibility of scale-up production of formaldehyde is demonstrated by inventing the “pause-flowing” reactor.

具有最佳相界面浓度的锐钛矿和金红石 TiO2 双相催化剂能够在水溶剂、氧气气氛和全光谱光照射的反应条件下，将甲烷高效、选择性地光氧化为甲醛。更重要的是，通过发明“暂停流动”反应器证明了扩大甲醛生产的可行性。

An excess electron residing on the diffuse nonvalence orbital of the dipole-bound state (DBS) of para-iodophenoxide plays the resonant “doorway” role into either the autodetachment (right) or the chemical-bond fragmentation (left).

驻留在对碘苯氧化物偶极结合态 (DBS) 的扩散非价轨道上的过量电子在自动分离（右）或化学键断裂（左）中发挥共振“门口”作用。

Spontaneous oxidative C–H/N–H cross-coupling can be catalyzed by an ultrahigh electric field on water microdroplets.

水微滴上的超高电场可以催化自发氧化 C-H/N-H 交叉偶联。

Light promotes electrons in certain positions of a three-dimensional covalent organic framework into collective excited states. Cover art by Alfy Benny.

光将三维共价有机框架中某些位置的电子促进到集体激发态。 Alfy Benny 的封面艺术。

Metal–organic frameworks (MOFs) with precisely controlled combinations of metal atoms are synthesized. Molecular complexes are used to lock the desired chemical codes and deliver them to the MOFs upon reaction with organic linkers.

合成了具有精确控制的金属原子组合的金属有机骨架 (MOF)。分子复合物用于锁定所需的化学代码，并在与有机接头反应后将它们传递给 MOF。

Liver fibrosis is characterized by accumulation and cross-linking of extracellular matrix components, chiefly fibrillar collagens. Lysine residues on the collagen triple helix can be oxidized to the aldehyde containing allysine residue (highlighted spots) during the cross-linking process. We targeted these allysine aldehydes on collagen by molecular magnetic resonance imaging to detect the disease activity in liver fibrosis.

肝纤维化的特征是细胞外基质成分（主要是纤维状胶原蛋白）的积累和交联。在交联过程中，胶原蛋白三螺旋上的赖氨酸残基可以被氧化成含有醛基的醛基残基（突出显示的点）。我们通过分子磁共振成像将这些 allysine 醛靶向胶原蛋白，以检测肝纤维化中的疾病活动。

Four types of metallo-macromolecules, including concentric ring, helicoid polymer, ladder polymer, and cross-linked polymer, with different geometries but the same chemical composition have been designed and synthesized from chevron-shaped monomers through stepwise platinum–acetylide polymerization. Microscopic characterization techniques including TEM, AFM, and UHV-LT-STM were employed to image these metallo-macromolecules at the single-molecule level.

以人字形单体为原料，通过逐步铂-乙炔聚合反应，设计并合成了四种金属大分子，包括同心环、螺旋聚合物、梯形聚合物和交联聚合物，它们具有不同的几何形状但化学成分相同。采用包括 TEM、AFM 和 UHV-LT-STM 在内的显微表征技术在单分子水平上对这些金属大分子进行成像。

Elongated and weakened carbon–carbon bonds achieved via solid-state topochemical polymerization yield fully depolymerizable polyolefin-derived single-crystalline materials. Some of these crystalline polymers exhibit facile processability and excellent mechanical properties, suggesting great promise for practical applications toward a greener and more sustainable future.

通过固态拓扑化学聚合实现的碳-碳键伸长和弱化产生完全可解聚的聚烯烃衍生单晶材料。其中一些结晶聚合物表现出易于加工和优异的机械性能，表明在实际应用中有望实现更绿色、更可持续的未来。

Artistic rendering of the geometric confluence of the experimentally inaccessible transition structure of the cyclic water dimer and a cyclooctatetraene-based “molecular balance” that probes this dimer in the form of dimethanol hydrogen-bonding contacts held in place by the unsaturated cycle. The thermodynamic measurement of the balance yields an estimate of the cyclic water dimer binding energy because all quantities that affect this equilibrium are known and can be determined rather accurately. Hence, this manifests an attempt to determine the binding energy of a transition state using an experimental equilibrium measurement approach.

环状水二聚体的实验上难以接近的过渡结构和基于环辛四烯的“分子平衡”的几何汇合的艺术渲染，该“分子平衡”以不饱和循环保持的二甲醇氢键接触的形式探测该二聚体。平衡的热力学测量产生了循环水二聚体结合能的估计，因为影响这种平衡的所有量都是已知的并且可以相当准确地确定。因此，这表明尝试使用实验平衡测量方法来确定过渡态的结合能。

Protomers of nicotine depending on its immediate environment: (left) 3:2 mixture of pyridine to pyrrolidine protomers in the gas phase, (middle) almost exclusively (9:1 ratio) pyridine protomer NICH+•••H2O) for a single water, and (right) exclusively pyrrolidine protomer in aqueous solution.

取决于其直接环境的尼古丁原体：（左）气相中吡啶与吡咯烷原体的 3:2 混合物，（中）几乎完全（9:1 比例）吡啶原体 NICH+•••H2O) 对于单一水，和（右）水溶液中的完全吡咯烷原体。

The dominant catalytic site for oxygen reduction in FeNC catalysts relevant to proton exchange fuel cells features pyrrolic nitrogen donors. We observe a new Mössbauer signal that emerges under operando conditions as other signals decay and use quantum chemistry to develop a structurally, spectroscopically, and thermodynamically consistent active site model.

与质子交换燃料电池相关的 FeNC 催化剂中氧还原的主要催化位点具有吡咯氮供体。我们观察到一个新的穆斯堡尔信号，该信号在操作条件下随着其他信号衰减而出现，并使用量子化学来开发结构、光谱和热力学一致的活性位点模型。

A main-group metal oxide catalyst with atomically dispersed In sites has been exploited, which shows remarkable performance for oxidative dehydrogenation of ethane. This work proposes a new strategy to regulate the activity of an inherently selective catalyst from weakness to strength for highly efficient oxidative dehydrogenation.

已开发出具有原子分散 In 位点的主族金属氧化物催化剂，其在乙烷氧化脱氢中显示出卓越的性能。这项工作提出了一种新策略来调节固有选择性催化剂的活性从弱到强，以实现高效氧化脱氢。

CdS nanosheets terminated by S2– atomic layers enable oriented migration of photoexcited electrons and holes toward spatially separated reductive and oxidative centers, leading to record-breaking photocatalytic performance for solar-driven CO2-to-CO conversion with selectivity of 99%, a CO formation rate reaching 2.13 mol g–1 h–1, and an effective apparent quantum efficiency of 42.1%.

由 S2- 原子层终止的 CdS 纳米片使光激发电子和空穴能够定向迁移到空间分离的还原和氧化中心，从而导致太阳能驱动的 CO2 转化为 CO 的光催化性能破纪录，选择性为 99%，CO 形成速率达到2.13 mol g-1 h-1，有效表观量子效率为42.1%。

A gold nanoparticle (AuNP)–bridge array was constructed with vertical permeability to maximize mass transfer efficiency. The capability of the AuNP–bridge array to improve DNA hybridization efficiency was verified by surface-enhanced Raman spectroscopy (SERS). The AuNP–bridge array provides new insights into the construction of various biosensor chips.

构建了具有垂直渗透性的金纳米颗粒 (AuNP)-桥阵列，以最大限度地提高传质效率。通过表面增强拉曼光谱 (SERS) 验证了 AuNP 桥阵列提高 DNA 杂交效率的能力。 AuNP 桥阵列为各种生物传感器芯片的构建提供了新的见解。

Abstraction of an optimal control solid-state NMR experiment. A powdered sample is spun inside a solenoidal coil. The coil delivers sophisticated radio-frequency pulses (gold numbers fed into coil wires) to manipulate the magnetization vector. Transferring both vector components between nuclei allows systematic sensitivity gains in multidimensional NMR spectra of solids.

最佳控制固态核磁共振实验的抽象。粉末状样品在螺线管线圈内旋转。线圈传送复杂的射频脉冲（送入线圈线的金号）来操纵磁化矢量。在原子核之间转移两个矢量分量可以在固体的多维核磁共振光谱中获得系统的灵敏度增益。

Peptide phosphorylation, an archetypal post-translational modification, is detected at the single-molecule level based on electrical measurements. The detection relies on bridging of a nanogap between electrodes by the phosphate group, which gives rise to high electrical conductance.

肽磷酸化是一种典型的翻译后修饰，可根据电学测量在单分子水平上检测到。检测依赖于磷酸基团桥接电极之间的纳米间隙，从而产生高电导。

We report the feasible and scalable exfoliation to produce free-standing 2D metal-organic framework nanosheets (MONs) with high aspect ratio up to 2000:1 and ultrathin thickness (~1.7 nm) from MOF films obtained by an efficient interfacial polycondensation and polycoordination of three active monomers. The MONs exhibited exceptional catalytic activity and excellent reusability for hydroboration reactions of alkynes, compared to reported homogenous and homogenous catalysts.

我们报告了可行且可扩展的剥离，以通过有效的界面缩聚和多配位获得的 MOF 薄膜生产具有高达 2000:1 的高纵横比和超薄厚度（~1.7 nm）的独立二维金属有机骨架纳米片（MON）三个活性单体。与报道的均相和均相催化剂相比，MON 对炔烃的硼氢化反应表现出卓越的催化活性和出色的可重复使用性。

The ATG12–ATG5–ATG16L1 complex formation is essential for targeting the ATG12–ATG5 conjugate to proper membranes and to generate LC3-II for the progression of autophagy. A stapled peptide derived from ATG16L1 exhibits potent binding affinity to ATG5, striking resistance to proteolysis, and significant autophagy inhibition activities in cells.

ATG12–ATG5–ATG16L1 复合物的形成对于将 ATG12–ATG5 结合物靶向适当的膜并产生 LC3-II 以促进自噬过程至关重要。源自 ATG16L1 的钉合肽对 ATG5 表现出强大的结合亲和力，对蛋白水解具有显着的抵抗力，并且在细胞中具有显着的自噬抑制活性。

1.Rapid Biodegradable Ionic Aggregates of Polyesters Constructed with Fertilizer Ingredients.

用肥料成分构建的快速可生物降解的聚酯离子聚集体。

2.Chemoselective Covalent Modification of K-Ras(G12R) with a Small Molecule Electrophile.

用小分子亲电试剂对 K-Ras(G12R) 进行化学选择性共价修饰。

3.Chalcogen Atoms as Electron Donors in Proton-Coupled Electron Transfer Reactions.

硫族原子作为质子耦合电子转移反应中的电子供体。

4.Low-Temperature, Solution-Based Synthesis of Luminescent Chalcogenide Perovskite BaZrS3 Nanoparticles.

低温、基于溶液的发光硫族化物钙钛矿 BaZrS3 纳米粒子的合成。

5.The Chromium Dimer: Closing a Chapter of Quantum Chemistry.

铬二聚体：结束量子化学的一章。

6.A Pyridine Dearomatization Approach to the Matrine-Type Lupin Alkaloids.

苦参碱类羽扇豆生物碱的吡啶脱芳构化方法。

7.High-Entropy Intermetallics Serve Ultrastable Single-Atom Pt for Propane Dehydrogenation.

高熵金属间化合物为丙烷脱氢提供超稳定的单原子铂。

8.Enzymatic Control over Reactive Intermediates Enables Direct Oxidation of Alkenes to Carbonyls by a P450 Iron-Oxo Species.

对反应性中间体的酶促控制使 P450 铁氧物种能够将烯烃直接氧化为羰基。

9.New Approach to the Detection of Short-Lived Radical Intermediates.

检测短寿命自由基中间体的新方法。

10.Elevating Photooxidation of Methane to Formaldehyde via TiO2 Crystal Phase Engineering.

通过 TiO2 晶相工程将甲烷光氧化为甲醛。

11.Adaptive Binding of Alkyl Glycosides by Nonpeptidic Helix Bundles in Water: Toward Artificial Glycolipid Binding Proteins.

水中非肽螺旋束对烷基糖苷的适应性结合：对人工糖脂结合蛋白的研究。

12.Periodic One-Dimensional Single-Atom Arrays.

周期性一维单原子阵列。

13.Electrochemical Upgrading of Formic Acid to Formamide via Coupling Nitrite Co-Reduction.

通过偶联亚硝酸盐共还原将甲酸电化学升级为甲酰胺。

14.Programmable Fabrication of Monodisperse Graphene Nanoribbons via Deterministic Iterative Synthesis.

通过确定性迭代合成可编程制造单分散石墨烯纳米带。

15.Tailoring the Time-Averaged Structure for Polarization-Sensitive Chiral Perovskites.

定制偏振敏感手性钙钛矿的时间平均结构。

16.On-Surface Design of a 2D Cobalt-Organic Network Preserving Large Orbital Magnetic Moment.

保持大轨道磁矩的二维钴有机网络的表面设计。

17.Total Syntheses of Calyciphylline A-Type Alkaloids (−)-10-Deoxydaphnipaxianine A, (+)-Daphlongamine E and (+)-Calyciphylline R via Late-Stage Divinyl Carbinol Rearrangements.

Calyciphylline A 型生物碱 (−)-10-Deoxydaphnipaxianine A、(+)-Daphlongamine E 和 (+)-Calyciphylline R 通过后期二乙烯基甲醇重排的全合成。

18.Viscoelastic Covalent Organic Nanotube Fabric via Macroscopic Entanglement.

通过宏观纠缠的粘弹性共价有机纳米管织物。

19.Resolving Isomeric Posttranslational Modifications Using a Biological Nanopore as a Sensor of Molecular Shape.

使用生物纳米孔作为分子形状传感器解决异构翻译后修饰。

20.Quantitatively Determining Surface–Adsorbate Properties from Vibrational Spectroscopy with Interpretable Machine Learning.

使用可解释的机器学习从振动光谱定量确定表面吸附性质。

21.Experimental Observation of the Resonant Doorways to Anion Chemistry: Dynamic Role of Dipole-Bound Feshbach Resonances in Dissociative Electron Attachment.

阴离子化学共振门道的实验观察：偶极束缚 Feshbach 共振在离解电子附着中的动态作用。

22.Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States.

用于模拟贝尔态量子退相干的五自旋超分子。

23.Electroactive Covalent Organic Framework Enabling Photostimulus-Responsive Devices.

电活性共价有机框架使光刺激响应设备成为可能。

24.Characterization of Binding Site Interactions and Selectivity Principles in the α3β4 Nicotinic Acetylcholine Receptor.

α3β4 烟碱型乙酰胆碱受体中结合位点相互作用和选择性原理的表征。

25.Mechanistic Basis for the Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates.

铱催化的烯基硼酸酯的对映选择性烯丙基化的机理基础。

26.Metal-Coordinated Phthalocyanines as Platform Molecules for Understanding Isolated Metal Sites in the Electrochemical Reduction of CO2.

金属配位酞菁作为平台分子，用于了解 CO2 电化学还原中的孤立金属位点。

27.Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal–Organic Frameworks.

捕获而不是释放：金属有机骨架中的缺陷调制放射性核素浸出动力学。

28.Selective Unnatural Base Pairing and Recognition of 2-Hydroxy-2′-deoxyadenosine in DNA Using Pseudo-dC Derivatives.

使用伪 dC 衍生物选择性非自然碱基配对和识别 DNA 中的 2-羟基-2'-脱氧腺苷。

29.Peptidyl Prolyl Isomerase A Modulates the Liquid–Liquid Phase Separation of Proline-Rich IDPs.

肽基脯氨酰异构酶 A 调节富含脯氨酸的 IDP 的液-液相分离。

30.Molecular Basis for Enzymatic Aziridine Formation via Sulfate Elimination.

通过硫酸盐消除酶促氮丙啶形成的分子基础。

31.Ir and NHC Dual Chiral Synergetic Catalysis: Mechanism and Stereoselectivity in γ-Butyrolactone Formation.

Ir 和 NHC 双手性协同催化：γ-丁内酯形成的机理和立体选择性。

32.High Electric Field on Water Microdroplets Catalyzes Spontaneous and Ultrafast Oxidative C–H/N–H Cross-Coupling.

水微滴上的高电场催化自发和超快氧化 C–H/N–H 交叉偶联。

33.Water-Soluble Self-Assembled Cage with Triangular Metal–Metal-Bonded Units Enabling the Sequential Selective Separation of Alkanes and Isomeric Molecules.

具有三角形金属-金属键合单元的水溶性自组装笼，可实现烷烃和异构分子的顺序选择性分离。

34.Stereocontrolled Synthesis of the Fully Glycosylated Monomeric Unit of Lomaiviticin A.

Lomaiviticin A 完全糖基化单体单元的立体控制合成。

35.Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines.

催化路易斯碱添加剂可实现选择性铜催化的脂环族胺的硼基化 α-C-H 烯丙基化。

36.Photochemistry Journey to Multielectron and Multiproton Chemical Transformation.

多电子和多质子化学转化的光化学之旅。

37.Precise Assembly of Proteins and Carbohydrates for Next-Generation Biomaterials.

为下一代生物材料精确组装蛋白质和碳水化合物。

38.The Implications of the Brønsted Acidic Properties of Crabtree-Type Catalysts in the Asymmetric Hydrogenation of Olefins.

Crabtree 型催化剂的 Brønsted 酸性在烯烃不对称加氢中的意义。

39.Heterometallic Molecular Complexes Act as Messenger Building Units to Encode Desired Metal-Atom Combinations to Multivariate Metal–Organic Frameworks.

异金属分子复合物作为信使构建单元将所需的金属-原子组合编码为多元金属-有机框架。

40.Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface.

N-杂环卡宾在氧化铜表面的共价吸附。

41.High-Spin Orbital Interactions Across van der Waals Gaps Controlling the Interlayer Ferromagnetism in van der Waals Ferromagnets.

跨范德瓦尔斯间隙的高自旋轨道相互作用控制范德瓦尔斯铁磁体中的层间铁磁性。

42.Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone.

9-Carbene-9-borafluorene 单阴离子对二氧化碳的活化：一氧化碳释放 Trioxaborinanone 转化为发光的 Dioxaborinanone。

43.Supramolecular Substructure of C60-Embedded Schwarzite.

C60 包埋黑石英的超分子亚结构。

44.Gigantic C120 Fullertubes: Prediction and Experimental Evidence for Isomerically Purified Metallic [5,5] C120-D5d(1) and Nonmetallic [10,0] C120-D5h(10766).

巨大的 C120 Fullertubes：异构纯化金属 [5,5] C120-D5d(1) 和非金属 [10,0] C120-D5h(10766) 的预测和实验证据。

45.Bioinspired Synthesis of Spirochensilide A from Lanosterol.

从羊毛甾醇中仿生合成 Spirochensilide A。

46.Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Carbon Stereocenters in Acyclic Systems.

Borylated Cyclopropanes 作为弹簧加载的实体：在无环系统中获得邻位三级和四级碳立体中心。

47.Copper Hydride-Catalyzed Enantioselective Olefin Hydromethylation.

氢化铜催化的对映选择性烯烃氢甲基化。

48.Enhancing CRISPR-Cas-Mediated Detection of Nucleic Acid and Non-nucleic Acid Targets Using Enzyme-Labeled Reporters.

使用酶标记报告基因增强 CRISPR-Cas 介导的核酸和非核酸靶标检测。

49.Hydroamination of Unactivated Alkenes with Aliphatic Azides.

未活化烯烃与脂肪族叠氮化物的加氢胺化。

50.Activation of Ammonia by a Carbene-Stabilized Dithiolene Zwitterion.

卡宾稳定的二硫烯两性离子对氨的活化。

51.Total Synthesis of Resiniferatoxin.

树脂毒素的全合成。

52.Water Structure in the Electrical Double Layer and the Contributions to the Total Interfacial Potential at Different Surface Charge Densities.

双电层中的水结构以及在不同表面电荷密度下对总界面电势的贡献。

53.Forced Disorder in the Solid Solution Li3P–Li2S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

Li3P–Li2S 固溶体中的强制紊乱：一类用于锂金属阳极的新型完全还原固体电解质。

54.Lanthanide-Nucleotide Coordination Nanoparticles for STING Activation.

用于 STING 激活的镧系元素-核苷酸配位纳米粒子。

55.Ordering Transitions of Liquid Crystals Triggered by Metal Oxide-catalyzed Reactions of Sulfur Oxide Species.

由氧化硫物质的金属氧化物催化反应触发的液晶有序转变。

56.Versatile Inorganic Subnanometer Nanowire Adhesive.

多功能无机亚纳米纳米线粘合剂。

57.What Is the Right Level of Activation of a High-Spin {FeNO}7 Complex to Enable Direct N–N Coupling? Mechanistic Insight into Flavodiiron NO Reductases.

高自旋 {FeNO}7 络合物启用直接 N-N 耦合的正确激活水平是多少？ Flavodiiron NO 还原酶的机理洞察。

58.Development of a GalNAc-Tyrosine-Specific Monoclonal Antibody and Detection of Tyrosine O-GalNAcylation in Numerous Human Tissues and Cell Lines.

GalNAc-酪氨酸特异性单克隆抗体的开发和许多人体组织和细胞系中酪氨酸 O-GalNAcylation 的检测。

59.Exciton Diffusion and Annihilation in an sp2 Carbon-Conjugated Covalent Organic Framework.

sp2 碳共轭共价有机骨架中的激子扩散和湮灭。

60.Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ-Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light.

可见光下原位重组铜后金属化金属有机骨架对甲酸的选择性光催化脱氢。

61.Bright, Modular, and Switchable Near-Infrared II Emission from Compact Tetrathiafulvalene-Based Diradicaloid Complexes.

紧凑型基于四硫富瓦烯的双自由基复合物的明亮、模块化和可切换的近红外 II 发射。

62.Dopant-Stabilized Assembly of Poly(3-hexylthiophene).

聚（3-己基噻吩）的掺杂剂稳定组装。

63.Induction of Chiral Hybrid Metal Halides from Achiral Building Blocks.

从非手性构件中诱导手性杂化金属卤化物。

64.Rapid Screening of Bimetallic Electrocatalysts Using Single Nanoparticle Collision Electrochemistry.

使用单纳米粒子碰撞电化学快速筛选双金属电催化剂。

65.Asymmetric Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides Enabled by Organosulfide Catalysis: Modular Entry to Iodinated Chiral Molecules.

有机硫化物催化实现的烯丙基磺酰胺的不对称分子间碘化双功能化：碘化手性分子的模块化进入。

66.DNA Strand Displacement Driven by Host–Guest Interactions.

由主客体相互作用驱动的 DNA 链位移。

67.Peptide Sequence Determines Structural Sensitivity to Supramolecular Polymerization Pathways and Bioactivity.

肽序列决定了对超分子聚合途径和生物活性的结构敏感性。

68.Multilevel Computational Studies Reveal the Importance of Axial Ligand for Oxygen Reduction Reaction on Fe–N–C Materials.

多层次计算研究揭示了轴向配体对 Fe-N-C 材料上氧还原反应的重要性。

69.Radical Activation of N–H and O–H Bonds at Bismuth(II).

铋 (II) 上 N-H 和 O-H 键的自由基活化。

70.Detection of Epidermal Growth Factor Receptor Expression in Breast Cancer Cell Lines Using an Ion-Sensitive Field-Effect Transistor in Combination with Enzymatic Chemical Signal Amplification.

使用离子敏感场效应晶体管结合酶促化学信号放大检测乳腺癌细胞系中表皮生长因子受体的表达。

71.Dual Hydrazine-Equipped Turn-On Manganese-Based Probes for Magnetic Resonance Imaging of Liver Fibrogenesis.

肝纤维化磁共振成像的双联氨开启锰基探针。

72.Precise Synthesis of Concentric Ring, Helicoid, and Ladder Metallo-Polymers with Chevron-Shaped Monomers.

用人字形单体精确合成同心环、螺旋体和梯形金属聚合物。

73.Hole-Doping to a Cu(I)-Based Semiconductor with an Isovalent Cation: Utilizing a Complex Defect as a Shallow Acceptor.

具有等价阳离子的 Cu(I) 基半导体的空穴掺杂：利用复杂缺陷作为浅受体。

74.Preparation, Supramolecular Organization, and On-Surface Reactivity of Enantiopure Subphthalocyanines: From Bulk to 2D-Polymerization.

对映纯亚酞菁的制备、超分子组织和表面反应性：从本体到二维聚合。

75.Circularly Recyclable Polymers Featuring Topochemically Weakened Carbon–Carbon Bonds.

具有拓扑化学弱化碳-碳键的循环可回收聚合物。

76.Programmable Assembly of Amphiphilic DNA through Controlled Cholesterol Stacking.

通过受控胆固醇堆积的两亲性 DNA 的可编程组装。

77.Photochemical Identification of Auxiliary Severe Acute Respiratory Syndrome Coronavirus 2 Host Entry Factors Using μMap.

使用 μMap 光化学鉴定辅助严重急性呼吸系统综合症冠状病毒 2 宿主进入因子。

78.Robust Radical Cations of Hexabenzoperylene Exhibiting High Conductivity and Enabling an Organic Nonvolatile Optoelectronic Memory.

六苯并苝的稳健自由基阳离子表现出高导电性并使有机非易失性光电存储器成为可能。

79.Probing the Strong Nonadiabatic Interactions in the Triazolyl Radical Using Photodetachment Spectroscopy and Resonant Photoelectron Imaging of Cryogenically Cooled Anions.

使用低温冷却阴离子的光分离光谱和共振光电子成像探索三唑基中的强非绝热相互作用。