【标题速读】【Angew】【2022年】【4月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.An NHC-organocatalyzed remote C(sp3)−H acylation of amides is developed based on a 1,5-hydrogen atom transfer strategy. As reported in the Research Article by Jun-Long Li et al. (e202116629), over 120 functionalized δ-amino ketones and isoquinolinones were synthesized in up to 99 % yield under mild conditions. Mechanistic investigations, including control reactions, KIE experiments, and computational studies, shed light on the organocatalytic radical reaction mechanism.

基于 1,5-氢原子转移策略，开发了 NHC 有机催化的酰胺远程 C(sp3)−H 酰化。正如李俊龙等人在研究文章中所报道的那样。 (e202116629)，在温和条件下合成了超过 120 种官能化 δ-氨基酮和异喹啉酮，产率高达 99%。机理研究，包括控制反应、KIE 实验和计算研究，揭示了有机催化自由基反应机理。

2.Copper and zinc oxide are a dream team in transforming carbon dioxide and carbon monoxide together with hydrogen into the valuable base chemical methanol. Inspired by the cover art of the music masterpiece “Wish you were here” by Pink Floyd, the picture featuring the Research Article (e202200301) by Jeroen A. van Bokhoven and co-workers highlights the fundamental collaboration of the copper and zinc oxide phase in methanol catalysts for a sustainable future.

铜和氧化锌是将二氧化碳和一氧化碳与氢气一起转化为有价值的基础化学品甲醇的理想组合。受 Pink Floyd 音乐杰作“Wish you were here”封面艺术的启发，Jeroen A. van Bokhoven 及其同事的研究文章 (e202200301) 的图片强调了铜和氧化锌相的基本协作甲醇催化剂，实现可持续的未来。

3.A naphthalene-embedded conjugated nanobelt is an excellent design for achieving the synthesis of cyclophenacene-type and chiral-type carbon nanobelts. A cationic rhodium complex catalyst is a powerful tool for the (asymmetric) synthesis of these analogues, as reported by Ken Tanaka and co-workers in their Research Article (e202200800). In the picture, the three blue belts in the foreground and the rhodium complex in the back represent the cyclophenylene-naphthylene belts and the key catalyst, respectively.

萘嵌入共轭纳米带是实现环菲苯型和手性型碳纳米带合成的优异设计。 Ken Tanaka 及其同事在他们的研究文章 (e202200800) 中报道，阳离子铑配合物催化剂是这些类似物（不对称）合成的有力工具。图中，前景的三个蓝色带和后面的铑络合物分别代表环亚苯基-亚萘基带和关键催化剂。

4.A facile strategy for the controlled synthesis of discrete diamond-shaped two-dimensional platelets with tunable surface functionality and luminescence by crystallization-driven self-assembly of poly(L-lactides) is described by Anindita Das and Aritra Rajak in their Research Article (e202116572). By two-component co- and living-crystallization techniques, predetermined sequence-controlled supramolecular organization of two functional dyes on the co-platelet and block co-platelet surface, respectively, can be achieved.

Anindita Das 和 Aritra Rajak 在他们的研究文章 (e202116572) 中描述了一种通过聚（L-丙交酯）结晶驱动自组装来受控合成离散菱形二维片状体的简便策略，该片状体具有可调的表面功能和发光性）。通过双组分共结晶和活结晶技术，可以分别实现两种功能染料在共血小板和块共血小板表面上的预定序列控制的超分子组织。

5.Polymer Micelles Self-assembled fluorescent block copolymer micelles with responsive emission are reported by Birgit Weber et al. in their Research Article (e202117570).

聚合物胶束 Birgit Weber 等人在他们的研究文章（e202117570）中报道了具有响应发射能力的自组装荧光嵌段共聚物胶束。

6.Chemical Synthesis and Semisynthesis of Lipidated Proteins.

脂化蛋白质的化学合成和半合成。

7.Self-Assembled Fluorescent Block Copolymer Micelles with Responsive Emission.

具有响应发射能力的自组装荧光嵌段共聚物胶束。

8.Towards a Systematic Understanding of the Influence of Temperature on Glycosylation Reactions.

系统地了解温度对糖基化反应的影响。

9.Drastic Events and Gradual Change Define the Structure of an Active Copper-Zinc-Alumina Catalyst for Methanol Synthesis.

剧烈事件和逐渐变化定义了用于甲醇合成的活性铜-锌-氧化铝催化剂的结构。

10.Crystallization-Driven Controlled Two-Dimensional (2D) Assemblies from Chromophore-Appended Poly(L-lactide)s: Highly Efficient Energy Transfer on a 2D Surface.

来自附加发色团的聚（L-丙交酯）的结晶驱动受控二维（2D）组件：2D 表面上的高效能量转移。

11.Control of Hot Carrier Relaxation in CsPbBr3 Nanocrystals Using Damping Ligands.

使用阻尼配体控制 CsPbBr3 纳米晶体中的热载流子弛豫。

12.Structural Basis for Chaperone-Independent Ubiquitination of Tau Protein by Its E3 Ligase CHIP.

Tau 蛋白通过其 E3 连接酶芯片进行不依赖分子伴侣的泛素化的结构基础。

13.Design, Synthesis, and Targeted Delivery of an Immune Stimulant that Selectively Reactivates Exhausted CAR T Cells.

设计、合成和靶向递送可选择性重新激活耗尽的 CAR T 细胞的免疫刺激剂。

14.A Nuclear-Targeted AIE Photosensitizer for Enzyme Inhibition and Photosensitization in Cancer Cell Ablation.

一种核靶向 AIE 光敏剂，用于癌细胞消融中的酶抑制和光敏化。

15.Covalent Organic Framework (COF) Derived Ni-N-C Catalysts for Electrochemical CO2 Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites.

用于电化学 CO2 还原的共价有机框架 (COF) 衍生 Ni-NC 催化剂：揭示活性位点的基本动力学和结构参数。

16.Protein Ligation and Labeling Enabled by a C-Terminal Tetracysteine Tag.

C 端四半胱氨酸标签实现蛋白质连接和标记。

17.Switchable Polymerization Organocatalysis: From Monomer Mixtures to Block Copolymers.

可切换聚合有机催化：从单体混合物到嵌段共聚物。

18.A TMEDA–Iron Adduct Reaction Manifold in Iron-Catalyzed C(sp2)−C(sp3) Cross-Coupling Reactions.

铁催化 C(sp2)−C(sp3) 交叉偶联反应中的 TMEDA-铁加合物反应流形。

19.Versatile Construction of Biomimetic Nanosensors for Electrochemical Monitoring of Intracellular Glutathione.

用于细胞内谷胱甘肽电化学监测的仿生纳米传感器的多功能构建。

20.Interfacial Manganese-Doping in CsPbBr3 Nanoplatelets by Employing a Molecular Shuttle.

利用分子梭在 CsPbBr3 纳米片中进行界面锰掺杂。

21.Proton-Promoted Nickel-Catalyzed Asymmetric Hydrogenation of Aliphatic Ketoacids.

质子促进的镍催化脂肪族酮酸的不对称氢化。

22.N-Doped Carbon Electrocatalyst: Marked ORR Activity in Acidic Media without the Contribution from Metal Sites?.

N-掺杂碳电催化剂：在酸性介质中显着的 ORR 活性，无需金属位点的贡献？

23.Mechanism of Spatial and Temporal Control in Precision Cyclic Vinyl Polymer Synthesis by Lewis Pair Polymerization.

路易斯对聚合精密环状乙烯基聚合物合成中的时空控制机制。

24.Remote C(sp3)−H Acylation of Amides and Cascade Cyclization via N-Heterocyclic Carbene Organocatalysis.

通过 N-杂环卡宾有机催化进行酰胺的远程 C(sp3)−H 酰化和级联环化。

25.A Metallofullertube of Ce2@C100 with a Carbon Nanotube Segment: Synthesis, Single-Molecule Conductance and Supramolecular Assembly.

具有碳纳米管段的 Ce2@C100 金属富勒管：合成、单分子电导和超分子组装。

26.Side-Chain-Tuned Molecular Packing Allows Concurrently Boosted Photoacoustic Imaging and NIR-II Fluorescence.

侧链调节的分子堆积可同时增强光声成像和 NIR-II 荧光。

27.One-Step Synthesis of Degradable Vinylic Polymer-Based Latexes via Aqueous Radical Emulsion Polymerization.

通过水自由基乳液聚合一步合成可降解乙烯基聚合物基乳胶。

28.Advancing the Development of Recyclable Aromatic Polyesters by Functionalization and Stereocomplexation.

通过官能化和立体络合促进可回收芳香族聚酯的开发。

29.Logical Analysis of Multiple Single-Nucleotide-Polymorphisms with Programmable DNA Molecular Computation for Clinical Diagnostics.

利用可编程 DNA 分子计算对多个单核苷酸多态性进行逻辑分析，用于临床诊断。

30.Three-Dimensional Crystalline Covalent Triazine Frameworks via a Polycondensation Approach.

通过缩聚方法形成三维结晶共价三嗪框架。

31.Encoding Enantiomeric Molecular Chiralities on Graphene Basal Planes.

在石墨烯基底平面上编码对映体分子手性。

32.Local Symmetry Breaking Suppresses Thermal Conductivity in Crystalline Solids.

局部对称性破缺抑制晶体固体的导热性。

33.Pure Boric Acid Does Not Show Room-Temperature Phosphorescence (RTP).

纯硼酸不显示室温磷光 (RTP)。

34.Rhodium-Catalyzed ON-OFF Switchable Hydrogenation Using a Molecular Shuttle Based on a [2]Rotaxane with a Phosphine Ligand.

使用基于带有膦配体的[2]轮烷的分子梭进行铑催化的ON-OFF可切换氢化。

35.Macrocyclic Polyoxometalates: Selective Polyanion Binding and Ultrahigh Proton Conduction.

大环多金属氧酸盐：选择性聚阴离子结合和超高质子传导。

36.Multifunctional Wearable Silver Nanowire Decorated Leather Nanocomposites for Joule Heating, Electromagnetic Interference Shielding and Piezoresistive Sensing.

用于焦耳加热、电磁干扰屏蔽和压阻传感的多功能可穿戴银纳米线装饰皮革纳米复合材料。

37.Synthesis of Cyclophenacene- and Chiral-Type Cyclophenylene-Naphthylene Belts.

环苯并苯和手性型环亚苯基-亚萘基带的合成。

38.Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity.

用于煤层甲烷净化的镍基金属有机框架，具有创纪录的 CH4/N2 选择性。

39.Light-Powered Ion Pumping in a Cation-Selective Conducting Polymer Membrane.

阳离子选择性导电聚合物膜中的光动力离子泵浦。

40.Wavelength-Orthogonal Stiffening of Hydrogel Networks with Visible Light.

可见光下水凝胶网络的波长正交硬化。

41.Simultaneous Counting of Molecules in the Halo and Dense-Core of Nanovesicles by Regulating Dynamics of Vesicle Opening.

通过调节囊泡打开的动力学来同时计数纳米囊泡的光环和致密核心中的分子。

42.Frustrated Lewis Pair in Zeolite Cages for Alkane Activations.

沸石笼中用于烷烃活化的失意的刘易斯对。

43.Microscopic Mechanism of the Heat-Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance.

荧光粉中热致蓝移的微观机制以及对最近掺杂剂-空位距离的对数能量依赖性。

44.Enantioselective Synthesis of Tertiary β-Boryl Amides by Conjunctive Cross-Coupling of Alkenyl Boronates and Carbamoyl Chlorides.

通过链烯基硼酸酯和氨基甲酰氯的联合交叉偶联对映选择性合成叔 β-硼酰胺。

45.Crystalline Neutral Diboron Analogues of Cyclopropanes.

环丙烷的结晶中性二硼类似物。

46.Reactive Extrusion Printing for Simultaneous Crystallization-Deposition of Metal–Organic Framework Films.

用于同时结晶沉积金属有机框架薄膜的反应挤出印刷。

47.Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores.

负载型硼氢化镧催化沸石微孔内的 CH 硼化。

48.NHC Catalysis for Umpolung Pyridinium Alkylation via Deoxy-Breslow Intermediates.

NHC 通过 Deoxy-Breslow 中间体催化 Umpolung 吡啶烷基化。

49.Enantioselective Recognition of Helicenes by a Tailored Chiral Benzo[ghi]perylene Trisimide π-Scaffold.

通过定制的手性苯并苝三酰亚胺π-支架对螺旋烯进行对映选择性识别。

50.On-Surface Synthesis of [3]Radialenes via [1+1+1] Cycloaddition.

通过[1+1+1]环加成在表面合成[3]Radialenes。

51.A Calix[3]acridan-Based Host–Guest Cocrystal Exhibiting Efficient Thermally Activated Delayed Fluorescence.

基于 Calix[3] 吖啶丹的主客体共晶表现出高效的热激活延迟荧光。

52.Access to a Labile Monomeric Magnesium Radical by Ball-Milling.

通过球磨获得不稳定的单体镁自由基。

53.Photo-Imprinting of the Helical Organization in Liquid-Crystal Networks Using Achiral Monomers and Circularly Polarized Light.

使用非手性单体和圆偏振光对液晶网络中的螺旋组织进行光压印。

54.The DNA damage response , which includes DNA repair and cell cycle checkpoint pathways in cancer cells, has been considered one of the main impediments to traditional chemotherapy. In their Research Article (e202117075), Na Kong, Xingcai Zhang, Wei Tao, Jong Seung Kim, and co-workers developed a multifunctional construct, M1, to target the DNA damage response of cancer cells. The findings identified a critical role of DNA damage repair pathways during 5-FU/FUDR therapy and underscore the role of inhibition of these pathways in sensitizing cancer cells to chemotherapeutics.

DNA损伤反应，包括癌细胞中的DNA修复和细胞周期检查点途径，被认为是传统化疗的主要障碍之一。在他们的研究文章 (e202117075) 中，Na Kong、Xingcai Zhu、Wei Tao、Jong Seung Kim 及其同事开发了一种多功能结构 M1，以靶向癌细胞的 DNA 损伤反应。研究结果确定了 DNA 损伤修复途径在 5-FU/FUDR 治疗过程中的关键作用，并强调了抑制这些途径在使癌细胞对化疗药物敏感方面的作用。

55.Chalcogen bonding (ChB) is a type of σ-hole interaction between a Group 16 chalcogen atom bearing electron-withdrawing groups and a Lewis base. In their Research Article (e202116071), Xiang-Yu Chen, Zhi-Xiang Wang, and co-workers show that ChB of alkynyl sulfonium salts enables the generation of alkynyl radicals for the synthesis of a variety of chalcogenoacetylenes with diselenides under blue-light irradiation.

硫族键合 (ChB) 是带有吸电子基团的第 16 族硫族原子与路易斯碱之间的一种 σ-空穴相互作用。在他们的研究文章 (e202116071) 中，Xiang-Yu Chen、Zhi-Xiang Wang 及其同事表明，炔基锍盐的 ChB 能够在蓝光照射下产生炔基自由基，用于与二硒化物合成各种硫属乙炔。

56.The enzymatic synthesis of eight luciferin analogues from phenolic derivatives in one-pot reactions is reported by Pimchai Chaiyen and co-workers in their Research Article (e202116908). Two novel D-luciferin analogues with methyl substituents were obtained; these compounds emit red and brighter light than the native D-luciferin. A new detection technology named LUMOS was also developed for in situ detection of organophosphate pesticides (OPs), including parathion, methyl parathion, EPN, profenofos, and fenitrothion, at parts per trillion (ppt) levels without requiring sample pretreatment.

Pimchai Chaiyen 及其同事在他们的研究文章 (e202116908) 中报道了在一锅反应中从酚衍生物酶促合成八种荧光素类似物。获得了两种新型的带有甲基取代基的D-荧光素类似物；这些化合物发出比天然 D-荧光素更亮的红光。还开发了一种名为 LUMOS 的新检测技术，用于原位检测万亿分之一 (ppt) 水平的有机磷农药 (OP)，包括对硫磷、甲基对硫磷、EPN、丙溴磷和杀螟松，无需样品预处理。

57.Defect-free alternating conjugated polymers were produced by exploring palladium-catalyzed Stille polymerization at room temperature. The selected copolymers demonstrated no homocoupling defects and superior charge transport properties, thus paving the road for the development of plastic electronics. Details of this study are reported by Qinqin Shi, Hui Huang, and co-workers in their Research Article (e202115969).

通过探索室温下钯催化的 Stille 聚合反应，制备了无缺陷的交替共轭聚合物。所选共聚物没有表现出自偶联缺陷和优异的电荷传输性能，从而为塑料电子产品的发展铺平了道路。这项研究的详细信息由史勤勤、黄辉及其同事在他们的研究文章 (e202115969) 中报告。

58.Magnetic Materials In their Communication (e202117084), Qun Xu et al. report on the CO2-induced exposure of the intrinsic magnetic surface of BaTiO3 to give room-temperature ferromagnetism.

通信中的磁性材料 (e202117084)，Qun Xu 等人。关于 CO2 诱导 BaTiO3 固有磁性表面暴露以产生室温铁磁性的报告。

59.Light Harvesting In their Research Article (e202200466), Xu-Man Chen, Hong Yang, Quan Li et al. report an artificial light-harvesting system with controllable efficiency enabled by an annulene-based anisotropic fluid.

光采集 在他们的研究文章 (e202200466) 中，Xu-Man Chen、Hong Yang、Quan Li 等人。报告了一种由基于轮烯的各向异性流体实现的具有可控效率的人工光采集系统。

60.Synthetic Cells: From Simple Bio-Inspired Modules to Sophisticated Integrated Systems.

合成细胞：从简单的仿生模块到复杂的集成系统。

61.Unraveling Charge-Separation Mechanisms in Photocatalyst Particles by Spatially Resolved Surface Photovoltage Techniques.

通过空间分辨表面光电压技术揭示光催化剂颗粒中的电荷分离机制。

62.An Artificial Light-Harvesting System with Controllable Efficiency Enabled by an Annulene-Based Anisotropic Fluid.

由基于轮烯的各向异性流体实现的具有可控效率的人工光采集系统。

63.Topochemical Synthesis of a Heterochiral Peptide Polymer in Different Polymorphic Forms from Crystals and Aerogels.

从晶体和气凝胶中拓扑化学合成不同多晶型的异手性肽聚合物。

64.A Polymeric Nanobeacon for Monitoring the Fluctuation of Hydrogen Polysulfides during Fertilization and Embryonic Development.

用于监测受精和胚胎发育过程中多硫化氢波动的聚合物纳米信标。

65.Cation-Tuning Induced d-Band Center Modulation on Co-Based Spinel Oxide for Oxygen Reduction/Evolution Reaction.

阳离子调谐诱导钴基尖晶石氧化物的 d 带中心调制，用于氧还原/放出反应。

66.Support-Free PEDOT:PSS Fibers as Multifunctional Microelectrodes for In Vivo Neural Recording and Modulation.

无支撑 PEDOT:PSS 纤维作为多功能微电极，用于体内神经记录和调制。

67.DNA-Damage-Response-Targeting Mitochondria-Activated Multifunctional Prodrug Strategy for Self-Defensive Tumor Therapy.

用于自我防御肿瘤治疗的 DNA 损伤反应靶向线粒体激活多功能前药策略。

68.Biomimetic FeMo(Se, Te) as Joint Electron Pool Promoting Nitrogen Electrofixation.

仿生 FeMo(Se, Te) 作为联合电子池促进氮电固定。

69.Ferroptosis-Enhanced Cancer Immunity by a Ferrocene-Appended Iridium(III) Diphosphine Complex.

通过添加二茂铁的铱 (III) 二膦复合物来增强铁死亡增强的癌症免疫力。

70.Multicolour Fluorescence Based on Excitation-Dependent Electron Transfer Processes in o-Carborane Dyads.

基于邻碳硼烷二元组中激发依赖的电子转移过程的多色荧光。

71.Tuning Bulk O2 and Nonbonding Oxygen State for Reversible Anionic Redox Chemistry in P2-Layered Cathodes.

调节 P2 层阴极中的本体 O2 和非键合氧状态以实现可逆阴离子氧化还原化学。

72.Intercalation-Activated Layered MoO3 Nanobelts as Biodegradable Nanozymes for Tumor-Specific Photo-Enhanced Catalytic Therapy.

插层激活的层状 MoO3 纳米带作为可生物降解的纳米酶，用于肿瘤特异性光增强催化治疗。

73.Controlled Disassembly of Elemental Sulfur: An Approach to the Precise Synthesis of Polydisulfides.

元素硫的受控分解：聚二硫醚的精确合成方法。

74.Defect-Free Alternating Conjugated Polymers Enabled by Room- Temperature Stille Polymerization.

通过室温静聚合实现的无缺陷交替共轭聚合物。

75.Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light Irradiation.

炔基锍盐可用作硫族键合催化剂并在蓝光照射下产生炔基自由基。

76.Phosphorogenic Iridium(III) bis-Tetrazine Complexes for Bioorthogonal Peptide Stapling, Bioimaging, Photocytotoxic Applications, and the Construction of Nanosized Hydrogels.

用于生物正交肽缝合、生物成像、光细胞毒性应用和纳米水凝胶构建的发磷铱 (III) 双四嗪复合物。

77.Visible-Light-Driven Photocatalytic CO2 Reduction to CO/CH4 Using a Metal–Organic “Soft” Coordination Polymer Gel.

使用金属有机“软”配位聚合物凝胶，可见光驱动光催化 CO2 还原为 CO/CH4。

78.Enantioselective Total Synthesis of Hyperforin and Pyrohyperforin.

金丝桃素和焦金丝桃素的对映选择性全合成。

79.Luciferin Synthesis and Pesticide Detection by Luminescence Enzymatic Cascades.

荧光素合成和发光酶级联检测农药。

80.Double Lock Label Based on Thermosensitive Polymer Hydrogels for Information Camouflage and Multilevel Encryption.

基于热敏聚合物水凝胶的双锁标签，用于信息伪装和多级加密。

81.Unprecedented and Readily Tunable Photoluminescence from Aliphatic Quaternary Ammonium Salts.

脂肪族季铵盐产生前所未有的且易于调节的光致发光。

82.Coloration in Supraparticles Assembled from Polyhedral Metal-Organic Framework Particles.

由多面体金属有机框架颗粒组装而成的超颗粒的着色。

83.Unmasking the Critical Role of the Ordering Degree of Bimetallic Nanocatalysts on Oxygen Reduction Reaction by In Situ Raman Spectroscopy.

通过原位拉曼光谱揭示双金属纳米催化剂有序度对氧还原反应的关键作用。

84.A “Self-Checking” pH/Viscosity-Activatable NIR-II Molecule for Real-Time Evaluation of Photothermal Therapy Efficacy.

用于实时评估光热治疗功效的“自检”pH/粘度可激活 NIR-II 分子。

85.Chemical Defect-Driven Response on Graphene-Based Chemiresistors for Sub-ppm Ammonia Detection.

用于亚 ppm 氨检测的石墨烯化学电阻的化学缺陷驱动响应。

86.Chemoselective Transamidation of Thioamides by Transition-Metal-Free N−C(S) Transacylation.

通过无过渡金属的 N−C(S) 转酰基化对硫代酰胺进行化学选择性转酰胺基化。

87.Molecular-Level Insights into the Notorious CO Poisoning of Platinum Catalyst.

对铂催化剂臭名昭著的一氧化碳中毒的分子水平洞察。

88.Streamline Sulfur Redox Reactions to Achieve Efficient Room-Temperature Sodium–Sulfur Batteries.

简化硫氧化还原反应以实现高效的室温钠硫电池。

89.Overturned Loading of Inert CeO2 to Active Co3O4 for Unusually Improved Catalytic Activity in Fenton-Like Reactions.

将惰性 CeO2 翻转到活性 Co3O4 上，以显着提高类芬顿反应中的催化活性。

90.Extraordinary p–d Hybridization Interaction in Heterostructural Pd-PdSe Nanosheets Boosts C−C Bond Cleavage of Ethylene Glycol Electrooxidation.

异质结构 Pd-PdSe 纳米片中非凡的 p-d 杂化相互作用促进乙二醇电氧化的 C−C 键断裂。

91.Engineering MoOx/MXene Hole Transfer Layers for Unexpected Boosting of Photoelectrochemical Water Oxidation.

工程化 MoOx/MXene 空穴传输层可意外促进光电化学水氧化。

92.Alkylgold(III) Complexes Undergo Unprecedented Photo-Induced β-Hydride Elimination and Reduction for Targeted Cancer Therapy.

烷基金 (III) 配合物经历前所未有的光诱导 β-氢化物消除和还原，用于靶向癌症治疗。

93.Rapid and Controlled Polymerization of Bio-sourced δ-Caprolactone toward Fully Recyclable Polyesters and Thermoplastic Elastomers.

生物来源的 δ-己内酯快速、受控聚合成完全可回收的聚酯和热塑性弹性体。

94.Inverse Vulcanization of Norbornenylsilanes: Soluble Polymers with Controllable Molecular Properties via Siloxane Bonds.

降冰片烯基硅烷的逆硫化：通过硅氧烷键具有可控分子性质的可溶性聚合物。

95.Combining a Genetically Engineered Oxidase with Hydrogen-Bonded Organic Frameworks (HOFs) for Highly Efficient Biocomposites.

将基因工程氧化酶与氢键有机框架 (HOF) 相结合，打造高效生物复合材料。

96.CO2-Induced Exposure of the Intrinsic Magnetic Surface of BaTiO3 to Give Room-Temperature Ferromagnetism.

CO2 诱导 BaTiO3 固有磁性表面的暴露以产生室温铁磁性。

97.Exploring Unconventional SAM Analogues To Build Cell-Potent Bisubstrate Inhibitors for Nicotinamide N-Methyltransferase.

探索非常规 SAM 类似物来构建烟酰胺 N-甲基转移酶的细胞强效双底物抑制剂。

98.Site-Directed Chemical Modification of Amyloid by Polyoxometalates for Inhibition of Protein Misfolding and Aggregation.

通过多金属氧酸盐对淀粉样蛋白进行定点化学修饰，以抑制蛋白质错误折叠和聚集。

99.Oriented Nanoarchitectonics of Bacteriorhodopsin for Enhancing ATP Generation in a FoF1-ATPase-Based Assembly System.

用于增强基于 FoF1-ATPase 的组装系统中 ATP 生成的细菌视紫红质定向纳米结构。

100.Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition.

通过应变诱导 1,3-偶极环加成合成 π-扩展氮杂环烯芬烷。

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