总结: at用于在……那里(点)
eg:Shi is at the window.(她在窗户那里)
I'm working at the desk.(我在办公桌那里工作)
on用于在……那里(面)
eg:The cat is on the sofa.(猫在沙发(面)上)
I am workibg on the desk.(我在办公桌面上)