【标题速读】【JACS】【2022年】【8月】

2023-06-11 18:41 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

This cover image demonstrates the critical role of the solvent in the ion motion of intrinsically anionic metal–organic framework (MOF)-based quasi-solid-state electrolytes (QSSEs). Using hybrid theoretical and experimental approaches, we have identified solvent-assisted hopping as the dominant pathway for Li+ conduction in such materials, exemplified by MOF-688.

这张封面图片展示了溶剂在基于阴离子金属有机骨架 (MOF) 的准固态电解质 (QSSE) 的离子运动中的关键作用。使用混合理论和实验方法，我们已经确定溶剂辅助跃迁是此类材料中 Li+ 传导的主要途径，以 MOF-688 为例。

The cover depicts the cancer cell membrane-facilitated homotypic targeting analysis of exosomes for molecular subtype classification-based diagnosis of breast cancer.

封面描述了癌细胞膜促进的外泌体同型靶向分析，用于基于分子亚型分类的乳腺癌诊断。

A NIR-II fluorescence probe was developed for the detection of hepatic ischemia-reperfusion injury (HIRI) in mice livers. HIRI lesions of the livers glowed owing to the restricted rotation of the probe in the highly viscous lysosomes of the HIRI hepatocytes. View the article.

开发了一种 NIR-II 荧光探针，用于检测小鼠肝脏中的肝缺血再灌注损伤 (HIRI)。由于探针在 HIRI 肝细胞的高粘性溶酶体中的旋转受限，肝脏的 HIRI 病变会发光。

A heterostructured chiral membrane was designed using supramolecular templated self-assembly and an interfacial super-assembled strategy. This platform with the potential of chiral recognition was confirmed by the chiral transcription mechanism. The chiral membrane with cation selectivity as well as the general enantioseparation will motivate the development of the smart multifunctional membranes.

使用超分子模板化自组装和界面超组装策略设计了异质结构手性膜。手性转录机制证实了该平台具有手性识别的潜力。具有阳离子选择性以及一般对映分离的手性膜将推动智能多功能膜的发展。

An innovative strategy, I– vacancy, for designing stable charged domain walls (CDWs) in molecular ferroelectrics is proposed. A novel molecular ferroelectric, 1-adamantanammonium hydroiodate, with stable CDWs was successfully synthesized through the strategy, and CDWs can be precisely generated by the biased PFM tip. Statics and dynamics of domains were investigated on films.

提出了一种用于在分子铁电体中设计稳定带电畴壁 (CDW) 的创新策略 I– 空位。通过该策略成功合成了具有稳定 CDW 的新型分子铁电体 1-金刚烷氢碘酸铵，并且可以通过偏置 PFM 尖端精确地产生 CDW 在薄膜上研究了畴的静力学和动力学。

This cover image demonstrates the real chemistry of the synthesis and reversible transformation of AuCd bimetallic clusters. By subtly manipulating the steric hindrance of the ligands and/or the valence state of precursor (Au25q), the AuCd clusters with different structures and properties can be readily fabricated.

这张封面图片展示了 AuCd 双金属簇的合成和可逆转化的真实化学过程。通过巧妙地操纵配体的空间位阻和/或前体 (Au25q) 的价态，可以很容易地制造具有不同结构和性质的 AuCd 簇。

Mesoporous OMS-1 nanoparticles with high surface areas were successfully synthesized by the crystallization of precursors prepared in one step from Mg(MnO4)2, Mn(OAc)2, and Mg(OAc)2. Such a high surface area contributes to the catalytic performance for aerobic oxidation of alcohols and sulfides compared with other manganese oxide catalysts.

通过由 Mg(MnO4)2、Mn(OAc)2 和 Mg(OAc)2 一步制备的前体结晶，成功合成了具有高表面积的介孔 OMS-1 纳米粒子。与其他锰氧化物催化剂相比，如此高的表面积有助于醇类和硫化物的有氧氧化催化性能。

Plasma activates CO2 for hydrogenation into alternative fuels, enabling the conversion of renewable electricity to chemical energy. The combined effect of plasma-activated CO2 and a Pd2Ga alloy catalyst breaks the thermodynamic equilibrium limitation. The mechanistic insights improve the efficiency of catalytic CO2 conversion and allow the engineers to design new concept catalysts.

等离子激活 CO2 以氢化为替代燃料，从而使可再生电力转化为化学能。等离子活化 CO2 和 Pd2Ga 合金催化剂的联合作用打破了热力学平衡限制。对机理的了解提高了催化 CO2 转化的效率，并使工程师能够设计出新概念的催化剂。

In this work, such an emerging hydrogenated silicon nanosheet (H-silicene), which can favorably react with environmental water to generate H2 rapidly and continuously without any external energy input, has been explored as an effective anti-inflammatory agent for the therapeutics of diverse inflammatory diseases.

在这项工作中，这种新兴的氢化硅纳米片（H-silicene）可以在没有任何外部能量输入的情况下与环境水发生有利反应以快速连续地产生 H2，已被探索作为一种有效的抗炎剂用于治疗多种炎性疾病。

A quasi-three-dimensional pore refinement strategy, which is achieved by the tunability of ring size and number in polycycloalkane–dicarboxylate ligands, has been demonstrated to construct robust MOFs with confined aliphatic pore environment that can realize efficient separation of gases with similar structure, including CH4/C2H6/C3H8 and Xe/Kr.

通过聚环烷烃-二羧酸配体中环的大小和数量的可调性实现的准三维孔细化策略已被证明可以构建具有受限脂肪族孔环境的稳健 MOF，可以实现具有相似结构的气体的有效分离，包括 CH4/C2H6/C3H8 和 Xe/Kr。

Surface gelation triggered by Lewis acidic‒basic interactions among electrocatalysts, solvents, and lithium salts deteriorates the redox kinetics in Li‒S chemistry. As visually illustrated in the cover art, a Lewis basic salt lithium iodide is introduced to “clip” the Lewis acidic sites and boost the performances of Li‒S pouch cells.

由电催化剂、溶剂和锂盐之间的路易斯酸-碱相互作用引发的表面凝胶化会恶化 Li-S 化学中的氧化还原动力学。正如封面艺术中直观地说明的那样，引入路易斯碱性盐碘化锂以“夹住”路易斯酸性位点并提高 Li-S 软包电池的性能。

Existing measurement techniques have limited single-particle observation of chemical reactions to surface-tethered or immobilized systems. Active-feedback 3D single-particle tracking overcomes this barrier by “locking on” to freely diffusing and growing polymer particles to extract the growth rates of individual particles, revealing emergent heterogeneity while particles are still freely diffusing in solution.

现有的测量技术将化学反应的单粒子观察限制在表面系留或固定系统上。主动反馈 3D 单粒子跟踪通过“锁定”自由扩散和生长的聚合物粒子来提取单个粒子的生长速率，从而克服了这一障碍，揭示了粒子仍在溶液中自由扩散时出现的异质性。

A planar molecule with S•••O noncovalently intramolecular interactions (using a mortise-and-tenon joint to show the “locked” planar conformation in the cover art) has been developed as a solid additive for organic solar cells (OSCs). Based on this strategy, a record power conversion efficiency of 18.85% was achieved for single-junction binary OSCs.

具有 S•••O 非共价分子内相互作用的平面分子（使用榫眼接头显示封面艺术中的“锁定”平面构象）已被开发为有机太阳能电池 (OSC) 的固体添加剂。基于这一策略，单结二元 OSC 实现了创纪录的 18.85% 的功率转换效率。

An unusual ruthenium-catalyzed hydroboration of ynones provides efficient and selective access to previously inaccessible vinyl α-hydroxylboronates. This process involves unprecedented 1,4-hydroboration of ynones to form a boryl allenol ether followed by a second selective hydroboration of the allene intermediate.

一种不寻常的钌催化的炔烃硼氢化反应提供了高效和选择性地获得以前无法获得的乙烯基 α-羟基硼酸酯。该过程涉及炔酮前所未有的 1,4-硼氢化形成硼基丙二醇醚，然后是丙二烯中间体的第二次选择性硼氢化。

By means of post-synthetic modification, reversible redox reactions onto an open metal site (Au) are manipulated in an iron(II) metal–organic framework, which results in switchable one-/two-/three-step spin-crossover dynamics. The coupling of spin transition and redox states opens a new perspective for multi-responsive molecular switches.

通过合成后修饰，在铁 (II) 金属-有机框架中操纵开放金属位点 (Au) 上的可逆氧化还原反应，从而产生可切换的一步/两步/三步自旋交叉动力学。自旋跃迁和氧化还原态的耦合为多响应分子开关开辟了新的视角。

At the primary structure level, the balance of structural flexibility and rigidity significantly enhances the efficiency of CL without wavelength change. More importantly, manipulation of secondary structures can not only enhance the CL efficiency but also induce the redshift of CL.

在一级结构层面，结构柔性和刚性的平衡显着提高了 CL 的效率，无需改变波长。更重要的是，二级结构的操纵不仅可以提高发光效率，还可以诱导发光的红移。

In this Perspective, we highlighted the dedication to rigidly conjugated MCIs with multi-size and multi-dimensionality from molecular design evolution to functional landscapes.

在这个观点中，我们强调了对从分子设计演变到功能景观的多尺寸和多维度的刚性共轭 MCI 的奉献。

Ruthenate nanosheets are known as good two-dimensional conductors, but details including their atomic arrangements and conductivity mechanism are open to debate. Our study revealed polymorphism in them, where symmetry breakage by forming short Ru–Ru pairs resulted in a band structure similar to that of graphene and induced an excellent semi-metallic conductivity.

钌酸盐纳米片被称为良好的二维导体，但包括其原子排列和导电机制在内的细节仍有待商榷。我们的研究揭示了它们的多态性，通过形成短的 Ru-Ru 对导致对称性破缺，导致类似于石墨烯的能带结构，并诱导出优异的半金属导电性。

Ga-chabazite zeolites (Ga-CHA) have been found to efficiently catalyze propane dehydrogenation with high propylene selectivity (96%). External Ga2O3 particles are reduced in hydrogen and diffuse into the zeolite pores, displacing Brønsted acid sites and forming extra-framework Ga+ sites. These isolated Ga+ sites react reversibly with H2 to form gallium hydrides and are the active sites for propane dehydrogenation.

已发现镓菱沸石 (Ga-CHA) 可有效催化丙烷脱氢，并具有高丙烯选择性 (96%)。外部 Ga2O3 颗粒在氢气中被还原并扩散到沸石孔隙中，取代 Brønsted 酸位点并形成骨架外的 Ga+ 位点。这些孤立的 Ga+ 位点与 H2 发生可逆反应，形成氢化镓，是丙烷脱氢的活性位点。

Data carriers using spin waves in spintronic and magnonic logic devices can offer low power consumption and even a Joule-heat-free process. Distinct spin-wave excitations arising from antiferromagnetic exchange in combination with the dipole–dipole interaction were predicted in a series of heterometallic ring-like coordination complexes, namely, {ScnGdn} (n = 4, 6, 8).

在自旋电子和磁子逻辑器件中使用自旋波的数据载体可以提供低功耗甚至无焦耳热工艺。在一系列异金属环状配位化合物，即 {ScnGdn} (n = 4, 6, 8) 中预测了反铁磁交换与偶极-偶极相互作用相结合产生的不同自旋波激发。

Mechanistic understanding of atom transfer radical polymerization (ATRP) is fundamental to predict and control polymerization outcomes and to guide the next advances in ATRP, which include using Fe catalysts, combining various stimuli, expanding the monomer and functionality scope, running it at larger or smaller scale, and developing controlled depolymerization procedures.

对原子转移自由基聚合 (ATRP) 的机理理解是预测和控制聚合结果以及指导 ATRP 下一步进展的基础，包括使用 Fe 催化剂、结合各种刺激、扩大单体和功能范围、在更大或更小的条件下运行规模，并开发受控的解聚程序。

Through a joint experimental and theoretical study of charge transport through dimer molecules formed from graphene-like monomers, a unique quantum state is found, which enables unprecedented nonclassical room-temperature charge transport controlled by stacking interactions.

通过对由类石墨烯单体形成的二聚体分子进行的电荷传输的联合实验和理论研究，发现了一种独特的量子态，这使得通过堆叠相互作用控制的前所未有的非经典室温电荷传输成为可能。

A high local hydroxyl concentration is constructed near the Pt clusters on the surface of Ti3C2Tx. The increased hydroxyls promote the oxidation of adsorbed CO and improve the activity and durability of Pt clusters for the methanol oxidation reaction.

在 Ti3C2TX 表面的 Pt 簇附近构建了高局部羟基浓度。增加的羟基促进了吸附的 CO 的氧化，提高了 Pt 团簇对甲醇氧化反应的活性和耐久性。

The metathesis cascade polymerization of polycyclic enyne monomers can yield two different repeat unit structures corresponding to a complete or interrupted cascade reaction before propagation. In our study, we optimize monomer structures to achieve well-controlled polymerizations with high selectivity for the complete cascade.

多环烯炔单体的复分解级联聚合可以产生两种不同的重复单元结构，对应于传播前的完整或中断的级联反应。在我们的研究中，我们优化了单体结构，以实现对整个级联具有高选择性的可控聚合。

1.Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes.

基于金属有机骨架的准固态电解质的离子传导机制和设计。

2.Endocytosis of Coacervates into Liposomes.

凝聚层的内吞作用进入脂质体。

3.A Borosilicide with Clathrate VIII Structure.

具有笼形 VIII 结构的硼硅化物。

4.Enantioselective Reductive N-Cyclization–Alkylation Reaction of Alkene-Tethered Oxime Esters and Alkyl Iodides by Nickel Catalysis.

镍催化下烯烃系肟酯和烷基碘化物的对映选择性还原 N-环化-烷基化反应。

5.Enantioselective Radical Trifluoromethylation of Benzylic C–H Bonds via Cooperative Photoredox and Copper Catalysis.

通过协同光氧化还原和铜催化对苄基 C-H 键进行对映选择性自由基三氟甲基化。

6.Molecular Characterization of Exosomes for Subtype-Based Diagnosis of Breast Cancer.

外泌体的分子特征用于基于亚型的乳腺癌诊断。

7.Kinetic Diagnostics and Synthetic Design of Platinum Group Metal-Free Electrocatalysts for the Oxygen Reduction Reaction Using Reactivity Maps and Site Utilization Descriptors.

使用反应图和位点利用描述符进行氧还原反应的铂族无金属电催化剂的动力学诊断和合成设计。

8.Amplified Spontaneous Emission from Zwitterionic Excited-State Intramolecular Proton Transfer.

两性离子激发态分子内质子转移的放大自发发射。

9.Molecular and Electronic Structure of Isolated Platinum Sites Enabled by the Expedient Measurement of 195Pt Chemical Shift Anisotropy.

通过 195Pt 化学位移各向异性的便捷测量实现孤立铂位点的分子和电子结构。

10.Electrochemical Detection of a Few Copies of Unamplified SARS-CoV-2 Nucleic Acids by a Self-Actuated Molecular System.

通过自驱动分子系统对少量未扩增的 SARS-CoV-2 核酸进行电化学检测。

11.Structural Diversity in Dimension-Controlled Assemblies of Tetrahedral Gold Nanocrystals.

四面体金纳米晶体尺寸控制组件的结构多样性。

12.Iridium-Incorporated Strontium Tungsten Oxynitride Perovskite for Efficient Acidic Hydrogen Evolution.

用于高效酸性析氢的掺铱锶钨氮氧化物钙钛矿。

13.Free Piperazic Acid as a Precursor to Nonribosomal Peptides.

游离哌嗪酸作为非核糖体肽的前体。

14.Hydrogen-Bond Network Promotes Water Splitting on the TiO2 Surface.

氢键网络促进 TiO2 表面的水分解。

15.Real-Time Polymer Viscosity–Catalytic Activity Relationships on the Microscale.

微尺度上的实时聚合物粘度-催化活性关系。

16.Precision Navigation of Hepatic Ischemia–Reperfusion Injury Guided by Lysosomal Viscosity-Activatable NIR-II Fluorescence.

由溶酶体粘度激活的 NIR-II 荧光引导的肝缺血再灌注损伤的精确导航。

17.Polymer Dots as Photoactive Membrane Vesicles for [FeFe]-Hydrogenase Self-Assembly and Solar-Driven Hydrogen Evolution.

聚合物点作为光活性膜囊泡，用于 [FeFe]-氢化酶自组装和太阳能驱动的氢演化。

18.Time-Resolved Atomistic Imaging and Statistical Analysis of Daptomycin Oligomers with and without Calcium Ions.

含钙离子和不含钙离子的达托霉素低聚物的时间分辨原子成像和统计分析。

19.Universal Kinetic Mechanism Describing CO2 Photoreductive Yield and Selectivity for Semiconducting Nanoparticle Photocatalysts.

描述半导体纳米粒子光催化剂的 CO2 光还原产率和选择性的通用动力学机制。

20.Thermodynamics-Kinetics-Balanced Metal–Organic Framework for In-Depth Radon Removal under Ambient Conditions.

用于在环境条件下深度去除氡的热力学-动力学-平衡金属-有机框架。

21.Enantio- and Regioselective Ni-Catalyzed para-C–H Alkylation of Pyridines with Styrenes via Intermolecular Hydroarylation.

通过分子间氢化芳基化对映和区域选择性 Ni 催化吡啶与苯乙烯的对 C-H 烷基化。

22.N-Vinyl Acrylamides: Versatile Heterobifunctional Electrophiles for Thiol–Thiol Bioconjugations.

N-乙烯基丙烯酰胺：用于硫醇-硫醇生物共轭的多功能异双功能亲电试剂。

23.A Single-Component Luminescent Biosensor for the SARS-CoV-2 Spike Protein.

用于 SARS-CoV-2 刺突蛋白的单组分发光生物传感器。

24.Zinc Titanium Nitride Semiconductor toward Durable Photoelectrochemical Applications.

面向耐用光电化学应用的锌钛氮化物半导体。

25.Thermal Enhancement of Luminescence for Negative Thermal Expansion in Molecular Materials.

分子材料中负热膨胀的发光热增强。

26.Magnetic Interactions in Substitutional Core-Doped Graphene Nanoribbons.

替代核掺杂石墨烯纳米带中的磁相互作用。

27.Exploring Structure–Property Relations of B,S-Doped Polycyclic Aromatic Hydrocarbons through the Trinity of Synthesis, Spectroscopy, and Theory.

通过合成、光谱和理论的三位一体探索 B,S 掺杂多环芳烃的结构-性质关系。

28.Nanopore Identification of Alditol Epimers and Their Application in Rapid Analysis of Alditol-Containing Drinks and Healthcare Products.

糖醇差向异构体的纳米孔鉴定及其在含糖醇饮料和保健品快速分析中的应用。

29.Densified HKUST-1 Monoliths as a Route to High Volumetric and Gravimetric Hydrogen Storage Capacity.

致密的 HKUST-1 整体结构作为实现高体积和重量储氢能力的途径。

30.Probing the Electronic Structure and Bond Dissociation of SO3 and SO3– Using High-Resolution Cryogenic Photoelectron Imaging.

探测 SO3 和 SO3 的电子结构和键离解——使用高分辨率低温光电子成像。

31.Data-Driven Enhancement of ZT in SnSe-Based Thermoelectric Systems.

ZT 在基于 SnSe 的热电系统中的数据驱动增强。

32.Boosting Osmotic Energy Conversion of Graphene Oxide Membranes via Self-Exfoliation Behavior in Nano-Confinement Spaces.

通过纳米限制空间中的自剥离行为促进氧化石墨烯膜的渗透能转换。

33.Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family.

通过硼硫属元素混合物法和 NaCuTS3 族中的可逆吸水获得超铀硫化物。

34.Gd(OH)F2: A Promising Cryogenic Magnetic Refrigerant.

Gd(OH)F2：一种很有前途的低温磁性制冷剂。

35.Super-Assembled Chiral Mesostructured Heteromembranes for Smart and Sensitive Couple-Accelerated Enantioseparation.

用于智能和灵敏耦合加速对映分离的超级组装手性介观结构异质膜。

36.Rational Design of Molecular Ferroelectrics with Negatively Charged Domain Walls.

带负电畴壁的分子铁电体的合理设计。

37.The Role of Tryptophan in π Interactions in Proteins: An Experimental Approach.

色氨酸在蛋白质 π 相互作用中的作用：一种实验方法。

38.Combinatorial Synthesis and Screening of Mixed Halide Perovskite Megalibraries.

混合卤化物钙钛矿巨型文库的组合合成和筛选。

39.Confined Motion: Motility of Active Microparticles in Cell-Sized Lipid Vesicles.

受限运动：活性微粒在细胞大小的脂质囊泡中的运动。

40.Surface Re-Engineering of Perovskites with Buckybowls to Boost the Inverted-Type Photovoltaics.

用 Buckybowls 对钙钛矿进行表面再工程以促进倒置型光伏发电。

41.Discovery of a Transferrin Receptor 1-Binding Aptamer and Its Application in Cancer Cell Depletion for Adoptive T-Cell Therapy Manufacturing.

转铁蛋白受体 1 结合适体的发现及其在过继性 T 细胞疗法生产中癌细胞耗竭中的应用。

42.Isolation of a Cu–H Monomer Enabled by Remote Steric Substitution of a N-Heterocyclic Carbene Ligand: Stoichiometric Insertion and Catalytic Hydroboration of Internal Alkenes.

通过 N-杂环卡宾配体的远程空间取代实现 Cu-H 单体的分离：内部烯烃的化学计量插入和催化硼氢化。

43.Interconversion of Atomically Dispersed Platinum Cations and Platinum Clusters in Zeolite ZSM-5 and Formation of Platinum gem-Dicarbonyls.

沸石 ZSM-5 中原子分散的铂阳离子和铂簇的相互转化以及铂宝石-二羰基化合物的形成。

44.2.2 Å Cryo-EM Tetra-Protofilament Structure of the Hamster Prion 108–144 Fibril Reveals an Ordered Water Channel in the Center.

2.2 Å Cryo-EM Tetra-Protofilament 仓鼠朊病毒 108–144 Fibril 的结构显示中心有一个有序的水通道。

45.Electrophotochemical Ce-Catalyzed Ring-Opening Functionalization of Cycloalkanols under Redox-Neutral Conditions: Scope and Mechanism.

氧化还原中性条件下环烷醇的电光化学 Ce 催化开环功能化：范围和机制。

46.Heteroanionic Control of Exemplary Second-Harmonic Generation and Phase Matchability in 1D LiAsS2–xSex.

1D LiAsS2–xSex 中示例性二次谐波产生和相位匹配性的杂阴离子控制。

47.Iodine–Iodine Cooperation Enables Metal-Free C–N Bond-Forming Electrocatalysis via Isolable Iodanyl Radicals.

碘-碘合作通过可分离的碘自由基实现无金属 C-N 键形成电催化。

48.Template-Free Assembly of Functional RNAs by Loop-Closing Ligation.

通过闭环连接对功能性 RNA 进行无模板组装。

49.Decrypting Material Performance by Wide-field Femtosecond Interferometric Imaging of Energy Carrier Evolution.

通过载能子演化的宽视场飞秒干涉成像解密材料性能。

50.Deeper Insight into Photopolymerization: The Synergy of Time-Resolved Nonuniform Sampling and Diffusion NMR.

深入了解光聚合：时间分辨非均匀采样和扩散 NMR 的协同作用。

51.Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmI2.

非对映选择性自由基 1,4-酯迁移：无环酯与 SmI2 的自由基环化。

52.Direct Construction of Isomeric Benzobisoxazole–Vinylene-Linked Covalent Organic Frameworks with Distinct Photocatalytic Properties.

直接构建具有独特光催化性能的异构苯并双恶唑-亚乙烯基连接的共价有机骨架。

53.Ligand-Controlled Cobalt-Catalyzed Regiodivergent Alkyne Hydroalkylation.

配体控制的钴催化的区域发散性炔烃加氢烷基化。

54.Iterative Synthesis of Contorted Macromolecular Ladders for Fast-Charging and Long-Life Lithium Batteries.

用于快速充电和长寿命锂电池的扭曲大分子阶梯的迭代合成。

55.“Flash & Click”: Multifunctionalized Lipid Derivatives as Tools To Study Viral Infections.

“ Flash & Click”：多功能脂质衍生物作为研究病毒感染的工具。

56.Portable Models for Entropy Effects on Kinetic Selectivity.

熵对动力学选择性影响的便携式模型。

57.Mechanistic Insights into OC–COH Coupling in CO2 Electroreduction on Fragmented Copper.

碎铜上 CO2 电还原中 OC-COH 耦合的机理洞察。

58.Photooxidation of the Phenolate Anion is Accelerated at the Water/Air Interface.

酚盐阴离子的光氧化在水/空气界面处加速。

59.Polymerase η Recruits DHX9 Helicase to Promote Replication across Guanine Quadruplex Structures.

聚合酶 η 招募 DHX9 解旋酶以促进跨鸟嘌呤四链体结构的复制。

60.Enhancing Oxygenic Photosynthesis by Cross-Linked Perylenebisimide “Quantasomes”.

通过交联苝双酰亚胺“量子体”增强产氧光合作用。

61.Total Synthesis of Darobactin A.

Darobactin A 的全合成。

62.Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals.

非手性层状杂化钙钛矿铁电晶体圆偏振光检测的稳健自旋相关各向异性。

63.C–C σ-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex.

C-C σ-键氧化加成和大环支持的二铁配合物的氢化作用。

64.A Concise Synthesis of Pleurotin Enabled by a Nontraditional C–H Epimerization.

通过非传统 C-H 差向异构化实现的侧耳素简明合成。

65.Migrative Carbofluorination of Saturated Amides Enabled by Pd-Based Dyotropic Rearrangement.

基于 Pd 的变色重排实现饱和酰胺的迁移碳氟化。

66.The Energy Gap Law at Work: Emission Yield and Rate Fluctuations of Single NIR Emitters.

工作中的能隙定律：单个 NIR 发射器的发射产量和速率波动。

67.Structure and Function of a Dehydrating Condensation Domain in Nonribosomal Peptide Biosynthesis.

非核糖体肽生物合成中脱水缩合结构域的结构和功能。

68.(n-Bu)4NBr-Promoted N2 Splitting to Molybdenum Nitride.

(n-Bu)4NBr-促进 N2 分解为氮化钼。

69.Optically Induced Long-Lived Chirality Memory in the Color-Tunable Chiral Lead-Free Semiconductor (R)/(S)-CHEA4Bi2BrxI10–x (x = 0–10).

颜色可调手性无铅半导体 (R)/(S)-CHEA4Bi2BrxI10–x (x = 0–10) 中的光感应长寿命手性记忆。

70.Synthesis and Aerobic Oxidation Catalysis of Mesoporous Todorokite-Type Manganese Oxide Nanoparticles by Crystallization of Precursors.

前驱体结晶法合成介孔 Todorokite 型氧化锰纳米粒子及其有氧氧化催化。

71.Engineered Amber-Emitting Nano Luciferase and Its Use for Immunobioluminescence Imaging In Vivo.

工程琥珀色发光纳米荧光素酶及其在体内免疫生物发光成像中的应用。

72.Intracellular Communication between Synthetic Macromolecules.

合成大分子之间的细胞内通讯。

73.Unconventional Charge Transport in MgCr2O4 and Implications for Battery Intercalation Hosts.

MgCr2O4 中的非常规电荷传输及其对电池嵌入主体的影响。

74.Chemical Conformation of the Essential Glutamate Site of the c-Ring within Thermophilic Bacillus FoF1-ATP Synthase Determined by Solid-State NMR Based on its Isolated c-Ring Structure.

嗜热芽孢杆菌 FoF1-ATP 合酶中 c 环必需谷氨酸位点的化学构象，通过固态 NMR 基于其分离的 c 环结构确定。