【标题速读】【JACS】【2022年】【4月】

2023-06-06 17:02 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

Biochemical, spectroscopic, and computational investigation of the isonitrile forming non-heme iron dioxygenase ScoE reveals key intermediates including C5-OH CABA and imine CABA. The cover depicts a wrought iron sculpture of ScoE with the active site, elucidated intermediates, and isonitrile-containing product accented in gold.

异腈形成非血红素铁双加氧酶 ScoE 的生化、光谱和计算研究揭示了关键中间体，包括 C5-OH CABA 和亚胺 CABA。封面描绘了 ScoE 的锻铁雕塑，其中包含活性位点、阐明的中间体和含异腈的产品，并以金色点缀。

The multimodal and reversible manipulation of ligand accessibility using magnetic nanoparticle aggregates is demonstrated to dynamically regulate receptor–ligand binding in macrophages. The ligand accessibility of macrophages is magnetically manipulated to regulate their adhesion and pro-regenerative polarization both in vitro and in vivo.

使用磁性纳米颗粒聚集体对配体可及性的多模式和可逆操作被证明可以动态调节巨噬细胞中的受体-配体结合。巨噬细胞的配体可及性通过磁性操作来调节它们在体外和体内的粘附和促再生极化。

A robust strategy combining crystallographic group–subgroup theory and high-throughput ab initio calculations was proposed to discover and explore unknown crystals, as demonstrated in the design of ternary crystalline chalcogenide semiconductors for optoelectronic applications. Twenty-two new compounds were predicted to show excellent stability and high photovoltaic conversion efficiency.

提出了一种结合晶体学群-子群理论和高通量从头算计算的稳健策略来发现和探索未知晶体，正如用于光电应用的三元晶体硫族化物半导体的设计所证明的那样。预计 22 种新化合物表现出优异的稳定性和高光伏转换效率。

An orthogonal XNA circuit was achieved. Right-handed L-aTNA and left-handed D-aTNA orthogonally facilitated the hybridization chain reaction, generating long duplex products from hairpin monomers. There was no interaction between L-aTNA and D-aTNA even though they had the same sequence. Detection of the RNA sequence by D-aTNA HCR via SNA interface was also demonstrated.

实现了正交 XNA 电路。右手 L-aTNA 和左手 D-aTNA 正交促进了杂交链反应，从发夹单体生成长双工产物。 L-aTNA 和 D-aTNA 之间没有相互作用，即使它们具有相同的序列。还展示了通过 SNA 接口通过 D-aTNA HCR 检测 RNA 序列。

A novel self-assembly method called crystallization-driven in situ nanoparticlization of conjugated polymers (CD-INCP), which forms semiconducting 1D nanoparticles synchronously during polymerization, has been developed. Powerful SCTP enables successful polymerization of an unprecedented highly solubilizing conjugated shell as well as a slow polymerization of the core, leading to growth of micelles via a seeded-growth mechanism.

开发了一种称为共轭聚合物结晶驱动原位纳米颗粒化 (CD-INCP) 的新型自组装方法，该方法在聚合过程中同步形成半导体一维纳米颗粒。强大的 SCTP 能够成功聚合前所未有的高度增溶共轭壳以及缓慢聚合核心，从而通过种子生长机制导致胶束生长。

Theoretical calculations for the zeolite model in the virtual world guide the rational synthesis of self-pillared pentasil zeolite nanosheets.

虚拟世界中沸石模型的理论计算指导自柱五元沸石纳米片的合理合成。

A peptidomimetic approach toward mimicking wet-adhesive mussel foot proteins in the platform of poly(ethylene glycol)-based peptides (PEGtides) is suggested, revealing the synergistic interplay among catechol and amine, and the diverse hydrogen bonding with polyether backbone resulting in their highly adhesive properties.

提出了一种在基于聚乙二醇的肽 (PEGtides) 平台中模拟湿粘性贻贝足蛋白的拟肽方法，揭示了儿茶酚和胺之间的协同相互作用，以及与聚醚主链的多种氢键结合导致它们高度粘合性能。

Organic molecular microcrystals based on a naphthalene framework are exposed to light, progressing a [2 + 2] photodimerization and exhibiting dramatic photoinduced elongation behavior. When crystals crack as the photochemistry proceeds, aqueous dye solutions can be released from the unique sealed hollow cavities.

基于萘骨架的有机分子微晶暴露在光下，进行 [2 + 2] 光二聚化并表现出显着的光诱导伸长行为。当晶体随着光化学的进行而破裂时，染料水溶液可以从独特的密封空腔中释放出来。

Phenol molecules at the air–water interface are seen on aerosols in the atmosphere and undergo photochemical reactions much faster than in the bulk water. This paper elucidated the reaction mechanism characteristic to the water surfaces.

空气-水界面上的苯酚分子在大气中的气溶胶上可见，并且比在大量水中更快地进行光化学反应。本文阐明了水表面的反应机理特征。

Hydrogen intercalation transforms tungsten oxide into tungsten oxide hydrogen bronze, whose catalytic activity toward protons and electrons is fundamentally different from the starting oxide. Miu and co-workers used theory and experiments to show that electrochemical hydrogen evolution only proceeds at measurable rates after formation of the intercalated bronze.

氢嵌入将氧化钨转化为氧化钨氢青铜，其对质子和电子的催化活性与起始氧化物根本不同。 Miu 及其同事使用理论和实验表明，电化学析氢仅在夹层青铜形成后才以可测量的速率进行。

We report the synthesis of hyper-cross-linked polymer gels to yield a hierarchically porous network. The gels can be used as a platform to achieve molecular-level hybridization with a two-dimensional polymer during the gel formation, which provides functional gels with the enhancement of porosities and mechanical stiffness for molecular separation.

我们报告了超交联聚合物凝胶的合成，以产生分层多孔网络。该凝胶可用作在凝胶形成过程中与二维聚合物实现分子水平杂交的平台，从而为功能性凝胶提供具有增强的孔隙率和分子分离机械刚度的功能凝胶。

Going hybrid! The chemistry of ring-contracted porphyrinoids is fascinating but still remains underdeveloped. In this work, a new class of hybridized and core-contracted porphyrinoids, B(III)-submonoazaporphyrins, was reported. A new versatile strategy based on a boron-templated intramolecular SNAr reaction has been developed and permits imaginative design and construction of novel ring-contracted porphyrinoids.

混合动力！环缩型卟啉的化学性质令人着迷，但仍未得到充分开发。在这项工作中，报道了一类新的杂交和核心收缩的卟啉类化合物 B(III)-submonoazaporphyrins。已经开发出一种基于硼模板化分子内 SNAr 反应的新型多功能策略，并允许富有想象力的设计和构建新型环收缩类卟啉。

A thermally stable periodic monolayer array of discrete C60 was generated on an atomically flat Au(111) surface with the aid of a template adlayer. The template was a two-dimensional (2D) array of molecular pits prepared on a Au(111) surface through 2D crystallization of shape-persistent macrocycles composed of four carbazole and four salphens/Ni-salphens with a 1 nm hollow.

借助模板吸附层，在原子平坦的 Au(111) 表面上生成了离散 C60 的热稳定周期性单层阵列。该模板是在 Au(111) 表面上制备的分子凹坑的二维 (2D) 阵列，通过由四个咔唑和四个 salphens/Ni-salphens 组成的具有 1 nm 空心的形状持久大环的 2D 结晶。

This report presents the synthesis of core–shell nanoparticles composed of a liquid gallium core and a densely packed reduced graphene oxide (RGO) shell (Ga@RGO) via a one-pot nanoprobe sonication method. With enhanced near-infrared absorption and efficient photothermal conversion, these core–shell Ga@RGO nanoparticles can serve as superior photoacoustic imaging contrast agents.

本报告介绍了通过一锅纳米探针超声法合成由液态镓核和致密堆积的还原氧化石墨烯 (RGO) 壳 (Ga@RGO) 组成的核壳纳米粒子。凭借增强的近红外吸收和高效的光热转换，这些核壳结构的 Ga@RGO 纳米粒子可以作为优异的光声成像造影剂。

The combination of a flexible chain-driven molecular motion and resonance-engineered spin-flipping process enables the construction of photoactivated organic ultralong room temperature phosphorescence materials, which demonstrate a controllably regulated photoactivated rate, providing a useful platform to design stimuli-responsive optoelectronic materials for advanced encryption applications.

灵活的链驱动分子运动和共振工程自旋翻转过程的结合使得能够构建光活化有机超长室温磷光材料，其表现出可控调节的光活化速率，为设计刺激响应光电材料提供了一个有用的平台高级加密应用程序。

Visible light excitation of a perylenediimide radical anion results in electron injection into a ZrO2 insulator, yielding a potent reducing agent with a remarkable ~microsecond lifetime. The long-lived potent reducing agent provides new opportunities to reduce important reagents and catalysts present in low concentrations.

苝二酰亚胺自由基阴离子的可见光激发导致电子注入 ZrO2 绝缘体，产生具有显着~微秒寿命的强效还原剂。长寿命的强效还原剂为还原低浓度的重要试剂和催化剂提供了新的机会。

The cover art demonstrates the importance of proper computational methodology for predicting the structure of multicomponent solids that may exist as salts or cocrystals. An approach based on classical mechanics (represented by Newton's laws) favors salts, and an approach that includes quantum effects (hydrogen atom delocalization) predicts cocrystals.

封面艺术展示了正确的计算方法对于预测可能以盐或共晶形式存在的多组分固体结构的重要性。基于经典力学（以牛顿定律为代表）的方法支持盐，而包括量子效应（氢原子离域）的方法预测共晶。

Ultrathin chiral covalent organic framework (chirCOF) nanosheets with strong chirality and luminescence have been developed using a facile and scalable chiral-induced strategy. The resulting chirCOF nanosheets exhibit excellent circularly polarized luminescence (CPL) performance, and the CPL can be tuned by modifying carboxyl-containing fluorescent dye molecules.

使用简便且可扩展的手性诱导策略开发了具有强手性和发光的超薄手性共价有机框架（chirCOF）纳米片。所得的 chirCOF 纳米片表现出优异的圆偏振发光 (CPL) 性能，并且可以通过修饰含羧基的荧光染料分子来调节 CPL。

Core–shell porous nanophotoreactors are designed for highly stable and recyclable photobiocatalysis in combination with native enzymes under aerobic conditions, while conducting efficient cofactor regeneration and protecting enzymatic materials from photogenerated active oxygen species.

核壳多孔纳米光反应器设计用于在有氧条件下与天然酶结合进行高度稳定和可回收的光生物催化，同时进行有效的辅因子再生并保护酶材料免受光生活性氧的影响。

A new method for the treatment of drug-resistant cancer using biomolecules to activate certain apoptosis pathways has been proposed, which is achieved through intracellular tyrosinase-catalyzed oxidation of a tripeptide and subsequent in situ self-assembly into nanoparticles that are capable of interfering with tubulin polymerization and ultimately reversing the drug resistance of melanoma.

已经提出了一种使用生物分子激活某些细胞凋亡途径来治疗耐药性癌症的新方法，该方法是通过细胞内酪氨酸酶催化三肽氧化并随后原位自组装成能够干扰微管蛋白的纳米粒子来实现的聚合并最终逆转黑色素瘤的耐药性。

1.The Atypical Cobalamin-Dependent S-Adenosyl-l-Methionine Nonradical Methylase TsrM and Its Radical Counterparts.

非典型钴胺素依赖性 S-腺苷-l-甲硫氨酸非自由基甲基化酶 TsrM 及其自由基对应物。

2.Bioinspired Ice-Binding Materials for Tissue and Organ Cryopreservation.

用于组织和器官低温保存的仿生冰结合材料。

3.Covalently Engineered Protein Minibinders with Enhanced Neutralization Efficacy against Escaping SARS-CoV-2 Variants.

共价工程化的蛋白质微型结合剂，具有增强的中和效果，可抵抗逃逸的 SARS-CoV-2 变体。

4.Dissecting Electronic-Structural Transitions in the Nitrogenase MoFe Protein P-Cluster during Reduction.

在还原过程中剖析固氮酶 MoFe 蛋白 P 簇中的电子结构转变。

5.Protein-Interaction Affinity Gradient Drives [4Fe–4S] Cluster Insertion in Human Lipoyl Synthase.

蛋白质相互作用亲和梯度驱动 [4Fe–4S] 簇插入人硫辛酰合酶。

6.Fluorescence Enhancement by Supramolecular Sequestration of a C54-Nanographene Trisimide by Hexabenzocoronene.

六苯并苯并萘对 C54-纳米石墨烯三酰亚胺的超分子螯合增强荧光。

7.PhOxi-Seq: Single-Nucleotide Resolution Sequencing of N2-Methylation at Guanosine in RNA by Photoredox Catalysis.

PhOxi-Seq：通过光氧化还原催化对 RNA 中鸟苷的 N2-甲基化进行单核苷酸分辨率测序。

8.3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes.

具有基于 8 连接立方节点的互穿 pcb 拓扑结构的 3D 共价有机框架。

9.“Self-Adaptive” Coassembly of Colloidal “Saturn-like” Host–Guest Complexes Enabled by Toroidal Micellar Rubber Bands.

由环形胶束橡皮筋实现的胶体“类土星”主客体复合物的“自适应”组装。

10.Catalytic Performance and Near-Surface X-ray Characterization of Titanium Hydride Electrodes for the Electrochemical Nitrate Reduction Reaction.

电化学硝酸盐还原反应中氢化钛电极的催化性能和近表面 X 射线表征。

11.Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation.

通过催化剂控制的光氧化对商业聚苯乙烯进行化学升级。

12.Concise Enantioselective Total Synthesis of Daphenylline Enabled by an Intramolecular Oxidative Dearomatization.

通过分子内氧化脱芳构化实现 Daphenylline 的简明对映选择性全合成。

13.Hypoiodite-Catalyzed Oxidative Umpolung of Indoles for Enantioselective Dearomatization.

用于对映选择性脱芳构化的次碘酸盐催化的吲哚氧化反作用。

14.Chemoselective (Hetero)Arene Electroreduction Enabled by Rapid Alternating Polarity.

快速交替极性实现的化学选择性（杂）芳烃电还原。

15.Manipulating Nanoparticle Aggregates Regulates Receptor–Ligand Binding in Macrophages.

操纵纳米粒子聚集体调节巨噬细胞中的受体-配体结合。

16.Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals.

可溶液加工的导电 MOF 纳米晶体的尺寸依赖特性。

17.Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor.

堆垛层错有助于锂离子在卤化物基超离子导体中的传导。

18.Noninvasive and Spatiotemporal Control of DNAzyme-Based Imaging of Metal Ions In Vivo Using High-Intensity Focused Ultrasound.

使用高强度聚焦超声对体内金属离子基于 DNAzyme 的成像进行无创和时空控制。

19.Programmable Cell-Free Transcriptional Switches for Antibody Detection.

用于抗体检测的可编程无细胞转录开关。

20.A Low-Volatile and Durable Deep Eutectic Electrolyte for High-Performance Lithium–Oxygen Battery.

用于高性能锂氧电池的低挥发性和耐用的低共熔电解质。

21.Noncovalent Liquid Phase Functionalization of 2H-WS2 with PDI: An Energy Conversion Platform with Long-Lived Charge Separation.

2H-WS2 与 PDI 的非共价液相功能化：具有长寿命电荷分离的能量转换平台。

22.Metal–Metal Bonding as an Electrode Design Principle in the Low-Strain Cluster Compound LiScMo3O8.

金属-金属键合作为低应变簇化合物 LiScMo3O8 中的电极设计原则。

23.Diverse Catalytic Reactions for the Stereoselective Synthesis of Cyclic Dinucleotide MK-1454.

环状二核苷酸 MK-1454 立体选择性合成的多种催化反应。

24.Stabilization of Lead-Reduced Metal Halide Perovskite Nanocrystals by High-Entropy Alloying.

通过高熵合金稳定铅还原金属卤化物钙钛矿纳米晶体。

25.In Situ Control of Crystallinity of 3D Colloidal Crystals by Tuning the Growth Kinetics of Nanoparticle Building Blocks.

通过调整纳米颗粒构建块的生长动力学原位控制 3D 胶体晶体的结晶度。

26.Robust Design of High-Performance Optoelectronic Chalcogenide Crystals from High-Throughput Computation.

基于高吞吐量计算的高性能光电硫族化物晶体的稳健设计。

27.Orthogonal Amplification Circuits Composed of Acyclic Nucleic Acids Enable RNA Detection.

由无环核酸组成的正交放大电路可实现 RNA 检测。

28.Probing the Mechanism of Isonitrile Formation by a Non-Heme Iron(II)-Dependent Oxidase/Decarboxylase.

探索非血红素铁 (II) 依赖性氧化酶/脱羧酶形成异腈的机制。

29.Photoinduced Arylation of Acridinium Salts: Tunable Photoredox Catalysts for C–O Bond Cleavage.

吖啶盐的光诱导芳基化：用于 C-O 键裂解的可调光氧化还原催化剂。

30.Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal–Organic Framework.

金属有机骨架中阳离子耦合电子跳跃传输的微观观察。

31.Synchronous Preparation of Length-Controllable 1D Nanoparticles via Crystallization-Driven In Situ Nanoparticlization of Conjugated Polymers.

通过共轭聚合物的结晶驱动原位纳米粒子同步制备长度可控的一维纳米粒子。

32.Engineering O–O Species in Boron Nitrous Nanotubes Increases Olefins for Propane Oxidative Dehydrogenation.

在硼亚硝基纳米管中设计 O-O 物种可增加用于丙烷氧化脱氢的烯烃。

33.2H-Imidazol-2-one O-Oxide: A Criegee Intermediate from a σ0π2 Singlet Ground-State Carbene.

2H-Imidazol-2-one O-Oxide：来自 σ0π2 单线态基态卡宾的 Criegee 中间体。

34.Rapid Allylic 1,6 H-Atom Transfer in an Unsaturated Criegee Intermediate.

不饱和 Criegee 中间体中的快速烯丙基 1,6 H 原子转移。

35.Ruthenium Polypyridyl Complex Bound to a Unimolecular Chair-Form G-Quadruplex.

与单分子椅形 G-四链体结合的钌多吡啶复合物。

36.Benzylic Dehydroxylation of Echinocandin Antifungal Drugs Restores Efficacy against Resistance Conferred by Mutated Glucan Synthase.

棘白菌素类抗真菌药物的苄基脱羟基作用可恢复抗突变葡聚糖合酶产生的耐药性的功效。

37.Methane Monooxygenase Mimic Asymmetric Oxidation: Self-Assembling μ-Hydroxo, Carboxylate-Bridged Diiron(III)-Catalyzed Enantioselective Dehydrogenation.

甲烷单加氧酶模拟不对称氧化：自组装 μ-羟基、羧酸盐桥联二铁 (III) 催化的对映选择性脱氢。

38.Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl–Cu Species.

使用乙烯基杂芳烃亲核试剂应对具有挑战性的不对称羰基 1,2-加成：通过脱芳构化的烯丙基-铜物质进行配体控制的区域发散过程。

39.Chemical Inductor.

化学电感。

40.Sequencing-free Analysis of Multiple Methylations on Gene-Specific mRNAs.

基因特异性 mRNA 多重甲基化的无测序分析。

41.Dynamic Control of a Multistate Chiral Supramolecular Polymer in Water.

水中多态手性超分子聚合物的动态控制。

42.Hydrogen Spillover-Bridged Volmer/Tafel Processes Enabling Ampere-Level Current Density Alkaline Hydrogen Evolution Reaction under Low Overpotential.

氢溢出桥接 Volmer/Tafel 过程在低过电势下实现安培级电流密度碱性析氢反应。

43.Catalytic Asymmetric Construction of Axially and Centrally Chiral Heterobiaryls by Minisci Reaction.

通过 Minisci 反应催化不对称构建轴向和中心手性杂二芳基。

44.Self-Immolative Hydroxybenzylamine Linkers for Traceless Protein Modification.

用于无痕蛋白质修饰的自焚羟基苄胺接头。

45.High-Spin (S = 1) Blatter-Based Diradical with Robust Stability and Electrical Conductivity.

具有稳健稳定性和导电性的高自旋 (S = 1) Blatter 基双自由基。

46.Toward Totally Defined Nanocatalysis: Deep Learning Reveals the Extraordinary Activity of Single Pd/C Particles.

走向完全定义的纳米催化：深度学习揭示了单个 Pd/C 粒子的非凡活性。

47.Stability Enhancement of a π-Stacked Helical Structure Using Substituents of an Amino Acid Side Chain: Helix Formation via a Nucleation–Elongation Mechanism.

使用氨基酸侧链取代基增强 π 堆积螺旋结构的稳定性：通过成核-延伸机制形成螺旋。

48.Gradient Hierarchically Porous Structure for Rapid Capillary-Assisted Catalysis.

用于快速毛细管辅助催化的梯度分级多孔结构。

49.Access to Cyclic N-Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides.

通过氨基甲酰叠氮化物的光催化活化获得环状 N-三氟甲基脲。

50.Cross-Linked Polyphosphazene Nanospheres Boosting Long-Lived Organic Room-Temperature Phosphorescence.

交联聚磷腈纳米球促进长寿命有机室温磷光。

51.Correction to “C(sp3)–H Fluorination with a Copper(II)/(III) Redox Couple”.

更正“C(sp3)–H 用铜 (II)/(III) 氧化还原对进行氟化”。

52.Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology.

小分子和共轭聚合物合成方法中的循环发现。

53.Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages.

溶剂驱动 M8L6 立方笼的 Λ 和 Δ 金属中心立体化学之间的切换。

54.Synthesis and Characterization of Binary, Highly Endothermic, and Extremely Sensitive 2,2′-Azobis(5-azidotetrazole).

二元、高度吸热且极其敏感的 2,2'-偶氮双（5-叠氮四唑）的合成与表征。

55.Strong Circularly Polarized Luminescence at 1550 nm from Enantiopure Molecular Erbium Complexes.

对映体纯分子铒配合物在 1550 nm 处的强圆偏振发光。

56.μMap-Red: Proximity Labeling by Red Light Photocatalysis.

μ Map-Red：通过红光光催化进行邻近标记。

57.Decarboxylative Borylation and Cross-Coupling of (Hetero)aryl Acids Enabled by Copper Charge Transfer Catalysis.

铜电荷转移催化使（杂）芳基酸脱羧硼化和交叉偶联。

58.Enantioselective Organocopper-Catalyzed Hetero Diels–Alder Reaction through in Situ Oxidation of Ethers into Enol Ethers.

通过将醚原位氧化成烯醇醚的对映选择性有机铜催化的杂 Diels-Alder 反应。

59.Chirality Gearing in an Achiral Cage through Adaptive Binding.

通过自适应结合在非手性笼中进行手性传动。

60.Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)–C(sp3) Cross-Coupling via Radical Sorting.

醇和羧酸的非传统片段偶联：通过自由基排序的 C(sp3)–C(sp3) 交叉偶联。

61.Programmed Polyene Cyclization Enabled by Chromophore Disruption.

由发色团破坏启用的程序化多烯环化。

62.Asymmetric Azide–Alkyne Cycloaddition with Ir(I)/Squaramide Cooperative Catalysis: Atroposelective Synthesis of Axially Chiral Aryltriazoles.

Ir(I)/Squaramide 协同催化的不对称叠氮化物-炔烃环加成：轴向手性芳基三唑的阻转选择性合成。

63.Caging-Pnictogen-Induced Superconductivity in Skutterudites IrX3 (X = As, P).

方钴矿 IrX3 (X = As, P) 中的笼养-Pnictogen 诱导的超导性。

64.Mechanism of Tripeptide Trimming of Amyloid β-Peptide 49 by γ-Secretase.

γ-分泌酶对淀粉样蛋白 β-肽 49 的三肽修饰机制。

65.Donor–Acceptor Pyridinium Salts for Photo-Induced Electron-Transfer-Driven Modification of Tryptophan in Peptides, Proteins, and Proteomes Using Visible Light.

使用可见光对肽、蛋白质和蛋白质组中的色氨酸进行光诱导电子转移驱动修饰的供体-受体吡啶盐。

66.Small-Molecule Inhibitors Targeting Lipolysis in Human Adipocytes.

针对人体脂肪细胞脂解作用的小分子抑制剂。

67.Synthetic Mechanisms in the Formation of SnTe Nanocrystals.

SnTe 纳米晶体形成的合成机制。

68.Peptidomimetic Wet-Adhesive PEGtides with Synergistic and Multimodal Hydrogen Bonding.

具有协同和多模式氢键的拟肽湿粘合剂 PEGtides。

69.Design of a Small Organic Template for the Synthesis of Self-Pillared Pentasil Zeolite Nanosheets.

用于合成自柱 Pentasil 沸石纳米片的小型有机模板的设计。

70.Engineering Photomechanical Molecular Crystals to Achieve Extraordinary Expansion Based on Solid-State [2 + 2] Photocycloaddition.

工程光机械分子晶体以实现基于固态 [2 + 2] 光环加成的非凡膨胀。

71.Stochastic Emergence of Two Distinct Self-Replicators from a Dynamic Combinatorial Library.

动态组合库中两个不同的自我复制器的随机出现。

72.Synthetic Control of Exciton Dynamics in Bioinspired Cofacial Porphyrin Dimers.

Bioinspired Cofacial 卟啉二聚体中激子动力学的综合控制。

73.Single-Stranded DNA-Encoded Gold Nanoparticle Clusters as Programmable Enzyme Equivalents.

单链 DNA 编码的金纳米粒子簇作为可编程酶等价物。

74.Why the Photochemical Reaction of Phenol Becomes Ultrafast at the Air–Water Interface: The Effect of Surface Hydration.

为什么苯酚的光化学反应在空气-水界面变得超快：表面水化的影响。

75.Covalent Proximity Scanning of a Distal Cysteine to Target PI3Kα.

远端半胱氨酸的共价接近扫描以靶向 PI3Kα。

76.Orange-Light-Induced Photochemistry Gated by pH and Confined Environments.

由 pH 值和密闭环境门控的橙光诱导光化学。

77.Alkyne Metathesis with d2 Re(V) Alkylidyne Complexes Supported by Phosphino-Phenolates: Ligand Effect on Catalytic Activity and Applications in Ring-Closing Alkyne Metathesis.

膦基酚盐支持的 d2 Re(V) 炔烃配合物的炔复分解：配体对催化活性的影响及其在闭环炔烃复分解中的应用。

78.Oxidative Damage Induces a Vacancy G-Quadruplex That Binds Guanine Metabolites: Solution Structure of a cGMP Fill-in Vacancy G-Quadruplex in the Oxidized BLM Gene Promoter.

氧化损伤诱导结合鸟嘌呤代谢物的空位 G-四链体：氧化 BLM 基因启动子中 cGMP 填充空位 G-四链体的溶液结构。