【标题速读】【Angew】【2022年】【7月】

2023-08-17 21:56 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Advancing the construction of circularly polarized luminescence (CPL) materials by molecular design has become an important target in this research area. In their Research Article (e202204358), Yoshio Hisaeda, Toshikazu Ono, and co-workers demonstrate a new bipyrrole-based boron difluoride family exhibiting intense multicolor luminescence with easy synthetic access. Tuning the rotational barrier around the 2,2′-bipyrrole affords CPL, and multicolor CPL can be achieved by controlling the aggregation state.

通过分子设计推进圆偏振发光（CPL）材料的构建已成为该研究领域的重要目标。在他们的研究文章 (e202204358) 中，Yoshio Hisaeda、Toshikazu Ono 及其同事展示了一种新的基于联吡咯的二氟化硼家族，该家族表现出强烈的多色发光且易于合成。调节 2,2'-联吡咯周围的旋转势垒可提供 CPL，并且可以通过控制聚集状态来实现多色 CPL。

2.Photoacids have been understood, since the pioneering work of Theodor Förster more than seven decades ago, to show a pronounced increase in acidity when electronically excited, but the underlying microscopic mechanisms have remained elusive. Sebastian Eckert et al. show in their Research Article (e202200709) how time-resolved nitrogen K-edge spectroscopy along the Förster cycle of a photoacid provides key insight into the electronic structural factors responsible for the photoacidity phenomenon.

自七十多年前 Theodor Förster 的开创性工作以来，光酸已被人们理解为在电子激发时显示出酸度的显着增加，但其潜在的微观机制仍然难以捉摸。塞巴斯蒂安·埃克特等人。在他们的研究文章 (e202200709) 中展示了光酸福斯特循环的时间分辨氮 K 边光谱如何提供对导致光酸现象的电子结构因素的关键见解。

3.The morphinan alkaloids , especially codeine and morphine, are derived from the opium poppy and have been used for millennia for pain management. They remain vital medicines today, but climate change and geopolitical uncertainties threaten existing supply chains. In their Communication (e202203186), Martin G. Banwell, Ping Lan, and co-workers detail by far the shortest synthesis of (−)-codeine reported to date, which involves a total “in-flask” time of less than 24 hours.

吗啡喃生物碱，尤其是可待因和吗啡，源自罂粟，数千年来一直用于治疗疼痛。如今，它们仍然是重要的药物，但气候变化和地缘政治的不确定性威胁着现有的供应链。在他们的通讯 (e202203186) 中，Martin G. Banwell、Ping Lan 和同事详细介绍了迄今为止报告的 (−)-可待因的最短合成，其总“烧瓶内”时间不到 24 小时。

4.A chiral Lewis acid accelerated asymmetric Pudovik addition/[1,2]-phospha-Brook rearrangement is described by Shunxi Dong, Qian Peng, Xiaoming Feng, and co-workers in their Research Article (e202203650). Control experiments and theoretical calculations revealed that a synergistic effect of the counterion and water was critical for the regio- and enantioselective protonation after the [1,2]-phospha-Brook rearrangement.

Shunxi Dong、Qian Peng、Xiaoming Feng 及其同事在他们的研究文章 (e202203650) 中描述了手性 Lewis 酸加速不对称 Pudovik 加成/[1,2]-phospha-Brook 重排。对照实验和理论计算表明，抗衡离子和水的协同效应对于[1,2]-磷酸-布鲁克重排后的区域和对映选择性质子化至关重要。

5.Supramolecular Catalysis In their Communication (e202203671), Yao Wang and Xinglong Yuan report the synthesis and characterization of a selenide catalyst for the activation of alkenes through Se–π bonding.

超分子催化。在他们的通讯 (e202203671) 中，Yao Wang 和 Xinglong Yuan 报告了通过 Se-π 键活化烯烃的硒化物催化剂的合成和表征。

6.Immunotherapeutics The development of tumor-resident living immunotherapeutics is reported by Jinyao Liu et al. in their Research Article (e202202409). The strategy is based on decorating bacteria with triple immune nanoactivators via in situ dopamine polymerization.

免疫治疗 Jinyao Liu 等人在他们的研究文章（e202202409）中报道了肿瘤驻留活体免疫治疗的发展。该策略基于通过原位多巴胺聚合用三重免疫纳米激活剂装饰细菌。

7.Electrochemistry in Magnetic Fields.

磁场中的电化学。

8.Decorating Bacteria with Triple Immune Nanoactivators Generates Tumor-Resident Living Immunotherapeutics.

用三重免疫纳米激活剂修饰细菌可产生肿瘤驻留活体免疫疗法。

9.Strain of Supramolecular Interactions in Single-Stacking Junctions.

单堆叠连接中的超分子相互作用应变。

10.Nickel-Based High-Entropy Intermetallic as a Highly Active and Selective Catalyst for Acetylene Semihydrogenation.

镍基高熵金属间化合物作为乙炔半加氢的高活性和选择性催化剂。

11.Theory-Guided Regulation of FeN4 Spin State by Neighboring Cu Atoms for Enhanced Oxygen Reduction Electrocatalysis in Flexible Metal–Air Batteries.

邻近 Cu 原子对 FeN4 自旋态的理论引导调节，增强柔性金属空气电池中的氧还原电催化作用。

12.A Valence-Engineered Self-Cascading Antioxidant Nanozyme for the Therapy of Inflammatory Bowel Disease.

用于治疗炎症性肠病的价态工程自级联抗氧化剂纳米酶。

13.Computational Design, Synthesis, and Photochemistry of Cy7-PPG, an Efficient NIR-Activated Photolabile Protecting Group for Therapeutic Applications.

Cy7-PPG 的计算设计、合成和光化学，一种用于治疗应用的高效近红外激活的光不稳定保护基团。

14.Enhanced Blue Afterglow through Molecular Fusion for Bio-applications.

通过分子融合增强蓝色余辉的生物应用。

15.Electronically Engineering Water Resistance in Methane Combustion with an Atomically Dispersed Tungsten on PdO Catalyst.

使用 PdO 催化剂上原子分散的钨对甲烷燃烧中的电子工程耐水性进行研究。

16.Programmed Supramolecular Assemblies Using Orthogonal Pairs of Heterodimeric Coiled Coil Peptides.

使用异二聚体卷曲螺旋肽正交对的编程超分子组装体。

17.Introducing 4s–2p Orbital Hybridization to Stabilize Spinel Oxide Cathodes for Lithium-Ion Batteries.

引入 4s–2p 轨道杂交来稳定锂离子电池的尖晶石氧化物阴极。

18.Photocatalytic Chemical Crosslinking for Profiling RNA–Protein Interactions in Living Cells.

用于分析活细胞中 RNA-蛋白质相互作用的光催化化学交联。

19.Reticular Synthesis of Hydrogen-Bonded Organic Frameworks and Their Derivatives via Mechanochemistry.

通过机械化学来网状合成氢键有机框架及其衍生物。

20.Modular Nitrogen-Doped Concave Polycyclic Aromatic Hydrocarbons for High-Performance Organic Light-Emitting Diodes with Tunable Emission Mechanisms.

用于具有可调发射机制的高性能有机发光二极管的模块化氮掺杂凹面多环芳烃。

21.Efficient Triplet-Triplet Annihilation Upconversion Sensitized by a Chromium(III) Complex via an Underexplored Energy Transfer Mechanism.

通过未充分探索的能量转移机制，由铬 (III) 络合物敏化的高效三重态-三重态湮灭上转换。

22.Minimizing the Reorganization Energy of Cobalt Redox Mediators Maximizes Charge Transfer Rates from Quantum Dots.

最小化钴氧化还原介体的重组能可最大化量子点的电荷转移率。

23.Manganese-Catalysed Deuterium Labelling of Anilines and Electron-Rich (Hetero)Arenes.

锰催化氘标记苯胺和富电子（杂）芳烃。

24.Poly(ionic liquid)-Armored MXene Membrane: Interlayer Engineering for Facilitated Water Transport.

聚（离子液体）铠装 MXene 膜：促进水传输的层间工程。

25.Multimodal Imaging-Guided Photothermal Immunotherapy Based on a Versatile NIR-II Aggregation-Induced Emission Luminogen.

基于多功能 NIR-II 聚集诱导发射发光原的多模态成像引导光热免疫治疗。

26.Multicolor Zinc(II)-Coordinated Hydrazone-Based Bistable Photoswitches for Rewritable Transparent Luminescent Labels.

用于可重写透明发光标签的多色锌 (II) 配位腙基双稳态光电开关。

27.Amine-Catalyzed Copper-Mediated C−H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group.

通过瞬态亚胺导向基团，胺催化铜介导苯甲醛的 C−H 磺酰化。

28.Lattice-Confined Single-Atom Fe1Sx on Mesoporous TiO2 for Boosting Ambient Electrocatalytic N2 Reduction Reaction.

介孔 TiO2 上的晶格限制单原子 Fe1Sx 用于促进环境电催化 N2 还原反应。

29.Highly Selective Photocatalytic CO2 Methanation with Water Vapor on Single-Atom Platinum-Decorated Defective Carbon Nitride.

水蒸气对单原子铂修饰的缺陷氮化碳进行高选择性光催化二氧化碳甲烷化。

30.Metallo-Supramolecular Octahedral Cages with Three Types of Chirality towards Spontaneous Resolution.

具有三种手性的金属超分子八面体笼可实现自发解析。

31.An Activatable Polymeric Nanoprobe for Fluorescence and Photoacoustic Imaging of Tumor-Associated Neutrophils in Cancer Immunotherapy.

一种可激活的聚合物纳米探针，用于癌症免疫治疗中肿瘤相关中性粒细胞的荧光和光声成像。

32.Pushing Lithium–Sulfur Batteries towards Practical Working Conditions through a Cathode–Electrolyte Synergy.

通过阴极-电解质协同作用将锂硫电池推向实际工作条件。

33.Iridium-Catalyzed Ligand-Controlled Remote para-Selective C−H Activation and Borylation of Twisted Aromatic Amides.

铱催化配体控制的远程对位选择性 C−H 激活和扭曲芳香酰胺的硼化。

34.Interfacial Polymetallic Oxides and Hierarchical Porous Core–Shell Fibres for High Energy-Density Electrochemical Supercapacitors.

用于高能量密度电化学超级电容器的界面多金属氧化物和分层多孔核壳纤维。

35.Catalytic Regio- and Enantioselective Protonation for the Synthesis of Chiral Allenes: Synergistic Effect of the Counterion and Water.

用于合成手性丙二烯的催化区域和对映选择性质子化：抗衡离子和水的协同效应。

36.A Hybrid Supramolecular Polymeric Nanomedicine for Cascade-Amplified Synergetic Cancer Therapy.

用于级联放大协同癌症治疗的混合超分子聚合物纳米药物。

37.Synergy in Au−CuO Janus Structure for Catalytic Isopropanol Oxidative Dehydrogenation to Acetone.

Au−CuO Janus 结构催化异丙醇氧化脱氢制丙酮的协同作用。

38.A New Strategy to Fight Metallodrug Resistance: Mitochondria-Relevant Treatment through Mitophagy to Inhibit Metabolic Adaptations of Cancer Cells.

对抗金属耐药性的新策略：通过线粒体自噬抑制癌细胞代谢适应的线粒体相关治疗。

39.MXene Analogue: A 2D Nitridene Solid Solution for High-Rate Hydrogen Production.

MXene 类似物：用于高速制氢的 2D 氮化物固溶体。

40.Hydrogen-Bonded Supramolecular Polymer Adhesives: Straightforward Synthesis and Strong Substrate Interaction.

氢键超分子聚合物粘合剂：直接合成和强基材相互作用。

41.Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis.

超配位硅阴离子的合成和表征：捕获路易斯碱催化中间体。

42.Triarylamine/Bithiophene Copolymer with Enhanced Quinoidal Character as Hole-Transporting Material for Perovskite Solar Cells.

具有增强醌型特性的三芳胺/联噻吩共聚物作为钙钛矿太阳能电池的空穴传输材料。

43.Liquid Na/K Alloy Interfacial Synthesis of Functional Porous Carbon at Ambient Temperature.

室温下功能性多孔碳的液态Na/K合金界面合成。

44.Avoiding Structural Collapse to Reduce Lead Leakage in Perovskite Photovoltaics.

避免结构倒塌以减少钙钛矿光伏中的铅泄漏。

45.Highly Fluorescent Bipyrrole-Based Tetra-BF2 Flag-Hinge Chromophores: Achieving Multicolor and Circularly Polarized Luminescence.

基于双吡咯的高荧光 Tetra-BF2 旗铰链发色团：实现多色和圆偏振发光。

46.Fibrous Nanoreactors from Microfluidic Blow Spinning for Mass Production of Highly Stable Ligand-Free Perovskite Quantum Dots.

来自微流控吹纺的纤维纳米反应器用于大规模生产高度稳定的无配体钙钛矿量子点。

47.Thermal Alteration in Adsorption Sites over SAPO-34 Zeolite.

SAPO-34 沸石吸附位点的热变化。

48.Metal-Free SF6 Activation: A New SF5-Based Reagent Enables Deoxyfluorination and Pentafluorosulfanylation Reactions.

无金属 SF6 活化：一种新型 SF5 基试剂可实现脱氧氟化和五氟磺酰化反应。

49.Evolution of the Dearomative Functionalization of Activated Quinolines and Isoquinolines: Expansion of the Electrophile Scope.

活化喹啉和异喹啉的脱芳香功能化的演变：亲电子范围的扩展。

50.Beyond Bioisosteres: Divergent Synthesis of Azabicyclohexanes and Cyclobutenyl Amines from Bicyclobutanes.

超越生物电子等排体：从双环丁烷出发合成氮杂双环己烷和环丁烯基胺。

51.Electronic Structure Changes of an Aromatic Amine Photoacid along the Förster Cycle.

芳香胺光酸沿福斯特循环的电子结构变化。

52.A Selenide Catalyst for the Activation of Alkenes through Se⋅⋅⋅π Bonding.

通过 Se⋅⋅⋅π 键激活烯烃的硒化物催化剂。

53.A New Cation-Ordered Structure Type with Multiple Thermal Redistributions in Co2InSbO6.

Co2InSbO6 中具有多重热再分布的新型阳离子有序结构类型。

54.Expeditious Access to Morphinans by Chemical Synthesis.

通过化学合成快速获得吗啡喃。

55.A Ruthenium(II) Polypyridyl Complex Disrupts Actin Cytoskeleton Assembly and Blocks Cytokinesis.

钌 (II) 聚吡啶复合物会破坏肌动蛋白细胞骨架组装并阻止细胞分裂。

56.Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO2 Reduction in Aqueous Media.

用于在水介质中高效光催化二氧化碳还原的两亲性聚碳酸酯胶束铼催化剂。

57.anti-Selective Borylstannylation of Alkynes with (o-Phenylenediaminato)borylstannanes by a Radical Mechanism.

通过自由基机制用（邻苯二胺）硼基锡烷对炔烃进行反选择性硼基锡烷基化。

58.Silver-Templated γ-Keggin Alkyltin-Oxo Cluster: Electronic Structure and Optical Limiting Effect.

银模板化的 γ-Keggin 烷基锡-氧代簇：电子结构和光学限制效应。

59.Dewar Metallabenzenes from Reactions of Metallacyclobutadienes with Alkynes.

金属环丁二烯与炔烃反应产生的杜瓦金属苯。

60.Saving the Energy Loss in Lithium-Mediated Nitrogen Fixation by Using a Highly Reactive Li3N Intermediate for C−N Coupling Reactions.

通过使用高反应活性的 Li3N 中间体进行 CN 偶联反应，节省锂介导的固氮过程中的能量损失。

61.Tetrahedral Liquid-Crystalline Networks: An A15-Like Frank–Kasper Phase Based on Rod-Packing.

四面体液晶网络：基于棒堆积的类 A15 Frank-Kasper 相。

62.Scalable Nitrate Treatment for Constructing Integrated Surface Structures to Mitigate Capacity Fading and Voltage Decay of Li-Rich Layered Oxides.

用于构建集成表面结构的可扩展硝酸盐处理，以减轻富锂层状氧化物的容量衰减和电压衰减。

63.Vacuum-Assisted Thermal Annealing of CsPbI3 for Highly Stable and Efficient Inorganic Perovskite Solar Cells.

用于高度稳定和高效无机钙钛矿太阳能电池的 CsPbI3 真空辅助热退火。

64.Hydrophilic Catalysts with High Activity and Stability in the Aqueous Polymerization of Ethylene to High-Molecular-Weight-Polyethylene.

在乙烯水聚合成高分子量聚乙烯过程中具有高活性和稳定性的亲水催化剂。

65.Chiral Covalent Organic Framework Packed Nanochannel Membrane for Enantioseparation.

用于对映分离的手性共价有机框架填充纳米通道膜。

66.Organic Ammonium Ion Battery: A New Strategy for a Nonmetallic Ion Energy Storage System.

有机铵离子电池：非金属离子储能系统的新策略。

67.Bonding in a Crystalline Tri-Thorium Cluster: Not σ-Aromatic But Still Unique.

晶体三钍簇中的键合：不是 σ-芳香族，但仍然是独特的。

68.Synthesis of Single-Layer Two-Dimensional Metal–Organic Frameworks M3(HAT)2 (M=Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction.

利用表面反应合成单层二维金属有机骨架 M3(HAT)2（M=Ni, Fe, Co, HAT=1,4,5,8,9,12-六氮杂苯并菲）。

69.Binaphthyl-Bridged Pyrenophanes: Intense Circularly Polarized Luminescence Based on a D2 Symmetry Strategy.

联萘桥芘芬：基于 D2 对称策略的强圆偏振发光。

70.Doubling the Length of the Longest Pyrene-Pyrazinoquinoxaline Molecular Nanoribbons.

将最长的芘-吡嗪并喹喔啉分子纳米带的长度加倍。

71.A Novel Catalytic Route to Polymerizable Bicyclic Cyclic Carbonate Monomers from Carbon Dioxide.

从二氧化碳聚合双环环状碳酸酯单体的新催化路线。

72.Promising Deep-Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π-Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species.

通过平面π-共轭[B(OH)3]和[B3O3(OH)3]功能物种的合理设计和组装，开发出有前途的深紫外双折射材料。

73.Additive-Assisted Hydrophobic Li+-Solvated Structure for Stabilizing Dual Electrode Electrolyte Interphases through Suppressing LiPF6 Hydrolysis.

添加剂辅助的疏水性 Li+ 溶剂化结构通过抑制 LiPF6 水解来稳定双电极电解质界面。

74.Scalable Synthesis of Photoluminescent Single-Chain Nanoparticles by Electrostatic-Mediated Intramolecular Crosslinking.

通过静电介导的分子内交联大规模合成光致发光单链纳米粒子。

75.Anomalous Redox Features Induced by Strong Covalency in Layered NaTi1−yVyS2 Cathodes for Na-Ion Batteries.

钠离子电池层状 NaTi1−yVyS2 阴极中强共价引起的异常氧化还原特征。

76.The photocatalyzed uphill isomerization of drugs using Ru(bpy3)2 is reported by Nicolas Winssinger et al. in their Research Article (e202203390). This chemistry was shown to locally convert inactive drugs into active ones that alter the tubulin dynamics in cells (green structures in the background of the picture).

Nicolas Winssinger 等人在他们的研究文章（e202203390）中报道了使用 Ru(bpy3)2 进行药物光催化上坡异构化。这种化学反应被证明可以将非活性药物局部转化为活性药物，从而改变细胞中的微管蛋白动力学（图片背景中的绿色结构）。

77.Self-assembled architectures for the encapsulation and transport of anions and ion pairs are still rare. In their Research Article (e202201831), Max von Delius and co-workers used the dynamic covalent chemistry of orthoesters in combination with urea-based diols and triethylene glycol not only for the formation of a chloride cryptate, but also for the simultaneous encapsulation of both ions present in cesium chloride.

用于封装和传输阴离子和离子对的自组装结构仍然很少见。在他们的研究文章 (e202201831) 中，Max von Delius 及其同事使用原酸酯的动态共价化学与脲基二醇和三甘醇结合，不仅可以形成氯化物穴状化合物，还可以同时封装两者氯化铯中存在的离子。

78.A multifunctional nanoplatform that allows for in situ tracking of the spatial and temporal dynamics of enzymes in response to mitochondria-targeted photodynamic therapy is presented by Lele Li and co-workers in their Communication (e202203238). Activatable translocation of the specific enzyme to mitochondria is monitored during the NIR-light-triggered, spatially selective generation of reactive oxygen species.

Lele Li 及其同事在他们的通讯 (e202203238) 中提出了一种多功能纳米平台，可以原位跟踪酶的空间和时间动态，以响应线粒体靶向光动力疗法。在近红外光触发、空间选择性产生活性氧的过程中，监测特定酶向线粒体的可激活易位。

79.A biomimetic catalyst for CO2 photoreduction was developed through self-assembling porphyrins into a hydrogen-bonded organic framework, as reported by Tian-Fu Liu, Rong Cao, and co-workers in their Research Article (e202203955). The combination of photosensitizers and redox centers in the structure not only allows for adequate photon input and efficient utilization of the photogenerated charge, but also changes the microenvironment surrounding the active sites.

正如 Tian-Fu Liu、Rong Cao 及其同事在他们的研究文章 (e202203955) 中报道的那样，通过将卟啉自组装成氢键有机框架，开发了一种用于 CO2 光还原的仿生催化剂。结构中光敏剂和氧化还原中心的结合不仅可以实现足够的光子输入和光生电荷的有效利用，而且还可以改变活性位点周围的微环境。

80.Nanomembranes. In their Communication (e202204953), Andrey Turchanin et al. present two concepts to introduce a photoactive Ru(II) polypyridine complex into carbon nanomembranes. The photoactive units are either directly incorporated into the scaffold or covalently grafted to its surface. Frontispiece art by Ilia Ghiasedin.

纳米膜。 Andrey Turchanin 等人在他们的通讯 (e202204953) 中。提出了将光活性 Ru(II) 聚吡啶络合物引入碳纳米膜的两个概念。光敏单元要么直接掺入支架中，要么共价接枝到其表面。卷首艺术由 Ilia Ghiasedin 绘制。

81.Carbenes. In their Research Article (e202202637), Tharangattu N. Narayanan, Carola Schulzke, Cem B. Yildiz, Anukul Jana et al. report the in situ generation of cyclic (alkyl)(amino)carbenes through the thermal 1,1-dehydration of secondary pyrrolidin-2-ol alcohols.

卡宾。 Tharangattu N. Narayanan、Carola Schulzke、Cem B. Yildiz、Anukul Jana 等人在他们的研究文章 (e202202637) 中。报道了通过仲吡咯烷-2-醇的热1,1-脱水原位生成环状(烷基)(氨基)卡宾。

82.The Influence of Nanoconfinement on Electrocatalysis.

纳米限制对电催化的影响。

83.Realizing 1,1-Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin-2-ols as a Source of Cyclic (Alkyl)(Amino)Carbenes.

实现仲醇 1,1-脱水生成卡宾：吡咯烷-2-醇作为环状（烷基）（氨基）卡宾的来源。

84.Intermolecular Energy Gap-Induced Formation of High-Valent Cobalt Species in CoOOH Surface Layer on Cobalt Sulfides for Efficient Water Oxidation.

分子间能隙诱导硫化钴 CoOOH 表面层高价钴物质的形成，用于高效水氧化。

85.Hybrid Pyridine–Pyridone Foldamer Channels as M2-Like Artificial Proton Channels.

混合吡啶-吡啶酮折叠体通道作为 M2 类人工质子通道。

86.Modulating the Electronic Metal-Support Interactions in Single-Atom Pt1−CuO Catalyst for Boosting Acetone Oxidation.

调节单原子 Pt1−CuO 催化剂中的电子金属-载体相互作用以促进丙酮氧化。

87.Protein Flexibility and Dissociation Pathway Differentiation Can Explain Onset of Resistance Mutations in Kinases.

蛋白质灵活性和解离途径分化可以解释激酶耐药突变的发生。

88.Metal-Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand.

通过二芳基碘盐与化学稳定的虚拟配体进行无金属 C−H 官能化。

89.Hydrogen-Bonded Organic Framework (HOF)-Based Single-Neural Stem Cell Encapsulation and Transplantation to Remodel Impaired Neural Networks.

基于氢键有机框架（HOF）的单神经干细胞封装和移植以重塑受损的神经网络。

90.Harnessing Natural Products by a Pharmacophore-Oriented Semisynthesis Approach for the Discovery of Potential Anti-SARS-CoV-2 Agents.

通过面向药效团的半合成方法利用天然产物来发现潜在的抗 SARS-CoV-2 药物。

91.Copper-Catalyzed Radical Enantioselective Carbo-Esterification of Styrenes Enabled by a Perfluoroalkylated-PyBox Ligand.

全氟烷基化 PyBox 配体实现铜催化苯乙烯自由基对映选择性碳酯化。

92.In Operando Identification of In Situ Formed Metalloid Zincδ+ Active Sites for Highly Efficient Electrocatalyzed Carbon Dioxide Reduction.

原位形成的准金属锌δ+活性位点的现场鉴定，用于高效电催化二氧化碳还原。

93.Adatom Bonding Sites in a Nickel-Fe3O4(001) Single-Atom Model Catalyst and O2 Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free-Electron Laser Light.

采用红外自由电子激光的表面作用光谱揭示了镍-Fe3O4(001) 单原子模型催化剂中的吸附原子键合位点和 O2 反应性。

94.Crystalline Porphyrazine-Linked Fused Aromatic Networks with High Proton Conductivity.

具有高质子传导率的结晶四氮杂卟啉连接的稠合芳香族网络。

95.Towards Control and Oversight of SARS-CoV-2 Diagnosis and Monitoring through Multiplexed Quantitative Electroanalytical Immune Response Biosensors.

通过多重定量电分析免疫反应生物传感器控制和监督 SARS-CoV-2 诊断和监测。