【标题速读】【JACS】【2022年】【5月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

Photoelectrocatalytic (PEC) glycerol oxidation offers a sustainable approach to produce dihydroxyacetone (DHA) as a valuable chemical. In this work, Duan and co-workers achieved the reaction by fabricating Bi2O3 nanoparticles on TiO2, in which Bi2O3 prefers to interact with the middle hydroxyl of glycerol that facilitates 75.4% selectivity of DHA.

光电催化 (PEC) 甘油氧化提供了一种可持续的方法来生产二羟基丙酮 (DHA) 作为一种有价值的化学品。 在这项工作中，Duan 和同事通过在 TiO2 上制造 Bi2O3 纳米粒子实现了反应，其中 Bi2O3 更喜欢与甘油的中间羟基相互作用，从而促进了 75.4% 的 DHA 选择性。

The bottom-up synthesis of reticular nanoparticles, such as covalent–organic and metal–organic frameworks, allows their creation molecule-by-molecule with atomic precision and potentially provides the key to the targeted bottom-up design of (nano)materials with new, fine-tuned properties and functions, opening up a new application horizon.

网状纳米粒子的自下而上合成，例如共价有机和金属有机框架，允许以原子精度逐个分子地创建它们，并可能为（纳米）材料的目标自下而上设计提供关键 ，微调的属性和功能，开辟了一个新的应用领域。

Carbo[6]helicenes decorated with peripheral N-(2-(4-ethynylbenzamido)ethyl)-3,4,5-tridodecyloxybenzamides efficiently undergo supramolecular assembly through a four-fold H-bonding array between amides. Depending on the helicene's substitution pattern, helical aggregates with inverted circularly polarized luminescence are obtained. Strong chirality-induced spin selectivity (CISS effect) is also observed by magnetic conducting atomic force microscopy (mc-AFM).

修饰有周边 N-(2-(4-乙基苯甲酰胺) 乙基)-3,4,5-三十二烷氧基苯甲酰胺 的 Carbo[6]helicenes 通过酰胺之间的四倍氢键阵列有效地进行超分子组装。 根据螺旋烯的取代模式，获得具有倒圆偏振发光的螺旋聚集体。 通过磁导原子力显微镜 (mc-AFM) 也观察到强手性诱导的自旋选择性（CISS 效应）。

This study expands the active role of water in supramolecular chemistry and morphological optimization of synthetic matter and shows that, as a readily available guiding field, water can achieve morphological control to an extent exceeding the capability of conventional techniques.

这项研究扩大了水在超分子化学和合成物质形态优化中的积极作用，并表明，作为一个现成的指导领域，水可以实现超过传统技术能力的形态控制。

A new assembly concept is proposed: that is, a soft patch, which enables directional fusion of liquid droplets for designing complex hollow self-assemblies. The versatility and curvature-selective growth are demonstrated. By patterning a Au core/Ag shell nanorod, the nanoarchitecture can be programmed in response to either H2O2 or near-infrared light, exhibiting dual-mode response behavior.

提出了一种新的组装概念：即软贴片，可以实现液滴的定向融合，用于设计复杂的中空自组装。 证明了多功能性和曲率选择性增长。 通过图案化 Au 核/Ag 壳纳米棒，可以对纳米结构进行编程以响应 H2O2 或近红外光，表现出双模式响应行为。

The growth of the 1D metal–organic hybrids (MOHs) is realized by peri-aryl–metal bonds on both Au and Ag surfaces, whereas the 1D to 2D extension of MOHs is only achieved on the Ag surface and totally inhibited on the Au surface.

一维金属有机杂化物 (MOHs) 的生长是通过 Au 和 Ag 表面上的环芳基金属键实现的，而 MOHs 的一维到二维延伸仅在银表面实现，在金表面完全受到抑制 .

In a tailor-made foldamer system, the central heterocycle plays a gating role in the exploration of a ternary “matrix” beyond “0”s and “1”s via the introduction of “2”s, like a steering compass to regulate the synergy between the through-bond and through-space pathways to achieve multiple-interfered states as three different outputs.

在定制的折叠体系统中，中心杂环通过引入“2”在探索“0”和“1”之外的三元“矩阵”中起着门控作用，就像一个转向罗盘来调节 通过键和通过空间路径之间的协同作用以实现多重干扰状态作为三种不同的输出。

The first comprehensive study on the evolution of cationic species produced from an intermolecular complex of space-abundant molecules was performed using a powerful combination of spectroscopic methods and high-level ab initio calculations. It demonstrates a new strategy for simulation of synthetic chemistry occurring in the cold areas of the Universe.

使用光谱方法和高级从头算计算的强大组合，对空间丰富分子的分子间复合物产生的阳离子物种的演化进行了首次综合研究。 它展示了一种模拟发生在宇宙寒冷区域的合成化学的新策略。

A thin and dense layer of designed peptoid molecules (spiky red coating) on a nanoparticle (yellow and green spheres) stabilizes them in various solution environments. The destabilizing factors, represented by sharks, include high salt environments and organic solvents, and they are shown as the corresponding molecules.

纳米颗粒（黄色和绿色球体）上一层薄而致密的设计拟肽分子（尖锐的红色涂层）可在各种溶液环境中稳定它们。 以鲨鱼为代表的不稳定因素包括高盐环境和有机溶剂，它们被显示为相应的分子。

Taking advantage of high lattice matching, an α-BaF2 nanoparticle substrate has been successfully developed for the solution-processed heteroepitaxial growth of a γ-CsPbI3 thin film with low defect density and high stability and realizing high-efficiency deep red perovskite light-emitting diodes.

利用高晶格匹配的优势，成功开发了α-BaF2纳米粒子衬底，用于溶液法异质外延生长低缺陷密度、高稳定性的γ-CsPbI3薄膜，实现高效深红色钙钛矿发光二极管 .

Direct cleavage of an aliphatic C–OH bond has been developed via activation of free alcohols with a neutral diphenyl boryl radical generated from tetraphenylborate reagents under mild visible light photoredox catalysis. Based on this strategy, cross-electrophile coupling of free benzylic alcohols and carbon dioxide has been achieved.

在温和的可见光光氧化还原催化下，通过四苯基硼酸盐试剂产生的中性二苯基硼自由基活化游离醇，开发了脂肪族 C-OH 键的直接裂解。 基于该策略，实现了游离苄醇和二氧化碳的交叉亲电偶联。

We report an isostere of cyclohexane with two adjacent BN pairs, 1,6;2,3-bis-BN cyclohexane. Its ring-flipping barrier is similar to that of cyclohexane. Protic hydrogens on N in 1,6;2,3-bis-BN cyclohexane show reactivity higher than that of its isomeric bis-BN cyclohexane. This compound exhibits an appealing hydrogen storage capability of >9.0 wt %.

我们报告了具有两个相邻 BN 对的环己烷等排体，1,6;2,3-双 BN 环己烷。 它的翻环势垒类似于环己烷。 1,6;2,3-双 BN 环己烷中 N 上的质子氢显示出比其异构双 BN 环己烷更高的反应性。 该化合物表现出 >9.0 wt% 的吸引人的储氢能力。

In this work, the reduced Ag grew in the junction site of the AgNWs following a twin-crystal growth mode, inducing an atomic-level contact between the AgNWs and the reduced Ag. This facilitates a robust physical/electrical contact throughout the AgNW networks.

在这项工作中，还原的 Ag 按照双晶生长模式在 AgNW 的结点处生长，从而在 AgNW 和还原的 Ag 之间引起原子级接触。 这有助于在整个 AgNW 网络中建立稳健的物理/电气接触。

Photoeliminated chlorine radicals can be tamed for enantioselective nickel-catalyzed C(sp3)–H cross-coupling, enabling general and modular access to chiral α-(hetero)aryl amines via direct coupling of simple latent amines with abundant aryl halides. The nickel catalyst uncommonly plays multiple roles to orchestrate chlorine elimination, radical capture, cross-coupling, and asymmetric induction.

光消除的氯自由基可以被驯服用于对映选择性镍催化的 C(sp3)–H 交叉偶联，从而通过简单的潜胺与丰富的芳基卤化物的直接偶联，实现对手性 α-（杂）芳基胺的通用和模块化访问。 镍催化剂在协调氯消除、自由基捕获、交叉偶联和不对称诱导方面发挥着不同寻常的多重作用。

Near-field nano-FTIR spectroscopy beats the Abbe?s diffraction limit and enables nanometer-scale vibrational spectroscopic analysis of sulfur poisoning on catalytic Pd nanoparticles (NPs) over an Al2O3 support. Rather than analyzing a convoluted vibrational spectrum due to >106 catalytic active nanoparticles as in the case of conventional vibrational spectroscopic techniques, nano-FTIR spectroscopy allows investigation of spectroscopic/structural/adsorbate variations on a single NP (e.g., metal/support/metal-support interfacial sites).

近场纳米 FTIR 光谱突破了阿贝的衍射极限，能够对 Al2O3 载体上的催化 Pd 纳米颗粒 (NP) 上的硫中毒进行纳米级振动光谱分析。 不像传统振动光谱技术那样分析由 >106 个催化活性纳米颗粒引起的复杂振动光谱，纳米 FTIR 光谱允许研究单个 NP（例如，金属/载体/金属- 支持界面站点）。

We report a general and unprecedented electrocleavage synthesis of imine-linked covalent organic framework (COF) films directly on electrodes at room temperature. This strategy enables the cathodic exfoliation of the COF powders to nanosheets, followed by nanosheet migration and anodic oxidation to yield COF films with high crystallinity and hierarchical porosity.

我们报告了在室温下直接在电极上进行亚胺连接的共价有机骨架 (COF) 薄膜的普遍且前所未有的电裂解合成。 该策略能够将 COF 粉末阴极剥离成纳米片，然后进行纳米片迁移和阳极氧化，从而产生具有高结晶度和分级孔隙率的 COF 薄膜。

We report the discovery of the two-electron transfer in monolayer Ni(OH)2 nanosheets for energy storage, which contrasts with the traditional one-electron transfer found in multilayer materials.

我们报告了用于储能的单层 Ni(OH)2 纳米片中双电子转移的发现，这与多层材料中发现的传统单电子转移形成对比。

The cover art describes circular nanographene-spaced donor–acceptor systems which upon excitation by light result in a charge-separated state. Fast and efficient charge management is achieved via the π-system of the nanographene.

封面艺术描述了圆形纳米石墨烯间隔的供体-受体系统，该系统在被光激发后会导致电荷分离状态。 通过纳米石墨烯的 π 系统实现快速有效的电荷管理。

A highly effective osteoporosis-immunotherapeutic modality based on the acidity neutralization in synergy with immune microenvironment regulation has been developed, in which a CaAl-LDH nanocatalytic medicine functionalized with calcein could neutralize microenvironmental acidity and generate Ca3(PO4)2 nanoparticles, initiating M2 phenotype differentiation of macrophages and reversing the inflammatory immune microenvironment of osteoporosis.

开发了一种基于酸度中和与免疫微环境调节协同作用的高效骨质疏松症免疫治疗方式，其中钙黄绿素功能化的 CaAl-LDH 纳米催化药物可以中和微环境酸度并生成 Ca3(PO4)2 纳米颗粒，启动 M2 表型分化 巨噬细胞和逆转骨质疏松症的炎症免疫微环境。

Producing atomically flat 2D Pt nanodendrites through a 2D nanospace confinement strategy tackles the insufficient interfacial contact effect during HER catalysis by realizing an area-maximized and firmly bound lateral heterointerface with NiFe-LDH. The well-oriented {110} Pt crystal surface exposure promotes electronic interplay that bestows strong LDH binding.

通过 2D 纳米空间限制策略生产原子级平坦的 2D Pt 纳米枝晶，通过与 NiFe-LDH 实现面积最大化和牢固结合的横向异质界面，解决了 HER 催化过程中界面接触效应不足的问题。 定向良好的 {110} Pt 晶体表面暴露促进了赋予强 LDH 结合的电子相互作用。

1.Beyond Triphosphates: Reagents and Methods for Chemical Oligophosphorylation.

除了三磷酸盐：化学寡磷酸化的试剂和方法。

2.Reticular Nanoscience: Bottom-Up Assembly Nanotechnology.

网状纳米科学：自下而上的组装纳米技术。

3.Zero-Gap Bipolar Membrane Electrolyzer for Carbon Dioxide Reduction Using Acid-Tolerant Molecular Electrocatalysts.

用于使用耐酸分子电催化剂还原二氧化碳的零间隙双极膜电解槽。

4.Early Transition Metals Strengthen the B2 Bond in MB2 Complexes.

早期过渡金属加强 MB2 配合物中的 B2 键。

5.Nitrile Infrared Intensities Characterize Electric Fields and Hydrogen Bonding in Protic, Aprotic, and Protein Environments.

腈红外强度表征质子、非质子和蛋白质环境中的电场和氢键。

6.Fast and Effective Prediction of the Absolute Binding Free Energies of Covalent Inhibitors of SARS-CoV-2 Main Protease and 20S Proteasome.

SARS-CoV-2 主蛋白酶和 20S 蛋白酶体共价抑制剂的绝对结合自由能的快速有效预测。

7.Capturing Reactive Carbanions by Microdroplets.

通过微滴捕获反应性碳负离子。

8.Reactions of Tri-tert-Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes.

三叔丁基磷酸四面体作为弹簧负载磷化烯合成子的反应具有镍催化转移到未活化烯烃的作用。

9.Transference Number in Polymer Electrolytes: Mind the Reference-Frame Gap.

聚合物电解质中的迁移数：注意参考系间隙。

10.Structure and Reactivity of One- and Two-Electron Oxidized Manganese(V) Nitrido Complexes Bearing a Bulky Corrole Ligand.

带有大容量咔咯配体的单电子和双电子氧化锰 (V) 硝基配合物的结构和反应性。

11.Taming Shapeshifting Anions: Total Synthesis of Ocellatusone C.

驯服变形阴离子：Ocellatusone C 的全合成。

12.Intracellular Formation of a DNA Damage-Induced, Histone Post-Translational Modification Following Bleomycin Treatment.

博来霉素处理后 DNA 损伤诱导的组蛋白翻译后修饰的细胞内形成。

13.Sprayed Water Microdroplets Are Able to Generate Hydrogen Peroxide Spontaneously.

喷洒的水微滴能够自发产生过氧化氢。

14.Bioinspired Polypeptide Photonic Films with Tunable Structural Color.

具有可调结构颜色的仿生多肽光子薄膜。

15.Remote B-Ring Oxidation of Sclareol with an Engineered P450 Facilitates Divergent Access to Complex Terpenoids.

使用工程化 P450 对香紫苏醇进行远程 B 环氧化可促进对复杂萜类化合物的不同访问。

16.Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides.

掺杂镍氧化物的水氧化机理的光谱电化学分析。

17.DNA Engineered Lymphocyte-Based Homologous Targeting Artificial Antigen-Presenting Cells for Personalized Cancer Immunotherapy.

用于个性化癌症免疫治疗的基于 DNA 工程淋巴细胞的同源靶向人工抗原呈递细胞。

18.Computational Evidence for Tunneling and a Hidden Intermediate in the Biosynthesis of Tetrahydrocannabinol.

四氢大麻酚生物合成中隧道效应和隐藏中间体的计算证据。

19.Anodic Shock-Triggered Exsolution of Metal Nanoparticles from Perovskite Oxide.

阳极冲击触发金属纳米粒子从钙钛矿氧化物中溶出。

20.Stimuli-Responsive Macrocyclization Scaffold Allows In Situ Self-Assembly of Radioactive Tracers for Positron Emission Tomography Imaging of Enzyme Activity.

刺激响应大环化支架允许放射性示踪剂原位自组装，用于酶活性的正电子发射断层扫描成像。

21.Azetidomonamide and Diazetidomonapyridone Metabolites Control Biofilm Formation and Pigment Synthesis in Pseudomonas aeruginosa.

氮杂单酰胺和 二氮杂并吡啶酮代谢物控制铜绿假单胞菌中的生物膜形成和色素合成。

22.Gene-Guided Discovery and Ribosomal Biosynthesis of Moroidin Peptides.

Moroidin 肽的基因引导发现和核糖体生物合成。

23.Oxidation Catalysis over Solid-State Keggin-Type Phosphomolybdic Acid with Oxygen Defects.

具有氧缺陷的固态 Keggin 型磷钼酸的氧化催化。

24.Mutual Monomer Orientation To Bias the Supramolecular Polymerization of [6]Helicenes and the Resulting Circularly Polarized Light and Spin Filtering Properties.

相互单体取向偏向 [6] Helicenes 的超分子聚合以及由此产生的圆偏振光和自旋过滤特性。

25.Selective Photoelectrocatalytic Glycerol Oxidation to Dihydroxyacetone via Enhanced Middle Hydroxyl Adsorption over a Bi2O3-Incorporated Catalyst.

通过在掺入 Bi2O3 的催化剂上增强中间羟基吸附，选择性光电催化甘油氧化二羟基丙酮。

26.Structural Insights into the Mechanism of High-Affinity Binding of Ochratoxin A by a DNA Aptamer.

对 DNA 适配体对赭曲霉毒素 A 的高亲和力结合机制的结构洞察。

27.Identifying Luminol Electrochemiluminescence at the Cathode via Single-Atom Catalysts Tuned Oxygen Reduction Reaction.

通过单原子催化剂调谐氧还原反应识别阴极的鲁米诺电化学发光。

28.Quaternary Ammonium Ion-Tethered (Ambient-Temperature) HDDA Reactions.

季铵离子系链（环境温度）HDDA 反应。

29.Optical Cavity Manipulation and Nonlinear UV Molecular Spectroscopy of Conical Intersections in Pyrazine.

吡嗪中锥形交叉点的光腔操纵和非线性紫外分子光谱学。

30.Dual-Axis Alignment of Bulk Artificial Water Channels by Directional Water-Induced Self-Assembly.

通过定向水诱导自组装实现散装人工水道的双轴对齐。

31.Soft Patch Interface-Oriented Superassembly of Complex Hollow Nanoarchitectures for Smart Dual-Responsive Nanospacecrafts.

用于智能双响应纳米航天器的复杂空心纳米结构的面向软贴片接口的超级组件。

32.Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet.

自由流动液体平面射流中水-水界面的化学动力学成像。

33.Imaging Purely Nuclear Quantum Dynamics in Molecules by Combined X-ray and Electron Diffraction.

通过组合 X 射线和电子衍射对分子中的纯核量子动力学进行成像。

34.Catalytic Asymmetric Reductive Azaarylation of Olefins via Enantioselective Radical Coupling.

通过对映选择性自由基偶联催化烯烃的不对称还原氮杂芳基化。

35.Borole/Borapyramidane Relationship.

Borole/Borapyramidane 关系。

36.Dual Metalation in a Two-Dimensional Covalent Organic Framework for Photocatalytic C–N Cross-Coupling Reactions.

用于光催化 C-N 交叉偶联反应的二维共价有机骨架中的双金属化。

37.Poly(cyclosilane) Connectivity Tunes Optical Absorbance.

聚（环硅烷）连通性调节光学吸光度。

38.Electrically Fueled Active Supramolecular Materials.

电燃料活性超分子材料。

39.Palladium-Mediated Incorporation of Carboranes into Small Molecules, Peptides, and Proteins.

钯介导的碳硼烷掺入小分子、肽和蛋白质。

40.Spatiotemporal Coke Coupling Enhances para-Xylene Selectivity in Highly Stable MCM-22 Catalysts.

时空焦炭耦合增强了高度稳定的 MCM-22 催化剂中的对二甲苯选择性。

41.Fluorogenic Cyclopropenones for Multicomponent, Real-Time Imaging.

用于多组分实时成像的荧光环丙烯酮。

42.Surprising Rigidity of Functionally Important Water Molecules Buried in the Lipid Headgroup Region.

隐藏在脂质头基区域中的具有重要功能的水分子的惊人刚性。

43.Ti-Catalyzed Diastereoselective Cyclopropanation of Carboxylic Derivatives with Terminal Olefins.

含末端烯烃的羧酸衍生物的钛催化非对映选择性环丙烷化反应。

44.Through-Space Interaction of Tetraphenylethylene: What, Where, and How.

四苯乙烯的空间相互作用：什么、在哪里以及如何。

45.Cysteine-Based Mimic of Arginylation Reproduces Neuroprotective Effects of the Authentic Post-Translational Modification on α-Synuclein.

基于半胱氨酸的精氨酰化模拟再现了对 α-突触核蛋白的真实翻译后修饰的神经保护作用。

46.Synthesis and Characterization of Core-Shell Cu-Ru, Cu-Rh, and Cu-Ir Nanoparticles.

核-壳 Cu-Ru、Cu-Rh 和 Cu-Ir 纳米粒子的合成与表征。

47.Regulating Pseudo-Jahn–Teller Effect and Superstructure in Layered Cathode Materials for Reversible Alkali-Ion Intercalation.

调节层状阴极材料中的伪-Jahn-Teller 效应和超结构以实现可逆碱离子嵌入。

48.In Vitro Reconstitution of Cinnamoyl Moiety Reveals Two Distinct Cyclases for Benzene Ring Formation.

肉桂酰部分的体外重组揭示了苯环形成的两种不同的环化酶。

49.Correction to “Sugar-Based Polymers with Stereochemistry Dependent Degradability and Mechanical Properties”.

对“具有立体化学依赖性降解性和机械性能的糖基聚合物”的更正。

50.A Triple Photoredox/Cobalt/Brønsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes.

三重光氧化还原/钴/Brønsted 酸催化使未活化烯烃的 Markovnikov 加氢烷氧基化成为可能。

51.Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Iodocarboranes with (Hetero)Arenes via Boron-Centered Carboranyl Radicals.

可见光促进镍催化的碘碳硼烷与（杂）芳烃通过以硼为中心的碳硼烷基自由基的交叉偶联。

52.Electronic Mechanism of In Situ Inversion of Rectification Polarity in Supramolecular Engineered Monolayer.

超分子工程单层中整流极性原位反转的电子机制。

53.Palladium(II)-Catalyzed Enantioselective Hydrooxygenation of Unactivated Terminal Alkenes.

钯 (II) 催化未活化末端烯烃的对映选择性加氢。

54.The Lewis Acid Induced Formation of a Stable Diradical with an Intramolecular Ion Pairing State.

路易斯酸诱导形成具有分子内离子对状态的稳定双自由基。

55.Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers.

Ir 催化的丙二酸二烷基酯的不对称烯丙基烷基化反应能够构建对映体富集的全碳季中心。

56.Strain-Release [2π + 2σ] Cycloadditions for the Synthesis of Bicyclo[2.1.1]hexanes Initiated by Energy Transfer.

通过能量转移引发的双环[2.1.1]己烷合成的应变释放 [2π + 2σ] 环加成。

57.Stereocontrolled Total Synthesis of Bastimolide B Using Iterative Homologation of Boronic Esters.

使用硼酸酯的迭代同系化立体控制 Bastimolide B 的全合成。

58.Photoelectrochemical CO2 Reduction toward Multicarbon Products with Silicon Nanowire Photocathodes Interfaced with Copper Nanoparticles.

使用与铜纳米粒子连接的硅纳米线光电阴极对多碳产品进行光电化学 CO2 还原。

59.Missing Link in the Growth of Lead-Based Zintl Clusters: Isolation of the Dimeric Plumbaspherene [Cu4Pb22]4–.

铅基 Zintl 簇生长中的缺失环节：二聚体 Plumbaspherene [Cu4Pb22]4– 的分离。

60.Automated Image Analysis for Single-Atom Detection in Catalytic Materials by Transmission Electron Microscopy.

通过透射电子显微镜对催化材料中的单原子检测进行自动图像分析。

61.High-Throughput Screening for Thermoelectric Semiconductors with Desired Conduction Types by Energy Positions of Band Edges.

通过能带边缘的能量位置对具有所需传导类型的热电半导体进行高通量筛选。

62.Electronic and Optical Properties of Eu2+-Activated Narrow-Band Phosphors for Phosphor-Converted Light-Emitting Diode Applications: Insights from a Theoretical Spectroscopy Perspective.

用于荧光粉转换发光二极管应用的 Eu2+ 激活窄带荧光粉的电子和光学特性：来自理论光谱学视角的见解。

63.Structural Dynamics of a Common Mutagenic Oxidative DNA Lesion in Duplex DNA and during DNA Replication.

双链 DNA 和 DNA 复制过程中常见诱变氧化 DNA 损伤的结构动力学。

64.Quinone Electrodes for Alkali–Acid Hybrid Batteries.

用于碱-酸混合电池的醌电极。

65.Achieving Multiple Quantum-Interfered States via Through-Space and Through-Bond Synergistic Effect in Foldamer-Based Single-Molecule Junctions.

在基于 Foldamer 的单分子连接中通过穿透空间和穿透键协同效应实现多个量子干涉态。

66.Topological Design of Highly Anisotropic Aligned Hole Transporting Molecular Bottlebrushes for Solution-Processed OLEDs.

用于溶液处理 OLED 的高度各向异性排列的空穴传输分子洗瓶刷的拓扑设计。

67.In Situ Optical and X-ray Spectroscopy Reveals Evolution toward Mature CdSe Nanoplatelets by Synergetic Action of Myristate and Acetate Ligands.

原位光学和 X 射线光谱揭示了通过肉豆蔻酸酯和乙酸酯配体的协同作用向成熟 CdSe 纳米片的演化。

68.Oxidative Stability Matters: A Case Study of Palladium Hydride Nanosheets for Alkaline Fuel Cells.

氧化稳定性很重要：用于碱性燃料电池的氢化钯纳米片的案例研究。

69.Formation and Evolution of H2C3O+• Radical Cations: A Computational and Matrix Isolation Study.

H2C3O+• 自由基阳离子的形成和演变：计算和基质分离研究。

70.Basic Promotors Impact Thermodynamics and Catalyst Speciation in Homogeneous Carbonyl Hydrogenation.

碱性促进剂影响均相羰基氢化中的热力学和催化剂形态。

71.Compact Peptoid Molecular Brushes for Nanoparticle Stabilization.

用于纳米粒子稳定的紧凑型类肽分子刷。

72.Black Titanium-Oxo Clusters with Ultralow Band Gaps and Enhanced Nonlinear Optical Performance.

具有超低带隙和增强的非线性光学性能的黑色钛氧簇。

73.α-BaF2 Nanoparticle Substrate-Enabled γ-CsPbI3 Heteroepitaxial Growth for Efficient and Bright Deep-Red Light-Emitting Diodes.

α -BaF2 纳米粒子衬底支持 γ-CsPbI3 异质外延生长，用于高效明亮的深红色发光二极管。

74.Uncovering the Key Role of Distortion in Bioorthogonal Tetrazine Tools That Defy the Reactivity/Stability Trade-Off.

揭示扭曲在违反反应性/稳定性权衡的生物正交四嗪工具中的关键作用。

75.Can Brønsted Photobases Act as Lewis Photobases?.

Brønsted Photobases 可以充当 Lewis Photobases 吗？

76.Turn-on Fluorescent Biosensors for Imaging Hypoxia-like Conditions in Living Cells.

打开荧光生物传感器，用于成像活细胞中的缺氧样条件。

77.3,6-Carbazoylene Octaphyrin (1.0.0.0.1.0.0.0) and Its Bis-BF2 Complex.

3,6-咔唑 八叶酸(1.0.0.0.1.0.0.0) 及其 Bis-BF2 复合物。

78.Regulating the Spin State of FeIII Enhances the Magnetic Effect of the Molecular Catalysis Mechanism.

调节FeIII的自旋态增强分子催化机制的磁效应。

79.Substrate-Modulated Synthesis of Metal–Organic Hybrids by Tunable Multiple Aryl–Metal Bonds.

通过可调谐多芳基-金属键底物调制合成金属-有机杂化物。

80.Entropy Stabilization Effects and Ion Migration in 3D “Hollow” Halide Perovskites.

3D“空心”卤化物钙钛矿中的熵稳定效应和离子迁移。

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