【标题速读】【Angew】【2022年】【8月】

声明:本专栏主要对生命科学领域的一些期刊文章标题进行翻译,所有内容均由本人手工整理翻译。由于本人专业为生物分析相关,其他领域如果出现翻译错误请谅解。
1.The reaction path of the Lewis acid catalyzed intramolecular aza-Michael addition to form a C3 ammonium enolate is reported by Jan Paradies et al. in their Communication (e202204378). This transient intermediate rearranges diastereospecifically to the tetrahydroquinoline-4-one scaffold. The central structure in the picture represents the transition state of the diastereospecific sigmatropic [1,5] carbon shift which proceeds with retention of configuration on the migrating carbon center.
Jan Paradies 等人在他们的通讯(e202204378)中报道了路易斯酸催化分子内氮杂迈克尔加成形成 C3 烯醇铵的反应路径。该瞬时中间体非对映特异性地重排至四氢喹啉-4-酮支架。图中的中心结构代表非对映特异性同向性[1,5]碳转移的过渡态,该转移随着迁移碳中心构型的保留而进行。

2.Porous organic salts (POSs) are porous organic materials, in which various aromatic sulfonic acids and amines are regularly self-assembled by charge-assisted hydrogen bonding. Norimitsu Tohnai and co-workers demonstrate in their Research Article (e202202597) the advantages of diverse porous organic salts, such as all-organic, extremely facile preparation methods, diverse void structures and environments, and excellent CO2 adsorption properties.
多孔有机盐(POS)是多孔有机材料,其中各种芳香族磺酸和胺通过电荷辅助氢键有规律地自组装。 Norimitsu Tohnai 及其同事在他们的研究文章 (e202202597) 中展示了多种多孔有机盐的优点,例如全有机、极其简便的制备方法、多样化的孔隙结构和环境以及优异的 CO2 吸附性能。

3.Rapid and reagent-free pathogen tests are urgently needed. In their Research Article (e202204252), Leyla Soleymani, Yingfu Li and co-workers developed a dual-electrode electrochemical chip (DEE-Chip) and a barcode-releasing electroactive aptamer for rapid on-farm detection of porcine epidemic diarrhea viruses (PEDv). In contrast to current biosecurity surveillance with turnaround times of 2–4 days, this technology identifies infection with PEDv in pig saliva in one hour with a diagnostic sensitivity of 100 % and specificity of 83 %.
迫切需要快速、无试剂的病原体检测。在他们的研究文章 (e202204252) 中,Leyla Soleymani、Yingfu Li 及其同事开发了一种双电极电化学芯片 (DEE-Chip) 和一种释放条形码的电活性适体,用于在农场快速检测猪流行性腹泻病毒 (PEDv) 。与目前周转时间为 2-4 天的生物安全监测相比,该技术可在一小时内识别出猪唾液中的 PEDv 感染,诊断灵敏度为 100%,特异性为 83%。

4.Tandem catalysis of solid NaPr-CoRu@Al2O3 and molecular [HCo(CO)3PR3] catalysts allows the direct conversion of synthesis gas to alcohols. Walter Leitner, Andreas J. Vorholt, Gonzalo Prieto et al. show in their Research Article (e202201004) that the combination of Fischer–Tropsch and hydroformylation catalysts generates alcohols from synthesis gas with exceptional selectivity. While the bimodally porous solid catalyst generates 1-olefins with high efficiency, in situ hydroformylation of olefins to alcohols circumvents secondary hydrogenation and allows to push the alcohol selectivity even further.
固体NaPr-CoRu@Al2O3和分子[HCo(CO)3PR3]催化剂的串联催化可以将合成气直接转化为醇。沃尔特·莱特纳 (Walter Leitner)、安德烈亚斯·J·沃霍尔特 (Andreas J. Vorholt)、贡萨洛·普列托 (Gonzalo Prieto) 等人在他们的研究文章 (e202201004) 中表明,费托合成和加氢甲酰化催化剂的结合可以从合成气中以优异的选择性生成醇。虽然双峰多孔固体催化剂能够高效生成 1-烯烃,但烯烃原位加氢甲酰化为醇,避免了二次加氢,可以进一步提高醇的选择性。

5.Renewable Polymers. In their Communication (e202203353), Mukund P. Sibi, Dean C. Webster, Jayaraman Sivaguru et al. highlight a methodology for the generation of photodegradable and recyclable cross-linked polymers from biomass.
可再生聚合物。在他们的通讯 (e202203353) 中,Mukund P. Sibi、Dean C. Webster、Jayaraman Sivaguru 等人强调从生物质中生成可光降解和可回收的交联聚合物的方法。

6.Protein Structures. By collecting matched room-temperature and cryogenic datasets of the biomedical target Hsp90α, Marcus Fischer et al. identified in their Research Article (e202112919) changes in water networks that impact protein conformations at the ligand binding interface.
蛋白质结构。通过收集生物医学目标 Hsp90α 的匹配室温和低温数据集,Marcus Fischer 等人在他们的研究文章 (e202112919) 中发现水网络的变化会影响配体结合界面的蛋白质构象。

7.Stepping Out of the Blue: From Visible to Near-IR Triggered Photoswitches.
出人意料:从可见光到近红外触发光电开关。

8.Water Networks Repopulate Protein–Ligand Interfaces with Temperature.
水网络随温度重新填充蛋白质-配体界面。

9.Ternary Alloy PtWMn as a Mn Nanoreservoir for High-Field MRI Monitoring and Highly Selective Ferroptosis Therapy.
三元合金 PtWMn 作为锰纳米储库,用于高场 MRI 监测和高选择性铁死亡治疗。

10.Direct Conversion of Syngas to Higher Alcohols via Tandem Integration of Fischer–Tropsch Synthesis and Reductive Hydroformylation.
通过费托合成和还原加氢甲酰化的串联集成将合成气直接转化为高级醇。

11.“Sandwich” Diimine-Copper Catalysts for C−H Functionalization by Carbene Insertion.
通过卡宾插入实现 C−H 功能化的“三明治”二亚胺-铜催化剂。
12.Engineering Aptamers with Selectively Enhanced Biostability in the Tumor Microenvironment.
在肿瘤微环境中选择性增强生物稳定性的工程适体。

13.S,O-Ligand Promoted meta-C−H Arylation of Anisole Derivatives via Palladium/Norbornene Catalysis.
S,O-配体通过钯/降冰片烯催化促进苯甲醚衍生物的间位C−H芳基化。

14.Chemoenzymatic Cascades for the Enantioselective Synthesis of β-Hydroxysulfides Bearing a Stereocentre at the C−O or C−S Bond by Ketoreductases.
用于通过酮还原酶对映选择性合成在 C−O 或 C−S 键上带有立构中心的 β-羟基硫化物的化学酶级联。

15.Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics.
使用天然酚醛树脂生成的可持续余辉室温磷光发射材料。

16.Porous Organic Salts: Diversifying Void Structures and Environments.
多孔有机盐:使空隙结构和环境多样化。

17.Concise Synthesis of Tunicamycin V and Discovery of a Cytostatic DPAGT1 Inhibitor.
衣霉素 V 的简明合成和细胞抑制 DPAGT1 抑制剂的发现。

18.Restoration of the Immunogenicity of Tumor Cells for Enhanced Cancer Therapy via Nanoparticle-Mediated Copper Chaperone Inhibition.
通过纳米颗粒介导的铜伴侣抑制恢复肿瘤细胞的免疫原性以增强癌症治疗。

19.Polarization-Dependent Ultrasensitive Dynamic Wrinkling on Floating Films Induced by Photo-Orientation of Azopolymer.
偶氮聚合物光取向引起的浮动薄膜上的偏振相关超灵敏动态起皱。

20.From Copper to Basic Copper Carbonate: A Reversible Conversion Cathode in Aqueous Anion Batteries.
从铜到碱式碳酸铜:水性阴离子电池中的可逆转换阴极。

21.Hydrogen Production and Water Desalination with On-demand Electricity Output Enabled by Electrochemical Neutralization Chemistry.
通过电化学中和化学实现氢气生产和海水淡化以及按需电力输出。

22.Highly Selective Carbonylation of CH3Cl to Acetic Acid Catalyzed by Pyridine-Treated MOR Zeolite.
吡啶处理的 MOR 沸石催化 CH3Cl 高度选择性羰基化成乙酸。

23.Fast-Scanning Potential-Gated Organic Electrochemical Transistors for Highly Sensitive Sensing of Dopamine in Living Rat Brain.
快速扫描电位门控有机电化学晶体管,用于对活体大鼠大脑中的多巴胺进行高灵敏传感。

24.A DNA Barcode-Based Aptasensor Enables Rapid Testing of Porcine Epidemic Diarrhea Viruses in Swine Saliva Using Electrochemical Readout.
基于 DNA 条形码的适配体传感器能够使用电化学读数快速检测猪唾液中的猪流行性腹泻病毒。

25.Ruthenium-Catalyzed Geminal Hydroborative Cyclization of Enynes.
钌催化烯炔的偕硼氢化环化。

26.“Rim-Differentiated” Pillar[6]arenes.
“边缘差异化”支柱芳烃[6]。

27.Bipolar Magnetic Molecules for Spin-Polarized Electric Current in Molecular Junctions.
用于分子结中自旋极化电流的双极磁性分子。

28.Li−N Interaction Induced Deep Eutectic Gel Polymer Electrolyte for High Performance Lithium-Metal Batteries.
用于高性能锂金属电池的Li−N相互作用诱导的深共晶凝胶聚合物电解质。

29.Catalytic Atroposelective Electrophilic Amination of Indoles.
吲哚的催化天体选择性亲电胺化。

30.Mild Acidosis-Directed Signal Amplification in Tumor Microenvironment via Spatioselective Recruitment of DNA Amplifiers.
通过 DNA 放大器的空间选择性募集,在肿瘤微环境中实现轻度酸中毒定向信号放大。

31.Electrostatic-Induced Crystal-Rearrangement of Porous Organic Cage Membrane for CO2 Capture.
用于二氧化碳捕获的多孔有机笼膜的静电诱导晶体重排。

32.Nickel-Catalyzed Switchable Site-Selective Alkene Hydroalkylation by Temperature Regulation.
通过温度调节进行镍催化可切换位点选择性烯烃加氢烷基化。

33.Straightforward Access to Multifunctional π-Conjugated P-Heterocycles Featuring an Internal Ylidic Bond.
直接获得具有内部Ylidic 键的多功能π-共轭P-杂环。

34.Formation of a Hybrid 1-Bora-3-boratabenzene Heteroarene Anion Derivative.
杂化 1-Bora-3-borata 苯杂芳烃阴离子衍生物的形成。

35.Ultrafast Triplet–Singlet Exciton Interconversion in Narrowband Blue Organoboron Emitters Doped with Heavy Chalcogens.
掺杂重硫属元素的窄带蓝色有机硼发射体中的超快三线态-单线态激子相互转换。

36.Precision Synthesis of Various Low-Bandgap Donor–Acceptor Alternating Conjugated Polymers via Living Suzuki–Miyaura Catalyst-Transfer Polymerization.
通过活性铃木-宫浦催化剂转移聚合精确合成各种低带隙供体-受体交替共轭聚合物。

37.Stabilization of Cu+ via Strong Electronic Interaction for Selective and Stable CO2 Electroreduction.
通过强电子相互作用稳定 Cu+,实现选择性和稳定的 CO2 电还原。

38.Highly Active and Stable Li2S−Cu Nanocomposite Cathodes Enabled by Kinetically Favored Displacement Interconversion between Cu2S and Li2S.
通过动力学上有利的 Cu2S 和 Li2S 之间的位移相互转化实现高活性和稳定的 Li2S−Cu 纳米复合材料阴极。

39.Activating Lattice Oxygen in Layered Lithium Oxides through Cation Vacancies for Enhanced Urea Electrolysis.
通过阳离子空位激活层状氧化锂中的晶格氧以增强尿素电解。

40.PIII-Directed Late-Stage Ligation and Macrocyclization of Peptides with Olefins by Rhodium Catalysis.
通过铑催化进行 PIII 指导的肽与烯烃的后期连接和大环化。

41.Bioinspired Metalation of the Metal-Organic Framework MIL-125-NH2 for Photocatalytic NADH Regeneration and Gas-Liquid-Solid Three-Phase Enzymatic CO2 Reduction.
用于光催化 NADH 再生和气-液-固三相酶促 CO2 还原的金属有机框架 MIL-125-NH2 的仿生金属化。

42.Atroposelective Construction of Nine-Membered Carbonate-Bridged Biaryls.
九元碳酸酯桥联芳基的天体选择性构建。

43.Eutectic Electrolyte with Unique Solvation Structure for High-Performance Zinc-Ion Batteries.
用于高性能锌离子电池的具有独特溶剂化结构的共晶电解质。

44.An Ultrastable 155-Nuclei Silver Nanocluster Protected by Thiacalix[4]arene and Cyclohexanethiol for Photothermal Conversion.
由 Thiacalix[4] 芳烃和环己烷硫醇保护的超稳定 155 核银纳米团簇用于光热转换。

45.Embedding Multiphoton Active Units within Metal–Organic Frameworks for Turning on High-Order Multiphoton Excited Fluorescence for Bioimaging.
将多光子活性单元嵌入金属有机框架中,以开启高阶多光子激发荧光以进行生物成像。

46.Site-Selective Functionalization of Sila-Adamantane and Its Ensuing Optical Effects.
Sila-金刚烷的位点选择性功能化及其随之而来的光学效应。

47.Tailored Multivalent Targeting of Siglecs with Photosensitizing Liposome Nanocarriers.
使用光敏脂质体纳米载体定制 Siglecs 多价靶向。

48.The Chemistry of Cu3N and Cu3PdN Nanocrystals.
Cu3N 和 Cu3PdN 纳米晶体的化学性质。

49.Mesoporous Polyimide-Linked Covalent Organic Framework with Multiple Redox-Active Sites for High-Performance Cathodic Li Storage.
具有多个氧化还原活性位点的介孔聚酰亚胺连接的共价有机框架,用于高性能阴极锂存储。

50.Asymmetrically Doping a Platinum Atom into a Au38 Nanocluster for Changing the Electron Configuration and Reactivity in Electrocatalysis.
将铂原子不对称掺杂到 Au38 纳米团簇中,以改变电催化中的电子构型和反应性。

51.Spatiotemporal Mapping of Efficient Chiral Induction by Helicene-Type Additives in Copolymer Thin Films.
共聚物薄膜中螺旋烯型添加剂的高效手性感应的时空映射。

52.A Deep Eutectic Solvent Thermomorphic Multiphasic System for Biocatalytic Applications.
用于生物催化应用的深共晶溶剂热成型多相系统。

53.Towards Upcycling Biomass-Derived Crosslinked Polymers with Light.
利用光升级改造生物质衍生的交联聚合物。

54.Total Synthesis of (+)-Cochlearol B by an Approach Based on a Catellani Reaction and Visible-Light-Enabled [2+2] Cycloaddition.
基于 Catellani 反应和可见光 [2+2] 环加成的方法全合成 (+)-Cochlearol B。

55.Native Ambient Mass Spectrometry of an Intact Membrane Protein Assembly and Soluble Protein Assemblies Directly from Lens Tissue.
对直接来自晶状体组织的完整膜蛋白组件和可溶性蛋白组件进行天然环境质谱分析。

56.A Novel AgI-DNA Rod Comprising a One-Dimensional Array of 11 Silver Ions within a Double Helical Structure.
一种新型 AgI-DNA 棒,由双螺旋结构内的 11 个银离子一维阵列组成。

57.Total Synthesis of Complex Peptidyl Nucleoside Antibiotics: Asymmetric De Novo Syntheses of Miharamycin B and Its Biosynthetic Precursor.
复杂肽基核苷抗生素的全合成:米哈霉素 B 及其生物合成前体的不对称从头合成。

58.Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation.
催化不对称水解氧化合成硅立体硅烷醇。

59.Alkyl/Glycosyl Sulfoxides as Radical Precursors and Their Use in the Synthesis of Pyridine Derivatives.
烷基/糖基亚砜作为自由基前体及其在吡啶衍生物合成中的应用。

60.A Modular Approach for Diversity-Oriented Synthesis of 1,3-trans-Disubstituted Tetrahydroisoquinolines: Seven-Step Asymmetric Synthesis of Michellamines B and C.
1,3-反式二取代四氢异喹啉的多样性导向合成的模块化方法:米开胺 B 和 C 的七步不对称合成。

61.Sirtuin-Derived Covalent Binder for the Selective Recognition of Protein Crotonylation.
Sirtuin 衍生的共价结合剂,用于选择性识别蛋白质巴豆酰化。

62.Enhanced Photocatalytic CO2 Reduction through Hydrophobic Microenvironment and Binuclear Cobalt Synergistic Effect in Metallogels.
通过金属凝胶中的疏水性微环境和双核钴协同效应增强光催化二氧化碳还原。

63.Synthesis of an N-Heterocylic Boryl-Stabilized Disilyne and Its Application to the Activation of Dihydrogen and C−H Bonds.
N-杂环硼基稳定二硅炔的合成及其在二氢键和 C−H 键活化中的应用。

64.Exploring Equilibria between Aluminium(I) and Aluminium(III): The Formation of Dihydroalanes, Masked Dialumenes and Aluminium(I) Species.
探索铝 (I) 和铝 (III) 之间的平衡:二氢丙烷、掩蔽二铝烯和铝 (I) 物质的形成。

65.Fluorescence or Phosphorescence? The Metallic Composition of the Nanocluster Kernel Does Matter.
荧光还是磷光?纳米团簇内核的金属成分很重要。

66.Green-Light-Driven Reductive Elimination of Chlorine from a Carbene-Xanthylium Gold(III) Complex.
绿光驱动从卡宾-苍耳金 (III) 络合物中还原消除氯。

67.Formal β-C−H Arylation of Aldehydes and Ketones by Cooperative Nickel and Photoredox Catalysis.
通过镍和光氧化还原协同催化对醛和酮进行正式 β-C−H 芳基化。

68.Enantioselective Hydrocarbamoylation of Alkenes.
烯烃的对映选择性加氢甲酰化。

69.Intramolecular Energy and Solvent-Dependent Chirality Transfer within a BINOL-Perylene Hetero-Cyclophane.
BINOL-苝杂环芳内的分子内能量和溶剂依赖性手性转移。

70.Facile Synthesis of a Fluorinated-Squaramide Covalent Organic Framework for the Highly Efficient and Broad-Spectrum Removal of Per- and Polyfluoroalkyl Pollutants.
轻松合成氟化方酰胺共价有机框架,用于高效、广谱去除全氟烷基和多氟烷基污染物。

71.Accelerated Degradation of Microplastics at the Liquid Interface of Ice Crystals in Frozen Aqueous Solutions.
冷冻水溶液中冰晶液体界面处微塑料的加速降解。

72.Umpolung AlaB Reagents for the Synthesis of Non-Proteogenic Amino Acids, Peptides and Proteins.
用于合成非蛋白氨基酸、肽和蛋白质的 Umpolung AlaB 试剂。

73.Reductive Carbon–Carbon Coupling on Metal Sites Regulates Photocatalytic CO2 Reduction in Water Using ZnSe Quantum Dots.
金属位点上的还原性碳-碳耦合利用 ZnSe 量子点调节水中 CO2 的光催化还原。

74.Sigmatropic [1,5] Carbon Shift of Transient C3 Ammonium Enolates.
瞬态 C3 烯醇铵的 Sigmatropic [1,5] 碳转移。

75.Metathesis Reactions of a NHC-Stabilized Phosphaborene.
NHC 稳定的磷硼烯的复分解反应。

76.Preparation of Functionalized Amides Using Dicarbamoylzincs.
使用二氨基甲酰锌制备官能化酰胺。

77.A Planar Five-Membered Aromatic Ring Stabilized by Only Two π-Electrons.
仅由两个 π 电子稳定的平面五元芳环。

78.A unique anion exchangeable hybrid composite aerogel material was fabricated by Sujit K. Ghosh and co-workers in their Research Article (e202203385) by strategically implanting a stable cationic metal–organic polyhedron in a hierarchically porous metal–organic gel material. The composite scavenger efficiently and selectively sequestrates various metal-based toxic oxoanions from natural and simulated industrial wastewater samples in both batch and dynamic column exchange sorption experiments.
Sujit K. Ghosh 及其同事在其研究文章 (e202203385) 中通过在分层多孔金属有机凝胶材料中策略性地植入稳定的阳离子金属有机多面体,制备了一种独特的阴离子可交换杂化复合气凝胶材料。在批量和动态柱交换吸附实验中,复合清除剂可有效、选择性地从天然和模拟工业废水样品中隔离各种金属基有毒含氧阴离子。

79.Frustration under control: In their Communication (e202202727), Clémence Corminboeuf and co-workers developed a general approach to map the active site geometry of immobilized frustrated Lewis pair catalysts to their activity for CO2 hydrogenation and demonstrated that a manyfold increase in their performance is attainable through judicious spatial control of the acid and base components.
受阻可控:在他们的通讯 (e202202727) 中,Clémence Corminboeuf 和同事开发了一种通用方法,将固定受阻路易斯对催化剂的活性位点几何结构映射到其 CO2 加氢活性,并证明其性能可以实现数倍提高通过对酸和碱成分的明智的空间控制。

80.A small-molecule analogue of the formin FH2 domain inhibitor SMIFH2 was developed that selectively inhibits interferon-induced JAK-STAT signalling. Details of the study are reported by Cédric M. Blouin, Christophe Lamaze, Raphaël Rodriguez et al. in their Communication (e202205231).
开发了福尔马林 FH2 结构域抑制剂 SMIFH2 的小分子类似物,可选择性抑制干扰素诱导的 JAK-STAT 信号传导。 Cédric M. Blouin、Christophe Lamaze、Raphaël Rodriguez 等人在他们的通讯(e202205231)中报道了该研究的详细信息。

81.Nucleic acid detection plays a critical role in medical diagnostics, environmental monitoring, and food safety. In their Research Article (e202203826), Xue Gao, Yi Zhang and co-workers developed a new biosensor for amplification-free nucleic acid detection via harnessing the trans-cleavage mechanism of Cas13a and ultrasensitive graphene field-effect transistors (gFETs). The illustration shows the Cas13a-mediated RNA trans-cleavage on a gFET surface for sensor signal transduction.
核酸检测在医疗诊断、环境监测和食品安全中发挥着至关重要的作用。在他们的研究文章 (e202203826) 中,Xue Gau、YiZhang 及其同事通过利用 Cas13a 的反式切割机制和超灵敏石墨烯场效应晶体管 (gFET) 开发了一种用于无扩增核酸检测的新型生物传感器。插图显示了 gFET 表面 Cas13a 介导的 RNA 反式切割,用于传感器信号转导。

82.Radical Ions The synthesis and characterization of stable iron pentacarbonyl radical cation salts is reported by Ingo Krossing et al. in their Communication (e202204080).
自由基离子 Ingo Krossing 等人报道了稳定的五羰基铁自由基阳离子盐的合成和表征。在他们的通讯(e202204080)中。

83.Carboranes The aromatic nucleophilic amination of 1,2-diaryl- o-carboranes with (R2N)2Mg for the synthesis of 4-R2N-o-carboranes and 2-R2N-m-carboranes is reported by Zuowei Xie and Jie Zhang in their Research Article (e202202675).
碳硼烷Zuowei Xie 和 Jie Zhu 在他们的研究中报道了 1,2-二芳基-邻碳硼烷与 (R2N)2Mg 的芳香族亲核胺化反应合成了 4-R2N-o-碳硼烷和 2-R2N-m-碳硼烷文章(e202202675)。

84.Ultra-High Temperature Molten Oxide Electrochemistry.
超高温熔融氧化物电化学。

85.N-Ligand-Enabled Aromatic Nucleophilic Amination of 1,2-Diaryl-o-Carboranes with (R2N)2Mg for Selective Synthesis of 4-R2N-o-Carboranes and 2-R2N-m-Carboranes.
N-配体使 1,2-二芳基-邻碳硼烷与 (R2N)2Mg 发生芳香族亲核胺化,用于选择性合成 4-R2N-邻碳硼烷和 2-R2N-间碳硼烷。

86.Fast Magic-Angle-Spinning NMR Reveals the Evasive Hepatitis B Virus Capsid C-Terminal Domain.
快速魔角旋转 NMR 揭示了隐匿性乙型肝炎病毒衣壳 C 端结构域。

87.Sb3+–Er3+-Codoped Cs2NaInCl6 for Emitting Blue and Short-Wave Infrared Radiation.
Sb3+–Er3+-共掺杂 Cs2NaInCl6 用于发射蓝色和短波红外辐射。

88.Sodium Borates: Expanding the Electrolyte Selection for Sodium-Ion Batteries.
硼酸钠:扩大钠离子电池电解质的选择。

89.Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles.
使用由大环化合物构建的金属有机笼分离氢同位素。

90.Convergent Synthesis and Anti-Pancreatic Cancer Cell Growth Activity of a Highly Branched Heptadecasaccharide from Carthamus tinctorius.
红花高度支化十七糖的聚合合成及其抗胰腺癌细胞生长活性。

91.Four-in-One Stimulus-Responsive Long-Lived Luminescent Systems Based on Pyrene-Doped Amorphous Polymers.
基于芘掺杂非晶聚合物的四合一刺激响应长寿命发光系统。

92.Trap Inlaid Cationic Hybrid Composite Material for Efficient Segregation of Toxic Chemicals from Water.
用于有效分离水中有毒化学品的陷阱镶嵌阳离子杂化复合材料。

93.Methylamine Lithium Borohydride as Electrolyte for All-Solid-State Batteries.
甲胺硼氢化锂作为全固态电池的电解质。

94.Back-Gated van der Waals Heterojunction Manipulates Local Charges toward Fine-Tuning Hydrogen Evolution.
背门范德华异质结操纵局部电荷以微调氢的析出。

95.Intrinsic Nonflammable Ether Electrolytes for Ultrahigh-Voltage Lithium Metal Batteries Enabled by Chlorine Functionality.
用于超高压锂金属电池的固有不可燃醚电解质,由氯官能团实现。

96.Amplification-Free Detection of SARS-CoV-2 and Respiratory Syncytial Virus Using CRISPR Cas13a and Graphene Field-Effect Transistors.
使用 CRISPR Cas13a 和石墨烯场效应晶体管对 SARS-CoV-2 和呼吸道合胞病毒进行无扩增检测。

97.Homochiral Multiferroic Cyanido-Bridged Dimetallic Complexes Assembled by C−F⋅⋅⋅K Interactions.
通过 C−F⋅⋅⋅K 相互作用组装的同手性多铁氰基桥双金属配合物。

98.Relaxation of the Plant Cell Wall Barrier via Zwitterionic Liquid Pretreatment for Micelle-Complex-Mediated DNA Delivery to Specific Plant Organelles.
通过两性离子液体预处理松弛植物细胞壁屏障,以实现胶束复合物介导的 DNA 递送至特定植物细胞器。

99.A Cobalamin-Dependent Radical SAM Enzyme Catalyzes the Unique Cα-Methylation of Glutamine in Methyl-Coenzyme M Reductase.
钴胺素依赖性自由基 SAM 酶催化甲基辅酶 M 还原酶中谷氨酰胺的独特 Cα-甲基化。

100.Chemically Tuning Attractive and Repulsive Interactions between Solubilizing Oil Droplets.
化学调节增溶油滴之间的吸引和排斥相互作用。

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