【标题速读】【Angew】【2022年】【9月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.Electroreduction of CO2 to acetate provides a promising strategy to reduce CO2 emissions and store renewable energy, but acetate is usually a by-product. A covalent organic framework with isolated active sites for the highly selective electroreduction of CO2 to acetate is reported by Pei-Qin Liao and co-workers in their Communication (e202206470). The copper–phthalocyanine active site with high electron density is conducive to the key step of C−C coupling of *CH3 with CO2 to produce acetate, and can avoid the coupling of *CO with *CO or *CHO to produce ethylene and ethanol.

将二氧化碳电还原为乙酸盐为减少二氧化碳排放和储存可再生能源提供了一种有前途的策略，但乙酸盐通常是副产品。 Pei-Qin Liao 及其同事在他们的通讯 (e202206470) 中报道了一种具有隔离活性位点的共价有机框架，用于将 CO2 高选择性电还原为乙酸盐。高电子密度的铜酞菁活性位点有利于*CH3与CO2 C−C偶联生成乙酸的关键步骤，并且可以避免*CO与*CO或*CHO偶联生成乙烯和乙醇。

2.Atomically precise doping is a promising approach for functionalizing gold superatoms. In their Research Article (e202207290), Tatsuya Tsukuda and co-workers synthesized a series of M@Au12 superatoms (M=Au, Pd, Pt, Rh, or Ir) and investigated their photophysical and photochemical properties. Doping an M element positioned at the lower left of the periodic table led to a remarkable enhancement of the photoluminescence quantum yield and photocatalytic activities for intramolecular [2+2] cycloaddition of bisenone.

原子精确掺杂是金超原子功能化的一种有前途的方法。Tatsuya Tsukuda 和同事在他们的研究文章 (e202207290) 中合成了一系列 M@Au12 超原子（M=Au、Pd、Pt、Rh 或 Ir），并研究了它们的光物理和光化学性质。掺杂位于元素周期表左下角的M元素可以显着提高双烯酮分子内[2+2]环加成的光致发光量子产率和光催化活性。

3.Flying elephants and delicate cargo. Electrospray ionization of proteins has been likened to making molecular elephants fly. In their Communication (e202202075), Helen J. Cooper and co-workers demonstrate mass spectrometry detection and imaging of a non-covalent complex formed in vivo, comprising an endogenous protein and an exogenously administered drug molecule, directly from liver tissue. These methods will provide greater insight into protein–drug complexes in support of drug research and development.

飞翔的大象和精致的货物。蛋白质的电喷雾电离被比作使分子象飞翔。Helen J. Cooper 及其同事在他们的通讯 (e202202075) 中演示了直接从肝组织中形成的体内形成的非共价复合物的质谱检测和成像，该非共价复合物包含内源性蛋白质和外源性给药的药物分子。这些方法将提供对蛋白质-药物复合物的更深入的了解，以支持药物研究和开发。

4.An efficient polyelectrolyte hole-transport layer was explored for 2D perovskite solar cells by using a compatible butylamine cation, as reported by Jianyu Yuan and co-workers in their Research Article (e202205111). The tailored polyelectrolyte has an anchoring effect and acts as a passivator for 2D perovskites, which can improve 2D perovskite phase alignment and interfacial charge transfer efficiency, and finally enables high-efficiency and large-area 2D perovskite solar cells.

正如Jianyu Yuan 及其同事在他们的研究文章 (e202205111) 中报道的那样，通过使用相容的丁胺阳离子，探索了一种用于二维钙钛矿太阳能电池的高效聚电解质空穴传输层。定制的聚电解质具有锚定效应，作为二维钙钛矿的钝化剂，可以改善二维钙钛矿的相排列和界面电荷转移效率，最终实现高效、大面积的二维钙钛矿太阳能电池。

5.Electrochemistry. In their Communication (e202206236), Qinghua Ji et al. demonstrate an in operando visualization method for investigating the dynamic electrochemical processes occurring at electrode–solution interfaces.

电化学。Qinghua Ji 等人在他们的通讯（e202206236）中展示一种用于研究电极-溶液界面处发生的动态电化学过程的操作可视化方法。

6.Mass Spectrometry. In their Research Article (e202205720), Jana Roithová et al. introduce a method for determining enantioselectivities by mass spectrometry. This method is based on ion mobility separation of diastereomeric intermediates.

质谱。 Jana Roithová 等人在他们的研究文章 (e202205720) 中介绍一种通过质谱法测定对映选择性的方法。该方法基于非对映体中间体的离子淌度分离。

7.Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations.

发现有机催化和其他有机介导的（解）聚合和聚合物官能化的趋势。

8.Monitoring Reaction Intermediates to Predict Enantioselectivity Using Mass Spectrometry.

使用质谱法监测反应中间体以预测对映选择性。

9.Nickel-Catalyzed Asymmetric Hydroaryloxy- and Hydroalkoxycarbonylation of Cyclopropenes.

镍催化环丙烯的不对称加氢芳氧基和加氢烷氧基羰基化。

10.BTDAzo: A Photoswitchable TRPC5 Channel Activator.

BTDAzo：光可切换 TRPC5 通道激活剂。

11.A SLC35C2 Transporter-Targeting Fluorescent Probe for the Selective Detection of B Lymphocytes Identified by SLC-CRISPRi and Unbiased Fluorescence Library Screening.

用于选择性检测 SLC-CRISPRi 和无偏荧光文库筛选鉴定的 B 淋巴细胞的 SLC35C2 转运蛋白靶向荧光探针。

12.Molecularly Precise, Bright, Photostable, and Biocompatible Cyanine Nanodots as Alternatives to Quantum Dots for Biomedical Applications.

分子精确、明亮、光稳定且生物相容的花青纳米点作为生物医学应用中量子点的替代品。

13.DNA-Programmable AgAuS-Primed Conductive Nanowelding Wires-Up Wet Colloids.

DNA 可编程 AgAuS 底漆导电纳米焊丝湿胶体。

14.Low-Pt NiNC-Supported PtNi Nanoalloy Oxygen Reduction Reaction Electrocatalysts—In Situ Tracking of the Atomic Alloying Process.

低 Pt NiNC 负载的 PtNi 纳米合金氧还原反应电催化剂——原子合金化过程的原位跟踪。

15.A Traceless Site-Specific Conjugation on Native Antibodies Enables Efficient One-Step Payload Assembly.

天然抗体上的无痕位点特异性缀合可实现高效的一步有效负载组装。

16.Construction of Benzocyclobutenes Enabled by Visible-Light-Induced Triplet Biradical Atom Transfer of Olefins.

通过可见光诱导烯烃三重态双自由基原子转移构建苯并环丁烯。

17.Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes.

硅烷催化水解和醇解中的氢隧道。

18.Biodegradable Ca2+ Nanomodulators Activate Pyroptosis through Mitochondrial Ca2+ Overload for Cancer Immunotherapy.

可生物降解的 Ca2+ 纳米调节剂通过线粒体 Ca2+ 超载激活细胞焦亡，用于癌症免疫治疗。

19.Zirconium-oxo Nodes of MOFs with Tunable Electronic Properties Provide Effective ⋅OH Species for Enhanced Methane Hydroxylation.

具有可调电子特性的 MOF 的锆氧节点为增强甲烷羟基化提供了有效的·OH 物种。

20.Tailoring Phase Alignment and Interfaces via Polyelectrolyte Anchoring Enables Large-Area 2D Perovskite Solar Cells.

通过聚电解质锚定调整相对准和界面可实现大面积二维钙钛矿太阳能电池。

21.A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.

9,10-二叠氮基-9,10-二硼蒽的三维无机类似物：具有反应性和稳定性的路易斯超酸性叠氮基硼烷。

22.A Chimeric Conjugate of Antibody and Programmable DNA Nanoassembly Smartly Activates T Cells for Precise Cancer Cell Targeting.

抗体和可编程 DNA 纳米组件的嵌合缀合物可智能激活 T 细胞，实现精确的癌细胞靶向。

23.An Activity-Based Fluorescent Probe for Imaging Fluctuations of Peroxynitrite (ONOO−) in the Alzheimer's Disease Brain.

一种基于活动的荧光探针，用于对阿尔茨海默病大脑中过氧亚硝酸盐 (ONOO−) 的波动进行成像。

24.Efficient Production of L-Homophenylalanine by Enzymatic-Chemical Cascade Catalysis.

通过酶化学级联催化高效生产 L-高苯丙氨酸。

25.Metal-Free PAZE-NH4X3⋅H2O Perovskite for Flexible Transparent X-ray Detection and Imaging.

无金属 PAZE-NH4X3⋅H2O 钙钛矿，用于灵活的透明 X 射线检测和成像。

26.Structural and Dynamic Analysis of Sulphur Dioxide Adsorption in a Series of Zirconium-Based Metal–Organic Frameworks.

一系列锆基金属有机框架中二氧化硫吸附的结构和动态分析。

27.Doping-Mediated Energy-Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis.

用于高效光致发光和光催化的 M@Au12 超原子（M=Pd、Pt、Rh、Ir）的掺杂介导能级工程。

28.Sulfur–Phenolate Exchange: SuFEx-Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers.

硫-酚盐交换：SuFEx 衍生的动态共价反应和 SuFEx 聚合物的降解。

29.The Rational Design and Atroposelective Synthesis of Axially Chiral C2-Arylpyrrole-Derived Amino Alcohols.

轴向手性 C2-芳基吡咯衍生氨基醇的合理设计和旋转选择性合成。

30.Nickel-Catalyzed Enantioselective Reductive Alkyl-Carbamoylation of Internal Alkenes.

镍催化内烯烃的对映选择性还原烷基氨基甲酰化。

31.Design of Three-Dimensional Covalent Organic Framework Membranes for Fast and Robust Organic Solvent Nanofiltration.

用于快速、稳健的有机溶剂纳滤的三维共价有机框架膜的设计。

32.Lysosome Interference Enabled by Proton-Driven Dynamic Assembly of DNA Nanoframeworks inside Cells.

细胞内质子驱动的 DNA 纳米框架动态组装实现溶酶体干扰。

33.Creating Frustrated Lewis Pairs in Defective Boron Carbon Nitride for Electrocatalytic Nitrogen Reduction to Ammonia.

在有缺陷的碳氮化硼中产生受阻路易斯对，用于电催化氮还原为氨。

34.Third-Generation Covalent TMP-Tag for Fast Labeling and Multiplexed Imaging of Cellular Proteins.

用于细胞蛋白质快速标记和多重成像的第三代共价 TMP 标签。

35.para-Selective Radical Trifluoromethylation of Benzamide Derivatives via Iminium Intermediates.

通过亚胺中间体对苯甲酰胺衍生物进行对位选择性自由基三氟甲基化。

36.Impact of Strain Relaxation on 2D Ruddlesden–Popper Perovskite Solar Cells.

应变弛豫对二维 Ruddlesden-Popper 钙钛矿太阳能电池的影响。

37.High-Performance Thermoelectric α-Ag9Ga1−xTe6 Compounds with Ultralow Lattice Thermal Conductivity Originating from Ag9Te2 Motifs.

源自 Ag9Te2 基序的具有超低晶格热导率的高性能热电 α-Ag9Ga1−xTe6 化合物。

38.Dual Reactivity of a Geometrically Constrained Phosphenium Cation.

几何约束磷阳离子的双重反应性。

39.Trojan Nanobacteria System for Photothermal Programmable Destruction of Deep Tumor Tissues.

用于光热可编程破坏深部肿瘤组织的特洛伊纳米细菌系统。

40.Highly Regioselective Cobalt-Catalyzed Hydroboration of Internal Alkynes.

内炔烃的高度区域选择性钴催化硼氢化反应。

41.Tug-of-War between Two Distinct Catalytic Sites Enables Fast and Selective Ring-Opening Copolymerizations.

两个不同催化位点之间的拉锯战实现了快速、选择性的开环共聚。

42.Self-Assembly of Adaptive Chiral [1]Rotaxane for Thermo-Rulable Circularly Polarized Luminescence.

用于热控圆偏振发光的自适应手性[1]轮烷的自组装。

43.Tuning Proapoptotic Activity of a Phosphoric-Acid-Tethered Tetraphenylethene by Visible-Light-Triggered Isomerization and Switchable Protein Interactions for Cancer Therapy.

通过可见光触发的异构化和可切换的蛋白质相互作用来调节磷酸束缚的四苯乙烯的促凋亡活性，用于癌症治疗。

44.Consequences of Noncovalent Interfacial Contacts between Nanoparticles and Giant Vesicles.

纳米颗粒和巨型囊泡之间非共价界面接触的后果。

45.Phenacyl Bromide as a Single-Component Photoinitiator: Photoinduced Step-Growth Polymerization of N-Methylpyrrole and N-Methylindole.

苯甲酰溴作为单组分光引发剂：N-甲基吡咯和 N-甲基吲哚的光诱导逐步生长聚合。

46.A General and Efficient Solution to Monofluoroalkylation: Divergent Synthesis of Aliphatic Monofluorides with Modular Synthetic Scaffolds.

单氟烷基化的通用且有效的解决方案：使用模块化合成支架的脂肪族单氟化物的发散合成。

47.Over 70 % Faradaic Efficiency for CO2 Electroreduction to Ethanol Enabled by Potassium Dopant-Tuned Interaction between Copper Sites and Intermediates.

通过钾掺杂剂调节铜位点和中间体之间的相互作用，CO2 电还原为乙醇的法拉第效率超过 70%。

48.Atomically Dispersed Pentacoordinated-Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction.

用于氧还原反应的具有轴向氧配体的原子分散五配位锆催化剂。

49.Directed Dehydration as Synthetic Tool for Generation of a New Na4SnS4 Polymorph: Crystal Structure, Na+ Conductivity, and Influence of Sb-Substitution.

定向脱水作为生成新 Na4SnS4 多晶型物的合成工具：晶体结构、Na+ 电导率和 Sb 取代的影响。

50.An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.

控制硝基芳烃加氢网络的自适应铑催化剂。

51.Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes.

一对钴 (III) 末端亚氨基/亚胺基配合物中的 Umpolung。

52.In Operando Visualization and Dynamic Manipulation of Electrochemical Processes at the Electrode–Solution Interface.

电极-溶液界面电化学过程的操作可视化和动态操纵。

53.Mass Spectrometry Detection and Imaging of a Non-Covalent Protein–Drug Complex in Tissue from Orally Dosed Rats.

口服给药大鼠组织中非共价蛋白质-药物复合物的质谱检测和成像。

54.Drug Repurposing by Siderophore Conjugation: Synthesis and Biological Evaluation of Siderophore-Methotrexate Conjugates as Antibiotics.

通过铁载体结合物重新利用药物：铁载体-甲氨蝶呤结合物作为抗生素的合成和生物学评价。

55.Topochemical, Single-Crystal-to-Single-Crystal [2+2] Photocycloadditions Driven by Chalcogen-Bonding Interactions.

由硫属键相互作用驱动的拓扑化学、单晶到单晶 [2+2] 光环加成。

56.A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate.

具有隔离活性位点的稳定导电共价有机框架，用于二氧化碳高选择性电还原为乙酸。

57.Stereodivergent Construction of 1,4-Nonadjacent Stereocenters via Hydroalkylation of Racemic Allylic Alcohols Enabled by Copper/Ruthenium Relay Catalysis.

通过铜/钌中继催化外消旋烯丙醇的加氢烷基化来立体发散构建 1,4-不相邻立体中心。

58.PEG-Functionalized Hollow Multishelled Structures with On-Off Switch and Rate-Regulation for Controllable Antimicrobial Release.

具有开关和速率调节功能的 PEG 功能化中空多壳结构，可实现可控抗菌剂释放。

59.H2O2-Responsive NIR-II AIE Nanobomb for Carbon Monoxide Boosting Low-Temperature Photothermal Therapy.

H2O2 响应式 NIR-II AIE 纳米炸弹，用于一氧化碳促进低温光热疗法。

60.Methyl Substitution Destabilizes Alkyl Radicals.

甲基取代会破坏烷基自由基的稳定性。

61.High-Performance Lithium–Oxygen Batteries Using a Urea-Based Electrolyte with Kinetically Favorable One-Electron Li2O2 Oxidation Pathways.

使用尿素基电解质的高性能锂氧电池，具有动力学上有利的单电子 Li2O2 氧化途径。

62.A Mechanochemical, Catalyst-Free Cascade Synthesis of 1,3-Diols and 1,4-Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents.

使用苯乙烯和高价碘试剂机械化学、无催化剂级联合成 1,3-二醇和 1,4-碘醇。

63.Dearomative Ring Expansion of Polycyclic Arenes.

多环芳烃的脱芳香扩环。

64.Synergy of Weakly-Solvated Electrolyte and Optimized Interphase Enables Graphite Anode Charge at Low Temperature.

弱溶剂化电解质和优化界面的协同作用使石墨阳极能够在低温下充电。

65.Polyzwitterionic Hydrogels for Highly Efficient High Salinity Solar Desalination.

用于高效高盐度太阳能海水淡化的聚两性离子水凝胶。

66.Additive-Triggered Polar Polymorph Formation: β-Sc(IO3)3, a Promising Next-Generation Mid-Infrared Nonlinear Optical Material.

加法触发极性多晶型物形成：β-Sc(IO3)3，一种有前途的下一代中红外非线性光学材料。

67.Work-function-induced Interfacial Built-in Electric Fields in Os-OsSe2 Heterostructures for Active Acidic and Alkaline Hydrogen Evolution.

用于活性酸性和碱性析氢的 Os-OsSe2 异质结构中功函数诱导的界面内置电场。

68.(4+3) Annulation of Donor-Acceptor Cyclopropanes and Azadienes: Highly Stereoselective Synthesis of Azepanones.

供体-受体环丙烷和氮二烯的(4+3)环化：氮杂环庚酮的高度立体选择性合成。

69.Au20(tBu3P)8: A Highly Symmetric Metalloid Gold Cluster in Oxidation State 0.

Au20(tBu3P)8：氧化态 0 的高度对称非金属金簇。

70.Stable Two-Legged Parent Piano-Stool and Mixed Diborabenzene-E4 (E=P, As) Sandwich Complexes of Group 8.

稳定的双足母琴凳和第 8 族混合二硼苯-E4（E=P，As）夹心配合物。

71.Solvent-Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium-Zinc Bond.

镓锌键上 H2 的溶剂依赖性氧化加成和还原消除。

72.Crystal Structure Based Mutagenesis of Cattleyene Synthase Leads to the Generation of Rearranged Polycyclic Diterpenes.

基于晶体结构的 Cattleyene 合酶诱变导致重排多环二萜的产生。

73.A linker scissoring strategy to control the shape of metal–organic framework (MOF) nanoparticles from nanoplates to nanorods by surface conformational pairing is reported by Hong-Cai Zhou, Zhi-Yuan Gu et al. in their Research Article (e202207786). Both structure and shape influence the separation ability of MOF stationary phases in gas chromatography by affecting the thermodynamic and kinetic diffusion factors.

Hong-Cai Zhou、Zhi-Yuan Gu 等人在他们的研究文章（e202207786）中报道了一种通过表面构象配对来控制从纳米板到纳米棒的金属有机框架 (MOF) 纳米颗粒形状的连接器剪切策略。结构和形状都通过影响热力学和动力学扩散因子来影响气相色谱中 MOF 固定相的分离能力。

74.Bioremediation. The discovery of MG8, an efficient polyethylene terephthalate (PET) hydrolase enzyme from the human saliva metagenome, is reported by Worawan Bhanthumnavin, Chayasith Uttamapinant et al. in their Research Article (e202203061). Aside from its plastic degradation capability, MG8 was further engineered via genetic code expansion into a covalent binder of PET plastic and can be used to attach protein payloads to PET and other polyesters.

生物修复。 Worawan Bhanthumnavin、Chayasith Uttamapinant 等人在他们的研究文章（e202203061）中报道了从人类唾液宏基因组中发现的一种高效聚对苯二甲酸乙二醇酯 (PET) 水解酶 MG8。除了其塑料降解能力外，MG8还通过遗传密码扩展进一步设计为PET塑料的共价粘合剂，可用于将蛋白质有效负载附着到PET和其他聚酯上。

75.The site-selective functionalization of carboranes with multiple B−H sites is a long-standing challenge. In their Research Article (e202205672), Deshuang Tu, Changsheng Lu, Hong Yan, and co-workers developed an efficient reaction protocol for the selective alkylation, alkenylation, and heteroarylation of carboranes under mild conditions via boron-vertex-centered carboranyl radicals generated by photo-induced decarboxylation of boron-substituted carborane carboxylic acids.

具有多个 B−H 位点的碳硼烷的位点选择性官能化是一个长期存在的挑战。在他们的研究文章（e202205672）中，Deshuang Tu、Changsheng Lu、Hong Yan 及其同事开发了一种有效的反应方案，通过由以下物质产生的以硼顶点为中心的碳硼烷基自由基，在温和条件下对碳硼烷进行选择性烷基化、烯基化和杂芳基化：硼取代的碳硼烷羧酸的光诱导脱羧。

76.A universal dual photoredox catalysis platform based on metal–organic polymers synergistically constructed with triphenylpyrylium-mimicking ligands and reductive metal ions is reported by Yunhe Jin, Chunying Duan, and co-workers in their Research Article (e202204918). This strategy enables the integration of photoinduced electron transfer and ligand-to-metal charge transfer events for enhanced efficiency in photocatalytic organic couplings and molecular oxygen activation.

Yunhe Jin、Chunying Duan 及其同事在他们的研究文章 (e202204918) 中报道了一种基于金属有机聚合物的通用双光氧化还原催化平台，该平台由模拟三苯基吡喃鎓配体和还原性金属离子协同构建。该策略能够整合光诱导电子转移和配体到金属的电荷转移事件，从而提高光催化有机偶联和分子氧活化的效率。

77.Nonlinear Optics. In their Communication (e202208168), Mark G. Humphrey et al. report photo-stable materials with three-photon absorption cross-sections based on organometallic donors covalently attached to an s-heptazine acceptor.

非线性光学。在他们的通讯 (e202208168) 中，Mark G. Humphrey 等人。报告了基于共价连接到 s-庚嗪受体的有机金属供体的具有三光子吸收截面的光稳定材料。

78.Desalination Materials. A scalable MoS2-based hydrogel for highly efficient solar desalination through enhanced solar evaporation is reported in the Research Article (e202208587) by Baoling Yuan, Ming-Lai Fu et al.

海水淡化材料。 Baoling Yuan、Ming-Lai Fu 等人在研究文章 (e202208587) 中报道了一种可扩展的 MoS2 基水凝胶，可通过增强太阳能蒸发实现高效太阳能海水淡化。

79.Enabling Sustainable Chemistry with Ionic Liquids and Deep Eutectic Solvents: A Fad or the Future?.

使用离子液体和低共熔溶剂实现可持续化学：时尚还是未来？。

80.Enhanced Solar Evaporation Using a Scalable MoS2-Based Hydrogel for Highly Efficient Solar Desalination.

使用可扩展的 MoS2 水凝胶增强太阳能蒸发，实现高效太阳能海水淡化。

81.Two-Dimensional Organic Supramolecule via Hydrogen Bonding and π–π Stacking for Ultrahigh Capacity and Long-Life Aqueous Zinc–Organic Batteries.

通过氢键和π-π堆积形成二维有机超分子，用于超高容量和长寿命水系锌有机电池。

82.Discovery and Genetic Code Expansion of a Polyethylene Terephthalate (PET) Hydrolase from the Human Saliva Metagenome for the Degradation and Bio-Functionalization of PET.

来自人类唾液宏基因组的聚对苯二甲酸乙二醇酯 (PET) 水解酶的发现和遗传密码扩展，用于 PET 的降解和生物功能化。

83.Single-Atom Molybdenum-N3 Sites for Selective Hydrogenation of CO2 to CO.

用于 CO2 选择性加氢为 CO 的单原子钼-N3 位点。

84.Catalytic Enantioselective de novo Construction of Chiral Arenes through Desymmetrizing Oxidative [4+2]-Cycloaddition.

通过去对称氧化 [4+2]-环加成催化对映选择性从头构建手性芳烃。

85.Chromophore-Inspired Design of Pyridinium-Based Metal–Organic Polymers for Dual Photoredox Catalysis.

用于双光氧化还原催化的吡啶基金属有机聚合物的发色团启发设计。

86.Site-Selective Functionalization of Carboranes at the Electron-Rich Boron Vertex: Photocatalytic B−C Coupling via a Carboranyl Cage Radical.

碳硼烷在富电子硼顶点的位点选择性功能化：通过碳硼烷基笼自由基进行光催化 B−C 耦合。

87.Identification and Structure Analysis of an Unusual Halohydrin Dehalogenase for Highly Chemo-, Regio- and Enantioselective Bio-Nitration of Epoxides.

用于环氧化物高度化学、区域和对映选择性生物硝化的不寻常卤代醇脱卤酶的鉴定和结构分析。

88.A Specialized Polythioamide-Binding Protein Confers Antibiotic Self-Resistance in Anaerobic Bacteria.

一种特殊的聚硫酰胺结合蛋白赋予厌氧细菌抗生素自身耐药性。

89.Constructing Interfacial Boron-Nitrogen Moieties in Turbostratic Carbon for Electrochemical Hydrogen Peroxide Production.

在涡层碳中构建界面硼氮部分用于电化学过氧化氢生产。

90.Gauging Radical Stabilization with Carbenes.

用卡宾测量自由基稳定性。

91.A Ce-UiO-66 Metal–Organic Framework-Based Graphene-Embedded Photocatalyst with Controllable Activation for Solar Ammonia Fertilizer Production.

用于太阳能氨肥生产的具有可控活化作用的基于 Ce-UiO-66 金属有机框架的石墨烯嵌入光催化剂。

92.Polystyrene-based Macromolecular Ammonium Halides for Tuning Color and Exchange Kinetics of Perovskite Nanocrystals.

用于调节钙钛矿纳米晶体颜色和交换动力学的聚苯乙烯基大分子卤化铵。

93.Tuning the Anisotropic Facet of Lead Chromate Photocatalysts to Promote Spatial Charge Separation.

调节铬酸铅光催化剂的各向异性面以促进空间电荷分离。

94.From Ensemble Electrochemistry to Nano-Impact Electrochemistry: Altered Reaction Selectivity.

从整体电化学到纳米冲击电化学：改变反应选择性。

95.High-Field NMR, Reactivity, and DFT Modeling Reveal the γ-Al2O3 Surface Hydroxyl Network.

高场 NMR、反应性和 DFT 建模揭示了 γ-Al2O3 表面羟基网络。

96.A Plurizyme with Transaminase and Hydrolase Activity Catalyzes Cascade Reactions.

具有转氨酶和水解酶活性的多酶催化级联反应。

97.Solid–Liquid Interfacial Coordination Chemistry Enables High-Capacity Ammonium Storage in Amorphous Manganese Phosphate.

固液界面配位化学使无定形磷酸锰中高容量铵储存成为可能。

98.Linker Scissoring Strategy Enables Precise Shaping of Metal–Organic Frameworks for Chromatographic Separation.

连接子剪切策略可实现色谱分离金属有机框架的精确成型。

99.Cocrystallization Enabled Spatial Self-Confinement Approach to Synthesize Crystalline Porous Metal Oxide Nanosheets for Gas Sensing.

共晶空间自限制方法合成用于气体传感的结晶多孔金属氧化物纳米片。

100.Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SO2.

芳基卤化物与 SO2 的可扩展化学选择性镍电催化亚磺酰化。

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