【标题速读】【JACS】【2022年】【6月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

The cover image shows in schematic form a polyaromatic hydrocarbon expanded porphyrin hybrid system that is able to act as a ligand to complex seven zinc atoms in a post-synthetic fashion.

封面图片以示意图形式显示了一种聚芳烃膨胀卟啉杂化系统，该系统能够作为配体以合成后方式络合七个锌原子。

This cover image emphasizes the crucial roles of surface chemistry in the acquisition, avoidance, and exploitation of protein corona. One can design precision nanomedicine by chemical strategies to realize the full potential of nanomedicine for benefiting human health.

这张封面图片强调了表面化学在蛋白质冠的获取、避免和利用中的关键作用。 人们可以通过化学策略设计精密纳米医学，以充分发挥纳米医学造福人类健康的潜力。

Monolayer NiIr layered double hydroxide (NiIr-LDH) was prepared despite the large radius difference between 3d and 5d metals. The 3d−5d hybrid NiIr-LDH possesses optimized electronic structures for enhanced OER performance in the seawater splitting.

尽管 3d 和 5d 金属之间的半径差异很大，但仍制备了单层 NiIr 层状双氢氧化物 (NiIr-LDH)。 3d−5d 杂化 NiIr-LDH 具有优化的电子结构，可增强海水分解中的 OER 性能。

A comparative study was made between lattice-doping and surface-adsorbed single atoms, which created distinct interfacial structures to interact with oxygen-evolving intermediates. This work reveals the essence of electronic and steric effects for optimizing the catalytic process.

对晶格掺杂和表面吸附的单原子进行了比较研究，这产生了不同的界面结构以与放氧中间体相互作用。 这项工作揭示了优化催化过程的电子和空间效应的本质。

Morphological evolution and dynamic processes of the graphdiyne-based materials are revealed by in situ atomic force microscopy. The classical configuration of graphdiyne and well-defined N-doped graphdiyne with precise N content was fabricated to be utilized as working electrodes.

原位原子力显微镜揭示了石墨二炔基材料的形态演化和动力学过程。 石墨二炔的经典构型和具有精确 N 含量的明确定义的 N 掺杂石墨二炔被制造为用作工作电极。

Break by squeezing: activation of a hydrogen molecule in the junction of a scanning tunneling microscope can be induced by the atomic-scale confinement from squeezing the tunneling junction cavity with motion of the STM tip. A large energy barrier exists for dissociation of the hydrogen bond on a copper surface.

挤压破坏：扫描隧道显微镜连接处氢分子的激活可以通过 STM 尖端运动挤压隧道连接腔的原子级限制来诱导。 铜表面上的氢键解离存在很大的能垒。

A platform was designed using biomass-derived muconic acid to tailor Nylon 6,6 and to access materials with custom property enhancements. This platform's potential was demonstrated by synthesizing polyamides with built-in hydrophobicity and flame retardancy. A 70% reduction in water uptake and doubling of char were achieved while largely retaining key properties of the parent Nylon.

使用生物质衍生的粘康酸设计了一个平台来定制尼龙 6,6 并获取具有自定义属性增强功能的材料。 通过合成具有内置疏水性和阻燃性的聚酰胺证明了该平台的潜力。 在很大程度上保留了母体尼龙的关键特性的同时，吸水率降低了 70%，炭化量增加了一倍。

Type-II core–shell nanocrystals comprising a chiral low-dimensional perovskite shell and an achiral MAPbBr3 core were developed. Based on the chiral-induced spin selectivity (CISS) effect, the chiral shell works as a spin-filter to produce spin-polarized carriers. A spin light-emitting diode (spin-LED) was achieved under ambient conditions.

开发了包含手性低维钙钛矿壳和非手性 MAPbBr3 核的 II 型核壳纳米晶体。 基于手性诱导自旋选择性 (CISS) 效应，手性壳充当自旋过滤器以产生自旋极化载流子。 在环境条件下实现了自旋发光二极管（自旋 LED）。

DNA double strands are woven into a nanofabric structure with an interlacing pattern that is distinctively different from reported DNA nanostructures.

DNA 双链被编织成具有交错图案的纳米结构，这与报道的 DNA 纳米结构截然不同。

Complex de novo biosynthesis of sugar nucleotides from common sugars was reorganized as cascade reactions, which were driven through cofactor regeneration systems. The resultant clean conversions allowed the products to be obtained in high yields, with low preparation cost, and without the need for complicated purification manipulations.

从普通糖类复杂的糖核苷酸从头生物合成被重组为级联反应，通过辅因子再生系统驱动。 由此产生的清洁转化使产品能够以高产率、低制备成本获得，并且不需要复杂的纯化操作。

Incorporating a pH-sensitive station and a photoactive recognition site in a [2]rotaxane provides access to a light-powered molecular machine that operates through a closed reaction network. Therein, a catalytic photoinduced proton transfer enables reversible ring shuttling, triggering autonomous dissipative operation.

在 [2] 轮烷中加入 pH 敏感站和光活性识别位点，可以访问通过封闭反应网络运行的光动力分子机器。 其中，催化光诱导质子转移可实现可逆环穿梭，触发自主耗散操作。

Tetranuclear Cu(I)–pyrazolate macrocycles can produce solid-state emissions at yellow, green, or deep-blue wavelengths by virtue of a remote steric effect. The conformational behavior of substituents on the pyrazole ligands can impose a rigidochromic effect on the copper core, whose phosphorescence is mediated primarily through a cluster-centered triplet state.

四核 Cu(I)-pyrazolate 大环化合物可以凭借远程空间效应在黄色、绿色或深蓝色波长下产生固态发射。 吡唑配体上取代基的构象行为可以对铜核施加刚性变色效应，其磷光主要通过以簇为中心的三重态介导。

An innovative spark discharge plasma-enabled N2 oxidation–electroreduction system is presented for efficient/renewable NH3 synthesis, which achieves a high NH3 yield rate of ~40 nmol s–1 cm–2 over Cu nanoparticles. The plasma-enabled activation and recombination processes of N2 and O2 molecules, as well as the microscopic-level mechanism of NOx– electroreduction, are investigated and decoupled by in situ spectroscopy techniques in detail.

提出了一种创新的火花放电等离子体启用的 N2 氧化-电还原系统，用于高效/可再生 NH3 合成，在 Cu 纳米粒子上实现了约 40 nmol s-1 cm-2 的高 NH3 产率。 通过原位光谱技术详细研究和解耦了 N2 和 O2 分子的等离子体激活和重组过程，以及 NOx 电还原的微观机制。

Porous organic cage (i.e., CC3) membranes with hierarchical channels composed of discrete internal cavities and cage-aligned external cavities connected by sub-nanometer-sized windows, showing a high ion permselectivity with a monovalent ion flux of 1.0 mol m−2 h−1 and mono-/divalent ion selectivity (e.g., K+/Mg2+) up to 103.

多孔有机笼（即 CC3）膜具有分层通道，由离散的内腔和笼对齐的外腔组成，由亚纳米尺寸的窗口连接，显示出高离子选择性渗透率，单价离子通量为 1.0 mol m−2 h− 1 和高达 103 的单价/二价离子选择性（例如 K+/Mg2+）。

The on-surface reaction pathway of terminal alkynes was successfully steered from C–C coupling to C–H activation with high selectivity at different status by introducing O2. The catalytic performance and reaction mechanisms of the oxygen species involved were also clarified in this study.

通过引入 O2，末端炔烃的表面反应途径成功地从 C-C 偶联转向 C-H 活化，在不同状态下具有高选择性。 本研究还阐明了所涉及的氧物种的催化性能和反应机制。

A novel photoinduced fluorescent cross-link between aromatic side chains in proteins is generated by a single fluorine atom on a side chain indole. The cover portrays the atomic-resolution NMR structure of the Trp-Phe cross-linked CypA protein. This unprecedented finding suggests a controllable approach for exploiting aromatic cross-links in proteins and developing fluorescence probes.

蛋白质中芳香侧链之间的新型光诱导荧光交联是由侧链吲哚上的单个氟原子产生的。 封面描绘了 Trp-Phe 交联 CypA 蛋白的原子分辨率 NMR 结构。 这一前所未有的发现提出了一种可控的方法来利用蛋白质中的芳香族交联和开发荧光探针。

Sterically hindered Lewis acid ("B" center) and Lewis base ("N" center) sites were anchored within the rigid lattice of highly crystalline hexagonal boron nitride (h-BN) scaffolds via precision defect regulation. The as-afforded h-BN scaffolds achieved highly efficient H2/D2 activation and dissociation under ambient pressure via Frustrated Lewis Pair-like behavior.

空间位阻路易斯酸（“B”中心）和路易斯碱（“N”中心）位点通过精确缺陷调节固定在高结晶六方氮化硼 (h-BN) 支架的刚性晶格内。 所提供的 h-BN 支架通过 Frustrated Lewis Pair-like 行为在环境压力下实现了高效的 H2/D2 激活和解离。

Aerobic N2-fixing bacteria, Azotobacter vinelandii, produce NH3 using light when colloidal quantum dots are inside the cells. Culturing A. vinelandii in the presence of quantum dots enables the efficient cellular uptake of quantum dots via an energy-dependent pathway.

当胶体量子点位于细胞内时，好氧固氮细菌 Azotobacter vinelandii 会利用光产生 NH3。 在存在量子点的情况下培养 A. vinelandii 可以通过能量依赖性途径有效地吸收量子点。

Aggregation-enhanced singlet oxygen generation occurs by the irradiation of nanoparticles containing fuchsonarene chromophores encrypted by a macrocyclic scaffold. These organic nanoparticles have been applied in vitro, leading to effective cellular uptake and photoinduced cell death.

通过辐照含有由大环支架加密的品红芳烃发色团的纳米粒子，会产生聚集增强的单线态氧。 这些有机纳米粒子已在体外应用，导致有效的细胞摄取和光诱导细胞死亡。

We revealed a common dimension character of the fibrous structures of both Gerris legs and Argyroneta abdomens, featured as the conical topology and micrometer scaled cylindrical diameter. Following this dimension character, we developed a bioinspired micrometer scaled conical fiber array with robust water repellency in high humidity.

我们揭示了 Gerris 腿和 Argyroneta 腹部纤维结构的共同尺寸特征，以圆锥形拓扑结构和微米级圆柱直径为特征。 遵循这一维度特征，我们开发了一种受生物启发的微米级锥形纤维阵列，在高湿度下具有强大的防水性。

A combined computational and experimental study reveals that, contrary to previously hypothesized enantioinduction mechanisms, the radical rebound step is enantioselectivity-determining under the Curtin–Hammett conditions, whereas the preceding HAT step is only moderately stereoselective. This study highlights an unusual enantioinduction mechanism in metalloenzyme-catalyzed asymmetric transformations involving radical intermediates.

一项结合计算和实验的研究表明，与先前假设的对映诱导机制相反，自由基回弹步骤在 Curtin-Hammett 条件下是对映选择性决定的，而前面的 HAT 步骤仅具有适度的立体选择性。 这项研究强调了金属酶催化的涉及自由基中间体的不对称转化中不寻常的对映体诱导机制。

Three-dimensional hollow Ru colloidosomes were synthesized via a one-pot gas/liquid interface self-assembly strategy. The Ru colloidosomes as catalyst exhibit remarkable HOR catalytic activity.

通过一锅气/液界面自组装策略合成了三维空心 Ru 胶体。 Ru胶体作为催化剂表现出显着的HOR催化活性。

The charge transport of p-type organic semiconductors is known to occur via the electronic couplings of HOMO. We demonstrate that the electronic couplings of HOMO, second HOMO, and third HOMO all contribute to the formation of the valence band structures and charge transport of the thienopyrazine-containing R–BNTP π-electron system.

已知 p 型有机半导体的电荷传输是通过 HOMO 的电子耦合发生的。 我们证明了 HOMO、第二 HOMO 和第三 HOMO 的电子耦合都有助于价带结构的形成和含噻吩并吡嗪的 R-BNTP π 电子系统的电荷传输。

A robust anion concentration gradient-assisted solid-electrolyte interphase was constructed using an in situ chemical reaction of sulfonic acid polymer and zinc metal to enable the long-term stable cycling of the zinc electrode and recharged zinc metal batteries, which is visually illustrated in the cover art.

利用磺酸聚合物和锌金属的原位化学反应构建了一种稳健的阴离子浓度梯度辅助固体电解质界面，使锌电极和充电锌金属电池能够长期稳定循环，如图所示 封面艺术。

Rapid, cost-effective, and widely available diagnostics are needed to monitor and mitigate the spread of SARS-CoV-2 and future outbreaks. An engineered antibody–enzyme fusion protein (blue) recognizes human antibodies (red) and catalyzes the conversion of sucrose (pink) to glucose (magenta), allowing quantification of antibodies against disease antigens (yellow) using commercial glucometers.

需要快速、经济高效且广泛可用的诊断方法来监测和减轻 SARS-CoV-2 的传播和未来的爆发。 一种工程抗体-酶融合蛋白（蓝色）识别人类抗体（红色）并催化蔗糖（粉色）转化为葡萄糖（品红色），从而允许使用商用血糖仪对针对疾病抗原（黄色）的抗体进行定量。

1.Chemical and Biophysical Signatures of the Protein Corona in Nanomedicine.

纳米医学中蛋白质冠的化学和生物物理特征。

2.Multi-active Site Dynamics on a Molecular Cr/Co/Se Cluster Catalyst.

分子 Cr/Co/Se 团簇催化剂上的多活性位点动力学。

3.Pyrene-Bridged Expanded Carbaporphyrin Nanobelts.

芘桥接扩展碳卟啉纳米带。

4.Crystal Structure and Stability in Aqueous Solutions of Na0.5[NpO2(OH)1.5]·0.5H2O and Na[NpO2(OH)2].

Na0.5[NpO2(OH)1.5]·0.5H2O 和 Na[NpO2(OH)2] 水溶液中的晶体结构和稳定性。

5.Catalytic Enantioselective Synthesis of γ-Lactams with β-Quaternary Centers via Merging of C–C Activation and Sulfonyl Radical Migration.

通过合并 C-C 活化和磺酰基自由基迁移催化对映选择性合成具有 β-季中心的 γ-内酰胺。

6.Fast Photoswitchable Molecular Prosthetics Control Neuronal Activity in the Cochlea.

快速光开关分子假体控制耳蜗中的神经元活动。

7.Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid.

洞察碘新粒子形成的化学：碘氧化物的作用和碘酸的来源。

8.Monolayer NiIr-Layered Double Hydroxide as a Long-Lived Efficient Oxygen Evolution Catalyst for Seawater Splitting.

单层 NiIr-层状双氢氧化物作为海水分解的长寿命高效析氧催化剂。

9.Aptamer-Induced-Dimerization Strategy Attenuates AβO Toxicity through Modulating the Trophic Activity of PrPC Signaling.

适体诱导二聚化策略通过调节 PrPC 信号转导的营养活动减弱 AβO 毒性。

10.Tuning the Electronic and Steric Interaction at the Atomic Interface for Enhanced Oxygen Evolution.

调整原子界面处的电子和空间相互作用以增强氧气释放。

11.Metal–Organic Framework-Derived Graphene Mesh: a Robust Scaffold for Highly Exposed Fe–N4 Active Sites toward an Excellent Oxygen Reduction Catalyst in Acid Media.

金属-有机骨架衍生的石墨烯网状结构：一种坚固的支架，可用于高度暴露的 Fe-N4 活性位点，从而在酸性介质中实现出色的氧还原催化剂。

12.High CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer.

通过构建氧化物阻挡层制备高 CO 耐受性 Ru 基催化剂。

13.Suppressing Immune Responses Using Siglec Ligand-Decorated Anti-receptor Antibodies.

使用 Siglec 配体修饰的抗受体抗体抑制免疫反应。

14.In Situ Self-Sorting Peptide Assemblies in Living Cells for Simultaneous Organelle Targeting.

用于同时细胞器靶向的活细胞中的原位自分类肽组装。

15.Acid Catalysis over Low-Silica Faujasite Zeolites.

低硅八面沸石上的酸催化。

16.Direct Observation of the Dynamics of Ylide Solvation by Hydrogen-bond Donors Using Time-Resolved Infrared Spectroscopy.

使用时间分辨红外光谱法直接观察氢键供体对叶立德溶剂化的动力学。

17.“Capture-Backdonation-Recapture” Mechanism for Promoting N2 Reduction by Heteronuclear Metal-Free Double-Atom Catalysts.

“捕获-反捐赠-再捕获”机制。

18.Interfacial Evolution of the Solid Electrolyte Interphase and Lithium Deposition in Graphdiyne-Based Lithium-Ion Batteries.

石墨烯基锂离子电池中固体电解质界面的界面演化和锂沉积。

19.Sea Urchin Polyketide Synthase SpPks1 Produces the Naphthalene Precursor to Echinoderm Pigments.

海胆聚酮合酶 SpPks1 生产棘皮动物色素的萘前体。

20.Biosynthesis of Guanitoxin Enables Global Environmental Detection in Freshwater Cyanobacteria.

鸟毒素的生物合成使淡水蓝细菌的全球环境检测成为可能。

21.Helically Chiral Hybrid Cyclodextrin Metal–Organic Framework Exhibiting Circularly Polarized Luminescence.

表现出圆偏振发光的螺旋手性杂化环糊精金属-有机骨架。

22.Connecting Molecular and Supramolecular Shapeshifting by the Ostwald’s Nucleation Stages of a Star Giant Molecule.

通过星巨分子的奥斯特瓦尔德成核阶段连接分子和超分子变形。

23.Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction.

自组装脂质体增强电子转移以实现有效的光催化 CO2 还原。

24.Versatile Palladium-Catalyzed Approach to Acyl Fluorides and Carbonylations by Combining Visible Light- and Ligand-Driven Operations.

通过结合可见光和配体驱动的操作，多功能钯催化酰基氟化物和羰基化方法。

25.Surface and Bulk Chemistry of Mechanochemically Synthesized Tohdite Nanoparticles.

机械化学合成 Tohdite 纳米粒子的表面和本体化学。

26.A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode.

一种基于芘-4,5,9,10-四酮的共价有机骨架提供高比容量作为锂离子正极。

27.Living Cell Nanoporation and Exosomal RNA Analysis Platform for Real-Time Assessment of Cellular Therapies.

用于实时评估细胞疗法的活细胞纳米孔和外泌体 RNA 分析平台。

28.A Kinetic Isotope Effect in the Formation of Lanthanide Phosphate Nanocrystals.

镧系磷酸盐纳米晶体形成中的动力学同位素效应。

29.Radiotherapy Reduces N-Oxides for Prodrug Activation in Tumors.

放疗减少肿瘤中前体药物激活的 N-氧化物。

30.Transient Host–Guest Complexation To Control Catalytic Activity.

控制催化活性的瞬态主客体络合。

31.One Porphyrin Per Chain Self-Assembled Helical Ion-Exchange Channels for Ultrahigh Osmotic Energy Conversion.

用于超高渗透能量转换的每链一个卟啉自组装螺旋离子交换通道。

32.Scaling Up Multi-bit DNA Full Adder Circuits with Minimal Strand Displacement Reactions.

用最小链置换反应放大多位 DNA 全加器电路。

33.Phenyl Sulfones: A Route to a Diverse Family of Trisubstituted Cyclohexenes from Three Independent Nucleophilic Additions.

苯基砜：通过三个独立的亲核加成反应形成不同家族的三取代环己烯的途径。

34.Ionic Dopant-Free Polymer Alloy Hole Transport Materials for High-Performance Perovskite Solar Cells.

用于高性能钙钛矿太阳能电池的无离子掺杂聚合物合金空穴传输材料。

35.Diffuse Ions Coordinate Dynamics in a Ribonucleoprotein Assembly.

核糖核蛋白组装中的扩散离子协调动力学。

36.Structure and Magnetism of Iron- and Chromium-Intercalated Niobium and Tantalum Disulfides.

铁和铬插层铌和二硫化钽的结构和磁性。

37.Anticancer Agent with Inexplicable Potency in Extreme Hypoxia: Characterizing a Light-Triggered Ruthenium Ubertoxin.

在极度缺氧条件下具有无法解释的效力的抗癌剂：表征光触发的钌 Ubertoxin。

38.Bioenabled Platform to Access Polyamides with Built-In Target Properties.

用于访问具有内置目标属性的聚酰胺的生物启用平台。

39.Diaryl Ether Formation by a Versatile Thioesterase Domain.

多功能硫酯酶结构域形成二芳基醚。

40.Mimicking DNA Periodic Docking Grooves for Adaptive Identification of l-/d-Tryptophan in a Biological Metal–Organic Framework.

模拟 DNA 周期性对接槽以适应性识别生物金属-有机框架中的 l-/d-色氨酸。

41.Asymmetric Formal Nucleophilic o-Cresolylation with Morita–Baylis–Hillman Carbonates of 2-Cyclohexenones via Palladium Catalysis.

通过钯催化与 2-环己酮的 Morita-Baylis-Hillman 碳酸盐的不对称形式亲核 o-Cresolylation。

42.Site-Specific and Degree-Controlled Alkyl Deuteration via Cu-Catalyzed Redox-Neutral Deacylation.

通过 Cu 催化的氧化还原中性脱酰作用进行位点特异性和程度可控的烷基氘化。

43.Core–Shell Covalently Linked Graphitic Carbon Nitride–Melamine–Resorcinol–Formaldehyde Microsphere Polymers for Efficient Photocatalytic CO2 Reduction to Methanol.

核-壳共价连接的石墨化碳氮化物-三聚氰胺-间苯二酚-甲醛微球聚合物，用于高效光催化 CO2 还原为甲醇。

44.Mechanistic Studies Yield Improved Protocols for Base-Catalyzed Anti-Markovnikov Alcohol Addition Reactions.

机理研究改进了碱催化的反马尔可夫尼科夫醇加成反应的方案。

45.Ionic Conductivity of Nanocrystalline and Amorphous Li10GeP2S12: The Detrimental Impact of Local Disorder on Ion Transport.

纳米晶和非晶 Li10GeP2S12 的离子电导率：局部紊乱对离子传输的不利影响。

46.Trimer-to-Monomer Disruption Mechanism for a Potent, Protease-Resistant Antagonist of Tumor Necrosis Factor-α Signaling.

肿瘤坏死因子-α 信号转导的有效、耐蛋白酶拮抗剂的三聚体到单体的破坏机制。

47.Confinement-Induced Catalytic Dissociation of Hydrogen Molecules in a Scanning Tunneling Microscope.

扫描隧道显微镜中氢分子的限制诱导催化解离。

48.Asymmetric Hydrophosphonylation of Imines to Construct Highly Stable Covalent Organic Frameworks with Efficient Intrinsic Proton Conductivity.

亚胺的不对称氢膦酰化以构建具有高效本征质子传导率的高度稳定的共价有机骨架。

49.Biosynthesis of Argolaphos Illuminates the Unusual Biochemical Origins of Aminomethylphosphonate and Nε-Hydroxyarginine Containing Natural Products.

Argolaphos 的生物合成阐明了含有氨基甲基膦酸盐和 Nε-羟基精氨酸的天然产物的不寻常生化起源。

50.Laser-Triggered Bottom-Up Transcription of Chemical Information: Toward Patterned Graphene/MoS2 Heterostructures.

化学信息的激光触发自下而上转录：走向图案化石墨烯/MoS2 异质结构。

51.Water-Splitting Artificial Leaf Based on a Triple-Junction Silicon Solar Cell: One-Step Fabrication through Photoinduced Deposition of Catalysts and Electrochemical Operando Monitoring.

基于三结硅太阳能电池的水分解人造叶：通过光诱导沉积催化剂和电化学操作监测一步法制造。

52.Quasi-Covalently Coupled Ni–Cu Atomic Pair for Synergistic Electroreduction of CO2.

用于 CO2 协同电还原的准共价耦合 Ni-Cu 原子对。

53.High Gravimetric and Volumetric Ammonia Capacities in Robust Metal–Organic Frameworks Prepared via Double Postsynthetic Modification.

通过双重合成后修饰制备的稳健金属有机框架中的高重量和体积氨容量。

54.Water-Assisted Proton Transfer in the Sequential Hydration of Benzonitrile Radical Cation C6H5CN•+(H2O)n: Transition to Hydrated Distonic Cation •C6H4CNH+(H2O)n with n ≥ 4.

苯腈自由基阳离子 C6H5CN 顺序水合中的水辅助质子转移• +(H2O)n：转变为水合异质子阳离子• C6H4CNH+(H2O)n，n ≥ 4。

55.Voltage-Gated Electrocatalysis of Efficient and Selective Methane Oxidation by Tricopper Clusters under Ambient Conditions.

环境条件下三铜簇高效选择性甲烷氧化的电压门控电催化。

56.Core–Shell Three-Dimensional Perovskite Nanocrystals with Chiral-Induced Spin Selectivity for Room-Temperature Spin Light-Emitting Diodes.

用于室温自旋发光二极管的具有手性诱导自旋选择性的核壳三维钙钛矿纳米晶体。

57.Anaerobic Hydroxyproline Degradation Involving C–N Cleavage by a Glycyl Radical Enzyme.

涉及甘氨酰自由基酶 C-N 裂解的厌氧羟脯氨酸降解。

58.Homeostasis inside Single Activated Phagolysosomes: Quantitative and Selective Measurements of Submillisecond Dynamics of Reactive Oxygen and Nitrogen Species Production with a Nanoelectrochemical Sensor.

单活化吞噬溶酶体内的稳态：使用纳米电化学传感器对活性氧和氮物质产生的亚毫秒动力学进行定量和选择性测量。

59.Rate Controlling in Low-Temperature Standard NH3-SCR: Implications from Operando EPR Spectroscopy and Reaction Kinetics.

低温标准 NH3-SCR 中的速率控制：Operando EPR 光谱学和反应动力学的启示。

60.Stress in DNA Gridiron Facilitates the Formation of Two-Dimensional Crystalline Structures.

DNA Gridiron 中的应力促进二维晶体结构的形成。

61.Oxygen Reduction Reaction in Alkaline Media Causes Iron Leaching from Fe–N–C Electrocatalysts.

碱性介质中的氧还原反应导致铁从 Fe-N-C 电催化剂中浸出。

62.Carbene Complexes of Neptunium.

镎的卡宾络合物。

63.Chirality-Controlled Supramolecular Donor–Acceptor Copolymerization with Distinct Energy Transfer Efficiency.

具有不同能量转移效率的手性控制的超分子供体-受体共聚。

64.A Class of Magnetic Topological Material Candidates with Hypervalent Bi Chains.

一类具有超价双链的磁性拓扑材料候选者。

65.Time-Resolved Imaging of Stochastic Cascade Reactions over a Submillisecond to Second Time Range at the Angstrom Level.

在埃级别亚毫秒到秒时间范围内随机级联反应的时间分辨成像。

66.Anion π–π Stacking for Improved Lithium Transport in Polymer Electrolytes.

阴离子 π–π 堆叠以改善聚合物电解质中的锂传输。

67.Ultrafast Visible-Light-Induced ATRP in Aqueous Media with Carbon Quantum Dots as the Catalyst and Its Application for 3D Printing.

以碳量子点为催化剂的水介质中超快可见光诱导 ATRP 及其在 3D 打印中的应用。

68.Covalent Organic Frameworks with Irreversible Linkages via Reductive Cyclization of Imines.

通过亚胺的还原环化形成具有不可逆连接的共价有机框架。

69.Direct Detection of Lithium Exchange across the Solid Electrolyte Interphase by 7Li Chemical Exchange Saturation Transfer.

通过 7Li 化学交换饱和转移直接检测固体电解质界面的锂交换。

70.Light-Driven Molecular Whirligig.

光驱动分子旋转。

71.Copper(III) Metallacyclopentadienes via Zirconocene Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene.

铜 (III) 金属环戊二烯通过锆茂转移和还原消除生成可分离的菲环丁二烯。

72.Cobalt(III) Carbene Complex with an Electronic Excited-State Structure Similar to Cyclometalated Iridium(III) Compounds.

具有类似于环金属化铱 (III) 化合物的电子激发态结构的钴 (III) 卡宾络合物。

73.Controlling One- or Two-Electron Oxidation for Selective Amine Functionalization by Alternating Current Frequency.

通过交流频率控制选择性胺功能化的单电子或双电子氧化。

74.A Series of Soluble Thieno-Fused Coronene Nanoribbons of Precise Lengths.

一系列精确长度的可溶性噻吩并稠合晕烯纳米带。

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