【标题速读】【Angew】【2022年】【11月】

2023-08-19 15:47 作者:Rt_Cola 0人读过 | 我要投稿

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

1.A chiral Lewis acid catalysed asymmetric [2+2] cycloaddition reaction of allenyl imide and alkenes was developed by Xiaohua Liu, Xiaoming Feng et al. in their Research Article (e202211596). This protocol provided a series of axially chiral cyclobutenes in high yields with excellent enantioselectivities. A stepwise mechanism was proposed based on experimental studies and DFT calculations, and π–π stacking interactions were identified as crucial for the enantioselectivity.

刘晓华、冯晓明等人开发了一种手性路易斯酸催化的丙二烯酰亚胺与烯烃的不对称[2+2]环加成反应。在他们的研究文章（e202211596）中。该方案以高产率提供了一系列具有优异对映选择性的轴向手性环丁烯。基于实验研究和 DFT 计算提出了逐步机制，并且 π-π 堆积相互作用被认为对于对映选择性至关重要。

2.Zinc ion batteries (ZIBs) face several challenges, such as unstable Zn anodes and a low Zn ion transference number. A unique anion-trap strategy based on the host–guest interaction between β-CD and anions is proposed by Chunyi Zhi, Wenjie Mai, and co-workers in their Research Article (e202210979) to greatly improve the overall performance in terms of both capacity and stability of ZIBs via promoting the Zn ion transfer ability and assisting the formation of reorientated dominant Zn(002) facets on the Zn anode.

锌离子电池（ZIB）面临着一些挑战，例如不稳定的锌阳极和低锌离子迁移数。 Chunyizhi、WenjieMai 及其同事在他们的研究文章 (e202210979) 中提出了一种基于 β-CD 和阴离子之间的主客体相互作用的独特阴离子捕获策略，可大大提高两种容量的整体性能通过促进 Zn 离子转移能力并协助在 Zn 阳极上形成重新取向的主要 Zn(002) 面来提高 ZIB 的稳定性。

3.The precise co-conformation regulation of topologically chiral [2]catenanes under two different external stimuli led to the construction of a bidirectional circularly polarized luminescence (CPL) switch, as reported by Xiao He, Wei Wang, Hai-Bo Yang, and co-workers in their Research Article (e202210542). The results provide not only an attractive approach towards the construction of multistate CPL switches for practical uses but also a promising platform for the construction of novel chiral materials.

拓扑手性[2]链烷在两种不同的外部刺激下的精确共构象调节导致了双向圆偏振发光（CPL）开关的构建，如肖赫、王伟、杨海波和合作者在他们的研究文章（e202210542）中报道的那样。这些结果不仅为构建实际用途的多态 CPL 开关提供了一种有吸引力的方法，而且为构建新型手性材料提供了一个有前景的平台。

4.Electroreduction of CO2 to CO is a promising approach for the cyclic use of CO2, but still suffers from impractical current density and durability. A single-atom nanozyme (Ni−N5−C) that achieves industrial-scale performance for CO2-to-CO conversion is reported by Pei-Qin Liao and co-workers in their Research Article (e202210985). Compared with the planar Ni−N4 site, the square-pyramidal Ni−N5 site has significant differences in the dz² and dxz/yz orbital energy levels. Thus the Ni−N5 catalytic site has superior properties in activating CO2 molecules and promoting CO desorption.

将 CO2 电还原为 CO 是循环利用 CO2 的一种有前途的方法，但仍然存在电流密度和耐用性不切实际的问题。 Pei-Qin Liao 及其同事在他们的研究文章 (e202210985) 中报道了一种单原子纳米酶 (Ni−N5−C)，可实现工业规模的 CO2 至 CO 转化性能。与平面Ni−N4位点相比，方形锥体Ni−N5位点的dz²和dxz/yz轨道能级存在显着差异。因此，Ni−N5 催化位点在活化 CO2 分子和促进 CO 解吸方面具有优异的性能。

5.Acenes. Azulene-fused acenes are described in the Research Article (e202209286) by Qing Jiang, Chunyan Chi et al. Their dications display a local aromaticity shift, and one of them exhibits open-shell diradical character.

并苯。 Qing Jiang、Chunyan Chi 等人的研究文章 (e202209286) 中描述了甘菊环稠合并苯。它们的指示显示出局部芳香性变化，其中之一表现出开壳双自由基特征。

6.Big (Bio)Chemical Data Mining Using Chemometric Methods: A Need for Chemists.

使用化学计量方法进行大（生物）化学数据挖掘：对化学家的需求。

7.Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization.

用于电催化二氧化碳还原的金属配合物的分子工程：从内在活性的调整到分子固定化。

8.Regioselective Transition-Metal-Free C(sp2)−H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry.

区域选择性无过渡金属 C(sp2)−H 硼化：合成有机化学中实际和持续关注的主题。

9.Azulene-Fused Acenes.

甘菊稠合苯。

10.Photo-Excited Nickel-Catalyzed Silyl-Radical-Mediated Direct Activation of Carbamoyl Chlorides To Access (Hetero)aryl Carbamides.

光激发镍催化甲硅烷基自由基介导的氨基甲酰氯直接活化以获得（杂）芳基脲。

11.The Linkage of Sulfonimidoyl Fluorides and Unactivated Alkenes via Hydrosulfonimidoylation.

磺酰亚胺酰氟与未活化烯烃通过氢磺酰亚胺酰化的连接。

12.Oxidative Radical NHC Catalysis: Divergent Difunctionalization of Olefins through Intermolecular Hydrogen Atom Transfer.

氧化自由基 NHC 催化：通过分子间氢原子转移实现烯烃的发散双官能化。

13.sp2 to sp3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure.

前所未有的低压下离子晶体中 sp2 到 sp3 的杂化转化。

14.A Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission: Applications in Encryption.

基于交联诱导发射的多刺激响应荧光材料的多功能策略：在加密中的应用。

15.Simultaneously Enhanced Hydrophilicity and Stability of a Metal-Organic Framework via Post-Synthetic Modification for Water Vapor Sorption/Desorption.

通过水蒸气吸附/解吸的合成后改性同时增强金属有机框架的亲水性和稳定性。

16.Conferring BiVO4 Nanorods with Oxygen Vacancies to Realize Enhanced Sonodynamic Cancer Therapy.

赋予 BiVO4 纳米棒氧空位以实现增强的声动力癌症治疗。

17.3D Blockage Mapping for Identifying Familial Point Mutations in Single Amyloid-β Peptides with a Nanopore.

使用纳米孔识别单个淀粉样蛋白-β 肽中的家族点突变的 3D 阻断图谱。

18.Ultrastable Anti-Acid “Shield” in Layered Silver Coordination Polymers.

层状银配位聚合物中的超稳定抗酸“盾”。

19.Conservation of Nickel Ion Single-Active Site Character in a Bottom-Up Constructed π-Conjugated Molecular Network.

自下而上构建的 π 共轭分子网络中镍离子单活性位点特征的守恒。

20.2,4,6-Trimethylpyridine-Derived Vinylene-Linked Covalent Organic Frameworks for Confined Catalytic Esterification.

用于密闭催化酯化的 2,4,6-三甲基吡啶衍生的亚乙烯基连接的共价有机框架。

21.Temperature-Controlled Mechanochemistry for the Nickel-Catalyzed Suzuki–Miyaura-Type Coupling of Aryl Sulfamates via Ball Milling and Twin-Screw Extrusion..

通过球磨和双螺杆挤出进行镍催化芳基氨基磺酸盐的 Suzuki-Miyaura 型偶联的温控机械化学。

22.Polymerisation-Induced Self-Assembly of Graft Copolymers.

聚合诱导的接枝共聚物的自组装。

23.Multistate Circularly Polarized Luminescence Switching through Stimuli-Induced Co-Conformation Regulations of Pyrene-Functionalized Topologically Chiral [2]Catenane.

通过芘官能化拓扑手性 [2] 链烷的刺激诱导共构象调节进行多态圆偏振发光切换。

24.Intranuclear Nanoribbons for Selective Killing of Osteosarcoma Cells.

用于选择性杀死骨肉瘤细胞的核内纳米带。

25.Semi-Solid Superprotonic Supramolecular Polymer Electrolytes Based on Deep Eutectic Solvents and Polyoxometalates.

基于低共熔溶剂和多金属氧酸盐的半固态超质子超分子聚合物电解质。

26.Piezo-Photocatalytic Synergy in BiFeO3@COF Z-Scheme Heterostructures for High-Efficiency Overall Water Splitting.

BiFeO3@COF Z 型异质结构中的压电光催化协同作用可实现高效整体水分解。

27.Unraveling the Complex Chirality Evolution in DNA-Assembled High-Order, Hybrid Chiroplasmonic Superstructures from Multi-Scale Chirality Mechanisms.

从多尺度手性机制中揭示 DNA 组装的高阶混合手性等离子体超结构中复杂的手性演化。

28.The First Chiro-Inositol Organosilicon Ferroelectric Crystal.

第一个手性肌醇有机硅铁电晶体。

29.Bottom-Up Preparation of Twisted Graphene Nanoribbons by Cu-Catalyzed Deoxygenative Coupling.

通过铜催化脱氧偶联自下而上制备扭曲石墨烯纳米带。

30.Anion-Trap Engineering toward Remarkable Crystallographic Reorientation and Efficient Cation Migration of Zn Ion Batteries.

阴离子陷阱工程可实现锌离子电池显着的晶体重新取向和高效的阳离子迁移。

31.Single-Product Faradaic Efficiency for Electrocatalytic of CO2 to CO at Current Density Larger than 1.2 A cm−2 in Neutral Aqueous Solution by a Single-Atom Nanozyme.

单原子纳米酶在中性水溶液中电流密度大于 1.2 A cm−2 时将 CO2 电催化转化为 CO 的单产物法拉第效率。

32.Ti-doped CeO2 Stabilized Single-Atom Rhodium Catalyst for Selective and Stable CO2 Hydrogenation to Ethanol.

Ti 掺杂 CeO2 稳定单原子铑催化剂用于选择性和稳定 CO2 加氢生成乙醇。

33.Unique Double Intramolecular and Intermolecular Exciton Coupling in Ethene-Bridged aza-BODIPY Dimers for High-Efficiency Near-Infrared Photothermal Conversion and Therapy.

乙烯桥氮杂-BODIPY二聚体中独特的双分子内和分子间激子耦合，用于高效近红外光热转换和治疗。

34.In Vivo Olefin Metathesis in Microalgae Upgrades Lipids to Building Blocks for Polymers and Chemicals.

微藻中的体内烯烃复分解将脂质升级为聚合物和化学品的结构单元。

35.Programmable Assembly of Multivalent DNA-Protein Superstructures for Tumor Imaging and Targeted Therapy.

用于肿瘤成像和靶向治疗的多价 DNA-蛋白质超结构的可编程组装。

36.Activity-based Photoacoustic Probes Reveal Elevated Intestinal MGL and FAAH Activity in a Murine Model of Obesity.

基于活动的光声探针揭示肥胖小鼠模型中肠道 MGL 和 FAAH 活动升高。

37.Enantioselective [2+2] Cycloaddition of Allenyl Imide with Mono- or Disubstituted Alkenes.

烯酰亚胺与单取代或双取代烯烃的对映选择性 [2+2] 环加成。

38.The Continuum Between Hexagonal Planar and Trigonal Planar Geometries.

六边形平面和三角形平面几何形状之间的连续体。

39.Dynamic AIE crosslinks in liquid crystal networks: visualizing for actuation-guiding, re-bonding for actuation-altering.

液晶网络中的动态 AIE 交联：可视化用于驱动引导，重新键合用于驱动改变。

40.Origins of p-Doping and Nonradiative Recombination in CsSnI3.

CsSnI3 中 p 掺杂和非辐射复合的起源。

41.A Bifunctional CdS/MoO2/MoS2 Catalyst Enhances Photocatalytic H2 Evolution and Pyruvic Acid Synthesis.

双功能 CdS/MoO2/MoS2 催化剂增强光催化 H2 分解和丙酮酸合成。

42.The Microscopic Origin of Second Harmonic Generation Response: The Spatial Structure of Instantaneous Dipole Moments in Electron Excitation.

二次谐波产生响应的微观起源：电子激发中瞬时偶极矩的空间结构。

43.Synergistic Interfacial Bonding in Reduced Graphene Oxide Fiber Cathodes Containing Polypyrrole@sulfur Nanospheres for Flexible Energy Storage.

含有聚吡咯@硫纳米球的还原氧化石墨烯纤维阴极中的协同界面键合，用于灵活的能量存储。

44.Regioselective Access to Vicinal Diamines by Metal-Free Photosensitized Amidylimination of Alkenes with Oxime Esters.

通过用肟酯对烯烃进行无金属光敏脒基化，区域选择性地获得邻位二胺。

45.Pseudo-heterolepticity in Low-Symmetry Metal-Organic Cages.

低对称金属有机笼中的伪杂配性。

46.Tracking Hepatic Ischemia-Reperfusion Injury in Real Time with a Reversible NIR-IIb Fluorescent Redox Probe.

使用可逆 NIR-IIb 荧光氧化还原探针实时跟踪肝缺血再灌注损伤。

47.Regulating Surface Reaction Kinetics through Ligand Field Effects for Fast and Reversible Aqueous Zinc Batteries.

通过配体场效应调节快速可逆水性锌电池的表面反应动力学。

48.Facile Route to Novel Diazaphosphinine-Based Polycyclic Aromatic Hydrocarbons.

新型二氮杂膦基多环芳烃的简便路线。

49.Generation of Tunable Ultrastrong White-Light Emission by Activation of a Solid Supramolecule through Bromonaphthylpyridinium Polymerization.

通过溴萘基吡啶聚合激活固体超分子产生可调谐超强白光发射。

50.Differential Peptide Multi-Macrocyclizations at the Surface of a Helical Foldamer Template.

螺旋折叠体模板表面的差异肽多大环化。

51.Fast-Scan Cyclic Voltammetry (FSCV) Reveals Behaviorally Evoked Dopamine Release by Sugar Feeding in the Adult Drosophila Mushroom Body.

快速扫描循环伏安法 (FSCV) 揭示了成年果蝇蘑菇体内喂糖引起的行为诱发多巴胺释放。

52.Rapid and Economical Chemoselective Metabolomics Using Boronate Ester Formation on a Monolithic Substrate.

在整体基质上使用硼酸酯形成的快速且经济的化学选择性代谢组学。

53.Bi-polaron Transport and Magnetic Field Induced Pauli Spin Blockade in Redox-Active Molecular Junctions.

双极化子传输和磁场诱导氧化还原活性分子结中的泡利自旋封锁。

54.Dramatically Enhanced Reactivity of Fullerenes and Tetrazine towards the Inverse-Electron-Demand Diels–Alder Reaction inside a Porous Porphyrinic Cage.

富勒烯和四嗪对多孔卟啉笼内逆电子需求狄尔斯-阿尔德反应的反应活性显着增强。

55.Substrate Tumbling in a Chemisorbed Diastereomeric α-Ketoester/1-(1-Naphthyl)ethylamine Complex.

化学吸附的非对映体 α-酮酯/1-(1-萘基)乙胺复合物中的底物翻滚。

56.Silicon Catalyzed C−O Bond Ring Closing Metathesis of Polyethers.

硅催化聚醚的 C−O 键闭环复分解。

57.Dual-Network Structured Hydrogel Electrolytes Engaged Solid-State Rechargeable Zn-Air/Iodide Hybrid Batteries.

双网络结构水凝胶电解质参与固态可充电锌空气/碘化物混合电池。

58.Enantioselective Synthesis of N−N Bisindole Atropisomers.

N−N 双吲哚阻转异构体的对映选择性合成。

59.Photocatalyzed Cascade Reactions of Cyclopropanols and α-Trifluoromethyl-Substituted Olefins for the Synthesis of Fused gem-Difluorooxetanes.

环丙醇和 α-三氟甲基取代烯烃的光催化级联反应用于合成稠合宝石二氟氧杂环丁烷。

60.Optically Controlled Thermochromic Switching for Multi-Input Molecular Logic.

用于多输入分子逻辑的光控热致变色开关。

61.Heteroatoms Induce Localization of the Electric Field and Promote a Wide Potential-Window Selectivity Towards CO in the CO2 Electroreduction.

杂原子诱导电场局域化并促进 CO2 电还原中对 CO 的宽电位窗口选择性。

62.Redox-Regulated Conformational Change of Disulfide-Rich Assembling Peptides.

氧化还原调节的富含二硫键的组装肽的构象变化。

63.Scalable Electrosynthesis of Formamide through C−N Coupling at the Industrially Relevant Current Density of 120 mA cm−2.

在 120 mA cm−2 的工业相关电流密度下通过 CN 耦合可扩展甲酰胺电合成。

64.An anthracene-based molecular crystal with a unique "slipped herringbone" packing motif was developed by crystal engineering through terminal tert-butylation. Appropriate exciton–exciton coupling/electron–phonon coupling originating from the unique crystal packing induces a remarkably strong solid-state emission and efficient charge transport, as reported by Wenping Hu et al. in their Research Article (e202206825).

通过末端叔丁基化的晶体工程开发了一种具有独特“滑动人字形”堆积图案的蒽基分子晶体。正如 Wenping Hu 等人在他们的研究文章（e202206825）中报道的那样，源自独特晶体堆积的适当的激子-激子耦合/电子-声子耦合诱导了非常强的固态发射和有效的电荷传输。

65.A proton conductive hydrogen-bonded organic framework (HOF) was constructed from a C3-symmetric hexatopic carboxylic acid derivative with an 18-crown-6-ether component. Despite the flexibility of the macrocycle, H-bonding modules allow the derivative to yield a hexagonally networked framework with permanent porosity. As reported by Takayoshi Nakamura, Ichiro Hisaki, and co-workers in their Communication (e202211686), the HOF possesses 1D channels with a bottleneck composed of the macrocycles and shows proton conductivity (1.12×10−7 S cm−1) through the Grotthuss mechanism (Ea=0.27 eV) under 98 %RH.

由具有 18-冠-6-醚组分的 C3 对称六位羧酸衍生物构建了质子传导氢键有机骨架 (HOF)。尽管大环具有灵活性，但氢键模块允许衍生物产生具有永久孔隙率的六边形网络框架。正如 Takayoshi Nakamura、Ichiro Hisaki 及其同事在他们的 Communication (e202211686) 中所报道的，HOF 拥有由大环组成的瓶颈的一维通道，并通过 Grotthuss 显示出质子传导性 (1.12×10−7 S cm−1) 98%RH 下的机制（Ea=0.27 eV）。

66.The formation of ultrathin nanowires has thermodynamic advantages at low temperature. However, at low temperatures the monomers for nanocrystal growth are difficult to generate through precursor decomposition. In their Research Article (e202212251), Di Qiu, Yaping Du, and co-workers report an efficient growth process based on adding polyoxometalate clusters to the monomers. Fifteen types of rare earth oxide ultrathin nanowires were synthesized, all exhibiting polymer-like behavior due to the extremely high aspect ratio.

超细纳米线的形成在低温下具有热力学优势。然而，在低温下，用于纳米晶体生长的单体很难通过前体分解产生。在他们的研究文章 (e202212251) 中，Di Qiu、Yaping Du 和同事报告了一种基于向单体添加多金属氧酸盐簇的高效生长过程。合成了十五种稀土氧化物超细纳米线，由于极高的长径比，所有这些纳米线都表现出类似聚合物的行为。

67.A non-enzymatic circuitry activation strategy can realize an orthogonally controlled catalytic DNA (CCD) circuit through multiple molecular recognition events and progressively accelerated signal amplification, as reported by Fuan Wang and co-workers in their Research Article (e202206529). The on-site activated CCD circuitry system has considerable potential for high-precision in vivo imaging of low-abundance microRNA.

Fuan Wang 及其同事在他们的研究文章 (e202206529) 中报道，非酶电路激活策略可以通过多个分子识别事件和逐渐加速的信号放大来实现正交控制的催化 DNA (CCD) 电路。现场激活的 CCD 电路系统在低丰度 microRNA 的高精度体内成像方面具有巨大的潜力。

68.The Control of the Coordination Chemistry for the Genesis of Heterogeneous Catalytically Active Sites in Oxidation Reactions.

氧化反应中异质催化活性位点生成的配位化学控制。

69.Antibiotic-Derived Radiotracers for Positron Emission Tomography: Nuclear or “Unclear” Infection Imaging?.

用于正电子发射断层扫描的抗生素衍生放射性示踪剂：核或“不清楚”的感染成像？

70.Rationally Designing Efficient Electrocatalysts for Direct Seawater Splitting: Challenges, Achievements, and Promises.

合理设计用于直接海水分解的高效电催化剂：挑战、成就和承诺。

71.On-Site Non-enzymatic Orthogonal Activation of a Catalytic DNA Circuit for Self-Reinforced In Vivo MicroRNA Imaging.

用于自我强化体内 MicroRNA 成像的催化 DNA 电路的现场非酶促正交激活。

72.Regulating Crystal Packing by Terminal tert-Butylation for Enhanced Solid-State Emission and Efficacious Charge Transport in an Anthracene-Based Molecular Crystal.

通过末端叔丁基化调节晶体堆积，以增强蒽基分子晶体中的固态发射和有效电荷传输。

73.Affinity Bioorthogonal Chemistry (ABC) Tags for Site-Selective Conjugation, On-Resin Protein-Protein Coupling, and Purification of Protein Conjugates.

用于位点选择性缀合、树脂上蛋白质-蛋白质偶联和蛋白质缀合物纯化的亲和生物正交化学 (ABC) 标签。

74.Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers.

连接体氧化还原介导的半导体铁-半醌配位聚合物的形态和性能控制。

75.Simultaneous Photo-Induced Magnetic and Dielectric Switching in an Iron(II)-Based Spin-Crossover Hofmann-Type Metal-Organic Framework.

铁（II）基自旋交叉霍夫曼型金属有机框架中同时光致磁和介电开关。

76.Dual-Gradient Unified Chromatography: A New Paradigm for Versatility in Simultaneous Multicomponent Analysis.

双梯度统一色谱：同时多组分分析多功能性的新范例。

77.Mechanistic Insights into the Phase Separation Behavior and Pathway-Directed Information Exchange in all-DNA Droplets.

对全 DNA 液滴中相分离行为和通路定向信息交换的机制见解。

78.Uncertainty Quantification of Michaelis–Menten Kinetic Rates and Its Application to the Analysis of CRISPR-Based Diagnostics.

Michaelis-Menten 动力学速率的不确定性量化及其在基于 CRISPR 的诊断分析中的应用。

79.Metal-Free Allylic C−H Amination of Vinylsilanes and Vinylboronates using Silicon or Boron as a Regioselectivity Switch.

使用硅或硼作为区域选择性开关对乙烯基硅烷和乙烯基硼酸酯进行无金属烯丙基 C−H 胺化。

80.Target-Triggered Formation of Artificial Enzymes on Filamentous Phage for Ultrasensitive Direct Detection of Circulating miRNA Biomarkers in Clinical Samples.

丝状噬菌体上人工酶的靶向触发形成，用于临床样本中循环 miRNA 生物标志物的超灵敏直接检测。

81.Salting-Out Aldehyde from the Electrooxidation of Alcohols with 100 % Selectivity.

从醇的电氧化中盐析出醛，选择性为 100%。

82.Cascade Cyclopolymerization of 5-Ethynyl-1,8-Nonadiyne Derivatives to Synthesize Low Band Gap Conjugated Polyacetylenes Containing a Fused Bicyclic Structure.

5-乙炔基-1,8-壬二炔衍生物的级联环聚合合成含有稠合双环结构的低带隙共轭聚乙炔。

83.Decarboxylative Selective Phosphorylation of Aliphatic Acids: A Transition-Metal- and Photocatalyst-Free Avenue to Dialkyl and Trialkyl Phosphine Oxides from White Phosphorus.

脂肪酸的脱羧选择性磷酸化：从白磷制备二烷基和三烷基氧化膦的无过渡金属和光催化剂的途径。

84.Enantiomeric NIR-II Emitting Rare-Earth-Doped Ag2Se Nanoparticles with Differentiated In Vivo Imaging Efficiencies.

对映体 NIR-II 发射稀土掺杂 Ag2Se 纳米颗粒，具有差异化的体内成像效率。

85.An Ion-Enhanced Oncolytic Virus-Like Nanoparticle for Tumor Immunotherapy.

用于肿瘤免疫治疗的离子增强型溶瘤病毒样纳米颗粒。

86.Aggregation-Dependent Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence from Chiral Carbene-CuI-Amide Enantiomers.

手性卡宾-CuI-酰胺对映体的聚集依赖性圆偏振发光和热激活延迟荧光。

87.Regio- and Diastereoselective Formal [2+2] Cycloaddition of Allenes with Amino-Functionalized Alkenes by Rare-Earth-Catalyzed C(sp2)−H Activation.

通过稀土催化的 C(sp2)−H 活化，艾伦烯与氨基官能化烯烃的区域和非对映形式 [2+2] 环加成。

88.Intramolecular Thiol- and Selenol-Assisted Delivery of Hydrogen Sulfide.

分子内硫醇和硒醇辅助的硫化氢传递。

89.Vibration-Assisted Charge Transport through Positively Charged Dimer Junctions.

通过带正电荷的二聚体结进行振动辅助电荷传输。

90.Photoredox-Catalyzed Deoxygenation of Hexafluoroacetone Hydrate Enables Hydroxypolyfluoroalkylation of Alkenes.

六氟丙酮水合物的光氧化还原催化脱氧能够实现烯烃的羟基多氟烷基化。

91.Microbial Fermentation of Polyethylene Terephthalate (PET) Plastic Waste for the Production of Chemicals or Electricity.

用于生产化学品或电力的聚对苯二甲酸乙二醇酯 (PET) 塑料废物的微生物发酵。

92.Asymmetric Construction of an Aryl-Alkene Axis by Palladium-Catalyzed Suzuki–Miyaura Coupling Reaction.

钯催化的 Suzuki-Miyaura 偶联反应不对称构建芳基-烯烃轴。

93.Human Cyclophilin B Nuclease Activity Revealed via Nucleic Acid-Based Electrochemical Sensors.

通过核酸电化学传感器揭示人亲环蛋白 B 核酸酶活性。

94.Diatomic Pd−Cu Metal-Phosphorus Sites for Complete N≡N Bond Formation in Photoelectrochemical Nitrate Reduction.

双原子 Pd−Cu 金属-磷位点在光电化学硝酸盐还原中形成完整的 N=N 键。

95.Discovery of a Unique Structural Motif in Lanthipeptide Synthetases for Substrate Binding and Interdomain Interactions.

发现兰硫肽合成酶中用于底物结合和域间相互作用的独特结构基序。

96.Redesign of Rifamycin Antibiotics to Overcome ADP-Ribosylation-Mediated Resistance.

重新设计利福霉素抗生素以克服 ADP 核糖基化介导的耐药性。

97.Ag22 Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification.

Ag22 纳米团簇通过原位配体酯交换受到 Ag/氰尿酸盐/膦金属大环单层保护，具有热激活延迟荧光。