【标题速读】【JACS】【2022年】【2月】

声明：本专栏主要对生命科学领域的一些期刊文章标题进行翻译，所有内容均由本人手工整理翻译。由于本人专业为生物分析相关，其他领域如果出现翻译错误请谅解。

A protection-group-free, metal-free, and atom-economical chemistry combining hydroxyl-yne and thiol-ene click reactions was developed, by which sequence-defined linear and topological oligo(monothioacetal)s for high-density data storage were efficiently prepared.

开发了一种结合羟基-炔和硫醇-烯点击反应的无保护基团、无金属和原子经济化学，通过这种化学方法有效地制备了用于高密度数据存储的序列定义的线性和拓扑低聚物（单硫缩醛）.

A label-free nanophotonic biosensor was developed to detect pseudotyped SARS-CoV-2 with single-virus resolution by virtue of elastically scattered light. With DNA aptamers as the biorecognition element, the nanosensor can effectively capture and count individual active viruses in preference to deactivated viruses, providing a novel and versatile strategy for low-cost virus detection.

开发了一种无标记的纳米光子生物传感器，以利用弹性散射光以单病毒分辨率检测假型 SARS-CoV-2。 以 DNA 适体作为生物识别元件，纳米传感器可以有效地捕获和计数单个活性病毒，而不是灭活病毒，为低成本病毒检测提供了一种新颖、通用的策略。

Monovalent and multivalent cations in the electrolyte influence electrocatalytic water reduction and CO2 reduction, primarily by cation accumulation in the double layer.

电解质中的单价和多价阳离子主要通过双层中的阳离子积累影响电催化水还原和 CO2 还原。

Asymmetric porous hollow carbon nanoparticles are prepared via a kinetics-controlled interfacially super-assembly strategy through the precise regulation of polymerization and assembly rates of two kinds of precursors. The unique structure and unexpected excellent photothermal performance endow these nanoparticles with the ability to serve as smart NIR light-driven nanovehicles.

通过精确调节两种前体的聚合和组装速率，通过动力学控制的界面超组装策略制备不对称多孔中空碳纳米粒子。 独特的结构和意想不到的优异光热性能赋予这些纳米粒子作为智能近红外光驱动纳米载体的能力。

Novel single-fluorophore-based white-light-emitting polymers, which exhibit excellent color reproducibility via an excited-state intramolecular proton-transfer (ESIPT) process, have been developed through a powerful direct C–H amidation polymerization. Fine tunability of hydrogen bond strength enables white-light generation by controlling relative emission intensities between blue and yellow lights.

通过强大的直接 C-H 酰胺化聚合开发了新型基于单荧光团的白光发光聚合物，其通过激发态分子内质子转移 (ESIPT) 过程表现出出色的颜色再现性。 氢键强度的微调性可以通过控制蓝光和黄光之间的相对发射强度来产生白光。

Multiple chemically equivalent reactive sites are selectively and precisely activated by scanning probe microscopy tip-controlled plasmonic resonance at the submolecular scale.

通过扫描探针显微镜尖端控制的亚分子尺度等离子体共振，选择性且精确地激活多个化学等效的反应位点。

Expanding the dynamic chemistry toolbox is key to future smart materials. An emerging class of poly(disulfide)s featuring reversible disulfide-mediated ring-opening polymerization offers many opportunities in designing materials with unique dynamic functions, such as self-healing ability, responsiveness, adaptability, and chemical recyclability.

扩展动态化学工具箱是未来智能材料的关键。 一类新兴的聚（二硫化物）具有可逆二硫化物介导的开环聚合，为设计具有独特动态功能的材料提供了许多机会，例如自愈能力、响应能力、适应性和化学可回收性。

The image illustrates electrochemical carbon dioxide capture and release with a redox-active amine. Carbon dioxide was captured from the air by reduction potential and released as a pure gas by oxidation potential.

该图说明了氧化还原活性胺的电化学二氧化碳捕获和释放。 二氧化碳通过还原电位从空气中捕获，并通过氧化电位作为纯气体释放。

Single vacancies in defective graphene can trap atomic Pt to form a specific Pt–C3 configuration, which improves electron capture and lowers the Gibbs free energy difference (ΔG). The unique configuration promotes the reduction of adsorbed H2O and accelerates the H2 desorption, thus exhibiting extraordinary HER activity.

有缺陷的石墨烯中的单个空位可以捕获原子 Pt 以形成特定的 Pt-C3 构型，从而改善电子捕获并降低吉布斯自由能差 (ΔG)。 独特的构型促进了吸附H2O的还原并加速了H2的解吸，从而表现出非凡的HER活性。

Blue LED irradiation induced a copper-catalyzed highly enantioselective umpolung allylic acylation reaction with acylsilanes as acyl anion equivalents. Copper-to-acyl metal-to-ligand charge transfer (MLCT) photoexcitation of an acylcopper complex with a chiral NHC ligand generates a charge-separated triplet state as a highly reactive ketyl radical-type intermediate.

蓝色 LED 照射诱导了铜催化的高对映选择性 umpolung 烯丙基酰化反应，酰基硅烷作为酰基阴离子等价物。 具有手性 NHC 配体的酰基铜络合物的铜-酰基金属-配体电荷转移 (MLCT) 光激发产生电荷分离的三重态作为高反应性的羰基自由基型中间体。

Self-assembled metal–phenolic networks (MPNs) can be formed on the surface of microbes. These coatings were found to protect next-generation microbial biotherapeutics from harsh processing conditions and oxygen exposure. Cover image and design: Felice Frankel

自组装金属酚网络 (MPNs) 可以在微生物表面形成。 这些涂层被发现可以保护下一代微生物生物治疗药物免受恶劣的加工条件和氧气暴露。 封面图片和设计：Felice Frankel

N2 was efficiently split on a MoII complex, induced by visible light irradiation, forming the MoV terminal nitride. After the N–P coupling and hydrolysis, the N atom from N2 was transferred into iminophosphorane ultimately.

在可见光照射下，N2 在 MoII 络合物上有效分裂，形成 MoV 末端氮化物。 N-P偶联和水解后，N2中的N原子最终被转移到亚氨基正膦中。

A new class of thiol-containing polymers was synthesized. Dithiocatechol-pendant polymers were synthesized from their precursor polymers using lithium and naphthalene. This work paves the way toward the exploitation of dithiocatechol-containing polymers for engineering functional materials.

合成了一类新的含硫醇聚合物。 二硫代儿茶酚悬垂聚合物是使用锂和萘从其前体聚合物合成的。 这项工作为开发含二硫代儿茶酚的聚合物用于工程功能材料铺平了道路。

Copper K-edge X-ray absorption and valence-to-core X-ray emission spectroscopy of organocopper complexes in +1, +2, and +3 formal oxidation states reveals identifiable trends consistent with increased effective nuclear charge (deeper binding energy) for higher oxidation states.

+1、+2 和 +3 形式氧化态的有机铜配合物的铜 K 边 X 射线吸收和价核 X 射线发射光谱揭示了与有效核电荷增加（更深的结合能）一致的可识别趋势更高的氧化态。

Unprecedented switch between thermally activated fluorescence (TAF) and long persistent luminescence (LPL) is achieved in a unique ESIPT-attributed coordination polymer, manifesting the relevance and balance among reverse intersystem crossing (RISC), intersystem crossing (ISC), and internal conversion (IC).

在一种独特的 ESIPT 配位聚合物中实现了热激活荧光 (TAF) 和长余辉发光 (LPL) 之间前所未有的转换，体现了反向系统间交叉 (RISC)、系统间交叉 (ISC) 和内部转换（IC）之间的相关性和平衡。

In this work, a straightforward synthetic strategy to design a single-component organic long persistent luminescent (OLPL) system with detectable afterglow for at least 12 min under ambient conditions is presented. This work demonstrates a new design principle that can simplify the design and production of new OLPL materials.

在这项工作中，提出了一种直接的合成策略，用于设计单组分有机长余辉发光 (OLPL) 系统，该系统在环境条件下可检测余辉至少 12 分钟。 这项工作展示了一种新的设计原则，可以简化新 OLPL 材料的设计和生产。

A critical stage in the SARS-CoV-2 infection is the fusion of host and viral membranes induced by the spike protein. Calcium drives the N-terminal of the spike's fusion domain to fully cross the host membrane, while another region of the domain bridges viral and host membranes, thereby facilitating fusion.

SARS-CoV-2 感染的一个关键阶段是由刺突蛋白诱导的宿主和病毒膜的融合。 钙驱动刺突融合域的 N 端完全穿过宿主膜，而该域的另一个区域桥接病毒和宿主膜，从而促进融合。

A porous ionic crystal based on a Keggin-type polyoxometalate and a Cr complex was utilized as an electrocatalyst for oxygen evolution reaction under nonbasic conditions, taking advantage of its designability and well-defined structure. The synergistic catalysis originates from the increased electron density of the polyoxometalate via charge transfer from the Cr complex.

基于 Keggin 型多金属氧酸盐和 Cr 络合物的多孔离子晶体被用作非碱性条件下析氧反应的电催化剂，利用其可设计性和明确的结构。 协同催化源于多金属氧酸盐通过 Cr 络合物的电荷转移增加的电子密度。

Metallosupramolecular cages assembled from diazocine photoswitches are converted between a yellow-colored thermodynamically stable cis-form and its red trans-isomer by irradiation. Only the trans-cage can bind a guest. The host–guest complex is a transient species that falls apart via thermal backswitching unless its population is sustained by continuous irradiation.

由重氮辛光开关组装而成的金属超分子笼通过辐照在黄色热力学稳定的顺式异构体与其红色反式异构体之间进行转换。 只有传送笼才能绑定客体。 主客体复合体是一种瞬态物种，除非其种群通过连续辐射维持，否则会通过热反向切换而分裂。

The combination of single-molecule electrical detection and kinetic isotope effect provides a powerful tool to determine the rate-determining step and accurately quantify the transition state structure in a reaction, therefore establishing a novel approach for controlling the transition state by an electric field.

单分子电检测和动力学同位素效应的结合为确定反应中的决速步骤和准确量化反应中的过渡态结构提供了有力的工具，从而建立了一种通过电场控制过渡态的新方法。

1.Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry.

钴-氧立方体簇在氧化化学中的机制方面。

2.Aptamers Entirely Built from Therapeutic Nucleoside Analogues for Targeted Cancer Therapy.

完全由治疗性核苷类似物构建的适配体用于癌症靶向治疗。

3.Label-Free Digital Detection of Intact Virions by Enhanced Scattering Microscopy.

增强型散射显微镜下的无标签数字检测病毒的方法.

4.Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes.

阳离子对高价锰亚氨基化合物净氢原子键解离自由能的影响.

5.Fluorescent Colloidal Ferroelectric Nanocrystals.

荧光胶体铁电纳米晶体.

6.Efficient Pulsed Dynamic Nuclear Polarization with the X-Inverse-X Sequence.

X-Inverse-X 序列的高效脉冲动态核偏振.

7.Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds.

通过白磷的电化学活化方便地合成二氰化磷阴离子： 通往有机磷化合物的道路。

8.Room-Temperature Fast H– Conduction in Oxygen-Substituted Lanthanum Hydride.

氧取代的镧系氢化物中的室温快速氢传导。

9.Total Syntheses of Scabrolide A and Nominal Scabrolide B.

赤藓内酯A和赤藓内酯B的全合成。

10.Organometallic Fe2(μ-SH)2(CO)4(CN)2 Cluster Allows the Biosynthesis of the [FeFe]-Hydrogenase with Only the HydF Maturase.

有机金属Fe2(μ-SH)2(CO)4(CN)2簇允许只用HydF母体酶进行[FeFe]-氢化酶的生物合成。

11.Entanglement of Square Nets in Covalent Organic Frameworks.

共价有机框架中方网的纠缠。

12.Engineering a Hyperstable Yersinia pestis Outer Membrane Protein Ail Using Thermodynamic Design.

使用热力学设计来设计超稳定的耶尔森氏菌外膜蛋白Ail。

13.Electrochemical Strategy for the Simultaneous Production of Cyclohexanone and Benzoquinone by the Reaction of Phenol and Water.

酚与水反应同时生产环己酮和苯醌的电化学策略。

14.Color-Changing Fluorescent Barcode Based on Strand Displacement Reaction Enables Simple Multiplexed Labeling.

基于链式置换反应的变色荧光条形码实现了简单的多重标记。

15.Ultrasmall Magneto-chiral Cobalt Hydroxide Nanoparticles Enable Dynamic Detection of Reactive Oxygen Species in Vivo.

超小磁手性氢氧化钴纳米粒子可在体内动态检测活性氧物质。

16.The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO2 Reduction on Gold Electrodes.

阳离子酸度在金电极上氢气进化和二氧化碳还原竞争中的作用。

17.Kinetic Modulation of Amyloid-β (1–42) Aggregation and Toxicity by Structure-Based Rational Design.

基于结构的合理设计对淀粉样β（1-42）聚集和毒性的动力学调控。

18.Colloidal Platinum–Copper Nanocrystal Alloy Catalysts Surpass Platinum in Low-Temperature Propene Combustion.

胶体铂-铜纳米晶合金催化剂在低温丙烯燃烧中超过了铂。

19.Biosynthesis of Tasikamides via Pathway Coupling and Diazonium-Mediated Hydrazone Formation.

Tasikamides的生物合成通过路径耦合和偶氮化合物介导的腙形成。

20.Kinetics-Controlled Super-Assembly of Asymmetric Porous and Hollow Carbon Nanoparticles as Light-Sensitive Smart Nanovehicles.

不对称多孔和空心碳纳米粒子的动力学控制的超级组装作为光敏智能纳米粒子。

21.Catalytic Activation of Bioorthogonal Chemistry with Light (CABL) Enables Rapid, Spatiotemporally Controlled Labeling and No-Wash, Subcellular 3D-Patterning in Live Cells Using Long Wavelength Light.

用光催化激活生物正交化学(CABL)实现了快速、时空可控的标记，以及使用长波长的光在活细胞中进行免洗的亚细胞三维图案制作。

22.Chiral Generation of Hot Carriers for Polarization-Sensitive Plasmonic Photocatalysis.

用于偏振敏感的等离子体光催化的热载体的手性生成。

23.Combining Hydroxyl-Yne and Thiol-Ene Click Reactions to Facilely Access Sequence-Defined Macromolecules for High-Density Data Storage.

结合羟基-炔和硫醇-炔点击反应，方便地访问高密度数据存储的序列定义的大分子。

24.Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation.

基于金属有机框架的氢键纳米捕集器用于高效乙炔储存和分离.

25.Secondary Amine Pendant β-Peptide Polymers Displaying Potent Antibacterial Activity and Promising Therapeutic Potential in Treating MRSA-Induced Wound Infections and Keratitis.

二级胺挂件β-肽聚合物在治疗MRSA诱导的伤口感染和角膜炎中显示出强大的抗菌活性和良好的治疗潜力。

26.Chemical Polishing of Perovskite Surface Enhances Photovoltaic Performances.

过氧化物表面的化学抛光增强了光伏性能。

27.Multiple Proton-Coupled Electron Transfers at a Tricopper Cluster: Modeling the Reductive Regeneration Process in Multicopper Oxidases.

三铜簇上的多质子耦合电子转移： 多铜氧化酶中还原再生过程的建模。

28.Direct Measurement of Interhelical DNA Repulsion and Attraction by Quantitative Cross-Linking.

通过定量交联直接测量螺旋间DNA的排斥力和吸引力。

29.Pickering Interfacial Catalysis for Aerobic Alcohol Oxidation in Oil Foams.

Pickering界面催化作用在油泡沫中的有氧酒精氧化。

30.Short-Range Backbone Dihedral Rotations Modulate Internal Friction in Intrinsically Disordered Proteins.

短程骨架二面体旋转调节本征无序蛋白质的内部摩擦力

31.Energy Counterbalance to Harness Photoinduced Structural Planarization of Dibenzo[b,f]azepines toward Thermal Reversibility.

利用光诱导的二苯并[b,f]氮杂卓结构平面化的能量平衡，实现热可逆性。

32.Synthesis of Silacyclic Dipeptides: Peptide Elongation at Both N- and C-Termini of Dipeptide.

硅环类二肽的合成： 在二肽的N端和C端都有肽的延伸。

33.Evidence for Entropically Controlled Interfacial Hydration in Mesoporous Organosilicas.

中多孔有机硅中熵控界面水化的证据。

34.Powerful Direct C–H Amidation Polymerization Affords Single-Fluorophore-Based White-Light-Emitting Polysulfonamides by Fine-Tuning Hydrogen Bonds.

通过微调氢键，强大的直接C-H氨化聚合产生了基于单氟的白光发光聚磺酰胺。

35.Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex.

碱金属离子决定了铁(II)亚氨基化合物的结构和反应性。

36.Opening Diffusion Pathways through Site Disorder: The Interplay of Local Structure and Ion Dynamics in the Solid Electrolyte Li6+xP1–xGexS5I as Probed by Neutron Diffraction and NMR.

通过位点紊乱打开扩散途径： 中子衍射和核磁共振探测的固体电解质Li6+xP1-xGexS5I的局部结构和离子动力学的相互作用。

37.Both Charge-Regulation and Charge-Patch Distribution Can Drive Adsorption on the Wrong Side of the Isoelectric Point.

电荷调控和电荷斑点分布都能促使吸附在等电点的错误一侧。

38.Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal–Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold.

基于独特的[2.2]Paracyclophane支架的锆金属有机框架的网状结构所促成的水吸附进化。

39.The Role of Charge Density Coupled DNA Bending in Transcription Factor Sequence Binding Specificity: A Generic Mechanism for Indirect Readout.

电荷密度耦合的DNA弯曲在转录因子序列结合特异性中的作用： 一个间接读出的通用机制。

40.A Tunable Structural Family with Ultralow Thermal Conductivity: Copper-Deficient Cu1–x□xPb1–xBi1+xS3.

具有超低导热性的可调结构系列： 缺铜的Cu1-x□xPb1-xBi1+xS3.

41.Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction.

通过共价连接封闭和高度分散共价有机框架中的单个多氧金属簇，用于二氧化碳光还原。

42.Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand.

通过铁催化烯烃氧胺化获得β-内酰胺的π-受体酞菁配体的作用。

43.Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C–H Functionalization Reactions.

复杂反应位点拓扑结构与C-H功能化反应中催化剂性能相关的机制指导工作流程。

44.Radical Carbonyl Umpolung Arylation via Dual Nickel Catalysis.

通过双镍催化的自由基羰基乌姆波隆芳构化。

45.Atomically Resolved Electrically Active Intragrain Interfaces in Perovskite Semiconductors.

过氧化物半导体中原子分辨的电活性粒内界面.

46.Highly Dispersed Platinum Chlorine Atoms Anchored on Gold Quantum Dots for a Highly Efficient Electrocatalyst.

锚定在金量子点上的高度分散的铂氯原子的高效电催化剂。

47.Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites.

光诱导的近端和远端 Arenes 的选择性烯烃化。

48.Backbone Hydrocarbon-Constrained Nucleic Acids Modulate Hybridization Kinetics for RNA.

主链烃限制性核酸调节 RNA 的杂交动力学。

49.A Unified and Desymmetric Approach to Chiral Tertiary Alkyl Halides.

手性叔烷基卤化物的统一和不对称方法。

50.General Synthesis of N-Trifluoromethyl Compounds with N-Trifluoromethyl Hydroxylamine Reagents.

N-三氟甲基化合物与N-三氟甲基羟胺试剂的一般合成。

51.Dispersion and Steric Effects on Enantio-/Diastereoselectivities in Synergistic Dual Transition-Metal Catalysis.

协同双过渡金属催化中对映体/非对映体选择性的分散和立体效应。

52.Merging Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Suzuki–Miyaura-Type Cross-Coupling of Alkyl Iodides and Organoborons.

卤素原子转移（XAT）和铜催化合并用于烷基碘化物和有机硼的模块化铃木-米亚拉型交叉耦合。

53.Modulating the Reactivity of Liquid Ga Nanoparticle Inks by Modifying Their Surface Chemistry.

通过改变表面化学来调节液态Ga纳米粒子油墨的反应性。

54.Pathways for Electron Transfer at MgO–Water Interfaces from Ab Initio Molecular Dynamics.

来自Ab Initio分子动力学的氧化镁-水界面电子转移的途径。

55.Progressive Local Accumulation of Self-Assembled Nanoreactors in a Hydrogel Matrix through Repetitive Injections of ATP.

通过重复注入ATP在水凝胶基质中逐步实现自组装纳米反应器的局部积累。

56.Correction to “Chemically Stable Carbazole-Based Imine Covalent Organic Frameworks with Acidochromic Response for Humidity Control Applications”.

对 "化学上稳定的基于咔唑的亚胺共价有机框架的湿度控制应用 "的更正。

57.Disulfide-Mediated Reversible Polymerization toward Intrinsically Dynamic Smart Materials.

二硫化物介导的可逆聚合走向内在动态智能材料。

58.Carbon Monoxide in Main-Group Chemistry.

主族化学中的一氧化碳。

59.Controlling Localized Plasmons via an Atomistic Approach: Attainment of Site-Selective Activation inside a Single Molecule.

通过原子学方法控制局部质子： 单一分子内实现位点选择的激活。

60.Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape.

具有独特形状的对映纯手性双NHC稳定的边缘共享Au10纳米团簇的合成和特征。

61.Electrochemical Ring-Opening Dicarboxylation of Strained Carbon–Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters.

紧张的碳-碳单键与二氧化碳的电化学开环脱羧反应： 二元酸的简易合成及衍生为聚酯的方法.

62.In Vitro Selection of Foldamer-Like Macrocyclic Peptides Containing 2-Aminobenzoic Acid and 3-Aminothiophene-2-Carboxylic Acid.

体外选择含有2-氨基苯甲酸和3-氨基噻吩-2-羧酸的类似折叠器的大环肽。

63.Solid-State Pathway Control via Reaction-Directing Heteroatoms: Ordered Pyridazine Nanothreads through Selective Cycloaddition.

通过反应导向杂原子的固态途径控制： 通过选择性环加成的有序哒嗪纳米线。

64.Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane.

用固体溶液稳定Cu2+离子以促进CO2电还原成甲烷.

65.Precise Control of Radial Catenane Synthesis via Clipping and Pumping.

通过剪辑和泵送精确控制径向卡特兰的合成。

66.High-Throughput Activity Profiling of RNA-Cleaving DNA Catalysts by Deoxyribozyme Sequencing (DZ-seq).

通过脱氧核糖核酸酶测序（DZ-seq）对RNA切割DNA催化剂进行高通量活性分析。

67.π-Extended Doublet Open-Shell Graphene Fragments Exhibiting One-Dimensional Chain Stacking.

显示一维链堆积的π-扩展双壳石墨烯片段。

68.Divergent Reactivity of α,α-Disubstituted Alkenyl Hydrazones: Bench Stable Cyclopropylcarbinyl Equivalents.

α,α-二取代的烯基腙的不同反应性： 稳定的环丙基羰基等价物。

69.An N-Fluorinated Imide for Practical Catalytic Imidations.

一种用于实际催化酰亚胺的N-氟化酰亚胺。

70.A Fluorogenic ONOO–-Triggered Carbon Monoxide Donor for Mitigating Brain Ischemic Damage.

一种用于减轻脑缺血损伤的氟化ONOO-触发的一氧化碳供体。

71.Native Ambient Mass Spectrometry Imaging of Ligand-Bound and Metal-Bound Proteins in Rat Brain.

大鼠脑中配体结合和金属结合的蛋白质的本地环境质谱成像。

72.Revealing the Intrinsic Atomic Structure and Chemistry of Amorphous LiO2-Containing Products in Li–O2 Batteries Using Cryogenic Electron Microscopy.

利用低温电子显微镜揭示锂-O2电池中含无定形二氧化锂产品的内在原子结构和化学成分。

73.Emulating Membrane Protein Environments─How Much Lipid Is Required for a Native Structure: Influenza S31N M2.

模仿膜蛋白环境--本地结构需要多少脂质： 流感S31N M2.

74.Programmable Macroscopic Self-Assembly of DNA-Decorated Hydrogels.

可编程宏观自组装的DNA装饰水凝胶.

75.Asymmetric Twisting of C-Centered Octahedral Gold(I) Clusters by Chiral N-Heterocyclic Carbene Ligation.

手性N-杂环碳化物连接的C-中心八面体金（I）簇的不对称扭曲。

76.Electrochemical Carbon Dioxide Capture and Release with a Redox-Active Amine.

使用氧化还原活性胺的电化学二氧化碳捕获和释放。

77.Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis.

单一碳空位捕获原子铂的氢气进化催化作用。

78.Coordination-Assisted Precise Construction of Metal Oxide Nanofilms for High-Performance Solid-State Batteries.

配位法辅助的高性能固态电池金属氧化物纳米薄膜的精确构建.

79.Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal–Organic Framework.

通过调节多孔半导电金属有机框架中的激子行为提升光电性能.

80.Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction.

通过第二壳阴离子调控改变单原子位点的配体场，促进了氧气还原反应。

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